CN106287537A - A kind of solar LED street lamp - Google Patents
A kind of solar LED street lamp Download PDFInfo
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- CN106287537A CN106287537A CN201610709429.7A CN201610709429A CN106287537A CN 106287537 A CN106287537 A CN 106287537A CN 201610709429 A CN201610709429 A CN 201610709429A CN 106287537 A CN106287537 A CN 106287537A
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Classifications
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21S—NON-PORTABLE LIGHTING DEVICES; SYSTEMS THEREOF; VEHICLE LIGHTING DEVICES SPECIALLY ADAPTED FOR VEHICLE EXTERIORS
- F21S9/00—Lighting devices with a built-in power supply; Systems employing lighting devices with a built-in power supply
- F21S9/02—Lighting devices with a built-in power supply; Systems employing lighting devices with a built-in power supply the power supply being a battery or accumulator
- F21S9/03—Lighting devices with a built-in power supply; Systems employing lighting devices with a built-in power supply the power supply being a battery or accumulator rechargeable by exposure to light
- F21S9/035—Lighting devices with a built-in power supply; Systems employing lighting devices with a built-in power supply the power supply being a battery or accumulator rechargeable by exposure to light the solar unit being integrated within the support for the lighting unit, e.g. within or on a pole
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21W—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO USES OR APPLICATIONS OF LIGHTING DEVICES OR SYSTEMS
- F21W2131/00—Use or application of lighting devices or systems not provided for in codes F21W2102/00-F21W2121/00
- F21W2131/10—Outdoor lighting
- F21W2131/103—Outdoor lighting of streets or roads
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
- Y02B20/72—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps in street lighting
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- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The application relates to a kind of solar LED street lamp, including lamp socket, lamp stand, lamp body, lampshade, LED lamp holder, solar panel, controller and accumulator, described lamp body upper end is wide-mouth structure, LED lamp holder is arranged in lamp body, described lamp stand top is fixing with lamp body bottom to be connected, lamp stand bottom is fixed on lamp socket, and lamp stand is hollow structure, and described accumulator and controller are arranged in the cavity of lamp stand upper end；Described lamp body top arranges lampshade, and lampshade top covers solar panel.
Description
Technical field
The application relates to street lamp field, particularly relates to a kind of solar LED street lamp.
Background technology
Due to present stage energy shortage, solar street light has advantage in terms of environmental protection and energy conservation, the most progressively substitutes
Conventional road lamp illuminates.
But, owing to the humidity of the inside and outside environment of street lampshade is different with temperature, when humidity in environment, temperature difference are bigger
Time, easily form one layer of water smoke at cover surface, thus affect the illuminating effect of street lamp, bring inconvenience and the waste of the energy.
Summary of the invention
It is desirable to provide a kind of solar LED street lamp, to solve problem set forth above.
Embodiments of the invention provide a kind of solar LED street lamp, including lamp socket, lamp stand, lamp body, lampshade, LED
Head, solar panel, controller and accumulator, described lamp body upper end is wide-mouth structure, and LED lamp holder is arranged in lamp body, institute
Stating that lamp stand top and lamp body bottom are fixing to be connected, lamp stand bottom is fixed on lamp socket, and lamp stand is hollow structure, described accumulator
It is arranged in the cavity of lamp stand upper end with controller；Described lamp body top arranges lampshade, and lampshade top covers solaode
Plate, described lampshade is that antifog glass substrate is constituted.
The technical scheme that embodiments of the invention provide can include following beneficial effect:
The lampshade of solar LED street lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, it is less than 1 degree to the contact angle of water droplet, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur,
Thus solve problem set forth above.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description
Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe
It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
The invention will be further described to utilize accompanying drawing, but the embodiment in accompanying drawing does not constitute any limit to the present invention
System, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain according to the following drawings
Other accompanying drawing.
Fig. 1 is the structural representation of solar LED street lamp of the present invention.
Fig. 2 is the Making programme figure of antifogging coating of the present invention.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to
During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended
The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Transparent material has a wide range of applications in industrial and agricultural production and life, but, due to the impact of surrounding, special
Not being the impact of humidity in environment, transparent material surface easily produces atomization, causes transparency to decline, to production and the life of people
Live and bring inconvenience, even cause heavy losses.
