CN106283748A - A kind of textile printing and dyeing environmental protection food grade acid gonosome and preparation method thereof - Google Patents
A kind of textile printing and dyeing environmental protection food grade acid gonosome and preparation method thereof Download PDFInfo
- Publication number
- CN106283748A CN106283748A CN201610562860.3A CN201610562860A CN106283748A CN 106283748 A CN106283748 A CN 106283748A CN 201610562860 A CN201610562860 A CN 201610562860A CN 106283748 A CN106283748 A CN 106283748A
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- CN
- China
- Prior art keywords
- acid
- textile
- citric acid
- dyeing
- deionized water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/653—Nitrogen-free carboxylic acids or their salts
- D06P1/6533—Aliphatic, araliphatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
Abstract
The present invention relates to a kind of textile printing and dyeing environmental protection food grade acid gonosome and preparation method thereof；Belong to technical field of textile printing.The acid body of the present invention, its raw material and weight portion be: deionized water 26 36 parts, potassium hydrogen peroxymonosulfate 4.6 6.8 parts, white vinegar 10 16 parts and citric acid 56 68 parts.Nontoxic, safe and environment-friendly, edible, and compared with citric acid, possess price advantage；Energy preferably complexation loose colour, the color making textile is more gorgeous, bright；Without additionally adding soaping agent during use；Can the metal ion such as calcium in complexation water quality, magnesium, arsenic, lead, Gong, make product safety, nontoxic；The surface making the textile after printing and dyeing does not have one layer of white；There is stronger dirt-removing power, can prevent by variegated pollution；The color fastness of the textile after process is good, colour-fast；Can effectively prevent the textile after processing from use other products are caused secondary pollution.
Description
Technical field
The present invention relates to a kind of textile printing and dyeing environmental protection food grade acid gonosome and preparation method thereof；Belong to textile printing and dyeing
Technical field.
Background technology
At present, the kind of the dyeing acid used during textile printing and dyeing has: sulphuric acid, synthesis acid (dyeing acid), technical grade
Glacial acetic acid；These products belong to dangerous materials, no matter bring inconvenience and insecurity greatly in terms of transport and business administration.And
And, use above-mentioned dyeing acid to exist human body unsafe factor in textile and dyeing industry；As, in operative, above-mentioned dyeing
Acid splashes and causes burn, scald to leave permanent scar on workman's skin, and the event in workman's eyes that splashes happens occasionally and causes
Life-long disabilities.More allow people worry, use medical textile products (medical absorbent cotton, medical yarn prepared by above-mentioned dyeing acid at present
Cloth, medical cotton ball, medical cotton stick etc.) usually contain heavy metal, such as arsenic, lead, Gong, do not reach food grade level of security.
Summary of the invention
It is an object of the invention to provide a kind of efficiently, environmental protection, nontoxic, safe textile printing and dyeing environmental protection food grade
Acid body；To substitute existing dyeing acid, and can realize with existing dyeing acid quite, even preferably effect.
Present invention also offers the preparation method of this textile printing and dyeing environmental protection food grade acid gonosome.
Technical scheme
A kind of textile printing and dyeing environmental protection food grade acid gonosome, its raw material and weight portion be: deionized water 26-36 part, crosses one
Potassium acid sulfate 4.6-6.8 part, white vinegar 10-16 part and citric acid 56-68 part.
Described potassium hydrogen peroxymonosulfate, also known as Potassium Monopersulfate, molecular formula is KHSO5。
Described white vinegar, be cooking tart flavour adjuvant, color and luster is bright, tart flavour alcohol just；Acetic acid containing mass concentration 3-5% and water.
Described citric acid, white crystalline powder.
Above-mentioned textile printing and dyeing environmental protection food grade acid gonosome, preferably constitutes as deionized water 26 parts, permonosulphuric acid
4.6 parts of hydrogen potassium, white vinegar 16 parts and citric acid 60 parts.
White vinegar and citric acid are food grade materials so that the product environmental protection of the present invention, nontoxic, edible.White vinegar and lemon
Lemon acid coordinates, and one side can make citric acid to be completely dissolved, (citric acid crystallization can cause to prevent the citric acid crystallization after dissolving
Filament damage), on the other hand can surprisingly play effect of preferably soaping.
The preparation method of above-mentioned textile printing and dyeing environmental protection food grade acid gonosome, comprises the following steps:
In a kettle., after being dissolved in deionized water by potassium hydrogen peroxymonosulfate, it is warming up to 100-120 DEG C, after insulation 28min
It is cooled to 46 DEG C；It is subsequently adding white vinegar stirring 6min, adds citric acid, capping still, insulation 48min.
