CN106283844A - A kind of environment-friendly type high luster water-proof printing paper and preparation method thereof - Google Patents

A kind of environment-friendly type high luster water-proof printing paper and preparation method thereof Download PDF

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Publication number
CN106283844A
CN106283844A CN201610677152.4A CN201610677152A CN106283844A CN 106283844 A CN106283844 A CN 106283844A CN 201610677152 A CN201610677152 A CN 201610677152A CN 106283844 A CN106283844 A CN 106283844A
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paper
fiber
printing paper
type high
environment
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CN201610677152.4A
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CN106283844B (en
Inventor
顾劲松
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Anhui Wenfeng New Material Technology Co ltd
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Anhui Wenfeng Special Paper Co Ltd
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    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H15/00Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
    • D21H15/02Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
    • D21H15/10Composite fibres
    • D21H15/12Composite fibres partly organic, partly inorganic
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/10Organic non-cellulose fibres
    • D21H13/12Organic non-cellulose fibres from macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H13/14Polyalkenes, e.g. polystyrene polyethylene
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H13/00Pulp or paper, comprising synthetic cellulose or non-cellulose fibres or web-forming material
    • D21H13/36Inorganic fibres or flakes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/21Macromolecular organic compounds of natural origin; Derivatives thereof
    • D21H17/24Polysaccharides
    • D21H17/25Cellulose
    • D21H17/26Ethers thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/20Macromolecular organic compounds
    • D21H17/33Synthetic macromolecular compounds
    • D21H17/34Synthetic macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D21H17/37Polymers of unsaturated acids or derivatives thereof, e.g. polyacrylates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/66Salts, e.g. alums
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/675Oxides, hydroxides or carbonates
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • D21H21/38Corrosion-inhibiting agents or anti-oxidants

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  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paper (AREA)

Abstract

The invention discloses a kind of environment-friendly type high luster water-proof printing paper and preparation method thereof, it is made up of following raw material: hardwood pulp fiber, softwood pulp fiber, styroflex, polypropylene fibre, titania fiber, hydroxyethylmethyl-cellulose, zirconium carbonate ammonium, polyacrylic ester latex, surface conditioning agent, zinc white.The present invention has the advantage that paper has good absorbability and breathability compared to existing technology, utilizes chemical assistant and filler, strengthens the stability of paper internal structure;Styroflex and polypropylene fibre all can be obtained by reclaiming waste material, safety and environmental protection;Surface conditioning agent defines good protective layer at paper surface after mixing with polyacrylic ester latex, improves its oxidation resistance;In the present invention, the printing paper whiteness of preparation is 92%, places invariant color for a long time, prints coloured image glossiness good, reduces the printing fault rate in print procedure, improves work efficiency.

