CN106309147A - Sunscreen cosmetic composition with high safeness and preparation method thereof - Google Patents
Sunscreen cosmetic composition with high safeness and preparation method thereof Download PDFInfo
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- CN106309147A CN106309147A CN201610886314.5A CN201610886314A CN106309147A CN 106309147 A CN106309147 A CN 106309147A CN 201610886314 A CN201610886314 A CN 201610886314A CN 106309147 A CN106309147 A CN 106309147A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/066—Multiple emulsions, e.g. water-in-oil-in-water
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/70—Biological properties of the composition as a whole
- A61K2800/72—Hypo-allergenic
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Abstract
The invention discloses a sunscreen cosmetic composition with high safeness and a preparation method thereof. The structure of the sunscreen cosmetic composition is an oil in water in oil structure, wherein inner phase oil comprises 12.0-30.0% of UV absorbant, 2.5-10% of grease and 0.1-2% of emulsifier 1; external phase oil comprises 10-55% of grease, 0.1-5.0% of oil soluble anti-allergy and anti-oxidation additive and 1.0-5.0% of emulsifier 2; intermediate water phase comprises 1.0-20.0% of humectant, 0.5-8% of emulsifier 3 and balance of water; the hydrophile-lipophile balance number of the emulsifier 1 is below 5, the hydrophile-lipophile balance number of the emulsifier 2 is 3-8, and the hydrophile-lipophile balance number of the emulsifier 3 is 10-15; and the weight ratio of the sum of the emulsifier 1 and emulsifier 3 to the emulsifier 2 is greater than 1.5. The sunscreen cosmetic composition prepared by the invention can effectively reduce irritation and has a higher sunscreen effect.
Description
Technical field
The invention belongs to household chemicals field, be specifically related to a kind of cosmetic composition with high security and preparation side
Method.
Background technology
Along with global pollution is day by day serious, depletion of the ozone layer, the sunlight middle-ultraviolet lamp amount arriving ground increases.In ultraviolet
UVA and UVB ultraviolet excessive radiation can cause human body skin photoaging sign occur, such as: skin acute dermatitis (erythema) and burn
Wound, Skin pigmentation, too early wrinkle, senile plaque occur, even induce skin carcinoma.Consumer it is becoming increasingly recognized that ultraviolet
The line adverse effect to skin, sun care preparations sustainable growth on market in recent years, Asia is with " in vain " for beautiful viewpoint more
It it is the favor causing consumer to sun care preparations.Sun care preparations in the market, its sun-proof principle is: add in the product
Adding chemically or physically sunscreen, chemical sun can absorb UVA and UVB ultraviolet in sunlight, and the energy conversion that will preserve
Become the radiation of harmless relatively long wave.Therefore chemical sun has the activity of photochemistry or physics, naturally also may show
Phototoxicity and optical sensibilization.The probability of the chemical sun initiation contact sensitization added in sun care preparations is higher.And thing
Reason sunscreen is also referred to as physical barriers agent, is by reflection, scatters ultraviolet, makes the ultraviolet dosage reaching on skin reduce
Reach sun-proof result.What utilization rate was the highest on the market is: titanium dioxide, zinc oxide.Titanium dioxide, zinc oxide to reach higher
The skinfeel that sun-proof result is become reconciled, its particle size have to be lower than (or partially below) 100 nanometers, but at present nano material for
Human safety is the most fully confirmed.Nano material is still held the prudent attitude by various countries for cosmetics.Titanium dioxide simultaneously
Titanium material also has photocatalysis, and in cosmetics, titanium dioxide all must process through excellent surface and could use, without place
Manage or deal with improperly and can promote photosensitivity reaction, increase the sensitization risk of product.Therefore keep higher ultraviolet to prevent at sun care preparations
Protect effect, but reduce the sensitization risk of product as far as possible, accomplish safely and effectively to remain one technical barrier.
Summary of the invention
It is contemplated that overcome the defect of prior art, it is provided that a kind of cosmetic composition with high security,
Described cosmetic composition can effectively reduce zest, has again higher sun-proof function.
Another object of the present invention is to provide the preparation method of described cosmetic composition.
The foregoing invention purpose of the present invention is achieved by the following technical programs:
The invention discloses a kind of multiple emulsification system cosmetic composition, comprise following component the most count by weight percentage:
Internal phase oil: UV absorbent 12.0～30.0%；
Oils and fats 2.5～10%；
Emulsifying agent 1 0.1～2%；
Foreign minister's oil: oils and fats 10～55%；
Oil-soluble antiallergic antioxidant 0.1～5.0%；
Emulsifying agent 2 1.0～5.0%；
Intermediate water phase: wetting agent 1.0～20.0%；
Polymer substance 1.0～5.0%；
Emulsifying agent 3 0.5～8%；
Surplus is water.
