CN106283748B - A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof - Google Patents
A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof Download PDFInfo
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- CN106283748B CN106283748B CN201610562860.3A CN201610562860A CN106283748B CN 106283748 B CN106283748 B CN 106283748B CN 201610562860 A CN201610562860 A CN 201610562860A CN 106283748 B CN106283748 B CN 106283748B
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The present invention relates to a kind of textile printing and dyeing environmentally protective food grade acidity bodies and preparation method thereof；Belong to technical field of textile printing.The acid body of the present invention, raw material and parts by weight are：56 68 parts of 26 36 parts of deionized water, 4.6 6.8 parts of potassium hydrogen peroxymonosulfate, 10 16 parts of light-coloured vinegar and citric acid.Nontoxic, safe and environment-friendly, edible, and compared with citric acid, have price advantage；Loose colour can preferably be complexed, keep the color of textile more gorgeous, bright；Without additional addition soaping agent when use；The metal ions such as calcium, magnesium, arsenic, lead, Gong in water quality can be complexed, make product safety, nontoxic；So that the surface of the textile after printing and dyeing does not have one layer of white；With stronger dirt-removing power, can prevent by variegated pollution；The good color fastness of treated textile, it is colour-fast；Can effectively prevent treated, textile causes secondary pollution to other products in use.
Description
Technical field
The present invention relates to a kind of textile printing and dyeing environmentally protective food grade acidity bodies and preparation method thereof；Belong to textile printing and dyeing
Technical field.
Background technology
Currently, the kind of the dyeing acid used during textile printing and dyeing has：Sulfuric acid, synthesis acid（Dyeing acid）, technical grade
Glacial acetic acid；No matter these product category dangerous material bring greatly inconvenient and insecurity in terms of transport and business administration.And
And existed to human body insecurity using above-mentioned dyeing acid in textile and dyeing industry；Such as, in operation, above-mentioned dyeing
Acid, which splashes, causes burn, scald to leave permanent scar on worker's skin, splash the event in worker's eyes and happen occasionally and cause
Life-long disabilities.People is more allowed to worry, the medical textile products prepared at present using above-mentioned dyeing acid（Medical absorbent cotton, medical yarn
Cloth, medical cotton ball, medical cotton stick etc.）Heavy metal, such as arsenic, lead, Gong are usually contained, food grade security level is not achieved.
Invention content
The purpose of the present invention is to provide a kind of environmentally protective food grades of efficient, environmentally friendly, nontoxic, safe textile printing and dyeing
Acid body；To substitute existing dyeing acid, and it can realize, even preferably effect suitable with existing dyeing acid.
The present invention also provides the textile printing and dyeing preparation methods of environmentally protective food grade acidity body.
Technical solution
A kind of environmentally protective food grade acidity body of textile printing and dyeing, raw material and parts by weight are：26-36 parts of deionized water,
56-68 parts of 4.6-6.8 parts of potassium hydrogen peroxymonosulfate, 10-16 parts of light-coloured vinegar and citric acid.
The potassium hydrogen peroxymonosulfate, also known as Potassium Monopersulfate, molecular formula are KHSO5。
The light-coloured vinegar is the tart flavour auxiliary material cooked, color and luster is bright, tart flavour alcohol just；The acetic acid and water of the 3-5% containing mass concentration.
The citric acid, white crystalline powder.
The environmentally protective food grade acidity body of above-mentioned textile printing and dyeing, preferably constitute for：26 parts of deionized water, permonosulphuric acid
60 parts of 4.6 parts of hydrogen potassium, 16 parts of light-coloured vinegar and citric acid.
Light-coloured vinegar and citric acid are food grade materials so that product of the invention is environmentally friendly, nontoxic, edible.Light-coloured vinegar and lemon
Lemon acid coordinates, and on the one hand citric acid can be enable to be completely dissolved, prevent dissolved lemon acid crystal（Lemon acid crystal can cause
Filament damage）, on the other hand can surprisingly play effect of preferably soaping.
