CN108699765A - The transfer method of printing and dyeing of polyester fiber material - Google Patents
The transfer method of printing and dyeing of polyester fiber material Download PDFInfo
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- CN108699765A CN108699765A CN201680082408.5A CN201680082408A CN108699765A CN 108699765 A CN108699765 A CN 108699765A CN 201680082408 A CN201680082408 A CN 201680082408A CN 108699765 A CN108699765 A CN 108699765A
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- dyeing
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Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/003—Transfer printing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
Abstract
The present invention provides a kind of transfer method of printing and dyeing of polyester fiber material, its process number is few, fixed expenditure and variable expenditure are cheap, drainage load is small, it can obtain the printing product of the polyester fiber material of excellent quality, the transfer method of printing and dyeing is characterized in that, body paper is assigned to have and is selected from acidic-group, the ester body of the acidic-group, ether body, amide body, alkali metal salt or alkali salt, and the paste of the functional group in cation group, or body paper is assigned and is selected from natural adhesive paste, cellulose derivative and polysaccharide, and also it is combined with the paste of carboxylic acid compound class, thus obtained transfer printing and dyeing are printed with paper using non-subliming type disperse dye inks, thus obtained transfer printing and dyeing paper is sealed at polyester fiber material and is pressurizeed, heating, to carry out transfer printing and dyeing.
Description
Technical field
The present invention relates to the transfer methods of printing and dyeing for the polyester fiber material for having used non-subliming type disperse dyes.
Background technology
As the method with disperse dyes to polyester fiber material printing design, it is known to be pasted using the color of disperse dyes
Screen printing, roller printing and dyeing, cylinder printing and dyeing, and industrially implemented.But the design table of these Plate making printing modes
Existing force difference makes a plate because needing due to is unsuitable for small lot, short delivery delivery date, and it is extra to need to make due to paste using a large amount of color
Color is pasted, thus drainage load is big, and multi-process handling and complicated, needs skilled behaviour to carry out fine colouring, molding etc.
Make, the incidence of defective work is easy to become high, and problem is more.
Use is disclosed in patent document 1, patent document 2, patent document 3, patent document 4 etc. will be containing the liter of E types
The sublimation transfer of printing and dyeing paper obtained by the oil-based ink or water-based ink inkjet printing to sublimation transfer printing and dyeing paper of magnificent dyestuff
Method, and industrially implemented.In the case where carrying out sublimation transfer printing and dyeing to polyester fiber using the sublimation transfer method, specially
The method for extending the residence time (5 minutes) under low temperature (140 DEG C) is disclosed in sharp document 4, but this method is in terms of productivity
There are problems.Thus, usually it was heat-treated with 30 seconds~1 minute at 190~200 DEG C.
However, for these sublimation transfer methods, it is desirable that therefore, right for the equalization and reproducibility of polyester fiber
In the dyestuff that colors require sublimability similar respectively, to have the problem of dyestuff that can be used is limited.In addition, distillation
Dyestuff is the dyestuff of small-molecular-weight, exists and is easy to move diffusion because of heat, and flies out from fibrous inside into air and pollute it
The problems such as his fiber, white background.For example, if transfer temperature is high temperature, the dyestuff once caught can be from fibrous material (cloth and silk)
In fly out, therefore have pattern blurring, pollution transfer apparatus or the problem of environment.Thus, also it is usually 200 in transfer temperature
It is processed when DEG C temperature below.Further, since the heat-resisting fastness for being sublimated the product of dyeing is extremely low, form and aspect, other
Fastness be also limited, therefore, as being unsuitable for clothes for processing object product.Further, since in sublimation transfer method
Waste paper used has laurustinus spot, therefore also has the problems such as can not being used in recycled writing paper.
On the other hand, using on well known sublimation transfer printing and dyeing paper using non-subliming type disperse dye inks print and
The transfer paper obtained, it is bad in the color emissivity for the method that 190~200 DEG C carried out transfer printing and dyeing with 30 seconds~1 minute, because without reality
Value.That is, good hair can not be obtained if even if well known sublimation transfer condition is applied to non-subliming type disperse dyes
Color.
As the method solved these problems, following method is disclosed in patent document 5, patent document 6:It is demoulding
It is dry after coating ink-receiver layer on paper, after then being printed to ink-receiver layer with disperse dyes, ink is carried out successively and is connect
It is removed, by the dyestuff fixation treatment of steam treatment etc. by dry transfer of the layer on fibrous material, processing release paper.But it should
Method has following problem:Of high cost, the use if humidity of the factory transferred, transfer are printed and dyed of processing release paper (transfer body paper)
The maintaining requirement of paper etc. is improper, then can not 100% transfer ink receiving layer, will produce defective work, the recycling of paper
Highly difficult, process number is mostly etc..
Following method (the paper method of printing and dyeing) is disclosed in patent document 7:Coating is added with because adding on cheap commercially available paper
Heat, the water-soluble synthesis pressurizeed and become by force with the provisional adhesive tension of fibrous material are adhesive, are naturally paste and auxiliary agent
Mixing paste liquid and drying, to form ink-receiver layer and adhesive layer, on the obtained transfer printing and dyeing paper printing divide
Dye ink is dissipated, by transfer printing and dyeing paper color development in the state of being pasted on fibrous material of gained.This method is not necessarily to fibrous material
Pre-treatment, be excellent processing method in this regard, however need crimping process, color development process (dry type is heat-treated or steam
Processing), soap washing etc., thus there is a problem of more than process number.
In addition, it is also known that have:Fabric (undulation degree obtained by paste (pre-treatment) is dried afterwards is assigned for fibrous material
Material), the direct method of disperse dye inks is printed with ink-jet printer.But this method need fibrous material pretreatment procedure,
Printing process, steaming procedure, soap washing, process number and drainage load are more, are deposited in terms of economy, the stability of quality
Problematic.
It should be noted that in present specification and claims, printing and dyeing are made to be applied with following meaning sometimes
Paper relational language.
(1) body paper:The paper (or film) being coated with before paste
(2) printing and dyeing paper is transferred:It is coated with the body paper of paste
(3) transfer printing and dyeing paper:Have been assigned the transfer printing and dyeing paper of dye ink
Existing technical literature
Patent document
Patent document 1:Japanese Unexamined Patent Publication 2003-313787 bulletins
Patent document 2:Japanese Unexamined Patent Application 53-55221 bulletins
Patent document 3:Japanese Unexamined Patent Publication 2011-21133 bulletins
Patent document 4:Japanese Unexamined Patent Publication 2002-292995 bulletins
Patent document 5:No. 4058470 bulletins of Japanese Patent No.
Patent document 6:Japanese Unexamined Patent Publication 06-270596 bulletins
Patent document 7:No. 4778124 bulletins of Japanese Patent No.
Invention content
Problems to be solved by the invention
As described, it is contaminated applied to the dispersion of non-subliming type in well known sublimation transfer method, by well known sublimation transfer condition
In the method for material, well known dry transfer method, direct method, other well known methods of printing and dyeing, it is noted following problem etc.:It can make
The problem of dyestuff is limited;The problem of product quality such as fastness, form and aspect/color emissivity, the stability of quality;Process number
The problem of economy such as more, cost of raw and processed materials height;It pollutes other fibers or environment (environmental protection) such as environment, drainage load are big is asked
Topic.Accordingly it is desirable to develop the method for printing and dyeing without these problems.
The object of the present invention is to provide a kind of method of printing and dyeing of polyester fiber material, process number is few, fixed expenditure and
Variable expenditure cheap (thus economy is excellent), drainage load are small (thus the feature of environmental protection is excellent), can obtain form and aspect/fastness etc.
Quality also excellent product.
The method for solving problem
The present inventor to develop the method for printing and dyeing for solving economy and the quality problems such as environmental problem and fastness as target,
In the way of inkjet printing, in the way of intaglio printing etc. well known to mode of printing, for polyester fiber material the method for printing and dyeing repeatedly
It has made intensive studies, as a result, it has been found that,
When printing and dyeing to polyester fiber material,
Only by using non-subliming type disperse dye inks to by paste assign to obtained by body paper transfer printing and dyeing paper into
Row prints, and above-mentioned transfer printing and dyeing paper is sealed at polyester fiber material by the transfer printing and dyeing paper obtained by use, and in specified conditions
Lower pressurization, heating, so that it may which to complete whole processes of transfer printing and dyeing, and it is also good by the poly- of printing and dyeing to obtain quality
Ester series fiber material, the transfer method of printing and dyeing so as to complete the present invention, the paste have selected from acidic-group, the acidic groups
Functional group in ester body, amide body, alkali metal salt or the cation groups such as alkali salt and quaternary ammonium group rolled into a ball, the acid
Property group be selected from carboxyl, sulfonic group and phosphate;Alternatively, the paste be selected from natural adhesive paste, cellulose derivative and polysaccharide,
And also it is combined with carboxylic acid compound class.
