CN109235137A - A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized - Google Patents

A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized Download PDF

Info

Publication number
CN109235137A
CN109235137A CN201811056101.5A CN201811056101A CN109235137A CN 109235137 A CN109235137 A CN 109235137A CN 201811056101 A CN201811056101 A CN 201811056101A CN 109235137 A CN109235137 A CN 109235137A
Authority
CN
China
Prior art keywords
coating
paper
electrolytic capacitor
pulp
carbonized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811056101.5A
Other languages
Chinese (zh)
Inventor
李南华
刘成跃
左磊刚
邵卫勇
颜鲁鸣
其他发明人请求不公开姓名
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang Kaine Special Paper Co Ltd
KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG
Original Assignee
Zhejiang Kaine Special Paper Co Ltd
KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang Kaine Special Paper Co Ltd, KAIEN SPECIAL MATERIALS CO Ltd ZHEJIANG filed Critical Zhejiang Kaine Special Paper Co Ltd
Priority to CN201811056101.5A priority Critical patent/CN109235137A/en
Publication of CN109235137A publication Critical patent/CN109235137A/en
Pending legal-status Critical Current

Links

Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F11/00Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines
    • D21F11/06Processes for making continuous lengths of paper, or of cardboard, or of wet web for fibre board production, on paper-making machines of the cylinder type

Landscapes

  • Paper (AREA)

Abstract

The invention belongs to electrolytic capacitor paper fields, and in particular to a kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized.The raw material of the electrolytic capacitor paper is made of wood pulp and chemical fibre;The beating degree of wood pulp is 5 ~ 25 ° of SR, and weight in wet base is 10 ~ 30g;The length of chemical fibre is 1.5 ~ 15mm, and fiber number is 0.1 ~ 3dtex;By dry mass percentages, wood pulp is 10 ~ 80%, and chemical fibre is 20 ~ 90%;The surface spray of the electrolytic capacitor paper sprays or dip coated has enhancement layer, and coating weight accounts for the 1 ~ 10% of paper absolute dry mass after coating.The present invention is coated paper, can further enhance the intensity of paper, is more conducive to ensureing the smooth production of capacitor.