Above-mentioned preparation method, in order to make potassium hydrogen peroxymonosulfate rapid solution in deionized water, preferably by deionized water
Potassium hydrogen peroxymonosulfate, and insulated and stirred 26min after adding potassium hydrogen peroxymonosulfate is added after being heated to 46 DEG C.
Above-mentioned preparation method, the purpose of " potassium hydrogen peroxymonosulfate is warming up to 100-120 DEG C after being dissolved in deionized water "
It is: make the acid body of preparation possess the sterilization of excellence, sterilization, insect protected, anti-mildew effect.
Above-mentioned preparation method, each temperature parameter obtains after great many of experiments；Only institute under this temperature parameter
The properties of acid body of preparation could meet " with existing dyeing acid quite, even preferably effect " requirement.
Above-mentioned textile printing and dyeing environmental protection food grade acid gonosome, as dyeing acid, in the dyeing process of textile；
Use temperature range: 30-80 DEG C；Consumption: 0.5-1kg acidity body/100kg textile.
Beneficial effect
The acid body of the present invention:
1, nontoxic, safe and environment-friendly, edible, and compared with citric acid, possess price advantage；
2, soap effective: can more preferable complexation loose colour, the color making textile is more gorgeous, bright；Without additionally adding during use
Add soaping agent；
The metal ions such as calcium in 3, complexation water quality, magnesium, arsenic, lead, Gong, make product safety, nontoxic；Make the textile after printing and dyeing
Surface do not have one layer of white；
4, there is stronger dirt-removing power, can prevent remaining color dirt impurity from contaminating；
The color fastness of the textile after 5, processing is good, colour-fast；Can effectively prevent the textile after processing the most right
Other products cause secondary pollution.
Detailed description of the invention
Embodiment 1
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg, white vinegar 10kg and citric acid 56kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add potassium hydrogen peroxymonosulfate, stir,
It is continuously heating to 100 DEG C after insulation 26min；It is cooled to 46 DEG C after stirring, insulation 28min；Add white vinegar, after stirring 6min slowly
Add citric acid；Add citric acid rear enclosed reactor, stir, be incubated 48min；Acid body can be obtained.The acidity obtained
Body, under normal temperature condition, exposed to air, within 96 days, do not have crystallization even if placing yet.
Embodiment 2
Deionized water 26kg, potassium hydrogen peroxymonosulfate 6.8kg, white vinegar 16kg and citric acid 68kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add potassium hydrogen peroxymonosulfate, stir,
It is continuously heating to 100 DEG C after insulation 26min；It is cooled to 46 DEG C after stirring, insulation 28min；Add white vinegar, after stirring 6min slowly
Add citric acid；Add citric acid rear enclosed reactor, stir, be incubated 48min；Acid body can be obtained.The acidity obtained
Body, under normal temperature condition, exposed to air, within 96 days, do not have crystallization even if placing yet.
Embodiment 3
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg, white vinegar 16kg and citric acid 60kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add potassium hydrogen peroxymonosulfate, stir,
It is continuously heating to 100 DEG C after insulation 26min；It is cooled to 46 DEG C after stirring, insulation 28min；Add white vinegar, after stirring 6min slowly
Add citric acid；Add citric acid rear enclosed reactor, stir, be incubated 48min；Acid body can be obtained.The acidity obtained
Body, under normal temperature condition, exposed to air, within 96 days, do not have crystallization even if placing yet.
Embodiment 4
Deionized water 36kg, potassium hydrogen peroxymonosulfate 4.6kg, white vinegar 10kg and citric acid 56kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add potassium hydrogen peroxymonosulfate, stir,
It is continuously heating to 100 DEG C after insulation 26min；It is cooled to 46 DEG C after stirring, insulation 28min；Add white vinegar, after stirring 6min slowly
Add citric acid；Add citric acid rear enclosed reactor, stir, be incubated 48min；Acid body can be obtained.The acidity obtained
Body, under normal temperature condition, exposed to air, within 96 days, do not have crystallization even if placing yet.
Embodiment 5
Deionized water 36kg, potassium hydrogen peroxymonosulfate 6.8kg, white vinegar 16kg and citric acid 68kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add potassium hydrogen peroxymonosulfate, stir,
It is continuously heating to 100 DEG C after insulation 26min；It is cooled to 46 DEG C after stirring, insulation 28min；Add white vinegar, after stirring 6min slowly
Add citric acid；Add citric acid rear enclosed reactor, stir, be incubated 48min；Acid body can be obtained.The acidity obtained
Body, under normal temperature condition, exposed to air, within 96 days, do not have crystallization even if placing yet.
