CN108149494A - A kind of Reactive Printing Process - Google Patents
A kind of Reactive Printing Process Download PDFInfo
- Publication number
- CN108149494A CN108149494A CN201711462990.0A CN201711462990A CN108149494A CN 108149494 A CN108149494 A CN 108149494A CN 201711462990 A CN201711462990 A CN 201711462990A CN 108149494 A CN108149494 A CN 108149494A
- Authority
- CN
- China
- Prior art keywords
- reactive
- printing process
- dosage
- active group
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/02—After-treatment
- D06P5/10—After-treatment with compounds containing metal
Abstract
The invention discloses a kind of Reactive Printing Process.Include the following steps：Alkali process, vapour steaming colour fixing are rolled in stamp, drying, and washing is soaped, and is washed；In the technique of stamp, dyestuff is double vinyl-sulfone reactive dyess or " reactive dyes with double active group, processes of vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) active group and chloro-s-triazine active group composition " in print paste；It rolls in alkali process, pick-up rate is 30~50%, and the fixation lye of use includes following components：Sodium carbonate 5~15%, sodium metasilicate 5~10%, sodium hydroxide 0.5~2% and surplus are water.The printing technology can not add alkaline agent and urea in print paste, and alkali vapour steaming colour fixing is rolled after stamp drying, and process is not needed to using urea, can largely reduce the discharge of this ammonia nitrogen, it is ensured that sewage discharge is up to standard；In addition the technique can also reduce the hydrolysis of dyestuff, extend the stability of mill base, reduce steaming time and efficiency, reduce production cost.
Description
Technical field
The present invention relates to a kind of Reactive Printing Process.
Background technology
Reactive dye are the primary dyes of cellulose dyeing and stamp, for having beautiful in colour, feel during stamp
Well, the features such as simple for process, using than wide.Reactive dye are that one kind can be reacted with cellulose fibre covalent bond
Dyestuff, the process to react to each other need certain alkaline condition and humiture.
Conventional printing technology flow is as follows：White embryo cloth-stamp-drying (100 DEG C)-vapour steaming colour fixing (102 DEG C of * 8min)-
Wash-soap-it washes.In conventional printing technology, in the operation of stamp, in print paste containing alkaline agent (dosage 3% or so) and
Urea (dosage 10% or so), the presence of alkaline agent can accelerate the hydrolysis of dyestuff, be unfavorable for the long-time storage of mill base, particularly exist
Under conditions of summer temp is higher, and the use of urea is the main source of ammonia nitrogen in sewage discharge, to environmental protection pressure nor
Chang great.
With national environmental protection policy changes, the requirement of ammonia nitrogen is more and more stringenter in sewage discharge, and conventional printing technology
In largely using urea, main function is to absorb moisture in steaming procedure, promotes the fixation of dyestuff, is used in general print paste
It is 5~20% to measure, and is the main source of ammonia nitrogen discharge, the production of the print works greatly limited, many producers all are seeking to urinate
The substitute of element, but also do not go out to be now able to the product preferably substituted at present.In addition, it is padded after existing two-phase law technology stamp
Lye process meets the easy flushing of wet flower pattern and the stability of color color development is poor during wet short steaming.
Invention content
The technical problems to be solved by the invention be overcome it is easy using urea in conventional printing technology in the prior art
Cause that ammonia nitrogen discharge is exceeded, the easy flushing of wet flower pattern is met using alkali immerging process after two phase printing and in wet short steamed journey
The defects of stability of middle color color development is poor, provides a kind of Reactive Printing Process.The printing with reactive dye work of the present invention
Skill can not add alkaline agent and urea in print paste, and alkali vapour steaming colour fixing is rolled after stamp drying, and process is not needed to using urea,
For ammonia nitrogen emission request increasingly stringenter in current environmental protection, pressure in this respect can be largely reduced, it is ensured that sewage is arranged
Unconventional and unrestrained mark.Since alkaline agent can not be added in print paste, the hydrolysis of dyestuff can be greatly reduced, extends the stability of mill base, is reduced
Steaming time and efficiency reduce production cost.