Wherein, the hydrophilic-hydrophobic balance value (HLB) of described emulsifying agent 1 is less than 5, the hydrophilic-hydrophobic balance of described emulsifying agent 2
Value is 3～8, and the hydrophilic-hydrophobic balance value of described emulsifying agent 3 is 10～15；
Described emulsifying agent 1 is more than 1.5 with the summation of emulsifying agent 3 with the weight ratio of emulsifying agent 2.
Multiple emulsification system cosmetic composition prepared by the present invention is Water-In-Oil bag oil (O/W/O) structure, its effect
Principle is: will chemically or physically the maximization of UV absorbent control in internal phase oil；Containing a certain amount of high in the water of intermediate water phase
Molecular compound, adds the stability of compositions, and isolates chemically or physically UV absorbent and the skin of internal phase to a certain extent
The directly contact of skin, reduces the chemically or physically UV absorbent stimulation to skin；Foreign minister's oil resists containing a certain amount of oil-soluble
Quick, antioxidant product, easily infiltrates into keratodermatitis, protects skin.When by described multiple emulsification system cosmetics group
When compound embrocates skin surface, antiallergic, antioxidant in foreign minister's oil are preferentially covered on skin, due to the oleophylic of skin
Characteristic, oil soluble material easily infiltrates into keratodermatitis, after the antiallergic in oil phase, antioxidant preferentially enter skin, for
Skin provides protective effect；The high score material of intermediate water phase has become thin film, hinders internal phase material and direct skin contact,
Reduce the chemically or physically sunscreen zest to skin；Along with the volatilization on skin of the intermediate layer moisture, internal phase emulsified state
Destroying, the chemically or physically sunscreen of internal phase oil discharges, and plays anti-sunlight function.Inventor by experiment it has furthermore been found that
By selecting suitable emulsifying agent, and control the breast of the emulsifying agent summation with intermediate water phase of the emulsifying agent in internal phase oil and foreign minister's oil
When the ratio of the consumption of agent is more than 1.5, the beneficially preparation of cosmetic composition, and prepared cosmetic composition emulsifying
Structure is the most stable, can the most effectively reduce zest, have again higher sun-proof function.
Preferably, described UV absorbent is ethylhexyl methoxy cinnamate, octocrilene, ethylhexyl salicylate, recklessly
Not willow ester, Dimethicodiethylbenzalmalonate, butylmethoxydibenzoylmethane, Uvinul A Plus, 4-first
Base Benzylidene camphor, Uvinul T 150, Phenylbenzimidazolesulfonic acid, double ethyl hexyl oxy phenol anisyl triazines, two
Titanium oxide, at least two kinds in zinc oxide.
Preferably, described oils and fats is Cyclomethicone, ring five polydimethylsiloxane, polydimethylsiloxane,
Alkyl dimethicone, C12-15 alcohol benzoate, different n-nonanoic acid different nonyl fat, Parleam, hydrogenate poly-certain herbaceous plants with big flowers alkene, angle
Shark alkane, isoparaffin, dicaprylyl carbonate, propylene glycol carbonate, ethylhexyl palmitate, caprylic/capric triglyceride, olive oil
Fat, Jojoba oils and fats, at least one in Butyrospermum Parkii oils and fats.
Preferably, described emulsifying agent 1 is sorbitan stearate, glyceryl stearate, alkyl stereth, methyl Portugal
Polyglycoside polyglycol ether stearate, soybean lecithin, at least one in alkyl androstanediol.
Preferably, described emulsifying agent 2 is sorbitan stearate, glyceryl stearate, ceteareth, methyl Portugal
Polyglycoside sesquialter stearate, polyglycol ether dimethyl siloxane, polydimethylsiloxane polyether polymer, alkyl, polyether gathers
Dimethyl siloxane, at least one in polyglycereol poly dimethyl silicone hydroxyl ethyl polydimethylsiloxane.
Preferably, described emulsifying agent 3 is polyglycol ether glyceryl stearate for emulsifying agent, alkyl stereth, alkane
Base alcohol ether phosphate potassium, alkyl phosphate potassium, methyl glucoside polyglycol ether stearate, in alkyl androstanediol at least
A kind of.
Preferably, described wetting agent is glycerol, propylene glycol, butanediol, pentanediol, hexanediol, ethohexadiol, decanediol, hydroxyl
Ethyl carbamide, glycine betaine, pyrrolidone sodium carboxylate, hyaluronic acid and salt, vegetable polysaccharides apoplexy due to endogenous wind at least one.