The above-mentioned textile printing and dyeing preparation method of environmentally protective food grade acidity body, includes the following steps：
In a kettle, 100-120 DEG C is warming up to after potassium hydrogen peroxymonosulfate being dissolved in deionized water, heat preservation
46 DEG C are cooled to after 28min；Then light-coloured vinegar is added and stirs 6min, adds citric acid, capping kettle, heat preservation 48min.
Above-mentioned preparation method, in order to make potassium hydrogen peroxymonosulfate quickly be dissolved in deionized water, preferably by deionized water
Potassium hydrogen peroxymonosulfate, and the insulated and stirred 26min after potassium hydrogen peroxymonosulfate is added are added after being heated to 46 DEG C.
Above-mentioned preparation method, the purpose of " potassium hydrogen peroxymonosulfate is warming up to 100-120 DEG C after being dissolved in deionized water "
It is：The acid body of preparation is set to have excellent sterilization, disinfection, insect prevention, anti-mildew effect.
Above-mentioned preparation method, each temperature parameter are by being obtained after many experiments；The institute only under this temperature parameter
The properties of the acid body of preparation could meet the requirement of " suitable with existing dyeing acid, even preferably effect ".
The environmentally protective food grade acidity body of above-mentioned textile printing and dyeing, as dyeing acid, in the dyeing process of textile；
Use temperature range：30-80℃；Dosage：0.5-1kg acidity body/100kg textiles.
Advantageous effect
The acid body of the present invention：
1, nontoxic, safe and environment-friendly, edible, and compared with citric acid, have price advantage；
2, effect of soaping is good：Loose colour can preferably be complexed, keep the color of textile more gorgeous, bright；Volume is not necessarily to when use
Outer addition soaping agent；
3, the metal ions such as calcium, magnesium, arsenic, lead, Gong in water quality are complexed, make product safety, nontoxic；So that the spinning after printing and dyeing
The surface of fabric does not have one layer of white；
4, there is stronger dirt-removing power, remaining color dirt impurity dye can be prevented；
5, the good color fastness of treated textile, it is colour-fast；The textile that can effectively prevent that treated is using process
In secondary pollution is caused to other products.
Specific implementation mode
Embodiment 1
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg, light-coloured vinegar 10kg and citric acid 56kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate is added, stir,
It is continuously heating to 100 DEG C after heat preservation 26min；It is cooled to 46 DEG C after stirring, heat preservation 28min；Be added light-coloured vinegar, stir 6min after slowly
Citric acid is added；Add citric acid rear enclosed reaction kettle, stirring, heat preservation 48min；It can be obtained acid body.The acidity obtained
Body, under normal temperature condition, exposed to air will not crystallize placing 96 days.
Embodiment 2
Deionized water 26kg, potassium hydrogen peroxymonosulfate 6.8kg, light-coloured vinegar 16kg and citric acid 68kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate is added, stir,
It is continuously heating to 100 DEG C after heat preservation 26min；It is cooled to 46 DEG C after stirring, heat preservation 28min；Be added light-coloured vinegar, stir 6min after slowly
Citric acid is added；Add citric acid rear enclosed reaction kettle, stirring, heat preservation 48min；It can be obtained acid body.The acidity obtained
Body, under normal temperature condition, exposed to air will not crystallize placing 96 days.
Embodiment 3
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg, light-coloured vinegar 16kg and citric acid 60kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate is added, stir,
It is continuously heating to 100 DEG C after heat preservation 26min；It is cooled to 46 DEG C after stirring, heat preservation 28min；Be added light-coloured vinegar, stir 6min after slowly
Citric acid is added；Add citric acid rear enclosed reaction kettle, stirring, heat preservation 48min；It can be obtained acid body.The acidity obtained
Body, under normal temperature condition, exposed to air will not crystallize placing 96 days.
Embodiment 4
Deionized water 36kg, potassium hydrogen peroxymonosulfate 4.6kg, light-coloured vinegar 10kg and citric acid 56kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate is added, stir,
It is continuously heating to 100 DEG C after heat preservation 26min；It is cooled to 46 DEG C after stirring, heat preservation 28min；Be added light-coloured vinegar, stir 6min after slowly
Citric acid is added；Add citric acid rear enclosed reaction kettle, stirring, heat preservation 48min；It can be obtained acid body.The acidity obtained
Body, under normal temperature condition, exposed to air will not crystallize placing 96 days.
