CN108914675A - A kind of high-quality printing dedicated paper manufacturing method of weather-proof waterproof - Google Patents

Abstract

The present invention relates to printed matter consumptive material preparation fields, more particularly to a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof, including preliminary paper pulp is prepared, configuration increasing property auxiliary agent, copy paper slurry is made, prepares paper tire, preparing glue film solution and apply adhesive film correlation step.Paper prepared by the present invention has intensity high, printing effect is excellent, it is water-fast, oil resistant, chemicals-resistant, ageing-resistant, thermal insulation is good, there is certain flame retardant effect, its paper surface is smooth, is not easy warpage is suitable for roll printing, using a large amount of waste paper pulp fiber, resource is saved, paper is light, with certain fluorescence property, it is able to ascend visual effect with paper as advertisement, also there is good antibacterial vermins-proof effect, each addO-on therapy is nontoxic, safety and environmental protection, practical value with higher and good application prospect.

Description

A kind of high-quality printing dedicated paper manufacturing method of weather-proof waterproof

Technical field

The present invention relates to modern paper technical fields, and in particular to a kind of weather-proof high-quality printing dedicated paper manufacturer of waterproof Method.

Background technique

Flyer is commonly called as publicity single page, single page, color page, publicity coloured silk, poster, folding etc..It primarily serves to transmission unit The effect that information is publicized widely.Promotional pamphlet often carries out colored printing using dedicated advertisement paper, now due to the characteristic of its own Printing technology and printing equipment in the field all have evolved into ripe.And it is mentioned with the development of technology with people's living standard Height, the requirement to promotional pamphlet will attract audience as far as possible to play the role of publicity, thus further expansion publicity Effect, and the equal unstressed configuration effect of existing advertisement paper, night attract effect not strong.

Existing advertisement consumptive material manufacturing process has be easy to cause paper surface tension unbalanced simultaneously, and film layer is processed When, it being saturated and moistens by long-time, fibre density changes, paper breadth, the thickness of left, center, right, length, shrink, Stretch it is inconsistent, easy warpage cause made of brush with paper be difficult be suitable for various printing equipments, print content is in use process In be easy to fade, discoloration, and the paper adjacent to its causes to infect, poor waterproof properties, is easy dampness.

On the other hand, existing poster paper largely uses log paper pulp, does not meet national ecological forestry protection and requires, and makes It is easily reduced paper surface sense of touch, poor quality again with regeneration paper material.

Furthermore poster paper has the missing of the bacteria mildew-proofs anthelminthic effect such as Anti-moth-eating, moisture-proof function currently on the market, then It is easy to cause the loss for being difficult to retrieve.

Summary of the invention

In view of the drawbacks of the prior art, the object of the present invention is to provide a kind of weather-proof high-quality printing dedicated paper manufacturers of waterproof The influence that metal ion bleaches paper pulp can be effectively reduced in method, the invention, so that fiber obtains preferable swollen, paper is easier to It is dry, it is furthermore possible to reduce the generation of silk flow phenomenon, improves the intensity of paper, while improving page to the impervious of hydration liquid Saturating power also has good antibacterial vermins-proof effect, and each each component that adds is nontoxic, safety and environmental protection, practical valence with higher Value and good application prospect.

The present invention solves technical problem and adopts the following technical scheme that：

The present invention provides a kind of weather-proof high-quality printing dedicated paper manufacturing methods of waterproof, include the following steps：

Step 1 prepares preliminary paper pulp：

First waste paper pulp fiber is crushed, the dipping by lye 20-30h that concentration is 1.5% is added, side in fiber dissociation device is added and uses Clear water rinses side stirring, then 70-90 parts of the waste paper pulp fiber rinsed well, log are starched 10-20 parts, bleaching sulphur by weight It being handled after 20-30 parts of addition hydrabrusher fibrosis of hydrochlorate softwood pulp by conical refiner, beating degree is 22-24 ° of SR, Refining concentration is 4-6wt%, is uniformly mixed to fibre stuff, and the 2-3% curing slurry for accounting for fiber pulp weight is added, stirs It is even, obtain preliminary paper pulp；

The curing slurry is that water-bath heat treatment 60- in dilute mineral acid solution is added in the palygorskite that will be purified 70min, temperature are 80-90 DEG C, then lauryl sodium sulfate is added into the suspension after acidification and is sufficiently stirred, and cooperate with ultrasonic water After thermal method handles 80-100min, high speed centrifugation processing is then carried out to it, centrifugal rotational speed 6000-8000r/min, when centrifugation Between be 10-12min, be dehydrated after centrifugation, it is dry after the powder after drying is placed in chamber type electric resistance furnace, temperature is set as 500 DEG C, it roasts 2-3 hours, then takes out, add the coupling agent of powder quality 1-2%, agitation grinding at being 50-60 DEG C in temperature, 1000 mesh are crossed, the powder after grinding is mixed with deionized water, the curing slurry that mass concentration is 7-9% is made；

Step 2, configuration increasing property auxiliary agent：Graphene quantum dot, nano silica and nano-titanium dioxide are pressed according to weight ratio According to weight ratio 8:1:It is uniformly mixing to obtain mixture in 1 addition blender, then the beet for accounting for its weight 5% is added into mixture Alkali, 10% phosphate ester starch and 5% sodium carboxymethylcellulose are stirred to obtain increasing property auxiliary agent；

The graphene quantum dot is the single-layer graphene oxide quantum dot prepared using microwave stripping method；

The increasing auxiliary agent for accounting for its quality 1% is added into the preliminary paper pulp of step 1 preparation for step 3, is sent into PFI mill, continues Mashing, adds the conventional additive for papermaking including drying strengthening agent, wet strength agent, retention and drainage aid agent, obtains copy paper slurry；

Obtained copy paper slurry is carried out copy paper with twin-wire paper-machine by step 4, sequentially entered after pulp flow to head case wet end, Press section and drying section are dried in drying section, obtain paper tire；

Squeeze water is divided into 55wt% out when the twin-wire paper-machine is squeezed；

The drying section uses more cylinder drieds, controls surface temperature of drier curve, and gently dried ensures that page two sides difference is small：It presses According to paper feed direction, dryer temperature is since first 70-75 DEG C of dryer temperature according to latter dryer temperature than previous dryer temperature Rise 8-10 DEG C and be incremented to 110-120 DEG C, rises 6-8 DEG C than previous drying cylinder according still further to latter dryer temperature and be decremented to 80-85 DEG C, It after control paper fetal fluids is divided into 3-6wt%, reuses more cooling cylinders and ornamenting is carried out to paper, make that paper is smooth, paper tire is smooth；

Step 5 prepares glue film solution：In parts by weight, by 10-20 parts of chitosans, 5-9 parts of sodium alginates, 4-6 parts of gelatine, 2- 4 portions of galactomannans, 1-2 parts of alumino-silicates are placed in reaction kettle, and 150-200 parts of water is added, is filled with into reaction kettle Steam carries out heating stirring, and mixing time is 30-40 minutes；Water stirring and adjusting colloid concentration is re-injected to 6%, keeps colloid Temperature be 50 DEG C, sequentially add 5-7 parts of vinylite, 2-3 parts of polyvinyl alcohol, 0.8-1.2 parts of aluminium hydroxide and boric acid 0.4-0.6 parts and trimethylglycine 0.1-0.3 parts of zinc, under the driving of speed regulating motor, by mixing liquid after grinding 0.5 hour 80 DEG C are heated to, 1-2 parts of adhesion promoters are added and are mixed, 0.05 part of noble metal quantum dot is added and is mixed, obtain To glue film liquid；

Step 6 applies adhesive film, the glue film solution that step 5 prepares is carried out spraying sizing on paper tire prepared by step 4, Sizing butt amount is 8.2-8.6g/m²；It is sent into baking oven and carries out drying and processing, the temperature in baking oven is from 20 DEG C on 5 DEG C per minute 90 DEG C are risen to, and is being kept for 90 DEG C 5-7 minutes, by the paper after drying, is formed and eliminates using Vacuum shaping plate cooling down The high-quality paper of environmental protection that cutting is made of the invention is carried out after tension.