The difficult point of Reactive Printing Process of the present invention is that alkali immerging process meets the wet easy flushing of flower pattern after stamp, with
And during wet short steaming color color development stability difference problem.Present inventor makes the creative labor discovery, by right
In print paste, using specific reactive dyes with double active group, processes (double vinyl-sulfone reactive dyess or " vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) active group and a chlorine
The reactive dyes with double active group, processes of s-triazine active group composition "), specific pick-up rate (30~50%) and specific fixation alkali
The improvement of the techniques such as formula of liquid can overcome above-mentioned critical technological point.Wherein, " vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) active group and a chloro-s-triazine active group group
Into reactive dyes with double active group, processes " be represent in a dye structure include two active groups.
The present invention solves above-mentioned technical problem by the following technical programs.
The present invention provides a kind of Reactive Printing Process, include the following steps：Stamp, drying, rolls alkali process, vapour
Fixation is steamed, first wash is soaped, second wash；
Wherein, in the technique of the stamp, using reactive dyes with double active group, processes, the double-active radical activity in print paste
Dyestuff is double vinyl-sulfone reactive dyess or " reactive dyes with double active group, processes of vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) active group and chloro-s-triazine active group composition "；
Described to roll in alkali process, pick-up rate is 30~50%；
Described to roll in alkali process, the fixation lye of use includes following components：Sodium carbonate 5~15%, sodium metasilicate 5~
10%, sodium hydroxide 0.5~2% and surplus are water, and above-mentioned percentage is that each component is respectively relative to the fixation lye
Mass percent.
In the present invention, the raw material suitable for the Reactive Printing Process can be the embryo cloth of this field routine, generally
White can be the woven fabric or looped fabric of the manufacture of the cellulose fibres such as cotton, fiber crops, synthetic cotton.
In the present invention, the print paste is preferably comprised following components：The dosage of the reactive dyes with double active group, processes is 0
~5%, reservehao S dosage is 0.5~1.5%, and the dosage of sodium alginate paste is 45~55% and surplus is water, above-mentioned percentage
It is the mass percent that each component is respectively relative to the print paste total amount.Alkali is not included in the print paste preferably
Agent and/or urea.
Wherein, the reactive dyes with double active group, processes preferably pacify the plain Huang 3RE 150% of promise, the plain red 3BE 150% of peace promise,
Pacify the gorgeous indigo plant RV 120% of promise element, peace promise element indigo plant M-2GE or the black B 150% of peace promise element.The dosage of the reactive dyes with double active group, processes
Preferably 2~4%.
Wherein, the dosage of the reservehao S is preferably 1%.
Wherein, the dosage of the sodium alginate paste is preferably 50%.The sodium alginate paste is preferably 4~6wt%
Sodium alginate is dissolved in gained in 94~96wt% water.
In the present invention, the operation of the drying and condition can be operation and the condition of this field routine.The temperature of the drying
Preferably 95~105 DEG C of degree, is more preferably 100 DEG C.
In the present invention, in the fixation lye, interact between each component, certain cushioning effect can be played, and have one
Determine viscosity, it is ensured that color development stability and auxiliary ensure that stamp flower pattern is not easy flushing during decatize.
In the present invention, in the fixation lye, the dosage of the sodium carbonate is preferably 10%.
In the present invention, in the fixation lye, the dosage of the sodium metasilicate is preferably 8%.
In the present invention, in the fixation lye, the dosage of the sodium hydroxide is preferably 1%.
In the present invention, the operation for rolling alkali process and condition can be that this field is conventional, as long as the padding machine used can expire
Sufficient pick-up rate is 30~50%.For example, the alkali process of rolling rolls lye vehicle using the low of Germany GOLLER productions, in machine
A kind of special installation-low consumption of the liquid machine (MINI-FLUID) is employed on tool, it is 30~50% that can make pick-up rate.