Description

A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
Technical field
The invention belongs to electrolytic capacitor paper fields, and in particular to a kind of coating is enhanced to exempt from the solid electrolytic capacitor that is carbonized Paper and preparation method thereof.
Background technique
Electrolyte in solid electrolytic capacitor is solid-state conductive high molecular material, the structure packet of solid electrolytic capacitor Include anode, cathode, electrolytic paper and solid-state conductive high molecular material.Electrolytic capacitor paper be prepare electrolytic capacitor can not or One of scarce raw material is mainly used for adsorbing monomer and oxidant in the capacitor, forms polymer, while playing isolation pole plate Effect, prevents anode and cathode from directly contacting and short-circuit.
Traditional electrolytic capacitor paper is holocellulos material, weaker to the adsorption capacity of monomer, while being contained in cellulose There is a large amount of hydroxyl, side reaction can be generated in conductive high polymer monomer polymerization, influence the performance of capacitor;In addition, general electricity Fiber combination is more close in solution paper, and conductive high polymer monomer is difficult to be adsorbed in electrolytic paper completely, leads to conducting polymer list It is unevenly distributed in electrolytic paper after body polymerization, influences capacitor performance.Currently, the solid electrolytic capacitor produced in the market, It needs to carry out carbonization treatment to electrolytic paper at 250 ~ 270 DEG C in production process, to improve the sponginess of electrolytic paper and to monomer Adsorptivity.It under this technique, needs for entire capacitor to be heated under higher temperature, production technology is complicated, and high temperature cabonization Process will cause destruction to the structure of cathode and anode foil, cause properties of product unstable, leakage current is easy exceeded;Further, since plus Hot temperature is high, needs to consume a large amount of energy, adds somewhat to the production cost of enterprise.
Therefore, in order to simplify the production technology of solid electrolytic capacitor, production energy consumption is reduced, developing one kind, to exempt from carbonization solid State electrolytic capacitor paper (number of patent application: 2018091011182, the applying date: on September 10th, 2018), this kraft capacitor paper pair Conductive high polymer monomer has preferable adsorptivity, and can reduce side reaction when conductive high polymer monomer polymerization, while Without carrying out carbonization treatment to kraft capacitor paper in capacitor production process, but the intensity of the solid electrolytic capacitor paper is inadequate.
Summary of the invention
In order to solve the above technical problems, it is an object of the present invention to provide a kind of pair of monomers to have preferably absorption Property, side reaction is less, the electrolytic capacitor paper of carbonization treatment is not necessarily in capacitor production process, and have good intensity. Another object of the present invention is to provide the preparation method of above-mentioned electrolytic capacitor paper.
In order to realize above-mentioned first purpose, the invention adopts the following technical scheme:
A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper that is carbonized, and the raw material of the electrolytic capacitor paper is by wood pulp and chemical fibre Composition;The wood pulp includes non-bleaching needle-point leaf pulp, bleaching needle-point leaf pulp, non-bleached hardwood pulp, bleached hardwood pulp, grass One or more of slurry, the beating degree of wood pulp are 5 ~ 25 ° of SR, and weight in wet base is 10 ~ 30g;The chemical fibre includes polyester fibre One or more of dimension, Fypro, polyolefine fiber, vinylon fibre and polyacrylonitrile fibre, the length of chemical fibre For 1.5 ~ 15mm, fiber number is 0.1 ~ 3dtex;By dry mass percentages, wood pulp is 10 ~ 80%, and chemical fibre is 20 ~ 90%; The surface spray of the electrolytic capacitor paper sprays or dip coated has enhancement layer, and coating weight accounts for paper absolute dry mass after coating 1 ~ 10%.
Preferably, pressing dry mass percentages, wood pulp is 40 ~ 60%, and chemical fibre is 40 ~ 60%.
Preferably, the beating degree of wood pulp is 10 ~ 20 ° of SR, weight in wet base is 15 ~ 25g.
Preferably, the length of chemical fibre is 3 ~ 10mm, fiber number is 0.2 ~ 1.5dtex.
Preferably, the ingredient of spraying coating liquid or dip coated liquid is polyvinyl alcohol and its derivative, polyacrylamide One or more of with starch.
In order to realize above-mentioned second purpose, the invention adopts the following technical scheme:
A method of preparing that the coating is enhanced to exempt from the solid electrolytic capacitor paper that is carbonized, which is characterized in that this method packet Include following step:
1) dispersion is discongested after jute pulp being added water, obtains slurry A;
2) chemical fibre is uniformly dispersed, obtains slurry B;
3) slurry A and slurry B is sufficiently mixed, and obtains mixed slurry;
4) mixed slurry is subjected to online drainage and formation, using squeezing, drying, spraying coating or dip coated, drying, batched And cutting, it obtains the enhanced low tightness of coating and exempts from the solid electrolytic capacitor paper that is carbonized.
Preferably, forming is manufactured paper with pulp using cylinder in step 4), Top wire former concentration is 0.01 ~ 0.5%.
Further, the coating fluid mass concentration of spraying coating and dip coated is 0.1 ~ 10%.
The present invention exempts from the solid electrolytic capacitor paper that is carbonized by adopting the above-described technical solution, coating of the invention is enhanced There is good adsorptivity to monomer, and can be reduced the generation of side reaction during monomer polymerization, while paper is with lower Tightness, monomer is uniformly distributed in paper.Therefore, in the production process of capacitor without to kraft capacitor paper into Row carbonization treatment.Chemical fibre has preferable adsorptivity to monomer in above-mentioned component, therefore chemistry fibre is added in paper Dimension can improve paper to the adsorptivity of monomer, and monomer is made to be evenly distributed in paper;Again due to being combined between pure chemistry fiber Power is weaker, it is difficult to be manufactured paper with pulp by wet-formed, it is therefore desirable to and a certain amount of plant fiber assigns the paper certain intensity, It can smoothly manufacture paper with pulp.In addition, being coated to paper, the intensity of paper can be further enhanced, is more conducive to ensureing electricity The smooth production of container.
Specific embodiment
Reference example 1
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, are mixed Manila wood pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively afterwards, after mixing slurry concentration be 1%, two kinds After mixing, by cylinder forming, Top wire former concentration is 0.05% to fiber, then after squeezing, drying, batching and cutting Obtain finished product.
Reference example 2
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 6mm, fiber number 1.5dtex.Two kinds of fibers are mixed, are mixed Manila wood pulp and PET polyester fiber account for 40%, the 60% of fiber over dry total amount respectively afterwards, after mixing slurry concentration be 1%, two kinds After mixing, by cylinder forming, Top wire former concentration is 0.1% to fiber, then through squeezing, drying, batch and cut after must To finished product.
Embodiment 1
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, spraying coating, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 1.5%, coating weight is paper over dry after coating The 2.4% of quality.
Embodiment 2
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 6mm, fiber number 1.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.1%, then through squeezing, drying, spraying coating, drying, batch and Finished product is obtained after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 1.8%, coating weight is paper over dry matter after coating The 3.0% of amount.
Embodiment 3
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 40%, the 60% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, spraying coating, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 1.8%, coating weight is paper over dry after coating The 3.0% of quality.
Embodiment 4
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 6mm, fiber number 1.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 40%, the 60% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, spraying coating, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2.4%, coating weight is paper over dry after coating The 3.8% of quality.
Embodiment 5
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, dip coated, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2.0%, coating weight is paper over dry after coating The 4.5% of quality.
Embodiment 6
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 6mm, fiber number 1.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 50%, the 50% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.1%, then through squeezing, drying, dip coated, drying, batch and Finished product is obtained after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2.5%, coating weight is paper over dry matter after coating The 5.0% of amount.
Embodiment 7
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 5mm, fiber number 0.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 40%, the 60% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, dip coated, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 2.8%, coating weight is paper over dry after coating The 5.3% of quality.
Embodiment 8
Non- bleaching needle-point leaf pulp discongest after beating degree and weight in wet base be respectively 13 ° of SR, 17.5g, discongest rear pulp density 2%;PET After polyester fiber is dispersed, starching dense is 2%, fibre length 6mm, fiber number 1.5dtex.Two kinds of fibers are mixed, are mixed Wood pulp and PET polyester fiber account for 40%, the 60% of fiber over dry total amount respectively afterwards, and slurry concentration is 1% after mixing, and two kinds of fibers are mixed After closing uniformly, by cylinder forming, Top wire former concentration is 0.05%, then through squeezing, drying, dip coated, drying, batch With obtain finished product after cutting, coating fluid is polyvinyl alcohol water solution, and mass concentration 3%, coating weight is paper over dry matter after coating The 5.6% of amount.