Embodiment 6
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg, white vinegar 10kg and citric acid 56kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add potassium hydrogen peroxymonosulfate, stir,
It is continuously heating to 120 DEG C after insulation 26min；It is cooled to 46 DEG C after stirring, insulation 28min；Add white vinegar, after stirring 6min slowly
Add citric acid；Add citric acid rear enclosed reactor, stir, be incubated 48min；Acid body can be obtained.The acidity obtained
Body, under normal temperature condition, exposed to air, within 96 days, do not have crystallization even if placing yet.
Comparative example 1
Deionized water 26kg, white vinegar 10kg and citric acid 56kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add white vinegar, after stirring 6min slowly
Add citric acid；Add citric acid rear enclosed reactor, stir, be incubated 48min；Acid body can be obtained.The acidity obtained
Body, under normal temperature condition, exposed to air, within 96 days, do not have crystallization even if placing yet.
Comparative example 2
Deionized water 26kg, potassium hydrogen peroxymonosulfate 4.6kg and citric acid 56kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add potassium hydrogen peroxymonosulfate, stir,
It is continuously heating to 100 DEG C after insulation 26min；It is cooled to 46 DEG C after stirring, insulation 28min；Add citric acid；After adding citric acid
Capping still, stirs, is incubated 48min；Acid body can be obtained.The acid body obtained exists crystallization；At normal temperature condition
Under, exposed to air, after placing 1 day, crystalline content improves 9.6%.
Comparative example 3
Deionized water 26kg, citric acid 56kg.
Deionized water is joined in reactor, open stirring and be warming up to 46 DEG C；Add citric acid；After adding citric acid
Capping still, stirs, is incubated 48min；Acid body can be obtained.The acid body obtained exists crystallization；At normal temperature condition
Under, exposed to air, after placing 2 hours, crystalline content improves 16.8%.
Comparative example 4
Using sulfuric acid solution that mass concentration is 38% as acid body.
Embodiment 7
(1) be respectively adopted embodiment 1-6, acid body prepared by comparative example 1-4, use following dyeing condition that stained clot-h is contaminated
Color.Dyeing condition: the red B-4BD of dye activity, consumption 6%(is relative to the quality of stained clot-h)；Acid body, consumption 1%(relative to
The quality of stained clot-h)；Water consumption is 10 liters of water/1Kg stained clot-h；Bath raio is: 1:10；Other adjuvants are Matrii Sulfas Exsiccatus, soda, deoxidation
Enzyme, consumption should be mutually: 50g/ rises water, 25g/ rises water, 0.1g/ rises water；Temperature 130 DEG C；Time 15min.Take out stained clot-h, in
130 DEG C of drying.
(2) by the stained clot-h after dyed process respectively by cold rinse once, observing the depth of drift foot-washing water, result is such as
Table 1.
(3) stained clot-h that will process through rinsing, in 130 DEG C of drying；Press color fastness to washing experimental technique GB/ the most respectively
T 3921-2008 and colour fasteness to sunlight GB/T 8427-2008 tests its color fastness；Result is as shown in table 1.
Table 1
Claims (4)
1. a textile printing and dyeing environmental protection food grade acid gonosome, it is characterised in that its raw material and weight portion be: deionized water
26-36 part, potassium hydrogen peroxymonosulfate 4.6-6.8 part, white vinegar 10-16 part and citric acid 56-68 part.
Textile printing and dyeing environmental protection food grade acid gonosome the most according to claim 1, it is characterised in that deionized water 26
Part, potassium hydrogen peroxymonosulfate 4.6 parts, white vinegar 16 parts and citric acid 60 parts.
3. the preparation method for environmental protection food grade acid gonosome of textile printing and dyeing described in claim 1 or 2, its feature exists
In, comprise the following steps:
In a kettle., after being dissolved in deionized water by potassium hydrogen peroxymonosulfate, it is warming up to 100-120 DEG C, after insulation 28min
It is cooled to 46 DEG C；It is subsequently adding white vinegar stirring 6min, adds citric acid, capping still, insulation 48min.
Preparation method the most according to claim 3, it is characterised in that added a sulfur after deionized water is heated to 46 DEG C
Potassium hydrogen phthalate, and insulated and stirred 26min after adding potassium hydrogen peroxymonosulfate.