Preferably, the preparation method of the noble metal quantum dot is：Salt by weight by 7-9 parts containing noble metal is added It in the isopropanol of 30-40 parts of mass fractions 80%, is sufficiently stirred at room temperature, then 1.25-1.45 parts of ammonia is added into reaction system Water stirs evenly, and adds 0.02-0.04 parts of ethylenediamines, sodium citrate aqueous solutions, is put into hydrothermal reaction kettle and stirs 20-30 points Clock adds 0.5-1.5 parts of polyvinylpyrrolidone and 0.8-1.2 parts of ethyl orthosilicates, with ultrasonication 15-18min, It is passed through helium protection, back flow reaction 2-3 hours at 180-200 DEG C, then reaction vessel is placed in 0 DEG C of water and is quenched 5-7 points Clock, then be collected by centrifugation by centrifuge, at the same be put into after being washed with deionized in baking oven be 70-80 DEG C in temperature at dry To noble metal quantum dot；

The salt containing noble metal is AgNO₃、PdCl₂And ZnSO₄According to weight ratio 4:2:The mixture of 1 composition.

Preferably, in the step 6 be sent into baking oven drying before will spraying sizing after paper temperature be 110 DEG C and Pressure is hot pressing 7-9s under 50N.

Preferably, the drying strengthening agent in the step 3 is XQ-07 paper dry strength dose, and wet strength agent is PAE papermaking Wet strength agent, retention and drainage aid agent are polyacrylamide retention and drainage aid agent.

Preferably, which is characterized in that 1-2 parts of Plant Fungicides are also added in the glue film solution；

The preparation method of the Plant Fungicide is：By perilla leaf, Radix Glycyrrhizae, Radix Isatidis, Dalmatian chrysanthemum, Folium Forsythia, folium artemisiae argyi, polygonum cuspidate It is separately added into high speed disintegrator and crushes, then be separately added into extractor, be separately added into organic solvent, refluxing extraction 2-4 times, every time It extracts 1-3 hours, organic solvent is recovered under reduced pressure in combined extract, obtains Plant Fungicide.

Preferably, the phosphate ester starch that the step 2 is added also is modified by following steps：

By phosphate ester starch first under limited oxygen condition, 90 DEG C are warming up to the speed of 6 DEG C/min, 10min is kept the temperature, is subsequently cooled to Room temperature carries out Low Temperature Plasma Treating, and processing gas is oxygen, and pressure 200Pa, the processing time is 20-30s.

Preferably, the reinforcing fiber slurry for accounting for the preliminary pulp quality 1% of step 1 preparation is also added in the step 3；

The preparation method of the reinforcing fiber is：The bamboo material section got ready is sent into boiling vessel, using low temperature double tower continuous steaming-boiling 1kg/adt digesting assistant is added by bamboo material section OD wt. basis in skill, under the conditions of boiling temperature is 150 DEG C, continuously cooking 3-4 Hour, it is scattered in slightly being starched after boiling in dimethylacetamide solution, the alkali of bamboo material section oven dry weight 15%, sulphidity is added 22%, then 170 DEG C are warming up to, it back flow reaction 30-36 hours, filters, washing obtains stoste, send to spinning machine, pass through metering pump Then metering enters spinning head through candle filter, connecting tube；Reinforcing fiber is made in the stoste thread extruded from spinneret eyelet Slurry.

Preferably, the high-quality printing dedicated paper manufacturing method of the weather-proof waterproof includes the following steps：

Step 1 prepares preliminary paper pulp：

First waste paper pulp fiber is crushed, the dipping by lye 25h that concentration is 1.5% is added, side clear water in fiber dissociation device is added Side stirring is rinsed, then 80 parts of the waste paper pulp fiber rinsed well, log are starched into 15 parts, bleached sulphate needlebush by weight It is handled after starching 25 parts of addition hydrabrusher fibrosis by conical refiner, beating degree is 22-24 ° of SR, refining concentration 4- 6wt% is uniformly mixed to fibre stuff, and the 2.5% curing slurry for accounting for fiber pulp weight is added, stirs evenly, obtains preliminary Paper pulp；

The curing slurry is that water-bath heat treatment 65min in dilute mineral acid solution is added in the palygorskite that will be purified, Temperature is 85 DEG C, then lauryl sodium sulfate is added into the suspension after acidification and is sufficiently stirred, collaboration supersonic, water-heating method processing After 90min, high speed centrifugation processing is then carried out to it, centrifugal rotational speed 7000r/min, centrifugation time 11min take off after centrifugation The powder after drying is placed in chamber type electric resistance furnace after water, drying, temperature is set as 500 DEG C, roasts 2.5 hours, then takes Out, add powder quality 1.5% coupling agent, temperature be 55 DEG C at agitation grinding, cross 1000 mesh, by after grinding powder with Deionized water is mixed, and the curing slurry that mass concentration is 8% is made；

Step 2, configuration increasing property auxiliary agent：Graphene quantum dot, nano silica and nano-titanium dioxide are pressed according to weight ratio According to weight ratio 8:1:It is uniformly mixing to obtain mixture in 1 addition blender, then the beet for accounting for its weight 5% is added into mixture Alkali, 10% phosphate ester starch and 5% sodium carboxymethylcellulose are stirred to obtain increasing property auxiliary agent；

The graphene quantum dot is the single-layer graphene oxide quantum dot prepared using microwave stripping method；

The increasing auxiliary agent for accounting for its quality 1% is added into the preliminary paper pulp of step 1 preparation for step 3, is sent into PFI mill, continues Mashing, adds the conventional additive for papermaking including drying strengthening agent, wet strength agent, retention and drainage aid agent, obtains copy paper slurry；

Obtained copy paper slurry is carried out copy paper with twin-wire paper-machine by step 4, sequentially entered after pulp flow to head case wet end, Press section and drying section are dried in drying section, obtain paper tire；

Squeeze water is divided into 55wt% out when the twin-wire paper-machine is squeezed；

The drying section uses more cylinder drieds, controls surface temperature of drier curve, and gently dried ensures that page two sides difference is small：It presses According to paper feed direction, dryer temperature is since first 70-75 DEG C of dryer temperature according to latter dryer temperature than previous dryer temperature Rise 8-10 DEG C and be incremented to 110-120 DEG C, rises 6-8 DEG C than previous drying cylinder according still further to latter dryer temperature and be decremented to 80-85 DEG C, It after control paper fetal fluids is divided into 3-6wt%, reuses more cooling cylinders and ornamenting is carried out to paper, make that paper is smooth, paper tire is smooth；

Step 5 prepares glue film solution：In parts by weight, 15 parts of chitosans, 7 parts of sodium alginates, 5 parts of gelatine, 3 portions of galas are sweet Dew glycan, 1.5 parts of alumino-silicates are placed in reaction kettle, and 180 parts of water is added, and steam is filled with into reaction kettle carries out heating and stir It mixes, mixing time is 35 minutes；Water stirring and adjusting colloid concentration is re-injected to 6%, keeping the temperature of colloid is 50 DEG C, then according to 0.5 part of secondary 6 parts of addition vinylite, 2.5 parts of polyvinyl alcohol, 1 part of aluminium hydroxide and zinc borate and trimethylglycine 0.2 Part, under the driving of speed regulating motor, mixing liquid is heated to 80 DEG C after grinding 0.5 hour, 1.5 parts of adhesion promoters are added It is mixed, adds 0.05 part of noble metal quantum dot and be mixed, obtain glue film liquid；

Step 6 applies adhesive film, the glue film solution that step 5 prepares is carried out spraying sizing on paper tire prepared by step 4, Sizing butt amount is 8.2-8.6g/m²；It is sent into baking oven and carries out drying and processing, the temperature in baking oven is from 20 DEG C on 5 DEG C per minute 90 DEG C are risen to, and is being kept for 90 DEG C 6 minutes, by the paper after drying, is formed and is eliminated using Vacuum shaping plate cooling down and opened The high-quality paper of environmental protection that cutting is made of the invention is carried out after power.