The 1st aspect of the present invention is a kind of transfer method of printing and dyeing of polyester fiber material, which is characterized in that
It is printed with paper using disperse dye inks to assigning paste to transfer printing and dyeing obtained by body paper, by gained
Transfer printing and dyeing paper is sealed at polyester fiber material and pressurizes, heats, to carry out transfer printing and dyeing,
Above-mentioned disperse dye inks are non-subliming type disperse dye inks,
Aforesaid paste is that have selected from acidic-group, the ester body of above-mentioned acidic-group, amide body, alkali metal salt or alkaline earth gold
Belong to salt and the paste of the functional group in cation group, the acidic-group is selected from carboxyl, sulfonic group and phosphate;Or
Aforesaid paste is selected from natural adhesive paste, cellulose derivative and polysaccharide and is also combined with carboxylic acid compound class
Paste (technical solution 1).
As aforesaid paste, for example, being selected from one or more of animal system thickener and department of botany's thickener (technical side
Case 2).It should be noted that a kind or more refers to:It can be individual a kind of thickener, can also be the thickener being used in combination of two or more.
It is also identical for " a kind or more " given below.
It is to have to be selected from acidic-group, the ester body of above-mentioned acidic-group, amide body, alkali metal salt or alkaline earth in aforesaid paste
The paste of functional group in metal salt and cation group and the acidic-group are selected from carboxyl, sulfonic group and phosphate
In the case of, carboxylic acid compound class (technical solution 3) can also be further coordinated in the paste.
As carboxylic acid compound class, it is preferably selected from one or more of fatty family carboxylic acid and aromatic system carboxylic acid (technical side
Case 4).
In aforesaid paste, can also further it coordinate selected from Acidic Compounds, mineral system acid compound and mineral
It is one or more of additive, the Acidic Compounds are the salt (technical solution 5) formed by strong acid and weak base.
It, can also further compounding aid (technical solution 6) in aforesaid paste.
As above-mentioned non-subliming type disperse dye inks, it is preferred that, it can enumerate using micronized to average grain
Diameter is the base gravure ink or flexographic ink that 0.2~10 μm of disperse dyes are produced, or is using micronized to average grain diameter
The jetted ink that 0.05~0.2 μm of disperse dyes are produced.Herein, as disperse dyes, it is preferable to use being selected from S types or SE types
One or more of disperse dyes non-subliming type disperse dyes (technical solution 7).
As above-mentioned polyester fiber material, can enumerate selected from polyethylene terephthalate, poly terephthalic acid
1,3-PD ester, polybutylene terephthalate (PBT), polylactic acid, depolymerizing polyester, cation dyeable polyester, room temperature dyeable polyester
And the high molecular textile fabric of Polyester, braided fabric, non-woven fabrics, piece or film in Alkali reduction polyester;Or above-mentioned textile fabric, braiding
Object or non-woven fabrics are blended, mixed with the fiber in the synthetic fibers selected from natural fiber and other than above-mentioned Polyester macromolecule
It knits, intertexture or composite material (technical solution 8).
Transfer printing and dyeing in the transfer method of printing and dyeing of first method are preferably transfer temperature is 150~250 DEG C, transfer pressure is
It pressurizes under conditions of 0.01MPa or more, heat and carry out (technical solution 9).
The 2nd aspect of the present invention is a kind of manufacturing method of transfer printing and dyeing paper, which is characterized in that
It is the manufacturing method that printing and dyeing paper is transferred used in the transfer method of printing and dyeing of first method,
Being assigned to body paper has selected from acidic-group, the ester body of above-mentioned acidic-group, amide body, alkali metal salt or alkaline earth gold
Belong to salt and the paste of the functional group in cation group, the acidic-group is selected from carboxyl, sulfonic group and phosphate;Alternatively,
Assign body paper selected from natural adhesive paste, cellulose derivative and polysaccharide and be also combined with the paste (technology of carboxylic acid compound class
Scheme 10).
The 3rd aspect of the present invention is a kind of manufacturing method of polyester fiber material, which is characterized in that is had using upper
The transfer method of printing and dyeing for stating the polyester fiber material of first method carries out polyester fiber material the process (technology of transfer printing and dyeing
Scheme 11).
The effect of invention
The present invention is in order to which to develop process number, drainage load few for the non-subliming type disperse dyes for using fastness excellent
The transfer method of printing and dyeing and completed after being studied, be in terms of cost competitiveness excellent economy and the feature of environmental protection it is excellent, can
To provide the new method of the product of superior quality, be one process of polyester fiber material use can be processed as it is fine, firm
Gu and the transfer method of printing and dyeing of the good product of feel.
In the well known method of printing and dyeing, such as the dry transfer method of printing and dyeing or in the case of the paper method of printing and dyeing, indispensable transfer printing process
Or crimping process, fixation (steam treatment) process, cleaning process this 3 processes, according to the present invention it is possible to utilize thermal transfer process
This 1 process come complete transfer printing and dyeing whole processes (thus, by the present invention method be referred to as one-step method (a process method)).Cause
And not only process is simple and economy is excellent, but also cleaning process is can be omitted, therefore drainage load can be reduced, economy
It is excellent with the feature of environmental protection.
In addition, though the use of the sublimation transfer method of sublimable dye being the few method of process number, however, it is believed that this method is only
It is applicable to that fastness is low, Yin Re and the dyestuff to distil, non-distillation type dye can not be suitable for.That is, even if strong in order to improve
Degree and assign non-subliming type disperse dye inks to commercially available sublimation transfer printing and dyeing paper, it is closely sealed with fibrous material and well known
Under the conditions of heat, color emissivity also can be bad, thus using non-subliming type disperse dyes implement sublimation transfer method be considered highly difficult.
But the present invention in, using on the transfer printing and dyeing paper for impart specific paste with non-subliming type disperse dyes
Ink printed and produce transfer printing and dyeing paper, by the transfer printing and dyeing paper be sealed at fibrous material, in the item of particular range
It pressurizes, heat under part, it is hereby achieved that the good polyester fiber material of dyeing capacity (color emissivity), fastness, feel are also good
It is good.In addition, by using suitable paste, cleaning process (soap washing) can also be omitted.
The present invention can utilize common existing cylinder type (the also referred to as cycle type or continuous in dyeing industry at present
Formula) sublimation transfer machine or plate heating transfer device carry out the secured and transfer efficiency of Polyester composite fibre materials
Excellent printing and dyeing can use cheap body paper and cheap paste, also have the advantages that it in these areas.Furthermore, it is possible to
While playing these advantages, the qualities such as structure equalization, feel, tractability, color emissivity and fastness are good and economy and
The excellent method of printing and dyeing of the feature of environmental protection (zero-emission Water l oad etc.).
That is, using the present invention, the transfer method of printing and dyeing of the environmental protection that friend of sports fan is good over the ground and economy can be provided.
Specific implementation mode
[Hu Ji ]
The 1st aspect of the present invention is characterized in that the paste for body paper being assigned and being formed transfer printing and dyeing paper is to have
In acidic-group, the ester body of above-mentioned acidic-group, amide body, alkali metal salt or alkali salt and cation group
1 kind or more functional group paste of the compound as principal component, the acidic-group be selected from carboxyl (- COOH), sulfonic group (-
SO3) and phosphate (- PO H4H2);Alternatively, the paste is comprising in natural adhesive paste, cellulose derivative and polysaccharide
1 kind or more and also it is combined with the paste of carboxylic acid compound class.It should be noted that so-called paste, is with water-soluble macromolecule
Compound water solution of the compound as main body, refer to viscosity at 20 DEG C when 2 mass % aqueous solutions are made be 3mPas with
On paste, it is preferable to use 10mPas or more paste.In addition, as cation group, quaternary ammonium group etc. can be enumerated.
With selected from acidic-group, above-mentioned acidic-group ester body, amide body, alkali metal salt or alkali salt, with
And in the paste of functional group and the acidic-group selected from carboxyl, sulfonic group and phosphate in cation group, including natural
Be paste and synthesis be paste, can enumerate compound below as its example.
So-called is naturally paste, is directly to carry out object using paste obtained by the thickener of natural output or to above-mentioned thickener
Paste obtained by reason processing or chemical process has department of botany's thickener obtained by being processed to department of botany's raw material and to animal system original
Animal system thickener obtained by material is processed.
