CN106259251A - A kind of trap lamp of band demister screen - Google Patents

A kind of trap lamp of band demister screen Download PDF

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Publication number
CN106259251A
CN106259251A CN201610711390.2A CN201610711390A CN106259251A CN 106259251 A CN106259251 A CN 106259251A CN 201610711390 A CN201610711390 A CN 201610711390A CN 106259251 A CN106259251 A CN 106259251A
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China
Prior art keywords
caco
particle
sio
glass substrate
trap lamp
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CN201610711390.2A
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不公告发明人
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Individual
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Priority to CN201610711390.2A priority Critical patent/CN106259251A/en
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01MCATCHING, TRAPPING OR SCARING OF ANIMALS; APPARATUS FOR THE DESTRUCTION OF NOXIOUS ANIMALS OR NOXIOUS PLANTS
    • A01M1/00Stationary means for catching or killing insects
    • A01M1/02Stationary means for catching or killing insects with devices or substances, e.g. food, pheronones attracting the insects
    • A01M1/04Attracting insects by using illumination or colours
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/22Surface treatment of glass, not in the form of fibres or filaments, by coating with other inorganic material
    • C03C17/23Oxides
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C2217/00Coatings on glass
    • C03C2217/20Materials for coating a single layer on glass
    • C03C2217/21Oxides
    • C03C2217/213SiO2

Abstract

The application relates to the trap lamp of a kind of band demister screen, and including base, lamp stand one, lamp stand two, solar panels, accumulator and trap lamp, described base is hollow-core construction, is inside provided with accumulator, and lamp stand one is arranged over solar panels, and lamp stand two one end is provided with trap lamp.

