CN106287413A - A kind of for illuminating lamp under water - Google Patents
A kind of for illuminating lamp under water Download PDFInfo
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- CN106287413A CN106287413A CN201610709971.2A CN201610709971A CN106287413A CN 106287413 A CN106287413 A CN 106287413A CN 201610709971 A CN201610709971 A CN 201610709971A CN 106287413 A CN106287413 A CN 106287413A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21S—NON-PORTABLE LIGHTING DEVICES; SYSTEMS THEREOF; VEHICLE LIGHTING DEVICES SPECIALLY ADAPTED FOR VEHICLE EXTERIORS
- F21S8/00—Lighting devices intended for fixed installation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V17/00—Fastening of component parts of lighting devices, e.g. shades, globes, refractors, reflectors, filters, screens, grids or protective cages
- F21V17/10—Fastening of component parts of lighting devices, e.g. shades, globes, refractors, reflectors, filters, screens, grids or protective cages characterised by specific fastening means or way of fastening
- F21V17/12—Fastening of component parts of lighting devices, e.g. shades, globes, refractors, reflectors, filters, screens, grids or protective cages characterised by specific fastening means or way of fastening by screwing
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V31/00—Gas-tight or water-tight arrangements
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- Chemical & Material Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Surface Treatment Of Glass (AREA)
Abstract
The application relates to a kind of for illuminating lamp under water, including lamp housing, lampshade and luminescence component, described lamp housing is cylindric, described luminescence component is arranged on lamp housing one end, described lampshade is on described luminescence component, and described lamp housing top and bottom are furnished with top cover and bottom, described top cover and bottom and are connected with the locking of described lamp housing by lock-screw.
Description
Technical field
The application relates to illuminating lamp field, particularly relates to a kind of for illuminating lamp under water.
Background technology
Underwater luminaire is called for short underwater lamp, it is simply that being contained in the lamp under the bottom, its outward appearance is typically small, and external form is buried with some
Lamp is similar, generally LED light source, has the features such as energy-saving and environmental protection, life-span length, volume are little.The when of energising, can send
Multiple color, bright and colourful, usually it is contained in park or pool with fountain, there is the strongest sight.
But, owing to illuminating lamp works the most under water, its internal medium humidity is relatively big, when running into the feelings that the temperature difference is bigger
During condition, its cover surface is easily atomized, and makes troubles to illumination work.
Summary of the invention
It is desirable to provide it is a kind of for illuminating lamp under water, to solve problem set forth above.
Embodiments of the invention provide a kind of for illuminating lamp under water, including lamp housing, lampshade and luminescence component, institute
It is cylindric for stating lamp housing, and described luminescence component is arranged on lamp housing one end, described lampshade on described luminescence component, described lamp housing
Top and bottom are furnished with top cover and bottom, described top cover and bottom and are connected with the locking of described lamp housing by lock-screw, described lamp
Cover is antifog glass substrate.
The technical scheme that embodiments of the invention provide can include following beneficial effect:
The lampshade of the underwater luminaire of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, it is less than 1 degree to the contact angle of water droplet, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur,
Thus solve problem set forth above.
Aspect and advantage that the application adds will part be given in the following description, and part will become from the following description
Obtain substantially, or recognized by the practice of the application.It should be appreciated that above general description and details hereinafter only describe
It is exemplary and explanatory, the application can not be limited.
Accompanying drawing explanation
The invention will be further described to utilize accompanying drawing, but the embodiment in accompanying drawing does not constitute any limit to the present invention
System, for those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain according to the following drawings
Other accompanying drawing.
Fig. 1 is the structural representation of underwater luminaire of the present invention.
Fig. 2 is the Making programme figure of antifogging coating of the present invention.
Detailed description of the invention
Here will illustrate exemplary embodiment in detail, its example represents in the accompanying drawings.Explained below relates to
During accompanying drawing, unless otherwise indicated, the same numbers in different accompanying drawings represents same or analogous key element.Following exemplary embodiment
Described in embodiment do not represent all embodiments consistent with the present invention.On the contrary, they are only with the most appended
The example of the apparatus and method that some aspects that described in detail in claims, the present invention are consistent.
Transparent material has a wide range of applications in industrial and agricultural production and life, but, due to the impact of surrounding, special
Not being the impact of humidity in environment, transparent material surface easily produces atomization, causes transparency to decline, to production and the life of people
Live and bring inconvenience, even cause heavy losses.