Compared with prior art, the present invention has following beneficial effect：

Waste paper pulp fibrous material is largely used in preliminary paper pulp of the invention, reduce to magma slurrying link water pollution and Other energy usage amounts, reduce the dependence to wood pulp, alleviate the pressure of deforestation and environmental protection, and to waste and old fibre It ties up material and carries out dipping by lye dissociation so that fiber silk structure is more bulk, be preferably crosslinked with other wood pulp celluloses, it is real The intertexture for having showed different structure cellulose enhances the intensity that the later period prepares paper, effectively increases the surface smoothness of paper, It is creative palygorskite is modified after be added into paper pulp, on the one hand its modified suspension has preferable stream Denaturation and wall built-up, can effective fiberfill fibers gap, improve paper surface smoothness, while palygorskite hollow fiber Structure, other mineral that compare are lighter so that paper area is larger under unit mass thickness, effectively enhance paper toughness and Tearing toughness improves the mechanical property of paper；

Furthermore the increasing auxiliary agent of present invention addition creative in paper preparation process is mainly by graphene quantum dot and nanometer Silica, nano-titanium dioxide composition have excellent water by single-layer graphene oxide quantum dot prepared by microwave stripping method Dissolubility, chemical inertness and good surface modification function, the light shine that raising paper can be combined with nano-titanium dioxide are old The property changed, enhances the planarization of paper surface, additionally it is possible to it is effectively conducted heat when printing, so that paper surface is not easy warpage, The silica of addition can effectively improve the bonding force of paper-making fibre, improve the folding resistance and mechanical property of paper；

The film adhesive body that the glue film solution of advertisement paper configuration of the invention is formed on paper tire can prevent ink in paper table The diffusion and permeability in face guarantee that it does not allow fugitive color in use, discoloration, and the paper adjacent to its not will cause and invade Dye, improve consumptive material surface waterproof performance, the excellent amalgamation of the noble metal quantum dot of addition so that its addition in film liquid with Paper consumptive material is tightly combined smooth, on the one hand enables to advertisement consumptive material to have preferable fluorescent effect, improves the viewing of user Effect, on the other hand it can be improved the excellent performances such as the high thermal conductivity heat dissipation on consumptive material surface, effectively reduce dry and printing Paper injustice warpage caused by uneven heating in the process, in addition there are faint electric conductivities, improve printing effect；

Aluminium hydroxide and the zinc borate synergistic effect also added in glue application solution of the present invention enable to paper to have certain fire resisting Flame retardant property, the Plant Fungicide perilla leaf of addition, Radix Glycyrrhizae, Radix Isatidis, Dalmatian chrysanthemum, Folium Forsythia, folium artemisiae argyi, polygonum cuspidate, collaboration Effect is so that paper has the preferable anti-risk performance sterilized suppression worm effect, substantially increase when paper storage, vegetalitas Raw material can reduce damage of the chemical bactericide to human body, environmentally protective；

When sizing step that the present invention uses and technological parameter selected avoids film layer processing in the prior art through it is too long when Between be saturated wet so that fibre density changes, the present invention is by spraying and controlling the control of sizing butt amount, and to baking oven The repeatability controlling test of temperature change has obtained under rate temperature change of the invention, improves glue film liquid and paper tire base The combination of layer, reduces influence of the temperature change to paper surface tension, so that the advertisement consumptive material prepared has better heatproof Variability and leakproofness are spent, while reducing existing cumbersome preparation process, reduces 10% or more power consumption.

Specific embodiment

Combined with specific embodiments below, technical scheme in the embodiment of the invention is clearly and completely described, shows So, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the reality in the present invention Example is applied, every other embodiment obtained by those of ordinary skill in the art without making creative efforts all belongs to In the scope of protection of the invention.

Embodiment 1.

A kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof of the present embodiment, includes the following steps：

Step 1 prepares preliminary paper pulp：

First waste paper pulp fiber is crushed, the dipping by lye 20h that concentration is 1.5% is added, side clear water in fiber dissociation device is added Side stirring is rinsed, then 70 parts of the waste paper pulp fiber rinsed well, log are starched into 10 parts, bleached sulphate needlebush by weight It starches and is handled by conical refiner after 20 parts of addition hydrabrusher fibrosis, beating degree is 22 ° of SR, refining concentration 4wt%, It is uniformly mixed to fibre stuff, the 2% curing slurry for accounting for fiber pulp weight is added, stirs evenly, obtains preliminary paper pulp；

The curing slurry is that water-bath heat treatment 60min in dilute mineral acid solution is added in the palygorskite that will be purified, Temperature is 80 DEG C, then lauryl sodium sulfate is added into the suspension after acidification and is sufficiently stirred, collaboration supersonic, water-heating method processing After 80min, high speed centrifugation processing is then carried out to it, centrifugal rotational speed 6000r/min, centrifugation time 10min take off after centrifugation The powder after drying is placed in chamber type electric resistance furnace after water, drying, temperature is set as 500 DEG C, and it roasts 2 hours, then takes out, Add powder quality 1% coupling agent, temperature be 50 DEG C at agitation grinding, cross 1000 mesh, by after grinding powder and go from Sub- water is mixed, and the curing slurry that mass concentration is 7% is made；

Step 2, configuration increasing property auxiliary agent：Graphene quantum dot, nano silica and nano-titanium dioxide are pressed according to weight ratio According to weight ratio 8:1:It is uniformly mixing to obtain mixture in 1 addition blender, then the beet for accounting for its weight 5% is added into mixture Alkali, 10% phosphate ester starch and 5% sodium carboxymethylcellulose are stirred to obtain increasing property auxiliary agent；

The graphene quantum dot is the single-layer graphene oxide quantum dot prepared using microwave stripping method；

The increasing auxiliary agent for accounting for its quality 1% is added into the preliminary paper pulp of step 1 preparation for step 3, is sent into PFI mill, continues Mashing, adds the conventional additive for papermaking including drying strengthening agent, wet strength agent, retention and drainage aid agent, obtains copy paper slurry；

Obtained copy paper slurry is carried out copy paper with twin-wire paper-machine by step 4, sequentially entered after pulp flow to head case wet end, Press section and drying section are dried in drying section, obtain paper tire；