Description

A kind of trap lamp of band demister screen
Technical field
The application relates to trap lamp field, particularly relates to the trap lamp of a kind of band demister screen.
Background technology
Trap lamp is that a night is for luring and catch and kill the lamp of phototactic insecticide.
But, due to environmental effect, the lampshade of trap lamp easily produces water smoke, is unfavorable for transmitting and the attraction elder brother of light Worm.
Summary of the invention
It is desirable to provide the trap lamp of a kind of band demister screen, to solve problem set forth above.
Embodiments of the invention provide the trap lamp of a kind of band demister screen, including base, lamp stand one, lamp stand two, too Sun energy plate, accumulator and trap lamp, described base is hollow-core construction, is inside provided with accumulator, and lamp stand one is arranged over solar panels, Lamp stand two one end is provided with trap lamp.
The technical scheme that embodiments of the invention provide can include following beneficial effect:
The lampshade of trap lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifogging coating, and it is right The contact angle of water droplet is less than 1 degree, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur, thus solve Determine problem set forth above.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
The invention will be further described to utilize accompanying drawing, but the embodiment in accompanying drawing does not constitute any limit to the present invention System, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain according to the following drawings Other accompanying drawing.
Fig. 1 is the structural representation of trap lamp of the present invention.
Fig. 2 is the Making programme figure of antifogging coating of the present invention.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Transparent material has a wide range of applications in industrial and agricultural production and life, but, due to the impact of surrounding, special Not being the impact of humidity in environment, transparent material surface easily produces atomization, causes transparency to decline, to production and the life of people Live and bring inconvenience, even cause heavy losses.
Anti-fogging measure is mainly started with from the condition destroying fogging, and one is from thermodynamics, installs heater and makes base material Surface temperature is higher than steam dew point, or the little dewdrop that installation ultrasound wave dispersion makes steam produce volatilized within the extremely short time For steam, the measure being usually taken is the method heated with hair dryer or film metal silk, removes transparent material surface Water smoke;Two is from the performance changing material surface, changes chemical composition or the microstructure of substrate surface, such as at not shadow In the case of ringing the function of material own, construct one layer of hydrophilic or hydrophobic wear-resistant coating at material surface, when little water drop contact During to this coating, due to the hydrophilic of coating or hydrophobic effect, little water droplet can coating surface sprawl into thin layer moisture film or Person tumbles, thus inhibits the formation of coating surface water smoke.
But, in prior art, using hair dryer or tinsel heating, there is device complicated, original paper is many, cost Height, the problem such as fragile, therefore coating is the main method solving transparent material surface fogging.
Application scenarios one:
Fig. 1 shows the trap lamp of a kind of band demister screen that embodiments herein relates to, including base 1, lamp stand 1, Lamp stand 25, solar panels 3, accumulator 4 and trap lamp 6, it is characterised in that described base 1 is hollow-core construction, is inside provided with electric power storage Pond 4, lamp stand 1 is arranged over solar panels 3, and lamp stand 25 one end is provided with trap lamp 6, described solar panels 3 for being obliquely installed, Being 35~45 degree with horizontal plane angle, described solar panels 3, accumulator 4 and trap lamp 6 electrically connect, described trap lamp 6 outside by Lampshade 8 surrounds, and described lampshade 8 outer felt is wound with electrical network 7, and described trap lamp 6 and electrical network 7 electrically connect with accumulator 4, described lampshade 8 are constituted for antifog glass substrate.
The lampshade of trap lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifogging coating, has Preferably hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occurring.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment;This high temp glass Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle Footpath is 2 μm, described SiO2Nano particle diameter is 20nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure The hydrophilic of layer;3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 1 degree, possesses higher Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second Alkene pyrrolidone;
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C, The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter SiO2The suspension of nanoparticle;
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1~ The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all Even scattered suspension;
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing, To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle Surface adsorption is uniform;
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6 ~10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain Son, and SiO2Nanoparticle is three layers;
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment, The high temp glass substrate distilled water wash that will process, then dry up with nitrogen;
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface;
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600~850 DEG C3/SiO2CaCO in compound particle3Pyrolytic, The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios two:
Fig. 1 shows the trap lamp of a kind of band demister screen that embodiments herein relates to, including base 1, lamp stand 1, Lamp stand 25, solar panels 3, accumulator 4 and trap lamp 6, it is characterised in that described base 1 is hollow-core construction, is inside provided with electric power storage Pond 4, lamp stand 1 is arranged over solar panels 3, and lamp stand 25 one end is provided with trap lamp 6, described solar panels 3 for being obliquely installed, Being 35~45 degree with horizontal plane angle, described solar panels 3, accumulator 4 and trap lamp 6 electrically connect, described trap lamp 6 outside by Lampshade 8 surrounds, and described lampshade 8 outer felt is wound with electrical network 7, and described trap lamp 6 and electrical network 7 electrically connect with accumulator 4, described lampshade 8 are constituted for antifog glass substrate.
The lampshade of trap lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifogging coating, has Preferably hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occurring.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment;This high temp glass Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle Footpath is 4 μm, described SiO2Nano particle diameter is 20nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure The hydrophilic of layer;3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 2 degree, possesses higher Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second Alkene pyrrolidone;
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C, The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter SiO2The suspension of nanoparticle;
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1~ The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all Even scattered suspension;
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing, To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle Surface adsorption is uniform;
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6 ~10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain Son, and SiO2Nanoparticle is three layers;
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment, The high temp glass substrate distilled water wash that will process, then dry up with nitrogen;
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface;
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600~850 DEG C3/SiO2CaCO in compound particle3Pyrolytic, The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios three:
Fig. 1 shows the trap lamp of a kind of band demister screen that embodiments herein relates to, including base 1, lamp stand 1, Lamp stand 25, solar panels 3, accumulator 4 and trap lamp 6, it is characterised in that described base 1 is hollow-core construction, is inside provided with electric power storage Pond 4, lamp stand 1 is arranged over solar panels 3, and lamp stand 25 one end is provided with trap lamp 6, described solar panels 3 for being obliquely installed, Being 35~45 degree with horizontal plane angle, described solar panels 3, accumulator 4 and trap lamp 6 electrically connect, described trap lamp 6 outside by Lampshade 8 surrounds, and described lampshade 8 outer felt is wound with electrical network 7, and described trap lamp 6 and electrical network 7 electrically connect with accumulator 4, described lampshade 8 are constituted for antifog glass substrate.
The lampshade of trap lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifogging coating, has Preferably hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occurring.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment;This high temp glass Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle Footpath is 6 μm, described SiO2Nano particle diameter is 20nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure The hydrophilic of layer;3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 2 degree, possesses higher Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second Alkene pyrrolidone;
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C, The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter SiO2The suspension of nanoparticle;
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1~ The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all Even scattered suspension;
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing, To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle Surface adsorption is uniform;
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6 ~10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain Son, and SiO2Nanoparticle is three layers;
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment, The high temp glass substrate distilled water wash that will process, then dry up with nitrogen;
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface;
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600~850 DEG C3/SiO2CaCO in compound particle3Pyrolytic, The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios four:
Fig. 1 shows the trap lamp of a kind of band demister screen that embodiments herein relates to, including base 1, lamp stand 1, Lamp stand 25, solar panels 3, accumulator 4 and trap lamp 6, it is characterised in that described base 1 is hollow-core construction, is inside provided with electric power storage Pond 4, lamp stand 1 is arranged over solar panels 3, and lamp stand 25 one end is provided with trap lamp 6, described solar panels 3 for being obliquely installed, Being 35~45 degree with horizontal plane angle, described solar panels 3, accumulator 4 and trap lamp 6 electrically connect, described trap lamp 6 outside by Lampshade 8 surrounds, and described lampshade 8 outer felt is wound with electrical network 7, and described trap lamp 6 and electrical network 7 electrically connect with accumulator 4, described lampshade 8 are constituted for antifog glass substrate.
The lampshade of trap lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifogging coating, has Preferably hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occurring.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment;This high temp glass Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle Footpath is 8 μm, described SiO2Nano particle diameter is 20nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure The hydrophilic of layer;3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 3 degree, possesses higher Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second Alkene pyrrolidone;
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C, The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter SiO2The suspension of nanoparticle;
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1~ The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all Even scattered suspension;
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing, To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle Surface adsorption is uniform;
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6 ~10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain Son, and SiO2Nanoparticle is three layers;
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment, The high temp glass substrate distilled water wash that will process, then dry up with nitrogen;
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface;
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600~850 DEG C3/SiO2CaCO in compound particle3Pyrolytic, The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios five:
Fig. 1 shows the trap lamp of a kind of band demister screen that embodiments herein relates to, including base 1, lamp stand 1, Lamp stand 25, solar panels 3, accumulator 4 and trap lamp 6, it is characterised in that described base 1 is hollow-core construction, is inside provided with electric power storage Pond 4, lamp stand 1 is arranged over solar panels 3, and lamp stand 25 one end is provided with trap lamp 6, described solar panels 3 for being obliquely installed, Being 35~45 degree with horizontal plane angle, described solar panels 3, accumulator 4 and trap lamp 6 electrically connect, described trap lamp 6 outside by Lampshade 8 surrounds, and described lampshade 8 outer felt is wound with electrical network 7, and described trap lamp 6 and electrical network 7 electrically connect with accumulator 4, described lampshade 8 are constituted for antifog glass substrate.
The lampshade of trap lamp of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifogging coating, has Preferably hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occurring.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment;This high temp glass Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle Footpath is 10 μm, described SiO2Nano particle diameter is 20nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure The hydrophilic of layer;3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 3 degree, possesses higher Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second Alkene pyrrolidone;
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C, The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter SiO2The suspension of nanoparticle;
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1~ The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all Even scattered suspension;
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing, To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle Surface adsorption is uniform;
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6 ~10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain Son, and SiO2Nanoparticle is three layers;
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment, The high temp glass substrate distilled water wash that will process, then dry up with nitrogen;
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface;
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600~850 DEG C3/SiO2CaCO in compound particle3Pyrolytic, The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.