Embodiment 5
Deionized water 36kg, potassium hydrogen peroxymonosulfate 6.8kg, light-coloured vinegar 16kg and citric acid 68kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate is added, stir,
It is continuously heating to 100 DEG C after heat preservation 26min；It is cooled to 46 DEG C after stirring, heat preservation 28min；Be added light-coloured vinegar, stir 6min after slowly
Citric acid is added；Add citric acid rear enclosed reaction kettle, stirring, heat preservation 48min；It can be obtained acid body.The acidity obtained
Body, under normal temperature condition, exposed to air will not crystallize placing 96 days.
Embodiment 6
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg, light-coloured vinegar 10kg and citric acid 56kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate is added, stir,
It is continuously heating to 120 DEG C after heat preservation 26min；It is cooled to 46 DEG C after stirring, heat preservation 28min；Be added light-coloured vinegar, stir 6min after slowly
Citric acid is added；Add citric acid rear enclosed reaction kettle, stirring, heat preservation 48min；It can be obtained acid body.The acidity obtained
Body, under normal temperature condition, exposed to air will not crystallize placing 96 days.
Comparative example 1
Deionized water 26kg, light-coloured vinegar 10kg and citric acid 56kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Be added light-coloured vinegar, stir 6min after slowly
Citric acid is added；Add citric acid rear enclosed reaction kettle, stirring, heat preservation 48min；It can be obtained acid body.The acidity obtained
Body, under normal temperature condition, exposed to air will not crystallize placing 96 days.
Comparative example 2
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg and citric acid 56kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate is added, stir,
It is continuously heating to 100 DEG C after heat preservation 26min；It is cooled to 46 DEG C after stirring, heat preservation 28min；Citric acid is added；After adding citric acid
Capping kettle, stirring, heat preservation 48min；It can be obtained acid body.There is crystallization in the acid body obtained；In normal temperature condition
Under, exposed to air, after placing 1 day, crystalline content improves 9.6%.
Comparative example 3
Deionized water 26kg, citric acid 56kg.
Deionized water is added in reaction kettle, is opened and is stirred and be warming up to 46 DEG C；Citric acid is added；After adding citric acid
Capping kettle, stirring, heat preservation 48min；It can be obtained acid body.There is crystallization in the acid body obtained；In normal temperature condition
Under, exposed to air, after placing 2 hours, crystalline content improves 16.8%.
Comparative example 4
Using the sulfuric acid solution that mass concentration is 38% as acid body.
Embodiment 7
（1）Acid body prepared by embodiment 1-6, comparative example 1-4 is respectively adopted, using following dyeing conditions to stained clot-h into
Row dyeing.Dyeing condition：The red B-4BD of dye activity, dosage 6%（Quality relative to stained clot-h）；Acid body, dosage 1%（Phase
For the quality of stained clot-h）；Water consumption is 10 liters of water/1Kg stained clot-hs；Bath raio is：1:10；Other auxiliary materials be anhydrous sodium sulphate, soda ash,
Deoxygenase, dosage mutually should be：50g/ rises water, 25g/ rises water, 0.1g/ rises water；130 DEG C of temperature；Time 15min.Stained clot-h is taken out,
In 130 DEG C of drying.
（2）Treated that stained clot-h is primary with cold rinse respectively by dyed, the depth of observation drift foot-washing water, as a result such as
Table 1.
（3）By the stained clot-h by rinsing processing, in 130 DEG C of drying；Then color fastness to washing experimental method GB/ is pressed respectively
T 3921-2008 and colour fasteness to sunlight GB/T 8427-2008 test its color fastness；The results are shown in Table 1.