Step 5 prepares glue film solution：In parts by weight, 10 parts of chitosans, 5 parts of sodium alginates, 4 parts of gelatine, 2 portions of galas are sweet Dew glycan, 1 part of alumino-silicate are placed in reaction kettle, and 150 parts of water is added, and steam is filled with into reaction kettle carries out heating and stir It mixes, mixing time is 30 minutes；Water stirring and adjusting colloid concentration is re-injected to 6%, keeping the temperature of colloid is 50 DEG C, then according to 0.4 part of secondary 5 parts of addition vinylite, 2 parts of polyvinyl alcohol, 0.8 part of aluminium hydroxide and zinc borate and trimethylglycine 0.1 Part, under the driving of speed regulating motor, mixing liquid is heated to 80 DEG C after grinding 0.5 hour, it is mixed that 1 part of adhesion promoter is added Stirring is closed, 0.05 part of noble metal quantum dot is added and is mixed, obtain glue film liquid；

Step 6 applies adhesive film, the glue film solution that step 5 prepares is carried out spraying sizing on paper tire prepared by step 4, Sizing butt amount is 8.2g/m²；It is sent into baking oven and carries out drying and processing, the temperature in baking oven is risen to from 20 DEG C with 5 DEG C per minute 90 DEG C, and kept for 90 DEG C 5 minutes, by the paper after drying, after being formed using Vacuum shaping plate cooling down and eliminate tension Carry out the high-quality paper of environmental protection that cutting is made of the invention.

Squeeze water is divided into 55wt% out when twin-wire paper-machine is squeezed in the present embodiment；

The drying section uses more cylinder drieds, controls surface temperature of drier curve, and gently dried ensures that page two sides difference is small：It presses According to paper feed direction, dryer temperature rises according to latter dryer temperature than previous dryer temperature since first 70 DEG C of dryer temperature 8 DEG C are incremented to 110 DEG C, rise 6 DEG C than previous drying cylinder according still further to latter dryer temperature and are decremented to 80 DEG C, control paper fetal fluids is divided into 3- 6wt%.

Paper fetal fluids sub-control system carries out ornamenting to paper using more cooling cylinders, keeps paper flat after 3-6wt% in the present embodiment Cunning, paper tire are smooth.

The preparation method of noble metal quantum dot is in the present embodiment：Salt by weight by 7 parts containing noble metal is added 30 parts It in the isopropanol of mass fraction 80%, is sufficiently stirred at room temperature, then 1.25 parts of ammonium hydroxide is added into reaction system and stir evenly, 0.02 part of ethylenediamine, sodium citrate aqueous solution are added, is put into hydrothermal reaction kettle and stirs 20 minutes, add 0.5 part of poly- second Vinyl pyrrolidone and 0.8 part of ethyl orthosilicate are passed through helium protection with ultrasonication 15min, flow back at 180 DEG C anti- It answers 2 hours, then reaction vessel is placed in 0 DEG C of water and is quenched 5 minutes, then is collected by centrifugation by centrifuge, while using deionization Be put into after water washing in baking oven temperature be 70 DEG C at drying obtain noble metal quantum dot；

The salt containing noble metal is AgNO₃、PdCl₂And ZnSO₄According to weight ratio 4:2:The mixture of 1 composition.

In step six in the present embodiment be sent into baking oven drying before will spraying sizing after paper temperature be 110 DEG C and Pressure is hot pressing 7s under 50N.

Drying strengthening agent in the present embodiment step 3 is XQ-07 paper dry strength dose, and wet strength agent is that PAE papermaking is wet strong Agent, retention and drainage aid agent are polyacrylamide retention and drainage aid agent.

1 part of Plant Fungicide is also added in glue film solution in the present embodiment；

The preparation method of the Plant Fungicide is：By perilla leaf, Radix Glycyrrhizae, Radix Isatidis, Dalmatian chrysanthemum, Folium Forsythia, folium artemisiae argyi, polygonum cuspidate It is separately added into high speed disintegrator and crushes, then be separately added into extractor, be separately added into organic solvent, refluxing extraction 2-4 times, every time It extracts 1-3 hours, organic solvent is recovered under reduced pressure in combined extract, obtains Plant Fungicide.

The phosphate ester starch that step two in the present embodiment is added also is modified by following steps：

By phosphate ester starch first under limited oxygen condition, 90 DEG C are warming up to the speed of 6 DEG C/min, 10min is kept the temperature, is subsequently cooled to Room temperature carries out Low Temperature Plasma Treating, and processing gas is oxygen, and pressure 200Pa, the processing time is 20-30s.

The reinforcing fiber slurry for accounting for the preliminary pulp quality 1% of step 1 preparation is also added in step three in the present embodiment；

The preparation method of the reinforcing fiber is：The bamboo material section got ready is sent into boiling vessel, using low temperature double tower continuous steaming-boiling 1kg/adt digesting assistant is added by bamboo material section OD wt. basis in skill, under the conditions of boiling temperature is 150 DEG C, continuously cooking 3-4 Hour, it is scattered in slightly being starched after boiling in dimethylacetamide solution, the alkali of bamboo material section oven dry weight 15%, sulphidity is added 22%, then 170 DEG C are warming up to, it back flow reaction 30-36 hours, filters, washing obtains stoste, send to spinning machine, pass through metering pump Then metering enters spinning head through candle filter, connecting tube；Reinforcing fiber is made in the stoste thread extruded from spinneret eyelet Slurry.

Embodiment 2.

A kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof of the present embodiment, includes the following steps：

Step 1 prepares preliminary paper pulp：

First waste paper pulp fiber is crushed, the dipping by lye 30h that concentration is 1.5% is added, side clear water in fiber dissociation device is added Side stirring is rinsed, then 90 parts of the waste paper pulp fiber rinsed well, log are starched into 20 parts, bleached sulphate needlebush by weight It starches and is handled by conical refiner after 30 parts of addition hydrabrusher fibrosis, beating degree is 24 ° of SR, refining concentration 6wt%, It is uniformly mixed to fibre stuff, the 3% curing slurry for accounting for fiber pulp weight is added, stirs evenly, obtains preliminary paper pulp；

The curing slurry is that water-bath heat treatment 70min in dilute mineral acid solution is added in the palygorskite that will be purified, Temperature is 90 DEG C, then lauryl sodium sulfate is added into the suspension after acidification and is sufficiently stirred, collaboration supersonic, water-heating method processing After 100min, high speed centrifugation processing, centrifugal rotational speed 8000r/min, centrifugation time 12min, after centrifugation are then carried out to it Dehydration, it is dry after the powder after drying is placed in chamber type electric resistance furnace, temperature is set as 500 DEG C, roasts 2-3 hours, then Take out, add powder quality 2% coupling agent, temperature be 60 DEG C at agitation grinding, cross 1000 mesh, by after grinding powder with Deionized water is mixed, and the curing slurry that mass concentration is 9% is made；

Step 2, configuration increasing property auxiliary agent：Graphene quantum dot, nano silica and nano-titanium dioxide are pressed according to weight ratio According to weight ratio 8:1:It is uniformly mixing to obtain mixture in 1 addition blender, then the beet for accounting for its weight 5% is added into mixture Alkali, 10% phosphate ester starch and 5% sodium carboxymethylcellulose are stirred to obtain increasing property auxiliary agent；

The graphene quantum dot is the single-layer graphene oxide quantum dot prepared using microwave stripping method；

The increasing auxiliary agent for accounting for its quality 1% is added into the preliminary paper pulp of step 1 preparation for step 3, is sent into PFI mill, continues Mashing, adds the conventional additive for papermaking including drying strengthening agent, wet strength agent, retention and drainage aid agent, obtains copy paper slurry；