As department of botany's thickener obtained by being processed to department of botany's raw material, low viscosity, medium viscosity or high viscous can be enumerated
Sodium alginate (substance included in seaweeds etc.), potassium alginate, ammonium alginate, alginic acid ester, Arabic gum, the glucose of degree
Aldehydic acid, xanthans, pectin, heparin, carboxymethyl cellulose (hereinafter referred to as " CMC "), acidity CMC, alkyl etherified CMC, ester
Change CMC, sulfate cellulose, cationic starch, cationization oxidised maize starch, cationized cellulose, oxidized starch, second
Acylated hexane diacid-crosslinked starch, starch phosphate sodium, esterification starch, hydroxypropylation phosphoric acid crosslinked starch, phosphorylated starch, starch
Sodium glycollate, amylcose acetate, octenyl succinic acid starch, rosin soap etc..
As animal system thickener obtained by being processed to animal system raw material, the skin to animal, institute in bone can be enumerated
The collagen contained heated, extract obtained by gelatin, as the collagen peptide of its enzymatic degradation product, as caseinolytic
Casein peptide, egg protein, chondroitin sulfate, Sodium Hyaluronate, cationization polypeptide of object etc..
It is paste as synthesis, carboxy-modified polyvinyl alcohol, cationized polyvinyl alcohol, polyvinyl acetate can be enumerated
Ester, vinyl-vinyl acetate copolymer, vinyl carboxylates, maleinization resin, dicarboxylic acids ketene dimers, alkyl vinyl
Ketone dimer, polyacrylamide, acrylic latex, acrylic acid series synthesis paste, vinyl acetate system latex, alkenyl succinic acid
Acid anhydride, polyacrylate system ammonium salt, polyacrylate system sodium salt, the water-soluble polyester resin etc. with sulfonic group or carboxyl.
Preferably it is naturally paste in aforesaid paste.That is, as aforesaid paste, preferably be selected from animal system thickener and
Paste of one or more of the department of botany's thickener as main body.In the whole amount of paste is naturally the fit rate of paste with solid
Ingredient conversion is preferably 1 mass of mass %~100 %, and preferred fit rate is 10 mass % to 90 mass %.
Natural adhesive paste, cellulose derivative and polysaccharide be naturally paste, typically refer to be selected from acidic groups in addition to having
Group, the ester body of above-mentioned acidic-group, amide body, alkali metal salt or functional group in alkali salt and cation group and
The acidic-group is selected from the paste other than the paste of carboxyl, sulfonic group and phosphate.As natural adhesive paste, Luo Wang can be enumerated
Sub- glue, etherificate tamarind gum, etherificate locust bean gum, etherificate guar gum, Arabic gum, Acacia Arabia systems glue etc..As fibre
The plain derivative of dimension, can enumerate etherificate carboxymethyl cellulose, hydroxyethyl cellulose etc..As polysaccharide, starch, fibre can be enumerated
Element, glycogen, dextrin, amylose, chitin, agarose, heparin, pectin, Ge, Amorphophalus rivieris, agar, Cornstarch, etherificate is tieed up to form sediment
Processing of cellulose, the ether such as powder, producing starch, producing starch, the hydroxymethyl cellulose processed using seaweeds as starting material
Change starch, esterification starch etc..
In the case where paste includes selected from one or more of natural adhesive paste, cellulose derivative and polysaccharide, also coordinate
Carboxylic acid compound class.In aforesaid paste had selected from acidic-group, the ester body of above-mentioned acidic-group, amide body, alkali metal salt
Or functional group in alkali salt and cation group and the acidic-group are selected from carboxyl, sulfonic group and phosphate
In the case of paste, it is also preferred that further cooperation carboxylic acid compound class.It should be noted that the carboxylic joined together by these cases
Acid compound class refers to the compound for having carboxyl, wherein a kind be preferably selected from fatty family carboxylic acid and aromatic system carboxylic acid
Above compound.
As fatty family carboxylic acid, the aromatic system carboxylic acid for belonging to the carboxylic acid compound class being cooperated in paste, can incite somebody to action
Following compound as monocarboxylic acid and polybasic carboxylic acid is enumerated as concrete example.
Glycolic, lactic acid, hydroxymalonic acid, glyceric acid, 2- hydroxybutyric acids, 3-hydroxybutyrate, maleic acid, succinic acid, penta 2
Acid, adipic acid, fumaric acid, maleic acid, tartaric acid and its derivative, decanedioic acid, thioacetic acid, thiodipropionic acid, trichloroacetic acid, hydroxyl
Base isobutyric acid, hendecane dicarboxylic acid, isobutyric acid, malonic acid, itaconic acid, butyric acid, citric acid, malic acid, oxalic acid, benzoic acid, bigcatkin willow
Acid, P-hydroxybenzoic acid, m-Nitrobenzoic Acid, vanillic acid, phthalic acid, M-phthalic acid, terephthalic acid (TPA), inclined benzene front three
Acid, Pyromellitic Acid, stearic acid.
In the case where paste is natural adhesive paste, cellulose derivative, polysaccharide, carboxylic acid compound class pastes liquid in mixing
The rate that preferably comprises in (in the constituent of paste hydrous water and product obtained by homogeneous solution is made) is changed with solid constituent
It is 1 mass % to 50 mass % to calculate, and preferred containing ratio is 3 mass % to 30 mass %.It is combined with these carboxylic acid compounds
The mixing paste liquid of class shows faintly acid, it is however generally that, the range of PH=3~5 is fallen into mostly.
It is with ester body, amide body, alkali metal salt or alkaline-earth metal selected from acidic-group, above-mentioned acidic-group in paste
One or more of salt and cation group functional group and the acidic-group are the change selected from carboxyl, sulfonic group and phosphate
In the case of closing object, carboxylic acid compound class preferably comprises rate with solid constituent conversion also for 1 mass % to 50 matter in paste
% is measured, preferred containing ratio is 3 mass % to 30 mass %.
In aforesaid paste, can further it coordinate selected from Acidic Compounds, mineral system acid compound and mineral system
One or more of additive, the Acidic Compounds are the salt formed by strong acid and weak base.
The Acidic Compounds being cooperated in paste refer to the salt formed by strong acid and weak base, are dissolved in water and aobvious acid
Property, as specific example, ammonium sulfate, sodium dihydrogen phosphate, ammonium chloride, calcium chloride etc. can be enumerated.
The mineral system acid compound being cooperated in paste refers to the water soluble compound obtained by mineral or the compound
Complex etc., be dissolved in water and aobvious acidity.As mineral system acid compound, aluminum sulfate, alum, kaolin can be enumerated
Deng.By coordinating Acidic Compounds, mineral system acid compound, the effect of color emissivity raising can be obtained, therefore preferably.
The mineral system additive being cooperated in paste refers to the complex etc. of the compound or the compound that are obtained by mineral,
And be the compound other than above-mentioned mineral system acid compound, it is compound that is water-soluble or being dispersed in water.In mineral
It is to show neutral or alkalinity in the case that additive is dissolved in the water.As mineral system additive, it can enumerate and generally make
Coating pigment class, i.e. clay, talcum, titanium dioxide, calcium carbonate, silica, silica gel, colloidal state dioxy used in paper purposes
SiClx, aluminium oxide etc. or bentonite, clay, alumina silicate and its derivative, diatomite, kaolin, Emathlite etc. are referred to as
The additive of mineral thickener.By coordinating mineral system additive, it can be prevented adhesion, improve the profit on transfer printing and dyeing paper
With paste formed layer ink by capacitive effect, therefore preferably.
Acidic Compounds, mineral system acid compound and mineral system additive can individually coordinate a kind, can also
Coordinate two or more, can not also coordinate.Acidic Compounds, mineral system acid compound and mineral system additive can be coordinated
In arbitrary a kind, can also be used in combination of two or more.The preferred fit rate of Acidic Compounds and mineral system acid compound is opposite
It is scaled 0% to 30% with solid constituent for the gross mass of paste, preferred fit rate is 0.5% to 10%.It is pasting
Coordinate in agent and is mixed made of fatty family carboxylic acid, aromatic system carboxylic acid, Acidic Compounds and/or mineral system acid compound
Paste liquid shows faintly acid, it is however generally that, the range of pH2~6 is fallen into mostly.
In aforesaid paste, in order to improve the various physical property as the ink-receiver layer formed using paste, preferably also
Compounding aid.As the auxiliary agent being cooperated in paste, water-soluble resins, the surface-actives such as acrylic acid series synthesis paste can be enumerated
Agent, thickener, moisturizer, PH conditioning agents, deep dyed color agent, preservative, mould inhibitor, degasser, antifoaming agent, anti-reducing agent, dispersion
Agent and metal ion chelation agent etc..