Description

A kind of environment-friendly type high luster water-proof printing paper and preparation method thereof
Technical field
The invention belongs to the processing technique field of extraordinary printing paper, be specifically related to a kind of environment-friendly type high luster water-proof printing paper And preparation method thereof.
Background technology
Universal along with expanding economy and office appliance, the range of printer and printing paper is increasingly wider, different Mimeograph documents also have different requirements to printing paper, and for some colour print files, printing paper is to the resolution of pattern and color Color reducing power is the most important, and the most domestic Related product is relatively fewer, it is therefore desirable to one may be used for colored spray The printing paper of ink, has preferable waterproof effect, it is possible to process good to ink, it is achieved quickly absorb with good color also Former.
Summary of the invention
It is an object of the invention to for existing problem, it is provided that a kind of environment-friendly type high luster water-proof printing paper and preparation thereof Method.
The present invention is achieved by the following technical solutions: a kind of environment-friendly type high luster water-proof printing paper, by following weight The raw material of percentage ratio is made: hardwood pulp fiber 15-20%, softwood pulp fiber 25-30%, styroflex 6-10%, and poly-third Alkene fiber 8-15%, titania fiber 7-12%, hydroxyethylmethyl-cellulose 1-3%, zirconium carbonate ammonium 1-2%, polyacrylic acid ester gum Breast 8-12%, surface conditioning agent 2-3%, zinc white 6-10%;
Wherein, surface conditioning agent by titanate coupling agent TMC-311, heptafluoro-propane, zinc methionine with mass ratio 3:1:1 mixing and Become.
Wherein, the fineness of described styroflex is 50-70TEX, a length of 15-25mm;Described polypropylene fibre Fineness is 22-28TEX, a length of 5-15mm;The fineness of titania fiber is 25-40TEX, a length of 8-20mm.
The preparation method of a kind of environment-friendly type high luster water-proof printing paper, comprises the steps:
(1) pulling an oar after hardwood pulp fiber, the mixing of softwood pulp fiber, beating degree is 13-18 ° of SR, is subsequently adding polyphenyl second Alkene fiber, polypropylene fibre and titania fiber, use pulper dispersion to process 10-15 minute, and mixing speed is 350- 450r/min, obtains composite fibre;
(2) add in above-mentioned composite fibre in the water being equivalent to its weight 4 times, use ultrasound wave dispersal device, at 24-26KHz Under conditions of dispersion process 25-30 minute, after being subsequently adding hydroxyethylmethyl-cellulose, zirconium carbonate ammonium and zinc white, be heated to 50- 55 DEG C, by mechanical dispersion unit, mixed serum is disperseed 6-8 minute, after near room temperature, obtain mixed slurry;
(3) being manufactured paper with pulp by above-mentioned mixed slurry oblique net paper machine, online concentration is 0.03%, the most again under conditions of 100-105 DEG C, Dry 100-150s, obtain body paper semi-finished product;
(4) polyacrylic ester latex, surface conditioning agent are sufficiently mixed and uniformly obtain mixed liquor, above-mentioned body paper semi-finished product are impregnated In mixed liquor, under conditions of 140-155 DEG C, by heat circulating system, face coat is dried gel, obtains finished product.
The present invention has the advantage that styroflex, polypropylene fibre and titania fiber compared to existing technology It is mixed to join in paper pulp with corresponding standard, ultrasound wave dispersal device processes, make obtained paper have good suction The property received and breathability, utilize chemical assistant and filler, strengthens the stability of paper internal structure;Styroflex and poly-third Alkene fiber all can be obtained by reclaiming waste material, safety and environmental protection;Surface conditioning agent mix with polyacrylic ester latex after at paper surface Define good protective layer, improve its oxidation resistance;In the present invention, the printing paper whiteness of preparation is 92%, puts for a long time Put invariant color, print coloured image glossiness good, reduce the printing fault rate in print procedure, improve work efficiency.
Detailed description of the invention
Embodiment 1