Obtained copy paper slurry is carried out copy paper with twin-wire paper-machine by step 4, sequentially entered after pulp flow to head case wet end, Press section and drying section are dried in drying section, obtain paper tire；

Step 5 prepares glue film solution：In parts by weight, 20 parts of chitosans, 9 parts of sodium alginates, 6 parts of gelatine, 4 portions of galas are sweet Dew glycan, 2 parts of alumino-silicates are placed in reaction kettle, and 200 parts of water is added, and steam is filled with into reaction kettle carries out heating and stir It mixes, mixing time is 40 minutes；Water stirring and adjusting colloid concentration is re-injected to 6%, keeping the temperature of colloid is 50 DEG C, then according to 0.6 part of secondary 7 parts of addition vinylite, 3 parts of polyvinyl alcohol, 1.2 parts of aluminium hydroxide and zinc borate and trimethylglycine 0.3 Part, under the driving of speed regulating motor, mixing liquid is heated to 80 DEG C after grinding 0.5 hour, it is mixed that 2 parts of adhesion promoters are added Stirring is closed, 0.05 part of noble metal quantum dot is added and is mixed, obtain glue film liquid；

Step 6 applies adhesive film, the glue film solution that step 5 prepares is carried out spraying sizing on paper tire prepared by step 4, Sizing butt amount is 8.6g/m²；It is sent into baking oven and carries out drying and processing, the temperature in baking oven is risen to from 20 DEG C with 5 DEG C per minute 90 DEG C, and kept for 90 DEG C 7 minutes, by the paper after drying, after being formed using Vacuum shaping plate cooling down and eliminate tension Carry out the high-quality paper of environmental protection that cutting is made of the invention.

Squeeze water is divided into 55wt% out when twin-wire paper-machine is squeezed in the present embodiment；

The drying section uses more cylinder drieds, controls surface temperature of drier curve, and gently dried ensures that page two sides difference is small：It presses According to paper feed direction, dryer temperature rises according to latter dryer temperature than previous dryer temperature since first 75 DEG C of dryer temperature 10 DEG C are incremented to 120 DEG C, rise 8 DEG C than previous drying cylinder according still further to latter dryer temperature and are decremented to 85 DEG C, control paper fetal fluids is divided into 3-6wt%.

Paper fetal fluids sub-control system carries out ornamenting to paper using more cooling cylinders, keeps paper flat after 3-6wt% in the present embodiment Cunning, paper tire are smooth.

The preparation method of noble metal quantum dot is in the present embodiment：Salt by weight by 9 parts containing noble metal is added 40 parts It in the isopropanol of mass fraction 80%, is sufficiently stirred at room temperature, then 1.45 parts of ammonium hydroxide is added into reaction system and stir evenly, then 0.04 part of ethylenediamine, sodium citrate aqueous solution is added, is put into hydrothermal reaction kettle and stirs 30 minutes, add 1.5 parts of polyethylene Base pyrrolidones and 1.2 parts of ethyl orthosilicates are passed through helium protection, the back flow reaction 3 at 200 DEG C with ultrasonication 18min Hour, then reaction vessel is placed in 0 DEG C of water and is quenched 7 minutes, then is collected by centrifugation by centrifuge, it is washed with deionized water simultaneously Be put into after washing in baking oven temperature be 70-80 DEG C at drying obtain noble metal quantum dot；

The salt containing noble metal is AgNO₃、PdCl₂And ZnSO₄According to weight ratio 4:2:The mixture of 1 composition.

In step six in the present embodiment be sent into baking oven drying before will spraying sizing after paper temperature be 110 DEG C and Pressure is hot pressing 9s under 50N.

Drying strengthening agent in the present embodiment step 3 is XQ-07 paper dry strength dose, and wet strength agent is that PAE papermaking is wet strong Agent, retention and drainage aid agent are polyacrylamide retention and drainage aid agent.

2 parts of Plant Fungicides are also added in glue film solution in the present embodiment；

The preparation method of the Plant Fungicide is：By perilla leaf, Radix Glycyrrhizae, Radix Isatidis, Dalmatian chrysanthemum, Folium Forsythia, folium artemisiae argyi, polygonum cuspidate It is separately added into high speed disintegrator and crushes, then be separately added into extractor, be separately added into organic solvent, refluxing extraction 2-4 times, every time It extracts 1-3 hours, organic solvent is recovered under reduced pressure in combined extract, obtains Plant Fungicide.

The phosphate ester starch that step two in the present embodiment is added also is modified by following steps：

By phosphate ester starch first under limited oxygen condition, 90 DEG C are warming up to the speed of 6 DEG C/min, 10min is kept the temperature, is subsequently cooled to Room temperature carries out Low Temperature Plasma Treating, and processing gas is oxygen, and pressure 200Pa, the processing time is 30s.

The reinforcing fiber slurry for accounting for the preliminary pulp quality 1% of step 1 preparation is also added in step three in the present embodiment；

The preparation method of the reinforcing fiber is：The bamboo material section got ready is sent into boiling vessel, using low temperature double tower continuous steaming-boiling 1kg/adt digesting assistant is added by bamboo material section OD wt. basis in skill, under the conditions of boiling temperature is 150 DEG C, continuously cooking 3-4 Hour, it is scattered in slightly being starched after boiling in dimethylacetamide solution, the alkali of bamboo material section oven dry weight 15%, sulphidity is added 22%, then 170 DEG C are warming up to, it back flow reaction 36 hours, filters, washing obtains stoste, send to spinning machine, passes through metering pump meter Then amount enters spinning head through candle filter, connecting tube；Reinforcing fiber slurry is made in the stoste thread extruded from spinneret eyelet Material.

Embodiment 3.

A kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof of the present embodiment, includes the following steps：

Step 1 prepares preliminary paper pulp：

First waste paper pulp fiber is crushed, the dipping by lye 25h that concentration is 1.5% is added, side clear water in fiber dissociation device is added Side stirring is rinsed, then 80 parts of the waste paper pulp fiber rinsed well, log are starched into 15 parts, bleached sulphate needlebush by weight It is handled after starching 25 parts of addition hydrabrusher fibrosis by conical refiner, beating degree is 22-24 ° of SR, refining concentration 4- 6wt% is uniformly mixed to fibre stuff, and the 2.5% curing slurry for accounting for fiber pulp weight is added, stirs evenly, obtains preliminary Paper pulp；

The curing slurry is that water-bath heat treatment 65min in dilute mineral acid solution is added in the palygorskite that will be purified, Temperature is 85 DEG C, then lauryl sodium sulfate is added into the suspension after acidification and is sufficiently stirred, collaboration supersonic, water-heating method processing After 90min, high speed centrifugation processing is then carried out to it, centrifugal rotational speed 7000r/min, centrifugation time 11min take off after centrifugation The powder after drying is placed in chamber type electric resistance furnace after water, drying, temperature is set as 500 DEG C, roasts 2.5 hours, then takes Out, add powder quality 1.5% coupling agent, temperature be 55 DEG C at agitation grinding, cross 1000 mesh, by after grinding powder with Deionized water is mixed, and the curing slurry that mass concentration is 8% is made；

Step 2, configuration increasing property auxiliary agent：Graphene quantum dot, nano silica and nano-titanium dioxide are pressed according to weight ratio According to weight ratio 8:1:It is uniformly mixing to obtain mixture in 1 addition blender, then the beet for accounting for its weight 5% is added into mixture Alkali, 10% phosphate ester starch and 5% sodium carboxymethylcellulose are stirred to obtain increasing property auxiliary agent；