Claims (8)

  1. Exempt from the solid electrolytic capacitor paper that is carbonized 1. a kind of coating is enhanced, which is characterized in that the raw material of the electrolytic capacitor paper by Wood pulp and chemical fibre composition;The wood pulp include non-bleaching needle-point leaf pulp, bleaching needle-point leaf pulp, non-bleached hardwood pulp, One or more of bleached hardwood pulp, straw pulp, the beating degree of wood pulp are 5 ~ 25 ° of SR, and weight in wet base is 10 ~ 30g;The chemistry Fiber includes one or more of polyester fiber, Fypro, polyolefine fiber, vinylon fibre and polyacrylonitrile fibre, The length of chemical fibre is 1.5 ~ 15mm, and fiber number is 0.1 ~ 3dtex;By dry mass percentages, wood pulp is 10 ~ 80%, chemistry Fiber is 20 ~ 90%;The surface spray of the electrolytic capacitor paper sprays or dip coated has enhancement layer, coating weight after coating Account for the 1 ~ 10% of paper absolute dry mass.
  2. 2. a kind of coating according to claim 1 is enhanced to exempt from the solid electrolytic capacitor paper that is carbonized, which is characterized in that by dry Drying quality percentages, wood pulp are 40 ~ 60%, and chemical fibre is 40 ~ 60%.
  3. 3. a kind of coating according to claim 1 is enhanced to exempt from the solid electrolytic capacitor paper that is carbonized, which is characterized in that wood pulp Beating degree be 10 ~ 20 ° of SR, weight in wet base be 15 ~ 25g.
  4. 4. a kind of coating according to claim 1 is enhanced to exempt from the solid electrolytic capacitor paper that is carbonized, which is characterized in that chemistry The length of fiber is 3 ~ 10mm, and fiber number is 0.2 ~ 1.5dtex.
  5. 5. a kind of coating according to claim 1 is enhanced to exempt from the solid electrolytic capacitor paper that is carbonized, which is characterized in that spraying The ingredient of coating fluid or dip coated liquid is one or more of polyvinyl alcohol and its derivative, polyacrylamide and starch.
  6. 6. it is a kind of prepare coating described in claim 1 ~ 5 any one claim it is enhanced exempt from be carbonized solid electrolytic capacitor The method of paper, which is characterized in that this method includes the following steps:
    1) dispersion is discongested after jute pulp being added water, obtains slurry A;
    2) chemical fibre is uniformly dispersed, obtains slurry B;
    3) slurry A and slurry B is sufficiently mixed, and obtains mixed slurry;
    4) mixed slurry is subjected to online drainage and formation, using squeezing, drying, spraying coating or dip coated, drying, batched And cutting, it obtains the enhanced low tightness of coating and exempts from the solid electrolytic capacitor paper that is carbonized.
  7. 7. Top wire former is dense according to the method described in claim 6, manufacturing paper with pulp it is characterized in that, shaping in step 4) using cylinder Degree is 0.01 ~ 0.5%.
  8. 8. according to the method described in claim 6, it is characterized in that, the coating fluid mass concentration of spraying coating and dip coated is 0.1~10%。
CN201811056101.5A 2018-09-11 2018-09-11 A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized Pending CN109235137A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811056101.5A CN109235137A (en) 2018-09-11 2018-09-11 A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811056101.5A CN109235137A (en) 2018-09-11 2018-09-11 A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized

Publications (1)

Publication Number Publication Date
CN109235137A true CN109235137A (en) 2019-01-18

