CN106283738A - A kind of preparation method of environment-friendly type dyeing paste - Google Patents
A kind of preparation method of environment-friendly type dyeing paste Download PDFInfo
- Publication number
- CN106283738A CN106283738A CN201610731631.XA CN201610731631A CN106283738A CN 106283738 A CN106283738 A CN 106283738A CN 201610731631 A CN201610731631 A CN 201610731631A CN 106283738 A CN106283738 A CN 106283738A
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- CN
- China
- Prior art keywords
- environment
- friendly type
- attapulgite
- parts
- type dyeing
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Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
- D06P1/48—Derivatives of carbohydrates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67383—Inorganic compounds containing silicon
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Molecular Biology (AREA)
- Coloring (AREA)
Abstract
A kind of environment-friendly type dyeing paste, primary raw material is attapulgite and modified corn starch, greatly reduces the addition of sodium alginate, low cost, and raw material sources are wide；Without adding the harmful chemicals such as formaldehyde in course of reaction, health environment-friendly；Containing attapulgite and corn starch in printing and dyeing aqueous solution after using, under the conditions of simple high speed dispersion, colloidal precipitation can be generated, it is also possible to other element in waste water is adsorbed and precipitated, significantly reduce the difficulty that waste water processes.
Description
Technical field
The present invention relates to technical field of textile printing, be specifically related to the preparation method of a kind of environment-friendly type dyeing paste.
Background technology
In printing with reactive dye, thickener is commonly used as thickening agent to regulate the rheological property of mill base.Sodium alginate is because of it not
React with reactive dye, the advantage such as tinctorial yield is high, chromatograph is complete, easily wash away from fabric, fabrics feel soft, the most active
The first-selection of reactive dye printing paste.But it is expensive, stamp cost is of a relatively high, and therefore finding a kind of # with low cost can print
The thickener of fine chemical wastewater processed has become as the task of top priority.
Starch is a kind of Renewable resource, and its deposit is abundant, easily obtains, but there is active hydroxyl groups on its molecule, easily with
Dyestuff reacts, and is therefore restricted in the application of printing paste with active dye.
Chinese invention patent CN103924457A discloses a kind of amyloid dyeing paste, but prepared by this thickener
Journey needs spray formaldehyde, environment and operator all can be caused certain harm.Polluting for reducing, Appropriate application starch provides
Source, it is necessary to a kind of environment-friendly type dyeing paste of research and development.
Summary of the invention
Object of the present invention is to provide a kind of environment-friendly type dyeing paste and preparation method thereof.
The preparation method of a kind of environment-friendly type dyeing paste, comprises the following steps:
A, by attapulgite pulverize after, cross 120 mesh sieves；
B, will pulverize after attapulgite add water and after corn starch carries out ball milling 20-30min, add sodium hydroxide, dioxy
SiClx micropowder and ethanol, proceed ball milling 2-3h；
C, stir after cross 250 mesh sieves, be precipitated and suspension, by precipitation continuation ball milling, suspension is spray-dried,
Obtain mixed powder；
D, mixed powder and sodium alginate are stirred 15-20min under 100-150rpm stirs speed, obtain environment-friendly type dyeing paste.
Preferably, in described step A, the addition of each raw material, weight ratio is:
Attapulgite 8-15 part
100 parts of water
Corn starch 15-20 part
Sodium hydroxide 1-2 part
Fine silica powder 2-5 part
Ethanol 0.1-0.2 part.
Preferably, in described step D, described mixed powder and the mass ratio of sodium alginate are (10-15): 1.
In the present invention by by silicon dioxide and corn starch under highly basic effect, react, reduce the hydroxyl in starch
Base activity, prevents it from reacting with dyestuff, and ball milling common with attapulgite has following effect: on the one hand attapulgite can also part
Replacing sodium alginate, reduce cost, be on the other hand chain layer structure, surface area is beaten, and adding attapulgite can increase reaction
Place, under grinding condition, the reaction effect of silicon dioxide and corn starch is good.
The useful of the present invention is effectively: 1, adds attapulgite and modified corn starch in the present invention, greatly reduces
The addition of sodium alginate, low cost, raw material sources are wide；2, without adding the harmful chemicals such as formaldehyde in course of reaction, strong
Kang Huanbao；3, containing attapulgite and corn starch in printing and dyeing aqueous solution after using, under the conditions of simple high speed dispersion,
Generate colloidal precipitation, it is also possible to other element in waste water is adsorbed and precipitated, significantly reduce the difficulty that waste water processes.
Detailed description of the invention
Embodiment 1
The preparation method of a kind of environment-friendly type dyeing paste, comprises the following steps:
A, by attapulgite pulverize after, cross 120 mesh sieves；
B, will pulverize after attapulgite add water and after corn starch carries out ball milling 25min, add sodium hydroxide, silicon dioxide
Micropowder and ethanol, proceed ball milling 2.5h；
C, stir after cross 250 mesh sieves, be precipitated and suspension, by precipitation continuation ball milling, suspension is spray-dried,
Obtain mixed powder；
D, mixed powder and sodium alginate are stirred 18min under 120rpm stirs speed, obtain environment-friendly type dyeing paste.
In described step A, the addition of each raw material, weight ratio is:
Attapulgite 12 parts
100 parts of water
Corn starch 18 parts
Sodium hydroxide 1.5 parts
Fine silica powder 3.5 parts
Ethanol 0.1 part.
In described step D, described mixed powder and the mass ratio of sodium alginate are 12:1.