The graphene quantum dot is the single-layer graphene oxide quantum dot prepared using microwave stripping method；

The increasing auxiliary agent for accounting for its quality 1% is added into the preliminary paper pulp of step 1 preparation for step 3, is sent into PFI mill, continues Mashing, adds the conventional additive for papermaking including drying strengthening agent, wet strength agent, retention and drainage aid agent, obtains copy paper slurry；

Obtained copy paper slurry is carried out copy paper with twin-wire paper-machine by step 4, sequentially entered after pulp flow to head case wet end, Press section and drying section are dried in drying section, obtain paper tire；

Step 5 prepares glue film solution：In parts by weight, 15 parts of chitosans, 7 parts of sodium alginates, 5 parts of gelatine, 3 portions of galas are sweet Dew glycan, 1.5 parts of alumino-silicates are placed in reaction kettle, and 180 parts of water is added, and steam is filled with into reaction kettle carries out heating and stir It mixes, mixing time is 35 minutes；Water stirring and adjusting colloid concentration is re-injected to 6%, keeping the temperature of colloid is 50 DEG C, then according to 0.5 part of secondary 6 parts of addition vinylite, 2.5 parts of polyvinyl alcohol, 1 part of aluminium hydroxide and zinc borate and trimethylglycine 0.2 Part, under the driving of speed regulating motor, mixing liquid is heated to 80 DEG C after grinding 0.5 hour, 1.5 parts of adhesion promoters are added It is mixed, adds 0.05 part of noble metal quantum dot and be mixed, obtain glue film liquid；

Step 6 applies adhesive film, the glue film solution that step 5 prepares is carried out spraying sizing on paper tire prepared by step 4, Sizing butt amount is 8.2-8.6g/m²；It is sent into baking oven and carries out drying and processing, the temperature in baking oven is from 20 DEG C on 5 DEG C per minute 90 DEG C are risen to, and is being kept for 90 DEG C 6 minutes, by the paper after drying, is formed and is eliminated using Vacuum shaping plate cooling down and opened The high-quality paper of environmental protection that cutting is made of the invention is carried out after power.

Squeeze water is divided into 55wt% out when twin-wire paper-machine is squeezed in the present embodiment；

The drying section uses more cylinder drieds, controls surface temperature of drier curve, and gently dried ensures that page two sides difference is small：It presses According to paper feed direction, dryer temperature is since first 70-75 DEG C of dryer temperature according to latter dryer temperature than previous dryer temperature Rise 8-10 DEG C and be incremented to 110-120 DEG C, rises 6-8 DEG C than previous drying cylinder according still further to latter dryer temperature and be decremented to 80-85 DEG C, Control paper fetal fluids is divided into 3-6wt%.

Paper fetal fluids sub-control system carries out ornamenting to paper using more cooling cylinders, keeps paper flat after 3-6wt% in the present embodiment Cunning, paper tire are smooth.

The preparation method of noble metal quantum dot is in the present embodiment：30- is added in salt by weight by 7-9 parts containing noble metal It in the isopropanol of 40 parts of mass fractions 80%, is sufficiently stirred at room temperature, then 1.25-1.45 parts of ammonium hydroxide is added into reaction system It stirs evenly, adds 0.02-0.04 parts of ethylenediamines, sodium citrate aqueous solutions, be put into hydrothermal reaction kettle and stir 20-30 points Clock adds 0.5-1.5 parts of polyvinylpyrrolidone and 0.8-1.2 parts of ethyl orthosilicates, with ultrasonication 15-18min, It is passed through helium protection, back flow reaction 2-3 hours at 180-200 DEG C, then reaction vessel is placed in 0 DEG C of water and is quenched 5-7 points Clock, then be collected by centrifugation by centrifuge, at the same be put into after being washed with deionized in baking oven be 70-80 DEG C in temperature at dry To noble metal quantum dot；

The salt containing noble metal is AgNO₃、PdCl₂And ZnSO₄According to weight ratio 4:2:The mixture of 1 composition.

In step six in the present embodiment be sent into baking oven drying before will spraying sizing after paper temperature be 110 DEG C and Pressure is hot pressing 7-9s under 50N.

Drying strengthening agent in the present embodiment step 3 is XQ-07 paper dry strength dose, and wet strength agent is that PAE papermaking is wet strong Agent, retention and drainage aid agent are polyacrylamide retention and drainage aid agent.

1-2 parts of Plant Fungicides are also added in glue film solution in the present embodiment；

The preparation method of the Plant Fungicide is：By perilla leaf, Radix Glycyrrhizae, Radix Isatidis, Dalmatian chrysanthemum, Folium Forsythia, folium artemisiae argyi, polygonum cuspidate It is separately added into high speed disintegrator and crushes, then be separately added into extractor, be separately added into organic solvent, refluxing extraction 2-4 times, every time It extracts 1-3 hours, organic solvent is recovered under reduced pressure in combined extract, obtains Plant Fungicide.

The phosphate ester starch that step two in the present embodiment is added also is modified by following steps：

By phosphate ester starch first under limited oxygen condition, 90 DEG C are warming up to the speed of 6 DEG C/min, 10min is kept the temperature, is subsequently cooled to Room temperature carries out Low Temperature Plasma Treating, and processing gas is oxygen, and pressure 200Pa, the processing time is 20-30s.

The reinforcing fiber slurry for accounting for the preliminary pulp quality 1% of step 1 preparation is also added in step three in the present embodiment；

The preparation method of the reinforcing fiber is：The bamboo material section got ready is sent into boiling vessel, using low temperature double tower continuous steaming-boiling 1kg/adt digesting assistant is added by bamboo material section OD wt. basis in skill, under the conditions of boiling temperature is 150 DEG C, continuously cooking 3-4 Hour, it is scattered in slightly being starched after boiling in dimethylacetamide solution, the alkali of bamboo material section oven dry weight 15%, sulphidity is added 22%, then 170 DEG C are warming up to, it back flow reaction 30-36 hours, filters, washing obtains stoste, send to spinning machine, pass through metering pump Then metering enters spinning head through candle filter, connecting tube；Reinforcing fiber is made in the stoste thread extruded from spinneret eyelet Slurry.

Implementation result：

In order to verify implementation result of the invention, the paper prepared in specific embodiment is manufactured with the prior art in the market wide The test comparison that paper carries out corresponding index is accused, associated test standards refer to ISO 105X12：

Following table is the index test result of each embodiment and comparative example：

Test index	Embodiment 1	Embodiment 2	Embodiment 3	Comparative example
					The curling of paper deformation resistant（50 DEG C, 8 hours）	Without deformation	Without deformation	Without deformation	There is curling
Folding strength（It is secondary）	771	725	765	687
					Paper smoothness（Second）	18.4	18.1	17.8	16.2
Repeatedly occurs average number of prints when crimping after printing	406	510	497	245
					40 DEG C of water impregnate jitter time（Hour）	137	139	124	98
Whether fluorescent effect is had	It is	It is	It is	It is no

The advertisement consumptive material of 1-3 of embodiment of the present invention preparation is superior to the paper of prior art preparation as seen from the above table, occurs these The reason of advantage, has used related additive and work in addition to reason already described in above-mentioned beneficial effect, there are also the invention Skill is made a concrete analysis of as follows：

The present invention uses more cylinder drieds in drying section, controls surface temperature of drier curve, and gently dried ensures that page two sides is poor It is small, and dryer temperature passes through test of many times, and determining temperature rate-of-rise can either guarantee that suffered stress is big when paper is dry Small, being not in that contraction is too fast causes the excessively caused paper mechanical property of filament contraction to be affected, while cold using more Cylinder carries out ornamenting to paper, makes that paper is smooth, paper tire is smooth, provides good Zhi Tai base to subsequent application adhesive film；