Anti-fogging measure is mainly started with from the condition destroying fogging, and one is from thermodynamics, installs heater and makes base material
Surface temperature is higher than steam dew point, or the little dewdrop that installation ultrasound wave dispersion makes steam produce volatilized within the extremely short time
For steam, the measure being usually taken is the method heated with hair dryer or film metal silk, removes transparent material surface
Water smoke；Two is from the performance changing material surface, changes chemical composition or the microstructure of substrate surface, such as at not shadow
In the case of ringing the function of material own, construct one layer of hydrophilic or hydrophobic wear-resistant coating at material surface, when little water drop contact
During to this coating, due to the hydrophilic of coating or hydrophobic effect, little water droplet can coating surface sprawl into thin layer moisture film or
Person tumbles, thus inhibits the formation of coating surface water smoke.
But, in prior art, using hair dryer or tinsel heating, there is device complicated, original paper is many, cost
Height, the problem such as fragile, therefore coating is the main method solving transparent material surface fogging.
Application scenarios one:
It is a kind of for illuminating lamp under water that Fig. 1 shows that embodiments herein relates to, including lamp housing 1, and lampshade 2 and sending out
Optical assembly 3, it is characterised in that described lamp housing 1 is cylindric, described luminescence component 3 is arranged on lamp housing 1 one end, and described lampshade 2 covers
On described luminescence component 3, described lamp housing 1 top and bottom are furnished with top cover 4 and bottom 5, described top cover 4 and bottom 5 by lock
Tight screw is connected with the locking of described lamp housing 1, is provided with seal washer, described sealing gasket between described lamp housing 1 and top cover 4 and bottom 5
Circle is waterproof elastic packing packing ring, and with sealant sealing, described lampshade 2 is antifog glass substrate.
The lampshade of the underwater luminaire of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 1～10 μm, described SiO2Nano particle diameter is 50～100nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 1 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios two:
It is a kind of for illuminating lamp under water that Fig. 1 shows that embodiments herein relates to, including lamp housing 1, and lampshade 2 and sending out
Optical assembly 3, it is characterised in that described lamp housing 1 is cylindric, described luminescence component 3 is arranged on lamp housing 1 one end, and described lampshade 2 covers
On described luminescence component 3, described lamp housing 1 top and bottom are furnished with top cover 4 and bottom 5, described top cover 4 and bottom 5 by lock
Tight screw is connected with the locking of described lamp housing 1, is provided with seal washer, described sealing gasket between described lamp housing 1 and top cover 4 and bottom 5
Circle is waterproof elastic packing packing ring, and with sealant sealing, described lampshade 2 is antifog glass substrate.
The lampshade of the underwater luminaire of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 1 μm, described SiO2Nano particle diameter is 10nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 1 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios three:
It is a kind of for illuminating lamp under water that Fig. 1 shows that embodiments herein relates to, including lamp housing 1, and lampshade 2 and sending out
Optical assembly 3, it is characterised in that described lamp housing 1 is cylindric, described luminescence component 3 is arranged on lamp housing 1 one end, and described lampshade 2 covers
On described luminescence component 3, described lamp housing 1 top and bottom are furnished with top cover 4 and bottom 5, described top cover 4 and bottom 5 by lock
Tight screw is connected with the locking of described lamp housing 1, is provided with seal washer, described sealing gasket between described lamp housing 1 and top cover 4 and bottom 5
Circle is waterproof elastic packing packing ring, and with sealant sealing, described lampshade 2 is antifog glass substrate.
The lampshade of the underwater luminaire of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 3 μm, described SiO2Nano particle diameter is 30nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 2 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios four:
It is a kind of for illuminating lamp under water that Fig. 1 shows that embodiments herein relates to, including lamp housing 1, and lampshade 2 and sending out
Optical assembly 3, it is characterised in that described lamp housing 1 is cylindric, described luminescence component 3 is arranged on lamp housing 1 one end, and described lampshade 2 covers
On described luminescence component 3, described lamp housing 1 top and bottom are furnished with top cover 4 and bottom 5, described top cover 4 and bottom 5 by lock
Tight screw is connected with the locking of described lamp housing 1, is provided with seal washer, described sealing gasket between described lamp housing 1 and top cover 4 and bottom 5
Circle is waterproof elastic packing packing ring, and with sealant sealing, described lampshade 2 is antifog glass substrate.