Preferably, described polymer substance is xanthan gum, polyacrylate or salt, polyacrylic acid/C10-30 alkyl
Acid esters cross linked polymer, sodium acrylate/dimethyl acrylamide sodium acyl taurine, ammonium acryloyldime-thyltaurate/VP copolymer, second
Vinyl pyrrolidone/icosa alkene, VP/ eicosylene, VP/ vaccenic acid, vinyl pyrrolidone/icosa alkene, hydroxypropyl methyl
Cellulose, at least one in Cellulose ethyl hydroxypropyl ether.
Preferably, described oil-soluble antiallergic, antioxidant are bisabolol, ascorbic acid, retinol, retinol palm fibre
Palmitic acid acid esters, tocopherol, tocopherol acetas, ceramide, ubiquinone, algae extract, Fructus Canrii Albi extract, Aloe extract, sweet
Grass extract, sea salt at least one.
Further, described multiple emulsification system cosmetic composition is possibly together with one or more in following components:
The nourishing additive agent of percentage by weight 0.1 ~ 10%；
The coloring agent of percentage by weight 0.1 ~ 5%；
The percentage by weight preservative less than 1.5%；
The percentage by weight essence less than 1.0%.Coloring agent can be used for the colour of skin and modifies, such as ferrum oxide.It is anti-that essence can be used for regulation
Shine the abnormal smells from the patient of compositions, as lifted the fragrance of a flower, the Radix Aucklandiae, fruital.
The preparation method of described multiple emulsification system cosmetic composition, comprises the steps:
S1, be respectively configured by formula ratio internal phase oil, intermediate water phase, foreign minister oil；
S2, by internal phase oil with intermediate water phase mixing and emulsifying be oil-in-water type (O/W) emulsion system；
S3, emulsion oil-in-water system is added in foreign minister's oil and be emulsified into Water-In-Oil oil-in (O/W/O) multiple emulsion system,
To multiple emulsification system cosmetic composition.
Compared with prior art, there is advantages that the present invention is prepared for a kind of new multiple emulsified body
Being cosmetic composition, its structure is O/W/O type, when described multiple emulsification system cosmetic composition is embrocated skin surface
Time, antiallergic, antioxidant in foreign minister's oil are preferentially covered on skin, due to the oil-wet behavior of skin, oil soluble material
Easily infiltrate into keratodermatitis, after the antiallergic in oil phase, antioxidant preferentially enter skin, provide protection for skin and make
With；The high score material of intermediate water phase has become thin film, hinders internal phase material and direct skin contact, reduces and chemically or physically prevents
Shine the agent zest to skin；Along with the volatilization on skin of the intermediate layer moisture, internal phase emulsified state destroys, the chemistry of internal phase oil
Or physical sunscreen agent discharges, playing anti-sunlight function, described cosmetic composition can the most effectively reduce zest, has again
Higher sun-proof function.
Detailed description of the invention
Being further described the present invention below in conjunction with specific embodiment, following example and comparative example are raw materials used all
For common commercially available prod.
Embodiment 1
S1, formula as shown in table 1 are respectively configured internal phase oil, intermediate water phase, foreign minister's oil, carry out pretreatment (dissolving dispersion) respectively and become
Uniform state；
S2, by internal phase oil mix with intermediate water phase, emulsifying is oil-in-water type (O/W) emulsion system；
S3, emulsion oil-in-water system is added in foreign minister's oil and be emulsified into Water-In-Oil oil-in (O/W/O) multiple emulsion system,
To multiple emulsification system cosmetic composition.
Embodiment 2
S1, formula as shown in table 2 are respectively configured internal phase oil, intermediate water phase, foreign minister's oil, carry out pretreatment (dissolving dispersion) respectively and become
Uniform state；
S2, by internal phase oil mix with intermediate water phase, emulsifying is oil-in-water type (O/W) emulsion system；
S3, emulsion oil-in-water system is added in foreign minister's oil and be emulsified into Water-In-Oil oil-in (O/W/O) multiple emulsion system,
To multiple emulsification system cosmetic composition.
Embodiment 3
S1, formula as shown in table 3 are respectively configured internal phase oil, intermediate water phase, foreign minister's oil, carry out pretreatment (dissolving dispersion) respectively and become
Uniform state；
S2, by internal phase oil mix with intermediate water phase, emulsifying is oil-in-water type (O/W) emulsion system；
S3, emulsion oil-in-water system is added in foreign minister's oil and be emulsified into Water-In-Oil oil-in (O/W/O) multiple emulsion system,
To multiple emulsification system cosmetic composition.