Claims (4)

1. a trap lamp for band demister screen, including base, lamp stand one, lamp stand two, solar panels, accumulator and trap lamp, its Being characterised by, described base is hollow-core construction, is inside provided with accumulator, and lamp stand one is arranged over solar panels, and lamp stand two one end sets There is trap lamp.
Trap lamp the most according to claim 1, it is characterised in that described solar panels are for being obliquely installed, with horizontal plane angle Degree is 35~45 degree, described solar panels, accumulator and trap lamp electrical connection.
Trap lamp the most according to claim 2, it is characterised in that surrounded by lampshade outside described trap lamp, described lampshade Outer felt is wound with electrical network, and described trap lamp and electrical network are connected with storage battery.
Trap lamp the most according to claim 3, it is characterised in that described lampshade is that antifog glass substrate is constituted.
CN201610711390.2A 2016-08-22 2016-08-22 A kind of trap lamp of band demister screen Pending CN106259251A (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102019159A (en) * 2009-09-17 2011-04-20 中国科学院理化技术研究所 Raspberry-like polystyrene microsphere/silicon dioxide composite particles and preparation method and use thereof
KR20110039596A (en) * 2009-10-12 2011-04-20 서울대학교산학협력단 Trip
CN203273690U (en) * 2013-04-28 2013-11-06 常州容和高分子材料科技有限公司 Macromolecular fog-proof lampshade
CN203327795U (en) * 2013-04-09 2013-12-11 李晨 Mosquito killer lamp
CN203718613U (en) * 2014-03-14 2014-07-16 李杏 Solar lawn mosquito eradication lighting lamp
CN205284746U (en) * 2015-11-30 2016-06-08 青海祥田生态科技有限公司 Portable insect trap

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102019159A (en) * 2009-09-17 2011-04-20 中国科学院理化技术研究所 Raspberry-like polystyrene microsphere/silicon dioxide composite particles and preparation method and use thereof
KR20110039596A (en) * 2009-10-12 2011-04-20 서울대학교산학협력단 Trip
CN203327795U (en) * 2013-04-09 2013-12-11 李晨 Mosquito killer lamp
CN203273690U (en) * 2013-04-28 2013-11-06 常州容和高分子材料科技有限公司 Macromolecular fog-proof lampshade
CN203718613U (en) * 2014-03-14 2014-07-16 李杏 Solar lawn mosquito eradication lighting lamp
CN205284746U (en) * 2015-11-30 2016-06-08 青海祥田生态科技有限公司 Portable insect trap

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Application publication date: 20170104