Embodiment 2
The preparation method of a kind of environment-friendly type dyeing paste, comprises the following steps:
A, by attapulgite pulverize after, cross 120 mesh sieves；
B, will pulverize after attapulgite add water and after corn starch carries out ball milling 30min, add sodium hydroxide, silicon dioxide
Micropowder and ethanol, proceed ball milling 2h；
C, stir after cross 250 mesh sieves, be precipitated and suspension, by precipitation continuation ball milling, suspension is spray-dried,
Obtain mixed powder；
D, mixed powder and sodium alginate are stirred 15min under 150rpm stirs speed, obtain environment-friendly type dyeing paste.
In described step A, the addition of each raw material, weight ratio is:
Attapulgite 15 parts
100 parts of water
Corn starch 15 parts
Sodium hydroxide 2 parts
Fine silica powder 2 parts
Ethanol 0.2 part.
In described step D, described mixed powder and the mass ratio of sodium alginate are 10:1.
Embodiment 3
The preparation method of a kind of environment-friendly type dyeing paste, comprises the following steps:
A, by attapulgite pulverize after, cross 120 mesh sieves；
B, will pulverize after attapulgite add water and after corn starch carries out ball milling 20min, add sodium hydroxide, silicon dioxide
Micropowder and ethanol, proceed ball milling 3h；
C, stir after cross 250 mesh sieves, be precipitated and suspension, by precipitation continuation ball milling, suspension is spray-dried,
Obtain mixed powder；
D, mixed powder and sodium alginate are stirred 20min under 100rpm stirs speed, obtain environment-friendly type dyeing paste.
In described step A, the addition of each raw material, weight ratio is:
Attapulgite 8 parts
100 parts of water
Corn starch 20 parts
Sodium hydroxide 1 part
Fine silica powder 5 parts
Ethanol 0.1 part.
In described step D, described mixed powder and the mass ratio of sodium alginate are 15:1.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (4)
1. the preparation method of an environment-friendly type dyeing paste, it is characterised in that comprise the following steps:
A, by attapulgite pulverize after, cross 120 mesh sieves；
B, will pulverize after attapulgite add water and after corn starch carries out ball milling 20-30min, add sodium hydroxide, dioxy
SiClx micropowder and ethanol, proceed ball milling 2-3h；
C, stir after cross 250 mesh sieves, be precipitated and suspension, by precipitation continuation ball milling, suspension is spray-dried,
Obtain mixed powder；
D, mixed powder and sodium alginate are stirred 15-20min under 100-150rpm stirs speed, obtain environment-friendly type dyeing paste.
2. the preparation method of environment-friendly type dyeing paste as claimed in claim 1, it is characterised in that in described step A, each former
The addition of material, weight ratio is:
Attapulgite 8-15 part
100 parts of water
Corn starch 15-20 part
Sodium hydroxide 1-2 part
Fine silica powder 2-5 part
Ethanol 0.1-0.2 part.
3. the preparation method of environment-friendly type dyeing paste as claimed in claim 2, it is characterised in that in described step A, each former
The addition of material, weight ratio is:
Attapulgite 12 parts
100 parts of water
Corn starch 18 parts
Sodium hydroxide 1.5 parts
Fine silica powder 3.5 parts
Ethanol 0.1 part.
4. the preparation method of environment-friendly type dyeing paste as claimed in claim 1, it is characterised in that in described step D, described
Mixed powder and the mass ratio of sodium alginate be (10-15): 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610731631.XA CN106283738A (en) | 2016-08-26 | 2016-08-26 | A kind of preparation method of environment-friendly type dyeing paste |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610731631.XA CN106283738A (en) | 2016-08-26 | 2016-08-26 | A kind of preparation method of environment-friendly type dyeing paste |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106283738A true CN106283738A (en) | 2017-01-04 |
Family
ID=57677247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610731631.XA Pending CN106283738A (en) | 2016-08-26 | 2016-08-26 | A kind of preparation method of environment-friendly type dyeing paste |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110863375A (en) * | 2019-11-19 | 2020-03-06 | 湖州世合纺织有限公司 | Preparation method of low-salt efficient printing and dyeing paste for terylene |
| CN112301767A (en) * | 2020-11-12 | 2021-02-02 | 浙江贝隆纺织有限公司 | Preparation method of high-permeability paste for polyester fabric |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1118359A (en) * | 1994-09-09 | 1996-03-13 | 扬中县江岛精细化工厂 | Modified corn starch dyeing paste and its preparation |
| CN101864092A (en) * | 2010-06-13 | 2010-10-20 | 陕西科技大学 | Layered silicate clay-based starch suspension stabilizer and preparation method thereof |
| CN103911885A (en) * | 2014-04-17 | 2014-07-09 | 苏州润弘贸易有限公司 | Printing and dyeing paste |
-
2016
- 2016-08-26 CN CN201610731631.XA patent/CN106283738A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1118359A (en) * | 1994-09-09 | 1996-03-13 | 扬中县江岛精细化工厂 | Modified corn starch dyeing paste and its preparation |
| CN101864092A (en) * | 2010-06-13 | 2010-10-20 | 陕西科技大学 | Layered silicate clay-based starch suspension stabilizer and preparation method thereof |
| CN103911885A (en) * | 2014-04-17 | 2014-07-09 | 苏州润弘贸易有限公司 | Printing and dyeing paste |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110863375A (en) * | 2019-11-19 | 2020-03-06 | 湖州世合纺织有限公司 | Preparation method of low-salt efficient printing and dyeing paste for terylene |
| CN112301767A (en) * | 2020-11-12 | 2021-02-02 | 浙江贝隆纺织有限公司 | Preparation method of high-permeability paste for polyester fabric |
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Application publication date: 20170104 |