For the use level (by based on the apparent mass of paste gross mass) of these auxiliary agents, as surface tension tune
Whole dose, anticrater agent, bleeding agent and in the case of the anionic system or nonionic surfactants that coordinate, preferably 0~5%
(more preferably 1~3%), it is more in polyethylene glycol, glycerine, thiodiglycol, the diethylene glycol coordinated as moistening/moisturizer etc.
In the case of first alcohols, urea, thiocarbamide, dicyandiamide etc., preferably 0~10%, liquid is pasted in mixing when in order to increase coating
Viscosity and in the case of the acrylic acid series synthesis paste that coordinates, preferably 0~5% (more preferably 0~3%), as long as not damaging this
The purport of invention is then not limited to the range.Auxiliary agent can be independently matched with a kind, can also coordinate two or more.
In addition, in order to improve with the adaptation of fabric (fibrous material), can also be added into auxiliary agent on a small quantity will not damage
The evil dyeability and synthesis that will not pollute fiber is high score subclass or water-soluble resins (water-soluble synthesis is high score subclass),
And it is the substance other than above-mentioned synthesis is paste.It is the concrete example of high score subclass, Ke Yiju as water-soluble synthesis
Go out polyvinyl alcohol, polyester based resin, polyacrylic based resin, polyurethane series resin, polyethylene oxide system resin, polyamide-based tree
Fat, vinyl acetate system resin, styrene acrylic system resin, styrene maleic acid system resin, Pioloform, polyvinyl acetal system resin,
Water soluble polyether-carbamate system resin etc., can coordinate selected from one or more of they.These resins can be with water-soluble
The state of liquid or lotion is coordinated.Fit rate is preferably 0~20 mass % relative to the gross mass of auxiliary agent.
[Yuan Zhi ]
In order to by assign paste make the body paper that is used with paper of transfer printing and dyeing can be brown paper, fine paper, in
The arbitrary processing paper such as grade paper, coarse paper, art paper, paper fillers, smoothing processing paper, one side coated or undressed paper, recycled writing paper,
General used cheap paper can be used as body paper.Without using the paper of the high prices such as processing release paper.It should be noted that
It can be used synthetic resin film as body paper.
As the paper pulp for forming body paper base paper, it can enumerate and not bleach or bleached softwood tree paper pulp, broad leaf tree paper pulp, ox-hide
Paper pulp grinds paper pulp or using reclaim paper as regenerated paper pulp of raw material etc..It, can be in the base paper obtained by these paper pulp
Can also be in paper to control the water imbibition of paper, the generation of fold containing sizing agent, paper power reinforcing agent, filler, pigment etc.
On be coated with the paper of the fillers such as clay, synthetic resin.
For the base weight of body paper, consider from operability, preferably 10~120g/m2, more preferably 25~100g/m2, thickness
Preferably 0.01~0.5mm or so.If enumerating concrete example, the coating paper, ultralight of Nippon Paper corporation can be enumerated
Measure coating paper, fine paper, middle coarse paper, such as pure white, bleaching or non-BK bleached kraft, silver-colored bamboo, Yin Ling, silver, monochromatic light ox-hide
Paper, glassine paper, the non-BK bleached kraft of king paper company, half bleaching brown paper, BK bleached kraft, bleaching monochromatic light ox-hide
Paper, pure white roll web, various art papers, various calendering paper etc., however they are only an examples.As the physical property of body paper,
The physical property of the various paper such as air permeability, density, tensile strength, surface strength, moistening intensity is not particularly limited, as long as being to ensure that painting
The body paper of tensile strength when cloth is pasted, either which kind of paper can use.Alternatively, it is also possible to using the film of synthetic resin as original
Paper uses.But using gravure printing method, if the smoothness of paper is good, for printing applicability
It is preferred that therefore, it is desirable to after assigning paste, carries out calendering processing and improve smoothness.
[Transfer printing and dyeing Zhi ]
The present invention the transfer method of printing and dyeing used in transfer printing and dyeing with paper be by body paper imparting aforesaid paste by
Ink-receiver layer and dyeing promotion layer is formed on the surface of body paper to make.For the imparting amount of paste, relative to body paper, with
Dry type conversion is preferably 1~50g/m2, more preferably 2~20g/m2。
The paste imparting that body paper carries out is usually carried out:By the constituent of aforesaid paste (comprising required ingredient, with
And carboxylic acid compound class, Acidic Compounds, mineral system acid compound, mineral system additive, various auxiliary agents needed etc.
Ingredient) with water coordinate, and fully stir and make mixing paste liquid, by the mixing paste liquid to body paper coating (coating), spray or
Dipping is dried after thus absorbing body paper or it being made to be laminated in body paper.It is most preferably sharp in coating, spraying, dipping
With the method for coating.About the optimum viscosity of mixing paste liquid, carried out according to any one of coating, spraying or dipping, even if
, also can be different according to the machine of coating machine in the case of coating, it is easy to carry out the adjustment of viscosity by increasing and decreasing moisture.
According to mixing paste liquid and body paper type difference, coating when can be difficult to because of hydrophobic or paper shrinkage phenomenon to
The case where uniformly being coated on body paper.These phenomenons can by adjust separately mixed paste type and paste solid at
Point, the paper such as viscosity, the type of surface tension reducer (anionic system, nonionic surfactants, alcohols etc.) and additive amount
Type, formulation condition inhibits.
As the coating unit of mixing paste liquid, various doctor knife coaters, the direct coating machine of comma formula, die lip coating can be enumerated
Machine, gravure coater, comma formula reversion coating machine, Kohler coater, slot die coating machine, flush coater, bar coater, showering
Machine, size press coater etc..As needed, mechanical calender, soft calender, super calender can also be used after application
Equal calenders are smoothed and gloss working process.
[Dyestuff-ink-transfer printing and dyeing Zhi ]
By using inkjet printing or other methods, such as intaglio printing, flexographic printing process, print and dye to above-mentioned transfer
(printing) non-subliming type disperse dyes are assigned with the state of ink with paper and be dried, it is hereby achieved that transfer printing and dyeing paper.
Non- subliming type disperse dyes as used herein refer to:It is difficult to the dyestuff to distil at high temperature, and belongs to distillation as shown below
The disperse dyes of the excellent S types of fastness or SE types.The disperse dyes of so-called S types or SE types refer to by increasing molecular structure
Or import polar substituent and dyestuff is made to be difficult to the excellent disperse dyes of the distillation fastness to distil, which does not include distillation
The sublimability disperse dyes of E types used in transfer printing.As the concrete example of non-subliming type disperse dyes used in the present invention,
Dyestuff below can be enumerated.
C.I. disperse yellow 49,56,58,63,67,76,79,82,86,114,121,123,126,149,163,165,180,
184,185,192,198,222,226,228,231;C.I. disperse orange 10,13,17,21,29,30,32,50,51,55,61,
62,73,96,97,148;C.I. disperse red 5,12,13,17,43,54,56,58,64,72,73,74,76,78,82,86,88,
90,92,97,107,109,113,121,125,126,127,128,129,134,135,136,137,140,143,145,151,
152,153,154,160,167,177,179,181,183,184,188,189,191,202,205,210,221,225,257,
258,283,285,288,302,323,356,360;C.I. disperse violet 26,33,35,40,43,46,48,52,58,63,69,
77,92;C.I. disperse blue 7,27,40,54,60,62,73,75,77,79,82,83,85,87,90,94,96,99,102,103,
104,113,122,125,128,130,139,142,143,144,146,148,158,165,167,173,174,176,181,
183,197,198,200,201,207,211,214,257,259,264,266,270,301,354;C.I. disperse brown 1,4,9,
13,19,24,25 etc..Black can be made using the cooperation of 3 primary colors+α of these strong S type dyes.It should be noted that E
The concrete example of the sublimable dye of type can enumerate the dye described in the technical solution 9 of Japanese Unexamined Patent Publication 2011-21133 bulletins
Material, however much less distillation fastness is low, the low dyestuff of all fastness headed by light fastness is more.
Above-mentioned non-subliming type disperse dyes are turned to by ink to be used as jetted ink, base gravure ink or flexographic ink etc. to make
With.After by ink, (printing) is printed to above-mentioned transfer printing and dyeing paper using inkjet printing, intaglio printing, flexographic printing etc.
Ink, to make transfer printing and dyeing paper.Dye component (pigment substance) in ink is preferably 1~15 matter according to color depth
Measure %.Used ink can also be oil-based ink, however if it is considered that the safety and sanitation in workshop, environmental problem, danger
The disposition of object, economy then it is expected to use water-based ink.
, it is preferable to use the dyestuff for being 0.05~0.2 μm by micronized to average grain diameter in the case of jetted ink.It can be with
Using under the coexisting of dispersant micronized, the ink used in ink-jet printer are carried out using the known method of ball mill etc.