The quantum dot size for the preparation method preparation that the noble metal quantum dot that the present invention adds uses can preferably be merged in glue In coating solution, there is excellent capture light, issue the effect of fluorescence, simple process is lower to equipment requirement, controllable degree Height, combinational environment requirement, reduces costs；

The heat in the case where temperature is 110 DEG C and pressure is 50N of the paper after being glued will be sprayed in the present invention also before being sent into baking oven drying 7-9s is pressed, weather resistance of the consumptive material under print procedure high temperature environment can be effectively improved, avoid warpage；

The present invention makes it possible to the more uniform cellulose surface that is distributed in the correlation modification that phosphate ester starch carries out and plays one Surely clogging fiber hole and has apparent retention, filtrating aid function in paper-making process, has tangible technical effect and significant Progress；

The reinforcing fiber slurry that the present invention adds makes its fiber silk structure more bulk, more by creative preparation method Add the folding quality that paper can be substantially increased with other fiber fusion hinges；

Paper prepared by the present invention has intensity high, and printing effect is excellent, water-fast, oil resistant, chemicals-resistant, ageing-resistant, thermal insulation It is good, there is certain flame retardant effect, paper surface is smooth, is not easy warpage is suitable for roll printing, uses a large amount of waste paper Pulp fibres have saved resource, and paper is light, have certain fluorescence property, are able to ascend visual effect with paper as advertisement, also With good antibacterial vermins-proof effect, each addO-on therapy is nontoxic, safety and environmental protection, has significant progress and effect outstanding Fruit, to have higher practical value and good application prospect.

It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims Variation is included within the present invention.

In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art The other embodiments being understood that.

Claims (8)

1. a kind of high-quality printing dedicated paper manufacturing method of weather-proof waterproof, which is characterized in that include the following steps：

Step 1 prepares preliminary paper pulp：

First waste paper pulp fiber is crushed, the dipping by lye 20-30h that concentration is 1.5% is added, side in fiber dissociation device is added and uses Clear water rinses side stirring, then 70-90 parts of the waste paper pulp fiber rinsed well, log are starched 10-20 parts, bleaching sulphur by weight It being handled after 20-30 parts of addition hydrabrusher fibrosis of hydrochlorate softwood pulp by conical refiner, beating degree is 22-24 ° of SR, Refining concentration is 4-6wt%, is uniformly mixed to fibre stuff, and the 2-3% curing slurry for accounting for fiber pulp weight is added, stirs It is even, obtain preliminary paper pulp；

The curing slurry is that water-bath heat treatment 60- in dilute mineral acid solution is added in the palygorskite that will be purified 70min, temperature are 80-90 DEG C, then lauryl sodium sulfate is added into the suspension after acidification and is sufficiently stirred, and cooperate with ultrasonic water After thermal method handles 80-100min, high speed centrifugation processing is then carried out to it, centrifugal rotational speed 6000-8000r/min, when centrifugation Between be 10-12min, be dehydrated after centrifugation, it is dry after the powder after drying is placed in chamber type electric resistance furnace, temperature is set as 500 DEG C, it roasts 2-3 hours, then takes out, add the coupling agent of powder quality 1-2%, agitation grinding at being 50-60 DEG C in temperature, 1000 mesh are crossed, the powder after grinding is mixed with deionized water, the curing slurry that mass concentration is 7-9% is made；

Step 2, configuration increasing property auxiliary agent：Graphene quantum dot, nano silica and nano-titanium dioxide are pressed according to weight ratio According to weight ratio 8:1:It is uniformly mixing to obtain mixture in 1 addition blender, then the beet for accounting for its weight 5% is added into mixture Alkali, 10% phosphate ester starch and 5% sodium carboxymethylcellulose are stirred to obtain increasing property auxiliary agent；

The graphene quantum dot is the single-layer graphene oxide quantum dot prepared using microwave stripping method；

The increasing auxiliary agent for accounting for its quality 1% is added into the preliminary paper pulp of step 1 preparation for step 3, is sent into PFI mill, continues Mashing, adds the conventional additive for papermaking including drying strengthening agent, wet strength agent, retention and drainage aid agent, obtains copy paper slurry；

Obtained copy paper slurry is carried out copy paper with twin-wire paper-machine by step 4, sequentially entered after pulp flow to head case wet end, Press section and drying section are dried in drying section, obtain paper tire；

Squeeze water is divided into 55wt% out when the twin-wire paper-machine is squeezed；

The drying section uses more cylinder drieds, controls surface temperature of drier curve, and gently dried ensures that page two sides difference is small：It presses According to paper feed direction, dryer temperature is since first 70-75 DEG C of dryer temperature according to latter dryer temperature than previous dryer temperature Rise 8-10 DEG C and be incremented to 110-120 DEG C, rises 6-8 DEG C than previous drying cylinder according still further to latter dryer temperature and be decremented to 80-85 DEG C, It after control paper fetal fluids is divided into 3-6wt%, reuses more cooling cylinders and ornamenting is carried out to paper, make that paper is smooth, paper tire is smooth；

Step 5 prepares glue film solution：In parts by weight, by 10-20 parts of chitosans, 5-9 parts of sodium alginates, 4-6 parts of gelatine, 2- 4 portions of galactomannans, 1-2 parts of alumino-silicates are placed in reaction kettle, and 150-200 parts of water is added, is filled with into reaction kettle Steam carries out heating stirring, and mixing time is 30-40 minutes；Water stirring and adjusting colloid concentration is re-injected to 6%, keeps colloid Temperature be 50 DEG C, sequentially add 5-7 parts of vinylite, 2-3 parts of polyvinyl alcohol, 0.8-1.2 parts of aluminium hydroxide and boric acid 0.4-0.6 parts and trimethylglycine 0.1-0.3 parts of zinc, under the driving of speed regulating motor, by mixing liquid after grinding 0.5 hour 80 DEG C are heated to, 1-2 parts of adhesion promoters are added and are mixed, 0.05 part of noble metal quantum dot is added and is mixed, obtain To glue film liquid；

Step 6 applies adhesive film, the glue film solution that step 5 prepares is carried out spraying sizing on paper tire prepared by step 4, Sizing butt amount is 8.2-8.6g/m²；It is sent into baking oven and carries out drying and processing, the temperature in baking oven is from 20 DEG C on 5 DEG C per minute 90 DEG C are risen to, and is being kept for 90 DEG C 5-7 minutes, by the paper after drying, is formed and eliminates using Vacuum shaping plate cooling down The high-quality paper of environmental protection that cutting is made of the invention is carried out after tension.

2. a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof according to claim 1, which is characterized in that described expensive The preparation method of metal quantum point is：The different of 30-40 parts of mass fractions 80% is added in salt by weight by 7-9 parts containing noble metal It in propyl alcohol, is sufficiently stirred at room temperature, then 1.25-1.45 parts of ammonium hydroxide is added into reaction system and stir evenly, add 0.02- 0.04 part of ethylenediamine, sodium citrate aqueous solution are put into hydrothermal reaction kettle and stir 20-30 minutes, adds 0.5-1.5 parts of poly- second Vinyl pyrrolidone and 0.8-1.2 parts of ethyl orthosilicates are passed through helium protection, in 180-200 with ultrasonication 15-18min Back flow reaction 2-3 hours at DEG C, then reaction vessel is placed in 0 DEG C of water and is quenched 5-7 minutes, then is centrifuged and received by centrifuge Collection, at the same be put into after being washed with deionized in baking oven temperature be 70-80 DEG C at drying obtain noble metal quantum dot；

The salt containing noble metal is AgNO₃、PdCl₂And ZnSO₄According to weight ratio 4:2:The mixture of 1 composition.