A kind of environment-friendly type high luster water-proof printing paper, is made up of the raw material of following percentage by weight: hardwood pulp fiber 18%, pin Leaf wood pulp cellulose 27%, styroflex 8%, polypropylene fibre 12%, titania fiber 10%, hydroxyethylmethyl-cellulose 2%, zirconium carbonate ammonium 2%, polyacrylic ester latex 10%, surface conditioning agent 2%, zinc white 9%;
Wherein, surface conditioning agent by titanate coupling agent TMC-311, heptafluoro-propane, zinc methionine with mass ratio 3:1:1 mixing and Become.
Wherein, the fineness of described styroflex is 50-70TEX, a length of 15-25mm;Described polypropylene fibre Fineness is 22-28TEX, a length of 5-15mm;The fineness of titania fiber is 25-40TEX, a length of 8-20mm.
The preparation method of a kind of environment-friendly type high luster water-proof printing paper, comprises the steps:
(1) pulling an oar after hardwood pulp fiber, the mixing of softwood pulp fiber, beating degree is 13-18 ° of SR, is subsequently adding polyphenyl second Alkene fiber, polypropylene fibre and titania fiber, use pulper dispersion to process 10-15 minute, and mixing speed is 350- 450r/min, obtains composite fibre;
(2) add in above-mentioned composite fibre in the water being equivalent to its weight 4 times, use ultrasound wave dispersal device, at 24-26KHz Under conditions of dispersion process 25-30 minute, after being subsequently adding hydroxyethylmethyl-cellulose, zirconium carbonate ammonium and zinc white, be heated to 50- 55 DEG C, by mechanical dispersion unit, mixed serum is disperseed 6-8 minute, after near room temperature, obtain mixed slurry;
(3) being manufactured paper with pulp by above-mentioned mixed slurry oblique net paper machine, online concentration is 0.03%, the most again under conditions of 100-105 DEG C, Dry 100-150s, obtain body paper semi-finished product;
(4) polyacrylic ester latex, surface conditioning agent are sufficiently mixed and uniformly obtain mixed liquor, above-mentioned body paper semi-finished product are impregnated In mixed liquor, under conditions of 140-155 DEG C, by heat circulating system, face coat is dried gel, obtains finished product.
Embodiment 2
A kind of environment-friendly type high luster water-proof printing paper, is made up of the raw material of following percentage by weight: hardwood pulp fiber 15%, pin Leaf wood pulp cellulose 30%, styroflex 7%, polypropylene fibre 10%, titania fiber 8%, hydroxyethylmethyl-cellulose 3%, Zirconium carbonate ammonium 2%, polyacrylic ester latex 12%, surface conditioning agent 3%, zinc white 10%;
Wherein, surface conditioning agent by titanate coupling agent TMC-311, heptafluoro-propane, zinc methionine with mass ratio 3:1:1 mixing and Become.
Its preparation method is same as in Example 1.
Embodiment 3
A kind of environment-friendly type high luster water-proof printing paper, is made up of the raw material of following percentage by weight: hardwood pulp fiber 20%, pin Leaf wood pulp cellulose 26%, styroflex 7%, polypropylene fibre 12%, titania fiber 12%, hydroxyethylmethyl-cellulose 2%, zirconium carbonate ammonium 1%, polyacrylic ester latex 12%, surface conditioning agent 2%, zinc white 6%;
Wherein, surface conditioning agent by titanate coupling agent TMC-311, heptafluoro-propane, zinc methionine with mass ratio 3:1:1 mixing and Become.
Its preparation method is same as in Example 1.
The printing paper whiteness prepared by method in the present invention is 92%, arranges matched group 1, with hardwood pulp fiber, needlebush Pulp fibres is main material, and other raw materials are same as in Example 1 with preparation method, arranges matched group 2, and surface conditioning agent is conventional Titanate coupling agent, other raw materials are same as in Example 1 with preparation method, detect its performance indications and draw following result:
Group Anti-fracture length (mm) Transversal stretching rate (%) Picking speed (m/s) Opacity (%)
Matched group 1 2500 0.17 1.3 86
Matched group 2 2650 0.16 1.5 88
Embodiment 1 2800 0.22 1.8 87
Embodiment 2 2900 0.23 1.8 88
Embodiment 3 2800 0.22 1.9 89
Table 1
By data in table 1 it can be seen that in the present invention proportioning raw materials and preparation method enhance paper combine and physical property, no Transparency does not has significant change, it is possible to be prevented effectively from the generation phenomenon such as paperboard, curling occur, print coloured image glossiness Good, reduce the printing fault rate in print procedure, improve work efficiency.