Table 1
。
Claims (2)
1. a kind of environmentally protective food grade acidity body of textile printing and dyeing, which is characterized in that its raw material and parts by weight are：Deionized water
56-68 parts of 26-36 parts, 4.6-6.8 parts of potassium hydrogen peroxymonosulfate, 10-16 parts of light-coloured vinegar and citric acid；
Preparation method includes the following steps：
Deionized water is added in reaction kettle, stir and is warming up to 46 DEG C；Potassium hydrogen peroxymonosulfate, stirring, heat preservation 26min is added
After be continuously heating to 100-120 DEG C；It is cooled to 46 DEG C after stirring, heat preservation 28min；Light-coloured vinegar is added, stirs 6min, lemon is added
Acid, capping kettle, stirring, heat preservation 48min.
2. the environmentally protective food grade acidity body of textile printing and dyeing according to claim 1, which is characterized in that deionized water 26
Part, 4.6 parts of potassium hydrogen peroxymonosulfate, 16 parts of light-coloured vinegar and 60 parts of citric acid.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610562860.3A CN106283748B (en) | 2016-07-18 | 2016-07-18 | A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof |
| PCT/CN2017/092765 WO2018014775A1 (en) | 2016-07-18 | 2017-07-13 | Environmentally-friendly food grade acidic body for textile printing and dyeing and preparation method therefor |
| AU2017299652A AU2017299652B2 (en) | 2016-07-18 | 2017-07-13 | Environmentally-friendly food grade acidic body for textile printing and dyeing and preparation method therefor |
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| CN201610562860.3A CN106283748B (en) | 2016-07-18 | 2016-07-18 | A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof |
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| CN106283748B (en) * | 2016-07-18 | 2018-08-21 | 济宁锦祥科技发展有限公司 | A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof |
| CN107837210A (en) * | 2017-11-15 | 2018-03-27 | 济宁锦祥科技发展有限公司 | A kind of pollution-free food level disinfection hand cleanser |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1033469A (en) * | 1987-12-08 | 1989-06-21 | 新疆阜康助剂厂 | A kind of acid colouring agent |
| CN101302711A (en) * | 2008-06-20 | 2008-11-12 | 杭州下沙恒升化工有限公司 | Solid tasteless odorless acid agent for textile dyeing and finishing process |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1054627A (en) * | 1990-03-05 | 1991-09-18 | 孙德和 | The preparation method of uniform dyeing compound organic acid-staining acid |
| JPH04316687A (en) * | 1991-04-08 | 1992-11-09 | Kanebo Ltd | Coloring of cellulosic fiber structure containing protein fiber |
| CN1263964A (en) * | 1999-02-13 | 2000-08-23 | 黄成勋 | Dyeing acid |
| CN101906726B (en) * | 2010-08-19 | 2012-10-24 | 中国纺织科学研究院 | Method for dyeing modified polyester |
| CN102108641B (en) * | 2011-01-12 | 2012-09-05 | 郑州鸿盛数码科技股份有限公司 | Digital printing active dye jet ink |
| CN104404709A (en) * | 2014-09-03 | 2015-03-11 | 江苏阳光集团有限公司 | Production process for anti-ultraviolet radiation fabric |
| CN105623873A (en) * | 2015-12-29 | 2016-06-01 | 辛集市远翔环保能源科技有限公司 | Cleaning agent for removing pesticide residues on fruits |
| CN106283748B (en) * | 2016-07-18 | 2018-08-21 | 济宁锦祥科技发展有限公司 | A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof |
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Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1033469A (en) * | 1987-12-08 | 1989-06-21 | 新疆阜康助剂厂 | A kind of acid colouring agent |
| CN101302711A (en) * | 2008-06-20 | 2008-11-12 | 杭州下沙恒升化工有限公司 | Solid tasteless odorless acid agent for textile dyeing and finishing process |
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| CN106283748A (en) | 2017-01-04 |
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| AU2017299652B2 (en) | 2020-02-27 |
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Denomination of invention: A green and environmentally friendly edible grade acidic substance for textile printing and dyeing and its preparation method Effective date of registration: 20230705 Granted publication date: 20180821 Pledgee: China Postal Savings Bank Limited by Share Ltd. Wenshang County sub branch Pledgor: Jining Jinxiang Technology Development Co.,Ltd. Registration number: Y2023980047429 |
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