It is preferable to use further added into the dyestuff of micronized stably dispersing agent, anti-drying dose, surface tension modifier, viscosity
Conditioning agent, pH adjusting agent, preservative, mould inhibitor, metal ion chelation agent, antifoaming agent, degasser, dispersant etc. simultaneously mix, and use
0.8 micron of molecular filter below filters off ink obtained by micro foreign matter and degassing.In the case where average grain diameter is too small, have
It is easy to happen the trend of particle re-united, on the other hand, in the case where average grain diameter is excessive, easy tos produce ink-jet printer
Spray nozzle clogging the problem of.
In the case of intaglio printing ink (base gravure ink), flexographic printing ink (flexographic ink), preferably with point
The dyestuff that it is 0.2~10 μm by micronized to average grain diameter that powder, which is used together,.Either in the case where average grain diameter is too small
Or in the case of excessive, can all there are printing applicability, the undesirable trend of color emissivity.
In the case of intaglio printing, flexographic printing, the dyestuff of micronized can be made to coordinate, be dispersed in containing increasing
In thick dose of thick water solution, viscosity is adjusted to the ink of 30~500mPas or so.As the dispersant that can be used,
Naphthalenesulfonic acid formalin condensation product, methyl naphthalene sulfonic acid formaline condensates, lignin sulfonic acid, OLFINE PD- can be enumerated
003,OLFINE PD-001,OLFINE PD-002W,OLFINE PD-004,OLFINE PD-005,OLFINE PD-201,
OLFINE PD-301 etc..As the more specific example of intaglio printing ink, following ink can be enumerated:It will
METOLOSE 65SH400 (chemical company of SHIN-ETSU HANTOTAI system) and METOLOSE 65SH4000 (chemical company of SHIN-ETSU HANTOTAI system) and
POVAL AP-17(JAPAN VAM&POVAL corporations) etc. partial hydrolysis PVA used as thickener, with pigment substance convert
The non-subliming type disperse dyes for the S or SE types that micronized containing 1~15 mass % is 0.5~10 μm to average grain diameter, will print
The viscosity of brush ink is adjusted to ink obtained by 30~500mPas.
[Transfer Yin Rangongxu ]
Keep the transfer as above obtained printing and dyeing paper Chong Die with polyester fiber material (cloth and silk), makes dyestuff using pressurization, heating
In transfer dyeing to fibrous material, the transfer printing and dyeing of the present invention are carried out.In general, the temperature (transfer temperature) of heating, pressurization
Pressure (transfer pressure) be respectively 150~250 DEG C, the range of 0.01MPa or more, preferably respectively 200~230 DEG C, 0.02
The range of~4MPa.In the case where temperature, pressure are more than the upper limit, the trend that the feel of product is deteriorated is had, on the other hand,
Temperature, pressure have the trend that color emissivity becomes inadequate less than in the case of lower limit.
The time (processing time, transfer time) pressurizeed, heated is usually 1 second~10 minutes ranges, high
Temperature, high pressure, then can more obtain good color emissivity within short processing time, therefore, in order to improve productivity ratio, high
Temperature, high pressure are then better.For example, in the case of 220 DEG C of transfer temperature, transfer pressure 0.05MPa, even if processing time is 30
Second, it is also possible to obtain good color emissivity.
[Polyester fiber Cai Liao ]
Using the present invention the transfer method of printing and dyeing carry out transfer printing and dyeing polyester fiber material (cloth and silk) refer to:With Polyester
High molecular material is as the individual material such as the textile fabric of main body, braided fabric, non-woven fabrics, piece, film;Or above-mentioned textile fabric, volume
Fabric, non-woven fabrics etc. with other than natural fiber, Polyester high molecular material synthetic fibers formed it is blended, be blended, intertexture,
The fibrous materials such as composite material.As Polyester high molecular material, polyethylene terephthalate can be enumerated, is poly- to benzene two
Formic acid 1,3-PD ester, polybutylene terephthalate (PBT), polylactic acid, depolymerizing polyester, cation dyeable polyester, room temperature can contaminate
Polyester, the polyester-based material referred to as Alkali reduction polyester.As above-mentioned natural fiber, can enumerate cotton, fiber crops, tencel, artificial silk,
The cellulose fibres material such as acetic acid esters;The protein series fiber material such as silk, wool.Composite fibre materials refer to:Nylon, dimension
Well known all composite fibre materials other than the Polyesters high molecular material such as nylon, polyacrylic, polyurethane, in addition,
It can be compound series fiber.
Embodiment
Hereinafter, using embodiment, the present invention is described in more detail, however the scope of the present invention is not limited to these
Embodiment.It should be noted that in example, recorded as long as no special, then part refers to mass parts, and % refers to quality %.Implement
In example 1~7, comparative example 1~4 transfer printing and dyeing after dyeing capacity (color emissivity of fibrous material (cloth and silk)), equalization be according to
Benchmark below judges.
○:The color emissivity (dyeing capacity) of fibrous material, equalization, fastness are excellent, and quality is good.
△:The color emissivity (dyeing capacity) and equalization of fibrous material are slightly poor, and quality is bad.
×:The color emissivity (dyeing capacity) and equalization of fibrous material are obviously bad, and quality is obviously bad.
Embodiment 1
The mixing of layer formation is promoted to paste liquid as ink-receiver layer and dyeing, (etherificate is formed sediment by SOLVITOSE C-5
Powder:AVEBE corporations) 20g, FD ALGIN BL (sodium alginates:Gu Chuan chemical industrial companies system) 20g, EX-100 (tamarind
Glue:TOMOE paste producings corporation) 20g, tartaric acid 40g and ion exchange water 400g (total 500g) mixture high speed dispersion
Type blender (3000rpm) fully stirs, and produces uniform and smooth highly viscous slurry.It is added into the highly viscous slurry
Bubble is eliminated for 0.2% commercially available degasser or antifoaming agent relative to highly viscous slurry, (Hengshan Mountain makes institute using coating machine
System, comma coater) in paper (Nippon Paper corporation, BK bleached kraft, base weight 60g/m2) on be evenly coated with and dry.It is mixed
The coating weight (dry weight) for closing paste liquid is 8g/m2.So obtain transfer printing and dyeing paper.
On the above-mentioned transfer printing and dyeing paper of gained, the ink-jet printer (ink-jet printer of Roland companies manufacture is utilized:
Soljet EJ-640), by disperse dye inks liquid (C.I. disperse blue 60s:6%, ethylene glycol 5%, glycerine 15%, nonionic system
Dispersant 5%, anionic system dispersant 5%, ion exchange water 64%) it is printed as candy strip and drying, obtain transfer printing and dyeing
Paper.Keep obtained transfer printing and dyeing paper and polyester satin dough cloth closely sealed, heated, pressurizeed (210 DEG C, 0.8MPa, 40 seconds,
The flat pattern distillation pressing machine HSP-2210 manufactured using HASHIMA companies), thus dyestuff is shifted, is anchored on polyester fabric
Afterwards, paper is removed.It should be noted that the maximum pressure (drum pressure) of the distillation pressing machine of HASHIMA companies manufacture is 1MPa,
The pressure is equivalent to transfer pressure 0.049MPa.Thus, the drum pressure 0.8MPa of the present embodiment is equivalent to transfer pressure
0.039MPa.In embodiment below etc., the also phase in the case where having used the distillation pressing machine that HASHIMA companies manufacture
Together.
The obtained polyester dyeing cloth is dense, Delicatement dyes (quality judging of color emissivity etc. is zero), the hand of fiber
Sense is good, and the distillation fastness based on JISL0854 is 5 grades of (change), 4-5 grades of (dirt).Light fastness based on JISL0842 is
5 grades.