In the present invention, the pick-up rate is the liquid carrying rate of this field routine, and general calculation formula is：It (is knitted after mangle
Fabric weight before object weight-mangle) fabric weight X100% before/mangle.In the present invention, if pick-up rate not in the range of 30~50%, prints
The easy flushing when cloth cover band liquid is too many of flower flower pattern, so as to ensure the fineness of stamp.It is described to roll in alkali process, it is described to roll
Liquid rate is preferably 40%.
In the present invention, the operation of the vapour steaming colour fixing and condition can be operation and the item of Reactive Printing Process routine
Part.The condition of the vapour steaming colour fixing is preferably：125~135 DEG C, 30~60s of time of temperature is more preferably 130 DEG C of temperature, when
Between 45s.
In the present invention, the first wash, it is described soap, the operation of the second wash and condition can be activity dye
Expect operation and the condition of printing technology routine.
On the basis of common knowledge of the art, above-mentioned each optimum condition can be arbitrarily combined to get the preferred embodiments of the invention.
The reagents and materials used in the present invention are commercially available.
The positive effect of the present invention is：
In the Reactive Printing Process of the present invention, using double-active radical dye stamp, alkali can not be added in print paste
Agent and urea roll alkali vapour steaming colour fixing after stamp drying, and process is not needed to using urea, for increasingly stringenter in current environmental protection
Ammonia nitrogen emission request, can largely reduce pressure in this respect, it is ensured that sewage discharge is up to standard.Due to can not in print paste
Alkaline agent is added, can greatly reduce the hydrolysis of dyestuff, extends the stability of mill base, steaming time is reduced and efficiency, reduction is produced into
This.In addition, color development stability and auxiliary ensure that stamp flower pattern is not easy flushing during the technique decatize of the present invention.
Specific embodiment
It is further illustrated the present invention below by the mode of embodiment, but does not therefore limit the present invention to the reality
It applies among a range.Test method without specific conditions in the following example, according to conventional methods and conditions or according to quotient
Product specification selects.
Dyestuff employed in embodiment and comparative example is purchased from its group limited company of Town in Shanghai promise.Embodiment and
Sodium alginate paste is that 5wt% sodium alginates are dissolved in gained in 95wt% water in comparative example.
Examples 1 to 5
Reactive Printing Process includes the following steps in Examples 1 to 5：By white embryo cloth successively through stamp, drying
(100 DEG C) roll alkali process, and vapour steaming colour fixing (130 DEG C of temperature, time 45s), first wash is soaped, second wash, you can；
In printing technology, in print paste, the specific type of dyestuff and dosage refer to table 1 in Examples 1 to 5, except dyestuff
Outside, following components are further included：Reservehao S dosage is 1%, and sodium alginate paste dosage is 50% and surplus is water, above-mentioned percentage
It is the mass percent that each component is respectively relative to print paste total amount.Alkaline agent and/or urea are not included in print paste.
During rolling alkali process, the composition of fixation lye includes following components：The dosage of sodium carbonate is 10%, sodium metasilicate
Dosage is 8%, and the dosage of sodium hydroxide is 1% and surplus is water, and above-mentioned percentage is that each component is respectively relative to fixation alkali
The mass percent of liquid.It rolls alkali process and lye vehicle is rolled using the low of Germany GOLLER productions, mechanically employ a kind of spy
Different equipment-low consumption of the liquid machine (MINI-FLUID), pick-up rate 40%.
First wash is soaped, the operation and condition of the operation of second wash and condition for Reactive Printing Process routine.
Table 1
Embodiment 6
In addition to parameters described below, the technological parameter of embodiment 6 is same as Example 1.
Pick-up rate is 30%；During rolling alkali process, sodium carbonate amount for 5%, use by sodium metasilicate in the fixation lye used
It is 10% to measure, sodium hydroxide concentration 2%；The dosage of reactive dyes with double active group, processes is 5% in print paste, reservehao S dosage
It is 1.5%, sodium alginate paste dosage is 55%；The temperature of drying is that the condition of 105 DEG C of vapour steaming colour fixings is：135 DEG C of temperature, time
30s。
Embodiment 7
In addition to parameters described below, the technological parameter of embodiment 7 is same as Example 1.