3. a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof according to claim 1, which is characterized in that the step It further include before being sent into baking oven drying in rapid six by the hot pressing in the case where temperature is 110 DEG C and pressure is 50N of the paper after spraying sizing The operation of 7-9s.

4. a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof according to claim 1, which is characterized in that the step Drying strengthening agent in rapid three is XQ-07 paper dry strength dose, and wet strength agent is PAE wet strength agent for papermaking, and retention and drainage aid agent is poly- Acrylic amide retention and drainage aid agent.

5. a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof according to claim 1, which is characterized in that the glue 1-2 parts of Plant Fungicides are also added in coating solution；

The preparation method of the Plant Fungicide is：By perilla leaf, Radix Glycyrrhizae, Radix Isatidis, Dalmatian chrysanthemum, Folium Forsythia, folium artemisiae argyi, polygonum cuspidate It is separately added into high speed disintegrator and crushes, then be separately added into extractor, be separately added into organic solvent, refluxing extraction 2-4 times, every time It extracts 1-3 hours, organic solvent is recovered under reduced pressure in combined extract, obtains Plant Fungicide.

6. a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof according to claim 1, which is characterized in that the step Rapid two phosphate ester starches being added also are modified by following steps：

By phosphate ester starch first under limited oxygen condition, 90 DEG C are warming up to the speed of 6 DEG C/min, 10min is kept the temperature, is subsequently cooled to Room temperature carries out Low Temperature Plasma Treating, and processing gas is oxygen, and pressure 200Pa, the processing time is 20-30s.

7. a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof according to claim 1, which is characterized in that the step The reinforcing fiber slurry for accounting for the preliminary pulp quality 1% of step 1 preparation is also added in rapid three；

The preparation method of the reinforcing fiber is：The bamboo material section got ready is sent into boiling vessel, using low temperature double tower continuous steaming-boiling 1kg/adt digesting assistant is added by bamboo material section OD wt. basis in skill, under the conditions of boiling temperature is 150 DEG C, continuously cooking 3-4 Hour, it is scattered in slightly being starched after boiling in dimethylacetamide solution, the alkali of bamboo material section oven dry weight 15%, sulphidity is added 22%, then 170 DEG C are warming up to, it back flow reaction 30-36 hours, filters, washing obtains stoste, send to spinning machine, pass through metering pump Then metering enters spinning head through candle filter, connecting tube；Reinforcing fiber is made in the stoste thread extruded from spinneret eyelet Slurry.

8. a kind of weather-proof high-quality printing dedicated paper manufacturing method of waterproof according to claim 1, which is characterized in that including with Lower step：

Step 1 prepares preliminary paper pulp：

First waste paper pulp fiber is crushed, the dipping by lye 25h that concentration is 1.5% is added, side clear water in fiber dissociation device is added Side stirring is rinsed, then 80 parts of the waste paper pulp fiber rinsed well, log are starched into 15 parts, bleached sulphate needlebush by weight It is handled after starching 25 parts of addition hydrabrusher fibrosis by conical refiner, beating degree is 22-24 ° of SR, refining concentration 4- 6wt% is uniformly mixed to fibre stuff, and the 2.5% curing slurry for accounting for fiber pulp weight is added, stirs evenly, obtains preliminary Paper pulp；

The curing slurry is that water-bath heat treatment 65min in dilute mineral acid solution is added in the palygorskite that will be purified, Temperature is 85 DEG C, then lauryl sodium sulfate is added into the suspension after acidification and is sufficiently stirred, collaboration supersonic, water-heating method processing After 90min, high speed centrifugation processing is then carried out to it, centrifugal rotational speed 7000r/min, centrifugation time 11min take off after centrifugation The powder after drying is placed in chamber type electric resistance furnace after water, drying, temperature is set as 500 DEG C, roasts 2.5 hours, then takes Out, add powder quality 1.5% coupling agent, temperature be 55 DEG C at agitation grinding, cross 1000 mesh, by after grinding powder with Deionized water is mixed, and the curing slurry that mass concentration is 8% is made；

Step 2, configuration increasing property auxiliary agent：Graphene quantum dot, nano silica and nano-titanium dioxide are pressed according to weight ratio According to weight ratio 8:1:It is uniformly mixing to obtain mixture in 1 addition blender, then the beet for accounting for its weight 5% is added into mixture Alkali, 10% phosphate ester starch and 5% sodium carboxymethylcellulose are stirred to obtain increasing property auxiliary agent；

The graphene quantum dot is the single-layer graphene oxide quantum dot prepared using microwave stripping method；

The increasing auxiliary agent for accounting for its quality 1% is added into the preliminary paper pulp of step 1 preparation for step 3, is sent into PFI mill, continues Mashing, adds the conventional additive for papermaking including drying strengthening agent, wet strength agent, retention and drainage aid agent, obtains copy paper slurry；

Obtained copy paper slurry is carried out copy paper with twin-wire paper-machine by step 4, sequentially entered after pulp flow to head case wet end, Press section and drying section are dried in drying section, obtain paper tire；

Squeeze water is divided into 55wt% out when the twin-wire paper-machine is squeezed；

The drying section uses more cylinder drieds, controls surface temperature of drier curve, and gently dried ensures that page two sides difference is small：It presses According to paper feed direction, dryer temperature is since first 70-75 DEG C of dryer temperature according to latter dryer temperature than previous dryer temperature Rise 9 DEG C and be incremented to 110-120 DEG C, rises 7 DEG C than previous drying cylinder according still further to latter dryer temperature and be decremented to 80-85 DEG C, control It after paper fetal fluids is divided into 3-6wt%, reuses more cooling cylinders and ornamenting is carried out to paper, make that paper is smooth, paper tire is smooth；

Step 5 prepares glue film solution：In parts by weight, 15 parts of chitosans, 7 parts of sodium alginates, 5 parts of gelatine, 3 portions of galas are sweet Dew glycan, 1.5 parts of alumino-silicates are placed in reaction kettle, and 180 parts of water is added, and steam is filled with into reaction kettle carries out heating and stir It mixes, mixing time is 35 minutes；Water stirring and adjusting colloid concentration is re-injected to 6%, keeping the temperature of colloid is 50 DEG C, then according to 0.5 part of secondary 6 parts of addition vinylite, 2.5 parts of polyvinyl alcohol, 1 part of aluminium hydroxide and zinc borate and trimethylglycine 0.2 Part, under the driving of speed regulating motor, mixing liquid is heated to 80 DEG C after grinding 0.5 hour, 1.5 parts of adhesion promoters are added It is mixed, adds 0.05 part of noble metal quantum dot and be mixed, obtain glue film liquid；

Step 6 applies adhesive film, the glue film solution that step 5 prepares is carried out spraying sizing on paper tire prepared by step 4, Sizing butt amount is 8.2-8.6g/m²；It is sent into baking oven and carries out drying and processing, the temperature in baking oven is from 20 DEG C on 5 DEG C per minute 90 DEG C are risen to, and is being kept for 90 DEG C 6 minutes, by the paper after drying, is formed and is eliminated using Vacuum shaping plate cooling down and opened The high-quality paper of environmental protection that cutting is made of the invention is carried out after power.