Embodiment 2
By SOLVITOSE C-5 (etherification starch:AVEBE corporations) 10g, FD ALGIN BL (sodium alginates:Gu Chuanhua
Learn industrial group's system) 5g, EX-100 (tamarind gum:TOMOE paste producings corporation) 5g, Penon JE66 (producing starch:Day shallow lakeization
Learn corporation) the mixture high speed dispersion type blender of 10g, tartaric acid 10g and ion exchange water 170g (total 210g)
(3000rpm) is fully stirred, and produces uniform and smooth highly viscous slurry.A small amount of take off is added into the highly viscous slurry
Gas agent and antifoaming agent, and micro preservative, mould inhibitor is added, it adds water and viscosity is adjusted to about 1200mPas,
Obtain mixing paste liquid.Kohler coater is used as coating machine, and the mixing paste liquid of gained is uniformly coated on body paper (Japan
Paper company's system processed, monochromatic light brown paper, base weight 60g/m2) on and it is dry, obtain transfer printing and dyeing paper.The coating weight of mixing paste liquid
(dry weight) is 10g/m2。
On the transfer printing and dyeing paper of gained, the ink-jet printer (ink-jet printer of Roland companies manufacture is utilized:
SoljetPro4XF-640), by disperse dye inks liquid (C.I. disperse blue 60s:6%, ethylene glycol 5%, glycerine 15%, nonionic
It is dispersant 5%, anionic system dispersant 5%, ion exchange water 64%) it is printed as candy strip, to obtain transfer printing and dyeing
Paper.Keep transfer printing and dyeing paper and the polyester taffeta fabric of gained closely sealed, heated, pressurizeed (210 DEG C, 0.8MPa, 40 seconds,
HASHIMA flat patterns distillation pressing machine), thus dyestuff is shifted, is affixed on polyester fabric and removes paper, obtains polyester printing and dyeing
Cloth.
The obtained polyester dyeing cloth is dense, Delicatement dyes (chromatic to be determined as zero), and the feel of fiber is good,
Daylight fastness (change) and distillation fastness (become, is dirty) are 4 grades or more.
Embodiment 3
Other than citric acid 20g is added in substitution tartaric acid 40g, handles and mixed same as Example 1ly
The making and the coating on paper for pasting liquid obtain transfer printing and dyeing paper.On the transfer printing and dyeing paper of gained, inkjet printing is utilized
Machine (the ink-jet printer of Roland companies manufacture:SoljetProIIIXJ-640), by disperse dye inks liquid (C.I. disperse reds
92:5%, ethylene glycol 5%, glycerine 15%, nonionic system dispersant 5%, anionic system dispersant 5%, ion exchange water 64%)
It is printed as candy strip and drying, obtains transfer printing and dyeing paper.
Keep transfer printing and dyeing paper and the polyester satin dough cloth of gained closely sealed, heated, pressurizeed (218 DEG C, 1.0MPa, 30 seconds,
HASHIMA flat patterns distillation pressing machine), thus dyestuff is shifted, anchors on polyester fabric and remove paper, obtains polyester printing and dyeing
Cloth.The obtained polyester dyeing cloth is dense, Delicatement dyes (chromatic to be determined as zero), and the feel of fiber is good, daylight
Fastness and distillation fastness are excellent similarly to Example 1.
Embodiment 4
In addition to the amount of tartaric acid is become 4g from 40g, and the condition of heating, pressurization is become into transfer pressure 0.05MPa, is turned
195 DEG C of temperature of print other than 120 seconds processing times, is handled same as Example 1ly, as a result, obtaining same as Example 1
Firm dyeing and printing products.
Embodiment 5
Citric acid 20g is used in addition to substitution tartaric acid 40g, and is pasted to add in liquid to mixing and be relative to mixing paste liquid
1% マ ィ Network mouth イ De KM386P (silica gel:KD Corporation systems) other than, it handles same as Example 1ly, result
It is that the dyeing cloth of the polyester taffeta of gained has very thin design (being determined as zero), soft and fast light, the liter of fiber
The various fastness such as China, sweat, washing are also good.
Embodiment 6
The mixing of layer formation is promoted to paste liquid as ink-receiver layer and dyeing, by Gosenol GL-05 (water-soluble polies
Vinyl alcohol:Japan's synthesis chemical company system) 20g, Fine Gum HEL-3 (cellulose derivatives:First industrial drug company system)
50g, EX-200 (tamarind gum:TOMOE paste producings corporation) 50g, urea 50g, spy A clay KL-18:20g, マ ィ Network mouth ィ De
KM-386P:10g, citric acid 25g, tartaric acid 25g, the mixture of water 750g are abundant with the high speed dispersion type blender of 5000rpm
Ground stirs, and produces highly viscous slurry.After the viscosity for adjusting the highly viscous slurry, body paper is coated in using comma coater
(Nippon Paper corporation, silver-colored bamboo, 50g/m2) on and it is dry, obtain transfer printing and dyeing paper.The transfer is printed with the pressure of 3MPa
Dye carries out calendering processing with paper, has carried out smoothing processing.Paste coating weight is 12g/m2.On the transfer printing and dyeing paper of gained, profit
Disperse dyes base gravure ink liquid (C.I. disperse red 86 products are printed with intaglio press:Contain 15%, uses water, cellulose-based
Viscosity is adjusted to ink obtained by 120mPas by thickener, polyvinyl alcohol and isopropanol) and it is dry, obtain transfer printing and dyeing paper.
The transfer printing and dyeing paper of gained is set to be sealed on polyester taffeta fabric, the flat-plate compressed manufactured using HASHIMA companies
Machine is scalded, heated, pressurizeed with 210 DEG C, 0.8MPa, 40 seconds, to obtain making dye transfer, be bonded to made of polyester fabric
Polyester dyeing cloth.The polyester dyeing cloth is dense, Delicatement dyes (quality judging zero), and the feel of fiber is good, is based on
The distillation fastness of JISL0854 is 5 grades of (change), 4-5 grades of (dirt).In addition, the light fastness based on JISL0842 be 4 grades with
On.
Embodiment 7
In addition to the flat pattern sublimation transfer machine of substitution HASHIMA companies manufacture, and use the manufacture of Jing Shang metal industries company
Rotary drum type continous way thermal printer makes Polyester Fibers print and dye with transfer at 220 DEG C of drum surface temperature, pressure 0.5MPa
The hot rotating cylinder contact residence time of paper is to be handled same as Example 6ly, other than 30 seconds as a result, showing fibrous material
Good color emissivity (zero).
Embodiment 8
In addition to the flat pattern sublimation transfer machine of substitution HASHIMA companies manufacture, and use the double roller of Yuri Roll companies manufacture
Pressurized, heated machine, under conditions of 230 DEG C of the surface temperature of hot-rolling, pressure 3MPa, feed speed 1m/min, make fibrous material with
The hot-rolling contact residence time of transfer printing and dyeing paper is to be handled same as Example 1ly other than 20 seconds, as a result, display fiber
Tie up the good color emissivity (zero) of material.
Comparative example 1
In addition to using disperse dye inks used in embodiment 1 in commercially available company A sublimation transfer printing and dyeing paper, trade mark
A, it is printed on this 4 kinds of trade mark b, trade mark c, trade mark d and makes transfer printing and dyeing paper, and changed other than transfer printing and dyeing paper, with reality
It applies example 1 and has carried out transfer printing and dyeing in the same manner, (judgement of dyeing capacity be △~×) is in the case of arbitrary as a result, color emissivity
It is poorer than embodiment 1, it is determined as problematic in practical.
Comparative example 2
In addition to using commercially available B companies sublimation transfer printing and dyeing paper, C companies sublimation transfer printing and dyeing paper, and change transfer
Other than printing and dyeing paper, making, the transfer printing and dyeing of transfer printing and dyeing paper have been carried out same as Example 1ly, as a result, color emissivity is bright
Aobvious (chromatic be determined as ×) poorer than embodiment 1.
Comparative example 3
In addition to commercially available company A sublimation transfer printing and dyeing on paper merchants mark a with containing sublimation dye C.I. disperse red 60s
Ink is printed, and other than being handled with the pressure of 0.15MPa, handle same as Example 1ly after, as a result, hair
Color is good.But in addition to being printed with the ink containing non-sublimation dye C.I. disperse reds 92, and with the pressure of 0.15MPa
Other than power is handled, handle same as Example 1ly after, as a result, color emissivity is bad (△).
Comparative example 4
Other than tartaric acid is not added, process same as Example 2ly after, as a result, the color emissivity of fibrous material
It is insufficient (chromatic to be determined as △), produce unevenness.
Embodiment 9
By Fine Gum HEL-3 (sodium carboxymethylcelluloses:First industrial pharmaceutical corporation) 20 parts, FD ALGIN BL
(sodium alginate:Gu Chuan chemical industrial companies system) 20 parts, EX-100 (tamarind gums:TOMOE paste producings corporation) 10 parts and ion
The mixture of 400 parts of exchanged water (450 parts total) is fully stirred with high speed dispersion type blender (3000rpm), is produced
Even and smooth highly viscous slurry (mixing paste liquid).To mixing paste liquid in be added commercially available degasser, antifoaming agent and eliminate gas
Bubble.