Claims (3)

1. an environment-friendly type high luster water-proof printing paper, it is characterised in that be made up of the raw material of following percentage by weight: leaf wood Pulp fibres 15-20%, softwood pulp fiber 25-30%, styroflex 6-10%, polypropylene fibre 8-15%, titanium dioxide is fine Dimension 7-12%, hydroxyethylmethyl-cellulose 1-3%, zirconium carbonate ammonium 1-2%, polyacrylic ester latex 8-12%, surface conditioning agent 2-3%, Zinc white 6-10%;
Wherein, surface conditioning agent by titanate coupling agent TMC-311, heptafluoro-propane, zinc methionine with mass ratio 3:1:1 mixing and Become.
2. a kind of environment-friendly type high luster water-proof printing paper, it is characterised in that described styroflex Fineness is 50-70TEX, a length of 15-25mm;The fineness of described polypropylene fibre is 22-28TEX, a length of 5-15mm;Dioxy The fineness changing titanium fiber is 25-40TEX, a length of 8-20mm.
3. the preparation method of an environment-friendly type high luster water-proof printing paper as claimed in claim 1, it is characterised in that include as follows Step:
(1) pulling an oar after hardwood pulp fiber, the mixing of softwood pulp fiber, beating degree is 13-18 ° of SR, is subsequently adding polyphenyl second Alkene fiber, polypropylene fibre and titania fiber, use pulper dispersion to process 10-15 minute, and mixing speed is 350- 450r/min, obtains composite fibre;
(2) add in above-mentioned composite fibre in the water being equivalent to its weight 4 times, use ultrasound wave dispersal device, at 24-26KHz Under conditions of dispersion process 25-30 minute, after being subsequently adding hydroxyethylmethyl-cellulose, zirconium carbonate ammonium and zinc white, be heated to 50- 55 DEG C, by mechanical dispersion unit, mixed serum is disperseed 6-8 minute, after near room temperature, obtain mixed slurry;
(3) being manufactured paper with pulp by above-mentioned mixed slurry oblique net paper machine, online concentration is 0.03%, the most again under conditions of 100-105 DEG C, Dry 100-150s, obtain body paper semi-finished product;
(4) polyacrylic ester latex, surface conditioning agent are sufficiently mixed and uniformly obtain mixed liquor, above-mentioned body paper semi-finished product are impregnated In mixed liquor, under conditions of 140-155 DEG C, by heat circulating system, face coat is dried gel, obtains finished product.
CN201610677152.4A 2016-08-17 2016-08-17 A kind of environment-friendly type high luster water-proof printing paper and preparation method thereof Active CN106283844B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107034731A (en) * 2017-04-27 2017-08-11 安徽斌欣电子科技有限公司 Write copy paper and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1458337A (en) * 2003-06-02 2003-11-26 岳阳纸业股份有限公司 Color ink-jet print paper and its producing method
JP2006001580A (en) * 2004-06-17 2006-01-05 Tomoegawa Paper Co Ltd Self-adhering tape
CN101974868A (en) * 2010-11-18 2011-02-16 浙江华邦特种纸业有限公司 Method for manufacturing high-breathability non-woven wallpaper body paper and product
CN105568745A (en) * 2015-12-24 2016-05-11 浙江华川实业集团有限公司 Duplicating paper and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1458337A (en) * 2003-06-02 2003-11-26 岳阳纸业股份有限公司 Color ink-jet print paper and its producing method
JP2006001580A (en) * 2004-06-17 2006-01-05 Tomoegawa Paper Co Ltd Self-adhering tape
CN101974868A (en) * 2010-11-18 2011-02-16 浙江华邦特种纸业有限公司 Method for manufacturing high-breathability non-woven wallpaper body paper and product
CN105568745A (en) * 2015-12-24 2016-05-11 浙江华川实业集团有限公司 Duplicating paper and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107034731A (en) * 2017-04-27 2017-08-11 安徽斌欣电子科技有限公司 Write copy paper and preparation method thereof

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Address after: 237200 Mount Holyoke County Economic Development Zone, Lu'an, Anhui

Patentee after: Anhui Wenfeng New Material Technology Co.,Ltd.

Address before: 237200 Mount Holyoke County Economic Development Zone, Lu'an, Anhui

Patentee before: ANHUI WENFENG SPECIAL PAPER Co.,Ltd.