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610562860.3A CN106283748B (en) | 2016-07-18 | 2016-07-18 | A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof |
| PCT/CN2017/092765 WO2018014775A1 (en) | 2016-07-18 | 2017-07-13 | Environmentally-friendly food grade acidic body for textile printing and dyeing and preparation method therefor |
| AU2017299652A AU2017299652B2 (en) | 2016-07-18 | 2017-07-13 | Environmentally-friendly food grade acidic body for textile printing and dyeing and preparation method therefor |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610562860.3A CN106283748B (en) | 2016-07-18 | 2016-07-18 | A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106283748A true CN106283748A (en) | 2017-01-04 |
| CN106283748B CN106283748B (en) | 2018-08-21 |
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| Country | Link |
|---|---|
| CN (1) | CN106283748B (en) |
| AU (1) | AU2017299652B2 (en) |
| WO (1) | WO2018014775A1 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018014775A1 (en) * | 2016-07-18 | 2018-01-25 | 济宁锦祥科技发展有限公司 | Environmentally-friendly food grade acidic body for textile printing and dyeing and preparation method therefor |
| CN107837210A (en) * | 2017-11-15 | 2018-03-27 | 济宁锦祥科技发展有限公司 | A kind of pollution-free food level disinfection hand cleanser |
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| CN1033469A (en) * | 1987-12-08 | 1989-06-21 | 新疆阜康助剂厂 | A kind of acid colouring agent |
| JPH04316687A (en) * | 1991-04-08 | 1992-11-09 | Kanebo Ltd | Coloring of cellulosic fiber structure containing protein fiber |
| CN101302711A (en) * | 2008-06-20 | 2008-11-12 | 杭州下沙恒升化工有限公司 | Solid tasteless odorless acid agent for textile dyeing and finishing process |
| CN101906726A (en) * | 2010-08-19 | 2010-12-08 | 中国纺织科学研究院 | Method for dyeing modified polyester |
| CN102108641A (en) * | 2011-01-12 | 2011-06-29 | 郑州鸿盛数码科技股份有限公司 | Digital printing active dye jet ink |
| CN104404709A (en) * | 2014-09-03 | 2015-03-11 | 江苏阳光集团有限公司 | Production process for anti-ultraviolet radiation fabric |
| CN105623873A (en) * | 2015-12-29 | 2016-06-01 | 辛集市远翔环保能源科技有限公司 | Cleaning agent for removing pesticide residues on fruits |
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| CN1054627A (en) * | 1990-03-05 | 1991-09-18 | 孙德和 | The preparation method of uniform dyeing compound organic acid-staining acid |
| CN1263964A (en) * | 1999-02-13 | 2000-08-23 | 黄成勋 | Dyeing acid |
| CN106283748B (en) * | 2016-07-18 | 2018-08-21 | 济宁锦祥科技发展有限公司 | A kind of textile printing and dyeing environmentally protective food grade acidity body and preparation method thereof |
-
2016
- 2016-07-18 CN CN201610562860.3A patent/CN106283748B/en active Active
-
2017
- 2017-07-13 AU AU2017299652A patent/AU2017299652B2/en active Active
- 2017-07-13 WO PCT/CN2017/092765 patent/WO2018014775A1/en active Application Filing
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1033469A (en) * | 1987-12-08 | 1989-06-21 | 新疆阜康助剂厂 | A kind of acid colouring agent |
| JPH04316687A (en) * | 1991-04-08 | 1992-11-09 | Kanebo Ltd | Coloring of cellulosic fiber structure containing protein fiber |
| CN101302711A (en) * | 2008-06-20 | 2008-11-12 | 杭州下沙恒升化工有限公司 | Solid tasteless odorless acid agent for textile dyeing and finishing process |
| CN101906726A (en) * | 2010-08-19 | 2010-12-08 | 中国纺织科学研究院 | Method for dyeing modified polyester |
| CN102108641A (en) * | 2011-01-12 | 2011-06-29 | 郑州鸿盛数码科技股份有限公司 | Digital printing active dye jet ink |
| CN104404709A (en) * | 2014-09-03 | 2015-03-11 | 江苏阳光集团有限公司 | Production process for anti-ultraviolet radiation fabric |
| CN105623873A (en) * | 2015-12-29 | 2016-06-01 | 辛集市远翔环保能源科技有限公司 | Cleaning agent for removing pesticide residues on fruits |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018014775A1 (en) * | 2016-07-18 | 2018-01-25 | 济宁锦祥科技发展有限公司 | Environmentally-friendly food grade acidic body for textile printing and dyeing and preparation method therefor |
| CN107837210A (en) * | 2017-11-15 | 2018-03-27 | 济宁锦祥科技发展有限公司 | A kind of pollution-free food level disinfection hand cleanser |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2018014775A1 (en) | 2018-01-25 |
| AU2017299652A1 (en) | 2019-03-07 |
| AU2017299652B2 (en) | 2020-02-27 |
| CN106283748B (en) | 2018-08-21 |
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Denomination of invention: A green and environmentally friendly edible grade acidic substance for textile printing and dyeing and its preparation method Effective date of registration: 20230705 Granted publication date: 20180821 Pledgee: China Postal Savings Bank Limited by Share Ltd. Wenshang County sub branch Pledgor: Jining Jinxiang Technology Development Co.,Ltd. Registration number: Y2023980047429 |
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