Using coating machine (Hengshan Mountain makes manufactured comma coater), produced mixing paste liquid is equably coated with
In paper (Nippon Paper corporation, fine paper, base weight 60g/m2) on and it is dry, to obtain transfer printing and dyeing paper.Mixing paste liquid
Coating weight (dry weight) be 8g/m2。
On the obtained transfer printing and dyeing paper, the ink-jet printer (ink-jet printer of Roland companies manufacture is utilized:
Soljet EJ-640), it will use and carry out ink for 0.1 μm of disperse dyes with ball mill micronized to average grain diameter and obtain
Ink (C.I. Disperse Blue-79s:4%, ethylene glycol 5%, glycerine 15%, nonionic system dispersant 5%, anionic system dispersant
5%, ion exchange water 66%) it is printed as candy strip.Thereafter dry to obtain transfer printing and dyeing paper.
Keep the obtained transfer printing and dyeing paper and polyester satin dough cloth closely sealed, the flat pattern liter manufactured using HASHIMA companies
Magnificent pressing machine HSP-2210 is heated, is pressurizeed (215 DEG C, drum pressure 0.6MPa, 40 seconds), by dyestuff transfer, anchored at
After stating on fabric, removes paper and obtain polyester dyeing cloth.The obtained polyester dyeing cloth is dense, Delicatement dyes (color emissivity
Well), the feel of fiber is good, and the distillation fastness based on JISL0854 is 5 grades of (change), 4~5 grades of (dirt).It is based on
The light fastness of JISL0842 is 5 grades or more.
Embodiment 10
By POVAL AP-17 (carboxy-modified PVA, JAPAN VAM&POVAL corporations) 10 parts, FD ALGIN BL:20
Part, EX-100:10 parts, the mixture high speed dispersion type blender (3000rpm) of 200 parts of ion exchange water (total 240 parts)
It fully stirs, produces uniform and smooth highly viscous slurry (mixing paste liquid).Due to producing bubble, pasted to mixing
Be added in liquid commercially available degasser, antifoaming agent and eliminate bubble.In addition, being additionally added micro preservative, mould inhibitor.
Water is added into produced highly viscous slurry and viscosity is adjusted to about 1200mPas, as coating machine
Using Kohler coater, the mixing paste liquid of gained is uniformly coated on body paper (Nippon Paper corporation, BK bleached kraft, base
Weight 40g/m2) on and it is dry, to obtain transfer printing and dyeing paper.The coating weight (dry weight) of mixing paste liquid is 10g/m2。
Then, using METOLOSE 65SH400 (chemical company of SHIN-ETSU HANTOTAI system) and METOLOSE 65SH4000 (SHIN-ETSU HANTOTAIs
Chemical company's system), POVAL AP-17 (JAPAN VAM&POVAL corporations) and isopropanol, it is 200mPas to produce viscosity
Sticky ink addition agent.Coordinate the non-subliming type dispersion dye of the conduct of (being relative to ink addition agent) 15% into the ink addition agent
200% product of C.I. disperse red 86s (average grain diameter is 1.5 μm) of material, is adjusted to 150mPas by the viscosity of ink and makes
Make intaglio plate Magenta ink.
Using electrodynamic type intaglio printing testing machine GP-10 (Kurabo corporations), incited somebody to action with speed 15m/min, 25 DEG C of temperature
The obtained intaglio plate is printed in Magenta ink full versions on above-mentioned transfer printing and dyeing paper, to obtain transfer printing and dyeing paper.
Keep the transfer printing and dyeing paper and polyester taffeta fabric closely sealed, heated, pressurizeed (220 DEG C, roller pressure 0.5MPa, 40 seconds, roll
Cartridge type transfer interpreter), after thus dyestuff is transferred on above-mentioned fabric, paper is removed, polyester dyeing cloth is obtained.The obtained polyester
Dyeing cloth is dense, Delicatement dyes, and the feel of fiber is good, and daylight fastness (change) and distillation fastness (become, is dirty) are 5 grades
More than.
Embodiment 11
In addition to liquid is pasted in the mixing in substitution embodiment 9, and powder will be added in 55 parts of 10% aqueous solution to FD ALGIN BL
Other than solution obtained by 10 parts of 5% aqueous solution of last aluminum sulfate (great Ming chemical industrial companies system) is used as mixing paste liquid, with
Embodiment 9 has carried out the coating on paper in the same manner, obtains transfer printing and dyeing paper.
On the transfer printing and dyeing paper of gained, the ink-jet printer (ink-jet printer of Roland companies manufacture is utilized:
SoljetProIIIXJ-640), the disperse dyes of micronized will be used to carry out disperse dye inks liquid obtained by ink
(C.I. disperse reds 92:5%, ethylene glycol 5%, glycerine 15%, nonionic system dispersant 5%, anionic system dispersant 5%, ion
Exchanged water 65%) it is printed as candy strip and drying, obtain transfer printing and dyeing paper.
Keep transfer printing and dyeing paper and the polyester taffeta fabric of gained closely sealed, is distilled using the flat pattern of HASHIMA companies manufacture
Pressing machine HSP-2210 is heated, is pressurizeed (215 DEG C, drum pressure 1.0MPa, 30 seconds), thus by dyestuff transfer, be affixed to
After on above-mentioned fabric, removes paper and obtain polyester dyeing cloth.The obtained polyester dyeing cloth is dense, Delicatement dyes, fiber
Feel it is good, daylight fastness and distillation fastness it is excellent similarly to Example 9.
Embodiment 12
In addition to the mixing paste liquid in substitution embodiment 9, use includes EX-3 (cationic starch, Dian chemical companies
System) 100 parts of 10% aqueous solution, FD ALGIN BL 100 parts of 10% aqueous solution mixing paste liquid other than, same as Example 9ly
Obtain polyester taffeta dyeing cloth.The color emissivity of the polyester taffeta dyeing cloth of gained is good and has very thin design, fiber
It is soft, the various fastness such as fast light, distillation, sweat, washing are also good.
Embodiment 13
By 10 parts of Bribine (phosphorylated starch, Dian chemical companies system), Fine Gum HEL-3:50 parts, EX-200
(tamarind gum:TOMOE paste producings corporation) 10 parts, Gosenol GL-05 (water-soluble povals:Synthesis chemical company of Japan
System) 20 parts, マ ィ Network mouth ィ De KM-386P:10 parts, the high speed dispersion of the mixture 5000rpm of 650 parts of 50 parts of tartaric acid and water
Type blender fully stirs, and produces uniform and smooth highly viscous slurry (mixing paste liquid).Adjusting the highly viscous slurry
Viscosity after, using comma coater be coated in body paper (Nippon Paper corporation, one side coated 50g/m2) on and it is dry, produce
The transfer printing and dyeing paper of disperse dyes.The paste coating weight of the transfer printing and dyeing paper is 7.5g/m2。
On the transfer printing and dyeing paper of gained, intaglio press printing disperse dyes base gravure ink liquid (cooperation C.I. is utilized
Viscosity is adjusted to 80mPas by 92 product 15% of disperse red using water, cellulose-based thickeners, polyvinyl alcohol and isopropanol
Obtained by ink) and it is dry, obtain transfer printing and dyeing paper.
The transfer printing and dyeing paper of gained is set to be sealed on polyester taffeta fabric, the flat-plate compressed manufactured using HASHIMA companies
Boiling hot machine is heated, is pressurizeed (215 DEG C, drum pressure 0.8MPa, 40 seconds), to by dyestuff transfer, be affixed on above-mentioned fabric
Afterwards, it removes paper and obtains polyester dyeing cloth.The obtained polyester dyeing cloth is dense, Delicatement dyes, and the feel of fiber is good,
Distillation fastness based on JISL0854 is 5 grades of (change), 4-5 grades of (dirt).In addition, the light fastness based on JISL0842 is 5
Grade or more.
Embodiment 14
Cylinder type distillation is used to turn in addition to the flat pattern sublimation transfer machine of the HASHIMA companies manufacture in substitution embodiment 9
Print machine, and make fabric (undulation degree under conditions of 210 DEG C of the surface temperature of hot-rolling, roller pressure 2MPa (nip width 3cm)
Material) with transfer printing and dyeing paper hot-rolling time of contact be 30 seconds other than, handle same as Example 9ly, as a result, showing good
The color emissivity of good fibrous material.
Embodiment 15
In addition to the mixing paste liquid (highly viscous slurry) in substitution embodiment 9, use is by Fine Gum HEL-3:20 parts,
EX-3:10 parts, EX-100:20 parts and the mixing of 400 parts of water and other than the mixing paste liquid produced, handle same as Example 9ly,
As a result, the color emissivity of polyester dyeing cloth is good and has very thin design, the soft and fast light of fiber, distillation, sweat
The various fastness such as liquid, washing are also good.