The lampshade of the underwater luminaire of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 6 μm, described SiO2Nano particle diameter is 60nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 3 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Application scenarios five:
It is a kind of for illuminating lamp under water that Fig. 1 shows that embodiments herein relates to, including lamp housing 1, and lampshade 2 and sending out
Optical assembly 3, it is characterised in that described lamp housing 1 is cylindric, described luminescence component 3 is arranged on lamp housing 1 one end, and described lampshade 2 covers
On described luminescence component 3, described lamp housing 1 top and bottom are furnished with top cover 4 and bottom 5, described top cover 4 and bottom 5 by lock
Tight screw is connected with the locking of described lamp housing 1, is provided with seal washer, described sealing gasket between described lamp housing 1 and top cover 4 and bottom 5
Circle is waterproof elastic packing packing ring, and with sealant sealing, described lampshade 2 is antifog glass substrate.
The lampshade of the underwater luminaire of the present invention is antifog glass substrate, and this antifog glass substrate surface is provided with antifog painting
Layer, has preferable hydrophilic effect, it is possible to prevent glass substrate surface from water smoke etc. occur.
Preferably, described antifog glass substrate is high temp glass substrate, and described high temp glass substrate surface is for passing through electrostatic
The antifogging coating of self-assembling method deposition, described high temp glass substrate is through polyelectrolyte surface modification treatment；This high temp glass
Antifogging coating with positive charge, can be deposited on table by electrostatic attraction through polyelectrolyte process rear surface by substrate surface
Face.
Preferably, described antifogging coating is CaCO3/SiO2Compound particle, described CaCO3/SiO2Compound particle is nucleocapsid knot
Structure, CaCO3Particle is core, SiO2Nanoparticle adsorbs at described CaCO3Particle surface forms shell structure, described CaCO3Particle
Footpath is 10 μm, described SiO2Nano particle diameter is 100nm.
Due to CaCO3At high temperature produce after calcining and decompose, have CO2Gas produces, CO2Gas breaks through SiO2Nanoparticle
The shell structure formed so that this shell structure surface forms aperture, is formed by SiO2The hollow ball composition that nanoparticle is constituted is many
Hole coating, and increase the surface area of shell wall, adsorbed water molecule on the most more hollow ball wall, on the other hand, hollow ball
Duct on wall, due to capillary effect, also can provide sprawling of passage, beneficially water droplet in entering ball for hydrone, increase figure
The hydrophilic of layer；3rd, hollow ball also can increase light transmittance, it is to avoid because the effect of coating causes the decline of light transmittance.
Preferably, described CaCO3Particle surface coating layer of polyethylene ketopyrrolidine.
This polyvinylpyrrolidone is water-soluble high-molecular compound, can be at CaCO3Particle is protected as one layer of colloid
Material, it is to avoid without CaCO during high-temperature calcination3Particle decomposes in advance.
Preferably, deposition has the high temp glass substrate of described antifogging coating and the contact angle of water droplet less than 3 degree, possesses higher
Hydrophilic and self-cleaning property.
Further preferred, by Fig. 2, the making step of described antifogging coating is as follows:
Step one, prepares CaCO3Particle:
Choose CaCO3Particle, by its ultrasonic cleaning, then takes 3g polyvinylpyrrolidone and joins 100ml deionized water
In, the CaCO after cleaning3Particle adds in deionized water, and the most ultrasonic 30min makes CaCO3Particle surface coats a strata second
Alkene pyrrolidone；
Step 2, prepares SiO2Nanoparticle:
By 5ml ammonia, 100ml dehydrated alcohol joins stirring at normal temperature 10min in conical flask, stirs 2min at 60 DEG C,
The lower dropping 3ml tetraethyl orthosilicate of stirring, continues stirring 12h at 60 DEG C, and obtaining translucent is the solid of 50nm containing particle diameter
SiO2The suspension of nanoparticle；
Step 3, prepares CaCO3/SiO2Composite nanoparticle:
A) by the CaCO of step steady3Particle ultrasonic disperse forms suspension in water, by isopyknic concentration be 1～
The PDDA of 3mg/ml joins in this suspension, magnetic agitation, makes PDDA pass through Coulomb force absorption and is assembled in CaCO3Particle table
Face, centrifugation, supersound washing, remove the PDDA of physical absorption, then the CaCO obtained3Particle is dispersed in water and obtains all
Even scattered suspension；