Embodiment 4
S1, formula as shown in table 4 are respectively configured internal phase oil, intermediate water phase, foreign minister's oil, carry out pretreatment (dissolving dispersion) respectively and become
Uniform state；
S2, by internal phase oil mix with intermediate water phase, emulsifying is oil-in-water type (O/W) emulsion system；
S3, emulsion oil-in-water system is added in foreign minister's oil and be emulsified into Water-In-Oil oil-in (O/W/O) multiple emulsion system,
To multiple emulsification system cosmetic composition.
Table 1
Comparative example 1
By the formula of table 1 by internal phase oil and foreign minister's oil mix homogeneously, it is then added in intermediate water phase, room temperature emulsifying 15 points
Clock.
Comparative example 2
Changing the emulsifying agent 2 PEG-10 polydimethylsiloxane consumption in embodiment 1 into 1%, pure water consumption changes 14.3% into, its
Remaining same as in Example 1.
Respectively the cosmetic composition of embodiment 1 to 4 and comparative example 1, comparative example 2 preparation is tested, use centrifugal
Separate test and verify the production rate of O/W/O structure, verify product stability with temperature ring test, and with repeatedly skin
Zest test carrys out the safety of contrast product.
Centrifuge test:
In two step emulsification preparation thereofs of embodiment 1 to 4 and comparative example 2, chemical sun is dissolved in internal phase oil, due to two
Secondary emulsifying, if internal phase oil component is completely formed the interior oil phase of O/W/O structure, outer oil phase does not just have chemical sun.Therefore generalization
Learn sunscreen as marker, the production rate of evaluation O/W/O type structure.
Operational approach: by the cosmetic composition sample of preparation 5 20g samples of subpackage respectively in centrifuge tube, A sample
It is individually identified as A1, A2, A3, A4, A5 centrifugal speed 3000rpm/min, is centrifuged 1 hour.Take every sample supernatant respectively,
The content of wherein UV absorbent is tested with high performance liquid chromatograph.
Test data are as follows:
Embodiment 1
Embodiment 2
Embodiment 3
Embodiment 4
Comparative example 1
Comparative example 2
Temperature ring test: sample is filled respectively sample 200ml, 3, distinguishes labelling A6, A7, A8.It is labeled as putting into temperature automatic
Ring test case, test wrapper temperature and time is: 45 DEG C (24 hours) → 25 DEG C (24 hours) →-10 DEG C of (24 hours) → 25
DEG C (24 hours), repeat ring 5 times, observe whether outward appearance changes.For understanding the situation of change of emulsified body internal structure, ring
Sample after 5 times does above-mentioned centrifugal survey, and detects the content of chemical sun, and result shows, embodiment and the outward appearance of comparative example
All close without chemical sunscreen agent content before and after substantially changing and circulating.
The repeatedly zest test of skin: the sample of embodiment and comparative example is done repeatedly skin irritation test, test
By 2007 editions " cosmetics health specification " requirement method tests, sample being integrated comparation and assessment, integration more pinprick is the lowest, comments
Ratio the results are shown in Table 11.
Sun-proof function test (SPF (sun protection factor)): use Model 601 multiport spf testing 6 output
Preventing of solar simulator (SPF tests ultraviolet sunlight simulator) test, difference test sample embodiment and comparative example
Shine coefficient, the results are shown in Table 11.
Embodiment described above only have expressed embodiments of the present invention, therefore it describes more concrete and detailed, but can not be
And it is interpreted as the restriction to the scope of the claims of the present invention, as long as using the technical side that the form of equivalent or equivalent transformation is obtained
Case, within all should being included in the protection domain of the claims in the present invention.
Claims (10)
1. a multiple emulsification system cosmetic composition, it is characterised in that comprise following component the most count by weight percentage:
Internal phase oil: UV absorbent 12.0～30.0%；
Oils and fats 2.5～10%；
Emulsifying agent 1 0.1～2%；
Foreign minister's oil: oils and fats 10～55%；
Oil-soluble antiallergic antioxidant 0.1～5.0%；
Emulsifying agent 2 1.0～5.0%；
Intermediate water phase: wetting agent 1.0～20.0%；
Polymer substance 1.0～5.0%；
Emulsifying agent 3 0.5～8%；
Surplus is water；
Wherein, the hydrophilic-hydrophobic balance value of described emulsifying agent 1 is less than 5, and the hydrophilic-hydrophobic balance value of described emulsifying agent 2 is 3～8,
The hydrophilic-hydrophobic balance value of described emulsifying agent 3 is 10～15；
Described emulsifying agent 1 is more than 1.5 with the summation of emulsifying agent 3 with the weight ratio of emulsifying agent 2.