Anti-fogging measure is mainly started with from the condition destroying fogging, and one is from thermodynamics, installs heater and makes base material
Surface temperature is higher than steam dew point, or the little dewdrop that installation ultrasound wave dispersion makes steam produce volatilized within the extremely short time
For steam, the measure being usually taken is the method heated with hair dryer or film metal silk, removes transparent material surface
Water smoke；Two is from the performance changing material surface, changes chemical composition or the microstructure of substrate surface, such as at not shadow
In the case of ringing the function of material own, construct one layer of hydrophilic or hydrophobic wear-resistant coating at material surface, when little water drop contact
During to this coating, due to the hydrophilic of coating or hydrophobic effect, little water droplet can coating surface sprawl into thin layer moisture film or
Person tumbles, thus inhibits the formation of coating surface water smoke.
But, in prior art, using hair dryer or tinsel heating, there is device complicated, original paper is many, cost
Height, the problem such as fragile, therefore coating is the main method solving transparent material surface fogging.
Application scenarios one:
Fig. 1 shows a kind of solar LED street lamp that embodiments herein relates to, including lamp socket 1, lamp stand 2, lamp body 3,
Lampshade 6, LED lamp holder 4, solar panel 5, controller 7 and accumulator 8, described lamp body 3 upper end is wide-mouth structure, LED lamp holder
4 are arranged in lamp body 3, and described lamp stand 2 top is fixing with lamp body 3 bottom to be connected, and lamp stand 2 bottom is fixed on lamp socket 1, lamp stand 2
For hollow structure, described accumulator 8 and controller 7 are arranged in the cavity of lamp stand 2 upper end；Described lamp body 3 top is arranged
Lampshade 6, lampshade 6 top covers solar panel 5, described lamp body 3 be shaped as inverted trapezoidal, described solar panel 5 with
The inclination angle of horizontal plane is 31～45 degree, and described lampshade 6 is constituted for antifog glass substrate.
The lampshade of solar LED street lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 3～10 μm, described SiO2Nano particle diameter is 50～100nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 1 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios two:
Fig. 1 shows a kind of solar LED street lamp that embodiments herein relates to, including lamp socket 1, lamp stand 2, lamp body 3,
Lampshade 6, LED lamp holder 4, solar panel 5, controller 7 and accumulator 8, described lamp body 3 upper end is wide-mouth structure, LED lamp holder
4 are arranged in lamp body 3, and described lamp stand 2 top is fixing with lamp body 3 bottom to be connected, and lamp stand 2 bottom is fixed on lamp socket 1, lamp stand 2
For hollow structure, described accumulator 8 and controller 7 are arranged in the cavity of lamp stand 2 upper end；Described lamp body 3 top is arranged
Lampshade 6, lampshade 6 top covers solar panel 5, described lamp body 3 be shaped as inverted trapezoidal, described solar panel 5 with
The inclination angle of horizontal plane is 31～45 degree, and described lampshade 6 is constituted for antifog glass substrate.
The lampshade of solar LED street lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 3 μm, described SiO2Nano particle diameter is 50nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 1 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios three:
Fig. 1 shows a kind of solar LED street lamp that embodiments herein relates to, including lamp socket 1, lamp stand 2, lamp body 3,
Lampshade 6, LED lamp holder 4, solar panel 5, controller 7 and accumulator 8, described lamp body 3 upper end is wide-mouth structure, LED lamp holder
4 are arranged in lamp body 3, and described lamp stand 2 top is fixing with lamp body 3 bottom to be connected, and lamp stand 2 bottom is fixed on lamp socket 1, lamp stand 2
For hollow structure, described accumulator 8 and controller 7 are arranged in the cavity of lamp stand 2 upper end；Described lamp body 3 top is arranged
Lampshade 6, lampshade 6 top covers solar panel 5, described lamp body 3 be shaped as inverted trapezoidal, described solar panel 5 with
The inclination angle of horizontal plane is 31～45 degree, and described lampshade 6 is constituted for antifog glass substrate.