Embodiment 16
In addition to the mixing paste liquid (highly viscous slurry) in substitution embodiment 9, use is by Bribine (phosphorylated starch, day
Shallow lake chemical company system) 100 parts of 10% aqueous solution, FD ALGIN BL the mixing of 100 parts of 10% aqueous solution and the mixing paste produced
Other than liquid, handle same as Example 9ly, as a result, the color emissivity of polyester dyeing cloth is good and has very thin design, it is fine
The various fastness such as the soft and fast light of dimension, distillation, sweat, washing are also good.
Embodiment 17
In addition to the condition of heating, pressurization is set as 190 DEG C of transfer temperature, transfer pressure 0.01MPa, other than 60 seconds time,
It handles identically as embodiment 9 and 10, as a result, color emissivity is poorer than embodiment 9 and 10.But if temperature is set as 200
DEG C, pressure is set as 0.02MPa, will be set as the time 3 minutes, then as a result, color emissivity becomes good.
Comparative example 5
Commercially available sublimation transfer printing and dyeing paper Jetcol TA (Coldenhove companies are used as transfer printing and dyeing paper
System), it is printed with the ink comprising non-subliming type disperse dyes of embodiment 9, to obtain transfer printing and dyeing paper.Then, make
Transfer printing and dyeing paper and polyester taffeta are closely sealed, after carrying out color development experiment with 210 DEG C, 0.02MPa, 40 seconds, as a result, color development
Property is bad.
Claims (11)
1. a kind of transfer method of printing and dyeing of polyester fiber material, which is characterized in that using disperse dye inks to assigning paste
It is printed, the transfer printing and dyeing paper of gained is sealed at polyester fiber material and is added with paper to printing and dyeing are transferred obtained by body paper
Pressure, heating, to carry out transfer printing and dyeing,
The disperse dye inks are non-subliming type disperse dye inks,
The paste is that have to be selected from acidic-group, the ester body of the acidic-group, amide body, alkali metal salt or alkaline-earth metal
The paste of functional group in salt and cation group, the acidic-group are selected from carboxyl, sulfonic group and phosphate;Or
The paste is the paste for being selected from natural adhesive paste, cellulose derivative and polysaccharide and being also combined with carboxylic acid compound class.
2. the transfer method of printing and dyeing of polyester fiber material according to claim 1, which is characterized in that the paste is to be selected from
One or more of animal system thickener and department of botany's thickener.
3. the transfer method of printing and dyeing of the polyester fiber material according to claim 1 or claim 2, which is characterized in that institute
State paste be have selected from acidic-group, the ester body of the acidic-group, amide body, alkali metal salt or alkali salt and
The paste of functional group in cation group, and it is also combined with carboxylic acid compound class, the acidic-group is selected from carboxyl, sulfonic group
And phosphate.
4. the transfer method of printing and dyeing of the polyester fiber material according to any one of claim 1 to claim 3, feature
It is, the carboxylic acid compound class is to be selected from one or more of fatty family carboxylic acid and aromatic system carboxylic acid.
5. the transfer method of printing and dyeing of the polyester fiber material according to any one of claim 1 to claim 4, feature
It is, further coordinates into the paste in Acidic Compounds, mineral system acid compound and mineral system additive
1 kind or more, the Acidic Compounds are the salt formed by strong acid and weak base.
6. the transfer method of printing and dyeing of the polyester fiber material according to any one of claim 1 to claim 3, feature
It is, the further compounding aid into the paste.
7. the transfer method of printing and dyeing of the polyester fiber material according to any one of claim 1 to claim 6, feature
It is, the non-subliming type disperse dye inks are the disperse dyes systems for using micronized to be 0.2 μm~10 μm to average grain diameter
The base gravure ink or flexographic ink made or be the use of micronized to average grain diameter is 0.05 μm~0.2 μm disperse dyes
The jetted ink produced, the disperse dyes are the non-subliming types point of one or more of disperse dyes selected from S types or SE types
Dissipate dyestuff.
8. the transfer method of printing and dyeing of the polyester fiber material according to any one of claim 1 to claim 7, feature
It is, the polyester fiber material is selected from polyethylene terephthalate, poly terephthalic acid 1,3-PD ester, gathers
In mutual-phenenyl two acid bromide two alcohol ester, polylactic acid, depolymerizing polyester, cation dyeable polyester, room temperature dyeable polyester and Alkali reduction polyester
The high molecular textile fabric of Polyester, braided fabric, non-woven fabrics, piece or film;Or the textile fabric, braided fabric or non-woven fabrics and choosing
The fiber in synthetic fibers from natural fiber and other than the Polyester macromolecule it is blended, be blended, intertexture or multiple
Condensation material.
9. the transfer method of printing and dyeing of the polyester fiber material according to any one of claim 1 to claim 8, feature
It is, pressurizes, heats under conditions of transfer temperature is 150 DEG C~250 DEG C, transfer pressure is 0.01MPa or more, to carry out
The transfer printing and dyeing.
10. a kind of manufacturing method of transfer printing and dyeing paper, which is characterized in that being assigned to body paper has selected from acidic-group, described
Ester body, amide body, alkali metal salt or the paste of the functional group in alkali salt and cation group of acidic-group, institute
It states acidic-group and is selected from carboxyl, sulfonic group and phosphate,
Alternatively, assigning body paper selected from natural adhesive paste, cellulose derivative and polysaccharide and being also combined with carboxylic acid compound class
Paste.
11. a kind of manufacturing method of polyester fiber material, which is characterized in that have using in claim 1 to claim 9
The process that the transfer method of printing and dyeing of any one of them polyester fiber material carries out transfer printing and dyeing to polyester fiber material.
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-257879 | 2015-12-25 | ||
| JP2015257879 | 2015-12-25 | ||
| JP2016-108172 | 2016-05-31 | ||
| JP2016108172 | 2016-05-31 | ||
| PCT/JP2016/088527 WO2017111107A1 (en) | 2015-12-25 | 2016-12-22 | Transfer-printing method for polyester-based fibrous materials |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108699765A true CN108699765A (en) | 2018-10-23 |
Family
ID=59090662
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680082408.5A Pending CN108699765A (en) | 2015-12-25 | 2016-12-22 | The transfer method of printing and dyeing of polyester fiber material |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP6173641B1 (en) |
| KR (1) | KR20180098326A (en) |
| CN (1) | CN108699765A (en) |
| WO (1) | WO2017111107A1 (en) |
Cited By (3)
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|---|---|---|---|---|
| CN112030579A (en) * | 2020-08-11 | 2020-12-04 | 广东冠豪高新技术股份有限公司 | Use of functional compounds in intermediate transfer media |
| CN115522405A (en) * | 2022-09-28 | 2022-12-27 | 广东冠豪高新技术股份有限公司 | Thermal sublimation transfer printing paper coating and preparation method and application thereof |
| CN117430968A (en) * | 2023-09-15 | 2024-01-23 | 菲诺染料化工(无锡)有限公司 | Composite disperse blue dye composition for polylactic acid fibers |
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| JP6465325B1 (en) * | 2018-02-09 | 2019-02-06 | 眩士 山本 | Transfer printing method |
| JP2019173233A (en) * | 2018-03-29 | 2019-10-10 | 株式会社丸保 | Method for transfer-printing polyamide fiber material |
| CN109505173A (en) * | 2018-11-27 | 2019-03-22 | 杭州卓达染整有限公司 | A kind of digital transfering printing process for Zein fiber fabric |
| JP2020165070A (en) * | 2019-03-26 | 2020-10-08 | 三菱製紙株式会社 | Transfer paper |
| WO2020195284A1 (en) * | 2019-03-26 | 2020-10-01 | 三菱製紙株式会社 | Transfer paper and transfer printing method |
| JP7222486B2 (en) * | 2020-06-26 | 2023-02-15 | 株式会社丸保 | Transfer printing method for polyester fiber material and method for producing transfer-printed polyester fiber product |
| CN111851137B (en) * | 2020-07-24 | 2022-04-01 | 淄博圣泉纸业有限公司 | Preparation method of low-absorption high-efficiency transfer printing paper |
| CN112227093A (en) * | 2020-10-26 | 2021-01-15 | 章浙峰 | Pillowcase printing method |
| KR102461011B1 (en) * | 2020-12-14 | 2022-11-01 | (주)윤텍스타일 | Manufacturing method of antibacterial fabric for maks using copper coating thread |
| CN112941900B (en) * | 2021-02-03 | 2022-05-24 | 浙江工业职业技术学院 | Processing method of polyester fabric |
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Also Published As
| Publication number | Publication date |
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| KR20180098326A (en) | 2018-09-03 |
| JP6173641B1 (en) | 2017-08-02 |
| WO2017111107A1 (en) | 2017-06-29 |
| JPWO2017111107A1 (en) | 2017-12-21 |
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