The most multiple emulsification system cosmetic composition, it is characterised in that described UV absorbent is methoxy
Base 2-Ethylhexyl cinnamate, octocrilene, ethylhexyl salicylate, homosalate, Dimethicodiethylbenzalmalonate, butylmethoxy hexichol
Formoxyl methane, Uvinul A Plus, PARSOL 500, Uvinul T 150, benzene
Base benzimidazole sulfonic acid, double ethyl hexyl oxy phenol anisyl triazines, titanium dioxide, at least two kinds in zinc oxide.
The most multiple emulsification system cosmetic composition, it is characterised in that described oils and fats is the poly-diformazan of ring
Radical siloxane, ring five polydimethylsiloxane, polydimethylsiloxane, alkyl dimethicone, C12-15 alcohol benzoic acid
Ester, different n-nonanoic acid different nonyl fat, Parleam, hydrogenate poly-certain herbaceous plants with big flowers alkene, squalane, isoparaffin, dicaprylyl carbonate, carbonate propanediol
Ester, ethylhexyl palmitate, caprylic/capric triglyceride, Fructus Canarii albi oils and fats, Jojoba oils and fats, at least in Butyrospermum Parkii oils and fats
Kind.
The most multiple emulsification system cosmetic composition, it is characterised in that described emulsifying agent 1 is Pyrusussuriensis
Alcohol stearate, glyceryl stearate, alkyl stereth, methyl glucoside polyglycol ether stearate, Semen sojae atricolor ovum
Phospholipid, at least one in alkyl androstanediol.
The most multiple emulsification system cosmetic composition, it is characterised in that described emulsifying agent 2 is Pyrusussuriensis
Alcohol stearate, glyceryl stearate, ceteareth, methyl glucoside sesquialter stearate, polyglycol ether two
Methylsiloxane, polydimethylsiloxane polyether polymer, alkyl, polyether polydimethylsiloxane, polyglycereol poly dimethyl silicon hydroxyl
At least one in base ethyl polydimethylsiloxane.
The most multiple emulsification system cosmetic composition, it is characterised in that described emulsifying agent 3 is emulsifying
Agent is polyglycol ether glyceryl stearate, alkyl stereth, alkyl ethoxylated phosphate ester potassium, alkyl phosphate potassium, methyl
Glucoside polyglycol ether stearate, at least one in alkyl androstanediol.
The most multiple emulsification system cosmetic composition, it is characterised in that described wetting agent is glycerol,
Propylene glycol, butanediol, pentanediol, hexanediol, ethohexadiol, decanediol is ethoxy urea, glycine betaine, pyrrolidone sodium carboxylate, transparent
Matter acid and salt, vegetable polysaccharides apoplexy due to endogenous wind at least one.
The most multiple emulsification system cosmetic composition, it is characterised in that described polymer substance is yellow
Virgin rubber, polyacrylate or salt, polyacrylic acid/C10-30 alkyl acrylate cross-linked polymer, sodium acrylate/dimethyl acrylamide acyl
Sodium taurocholate, AVC, vinyl pyrrolidone/icosa alkene, VP/ eicosylene, VP/
Vaccenic acid, vinyl pyrrolidone/icosa alkene, hydroxypropyl methyl cellulose, at least one in Cellulose ethyl hydroxypropyl ether.
The most multiple emulsification system cosmetic composition, it is characterised in that possibly together with in following components
One or more:
The nourishing additive agent of percentage by weight 0.1 ~ 10%；
The coloring agent of percentage by weight 0.1 ~ 5%；
The percentage by weight preservative less than 1.5%；
The percentage by weight essence less than 1.0%.
10. the preparation method of multiple emulsification system cosmetic composition, its feature described in claim 1 to 9 any claim
It is, comprises the steps:
S1, be respectively configured by formula ratio internal phase oil, intermediate water phase, foreign minister oil；
S2, by internal phase oil with intermediate water phase mixing and emulsifying be emulsion oil-in-water system；
S3, emulsion oil-in-water system is added in foreign minister's oil it is emulsified into Water-In-Oil oil-in multiple emulsion system, obtain multiple
Emulsification system cosmetic composition.
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| CN110302109A (en) * | 2019-07-18 | 2019-10-08 | 福建省亚热带植物研究所 | A kind of oil/water containing peony seed oil/oil type sunscreen and preparation method thereof |
| CN110664661A (en) * | 2019-11-01 | 2020-01-10 | 陕西崇文生物科技有限公司 | Mild repairing skin-brightening sunscreen lotion and preparation method thereof |
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