Family

ID=65067751

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811056101.5A Pending CN109235137A (en) 2018-09-11 2018-09-11 A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized

Country Status (1)

Country Link
CN (1) CN109235137A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111926618A (en) * 2020-08-05 2020-11-13 中轻特种纤维材料有限公司 Preparation method of diaphragm paper for gold capacitor
CN114892448A (en) * 2022-06-13 2022-08-12 万国纸业太阳白卡纸有限公司 Paper and preparation method thereof
CN116180493A (en) * 2022-12-15 2023-05-30 株洲时代华先材料科技有限公司 Wide-temperature electrolytic capacitor paper and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1626731A (en) * 2003-12-09 2005-06-15 浙江凯恩特种材料股份有限公司 Paper of electrolytic capacitor and preparation method
CN1793508A (en) * 2005-12-23 2006-06-28 浙江凯恩特种材料股份有限公司 Process for preparing electrolytic capacitor paper
CN104988809A (en) * 2015-06-26 2015-10-21 浙江凯恩特种材料股份有限公司 High voltage resistant electrolytic capacitor paper and preparation method thereof
CN108221487A (en) * 2018-01-04 2018-06-29 浙江凯恩特种纸业有限公司 A kind of low internal resistance super electrolytic capacitor paper and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1626731A (en) * 2003-12-09 2005-06-15 浙江凯恩特种材料股份有限公司 Paper of electrolytic capacitor and preparation method
CN1793508A (en) * 2005-12-23 2006-06-28 浙江凯恩特种材料股份有限公司 Process for preparing electrolytic capacitor paper
CN104988809A (en) * 2015-06-26 2015-10-21 浙江凯恩特种材料股份有限公司 High voltage resistant electrolytic capacitor paper and preparation method thereof
CN108221487A (en) * 2018-01-04 2018-06-29 浙江凯恩特种纸业有限公司 A kind of low internal resistance super electrolytic capacitor paper and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111926618A (en) * 2020-08-05 2020-11-13 中轻特种纤维材料有限公司 Preparation method of diaphragm paper for gold capacitor
CN114892448A (en) * 2022-06-13 2022-08-12 万国纸业太阳白卡纸有限公司 Paper and preparation method thereof
CN116180493A (en) * 2022-12-15 2023-05-30 株洲时代华先材料科技有限公司 Wide-temperature electrolytic capacitor paper and preparation method thereof

Similar Documents

Publication Publication Date Title
CN108978322A (en) One kind is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN109137593A (en) A kind of enhanced low tightness of coating exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN109235136A (en) The enhanced low tightness of one kind exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN109208375A (en) A kind of low tightness exempts from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN109235137A (en) A kind of coating is enhanced to exempt from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN104631198B (en) Diaphragm paper for mercury-free alkaline zinc-manganese dioxide battery and preparation method thereof
CN102728144B (en) Wet papermaking forming battery capacitor diaphragm filtering material and preparation method thereof
CN103556543A (en) Special high-performance carbon paper for gas diffusion layer of fuel cell and preparation method of carbon paper
CN108179652A (en) A kind of reinforced electric electrolytic capacitor paper and preparation method thereof
CN106920696A (en) Nano hybridization aeroge electrode material for super capacitor and its preparation method and application
CN108203893A (en) A kind of low tightness high intensity electrolytic capacitor paper and preparation method thereof
CN108914675A (en) A kind of high-quality printing dedicated paper manufacturing method of weather-proof waterproof
CN105887553A (en) Supercapacitor dielectric absorption material and production method thereof
CN108046254A (en) A kind of corncob derives active carbon electrode material and preparation method thereof
CN101289822A (en) Nano far infrared anion carbon crystal conductive paper and method for preparing same
CN108166320A (en) A kind of method that on-line coater prepares low tightness high intensity electrolytic capacitor paper
CN101581054B (en) Paper pulp for gluing alkaline battery diaphragm paper and preparation process for preparing diaphragm paper by applying paper pulp
CN104957755A (en) Method for increasing retention rate of calcium carbonate in paper-making reconstituted tobacco
CN108978323A (en) A kind of preparation process of publicity brochure printing
JP2015193941A (en) sheet-like carbon material
CN109024084A (en) One kind exempting from the solid electrolytic capacitor paper and preparation method thereof that is carbonized
CN103114495B (en) A kind of carbon paper for electrode diffusion layer of fuel cell and preparation method thereof
CN108766773A (en) A kind of seaweed matrix activated carbon electrode material and preparation method for ultracapacitor
CN107841904A (en) A kind of preparation method of bamboo fibre conducting polymer paper
CN108894056A (en) A kind of preparation method of the high-quality advertisement consumptive material paper of environmental protection

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20190118

RJ01 Rejection of invention patent application after publication