B) suspension obtained above is joined in PSS aqueous solution, magnetic agitation 3h, centrifugation, supersound washing,
To CaCO3Surface adsorption has the spheroidal particle of polyvinylpyrrolidone, PDDA and PSS, repeat the above steps so that CaCO3Particle
Surface adsorption is uniform；
C) by CaCO obtained above3Particle joins prepared SiO2In the suspension of nanoparticle, magnetic agitation 6
～10h, centrifugation, supersound washing removes unadsorbed SiO2Nanoparticle, repeat the above steps so that SiO2Nanoparticle
At CaCO3Particle surface absorption uniformly, adsorbs twice PDDA/SiO the most again2Nanoparticle, obtains CaCO3/SiO2Compound grain
Son, and SiO2Nanoparticle is three layers；
Step 4, prepares antifogging coating:
A) Substrate treatment, using volume ratio is the 98%H of 7:32SO4And 30%H2O2To high temp glass substrate immersion treatment,
The high temp glass substrate distilled water wash that will process, then dry up with nitrogen；
B) the high temp glass substrate after cleaning alternately is immersed in PDDA and PSS solution, and distilled water wash thing is used in centre
PDDA and PSS of reason absorption, covers until obtaining obtaining 7 layers of PDDA and 6 layers of PSS at high temp glass substrate surface；
C) high temp glass substrate obtained above is immersed in the CaCO that step 3 obtains3/SiO2Compound particle suspension
In, stand 5h, deposit one layer of CaCO at high temp glass substrate surface3/SiO2Compound particle coating, then by this high temp glass base
Sheet is put in Muffle furnace, sinters 10h so that CaCO at 600～850 DEG C3/SiO2CaCO in compound particle3Pyrolytic,
The SiO of coarse structure and pore structure is had to deposition2The high temp glass substrate of hollow ball coating.
Those skilled in the art, after considering description and putting into practice invention disclosed herein, will readily occur to its of the present invention
Its embodiment.The application is intended to any modification, purposes or the adaptations of the present invention, these modification, purposes or
Person's adaptations is followed the general principle of the present invention and includes the undocumented common knowledge in the art of the application
Or conventional techniques means.Description and embodiments is considered only as exemplary, and true scope and spirit of the invention are by following
Claim is pointed out.
It should be appreciated that the invention is not limited in precision architecture described above and illustrated in the accompanying drawings, and
And various modifications and changes can carried out without departing from the scope.The scope of the present invention is only limited by appended claim.
Claims (4)
1. for an illuminating lamp under water, including lamp housing, lampshade and luminescence component, it is characterised in that described lamp housing is cylinder
Shape, described luminescence component is arranged on lamp housing one end, and described lampshade is on described luminescence component, and described lamp housing top and bottom are joined
Top cover and bottom, described top cover and bottom is had to be connected with the locking of described lamp housing by lock-screw.
Illuminating lamp the most according to claim 1, it is characterised in that be provided with sealing gasket between described lamp housing and top cover and bottom
Circle.
Illuminating lamp the most according to claim 2, it is characterised in that described seal washer is waterproof elastic packing packing ring,
Use sealant sealing.
Illuminating lamp the most according to claim 3, it is characterised in that described lampshade is antifog glass substrate.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610709971.2A CN106287413A (en) | 2016-08-22 | 2016-08-22 | A kind of for illuminating lamp under water |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610709971.2A CN106287413A (en) | 2016-08-22 | 2016-08-22 | A kind of for illuminating lamp under water |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106801858A (en) * | 2017-03-16 | 2017-06-06 | 陕西格兰浮实业有限公司 | A kind of underwater laser illuminates light compensating lamp device |
| WO2021147317A1 (en) * | 2020-01-21 | 2021-07-29 | 广州市浩洋电子股份有限公司 | Dustproof and anti-fogging stage lamp |
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| CN102019159A (en) * | 2009-09-17 | 2011-04-20 | 中国科学院理化技术研究所 | Raspberry-shaped polystyrene microsphere/silicon dioxide composite particle and preparation method and application thereof |
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| CN201983125U (en) * | 2011-04-01 | 2011-09-21 | 深圳市宇亮光电技术有限公司 | Landscape LED lamp |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106801858A (en) * | 2017-03-16 | 2017-06-06 | 陕西格兰浮实业有限公司 | A kind of underwater laser illuminates light compensating lamp device |
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