The lampshade of solar LED street lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 6 μm, described SiO2Nano particle diameter is 60nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 2 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios four:
Fig. 1 shows a kind of solar LED street lamp that embodiments herein relates to, including lamp socket 1, lamp stand 2, lamp body 3,
Lampshade 6, LED lamp holder 4, solar panel 5, controller 7 and accumulator 8, described lamp body 3 upper end is wide-mouth structure, LED lamp holder
4 are arranged in lamp body 3, and described lamp stand 2 top is fixing with lamp body 3 bottom to be connected, and lamp stand 2 bottom is fixed on lamp socket 1, lamp stand 2
For hollow structure, described accumulator 8 and controller 7 are arranged in the cavity of lamp stand 2 upper end；Described lamp body 3 top is arranged
Lampshade 6, lampshade 6 top covers solar panel 5, described lamp body 3 be shaped as inverted trapezoidal, described solar panel 5 with
The inclination angle of horizontal plane is 31～45 degree, and described lampshade 6 is constituted for antifog glass substrate.
The lampshade of solar LED street lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 8 μm, described SiO2Nano particle diameter is 70nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 2 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios five:
Fig. 1 shows a kind of solar LED street lamp that embodiments herein relates to, including lamp socket 1, lamp stand 2, lamp body 3,
Lampshade 6, LED lamp holder 4, solar panel 5, controller 7 and accumulator 8, described lamp body 3 upper end is wide-mouth structure, LED lamp holder
4 are arranged in lamp body 3, and described lamp stand 2 top is fixing with lamp body 3 bottom to be connected, and lamp stand 2 bottom is fixed on lamp socket 1, lamp stand 2
For hollow structure, described accumulator 8 and controller 7 are arranged in the cavity of lamp stand 2 upper end；Described lamp body 3 top is arranged
Lampshade 6, lampshade 6 top covers solar panel 5, described lamp body 3 be shaped as inverted trapezoidal, described solar panel 5 with
The inclination angle of horizontal plane is 31～45 degree, and described lampshade 6 is constituted for antifog glass substrate.
The lampshade of solar LED street lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 10 μm, described SiO2Nano particle diameter is 100nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 2 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention
Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or
Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application
Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following
Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and
And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.
Claims (3)
1. a solar LED street lamp, including lamp socket, lamp stand, lamp body, lampshade, LED lamp holder, solar panel, controller and
Accumulator, it is characterised in that described lamp body upper end is wide-mouth structure, LED lamp holder is arranged in lamp body, described lamp stand top and lamp
Body bottom is fixing to be connected, and lamp stand bottom is fixed on lamp socket, and lamp stand is hollow structure, and described accumulator and controller are respectively provided with
In the cavity of lamp stand upper end；Described lamp body top arranges lampshade, and lampshade top covers solar panel.
Solar LED street lamp the most according to claim 1, it is characterised in that described lamp body be shaped as inverted trapezoidal, described
Solar panel is 31～45 degree with the inclination angle of horizontal plane.
Solar LED street lamp the most according to claim 2, it is characterised in that described lampshade is that antifog glass substrate is constituted.
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| CN201610709429.7A CN106287537A (en) | 2016-08-22 | 2016-08-22 | A kind of solar LED street lamp |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610709429.7A CN106287537A (en) | 2016-08-22 | 2016-08-22 | A kind of solar LED street lamp |
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| CN201610709429.7A Pending CN106287537A (en) | 2016-08-22 | 2016-08-22 | A kind of solar LED street lamp |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106949438A (en) * | 2017-03-24 | 2017-07-14 | 上海巽晔计算机科技有限公司 | A kind of LED light device with antifreeze anti-fog effect |
| WO2021147317A1 (en) * | 2020-01-21 | 2021-07-29 | 广州市浩洋电子股份有限公司 | Dustproof and anti-fogging stage lamp |
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| CN205331964U (en) * | 2015-12-12 | 2016-06-22 | 重庆信德电子有限公司 | Passageway lamp |
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| CN106949438A (en) * | 2017-03-24 | 2017-07-14 | 上海巽晔计算机科技有限公司 | A kind of LED light device with antifreeze anti-fog effect |
| WO2021147317A1 (en) * | 2020-01-21 | 2021-07-29 | 广州市浩洋电子股份有限公司 | Dustproof and anti-fogging stage lamp |
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