Pick-up rate is 50%；During rolling alkali process, sodium carbonate amount for 15%, use by sodium metasilicate in the fixation lye used
It is 5% to measure, sodium hydroxide concentration 0.5%；Reservehao S dosage is 0.5% in print paste, and sodium alginate paste dosage is
45%；The temperature of drying is 95 DEG C；The condition of vapour steaming colour fixing is：125 DEG C of temperature, time 60s.
Comparative example 1~5
The specific type of dyestuff and dosage refer to table 1 in comparative example 1~5.
Reactive Printing Process includes the following steps in comparative example 1~5：By white embryo cloth successively through stamp, drying
(100 DEG C), vapour steaming colour fixing (102 DEG C of * 8min), washing are soaped, washing.
Above-mentioned stamp, drying, vapour steaming colour fixing, the operation washed and soaped and condition are operation and the item of this field routine
Part.Wherein, in addition to the dye, other compositions are as follows for the formula of print paste：Reservehao S is 1%, sodium alginate paste 50%, little Su
3% is made a call to, urea 10%, surplus is water, and above-mentioned percentage is each component relative to the mass percent of print paste total amount.
Effect example 1
Above-described embodiment 1~5 and 1~5 products obtained therefrom of comparative example are subjected to measure of merit, specific test result such as table 2, table
Shown in 3.Wherein, case depth is directly measured by colour photometer；Flower pattern fineness is judged by estimating；Ammonia-nitrogen content presses HJ
535-2009 standard testings；The testing standard of wear resistance is ISO105X12；The testing standard of fastness to perspiration is ISO
105E04；The testing standard of soaping fastness is ISO105C03.
2 Examples 1 to 5 of table, the case depth of 1~5 product of comparative example, flower pattern fineness and washing waste liquid ammonia-nitrogen content
As shown in Table 2, printing technology of the invention compares common process, and the color yield of dyestuff is high, illustrates that dyestuff is fully solid
Color, hydrolised dye is few, and flower pattern fineness is good, and ammonia nitrogen data are substantially reduced, and can reach general sewage discharge index request.
3 Examples 1 to 5 of table, every color fastness data of 1~5 product of comparative example
By every color fastness data of table 3 it is found that the color fastness of the present invention can meet the requirement of general printing textile.
Claims (10)
1. a kind of Reactive Printing Process, which is characterized in that it includes the following steps：Stamp, drying, rolls alkali process, decatize
Fixation, first wash are soaped, second wash；
Wherein, in the technique of the stamp, using reactive dyes with double active group, processes, the reactive dyes with double active group, processes in print paste
For double vinyl-sulfone reactive dyess or " reactive dyes with double active group, processes of vinyl sulfone(RemzaolHuo Xingranliaohuoxingjituan) active group and chloro-s-triazine active group composition "；
It rolls in alkali process, pick-up rate is 30~50%；
It rolls in alkali process, the fixation lye of use includes following components：Sodium carbonate 5~15%, sodium metasilicate 5~10%, hydroxide
Sodium 0.5~2% and surplus are water, and above-mentioned percentage is the mass percent that each component is respectively relative to fixation lye.
2. Reactive Printing Process as described in claim 1, which is characterized in that suitable for the Reactive Printing Process
Woven fabric or looped fabric of the raw material for the manufacture of the cellulose fibres such as cotton, fiber crops, synthetic cotton.
3. Reactive Printing Process as described in claim 1, which is characterized in that the print paste includes following components：
The dosage of the reactive dyes with double active group, processes is 0~5%, and reservehao S dosage is 0.5~1.5%, and the dosage of sodium alginate paste is
45~55% and surplus be water, above-mentioned percentage is the mass percent that each component is respectively relative to print paste total amount.
4. Reactive Printing Process as claimed in claim 3, which is characterized in that the reactive dyes with double active group, processes is peace promise
Plain Huang 3RE 150%, the red 3BE 150% of peace promise element, the gorgeous indigo plant RV 120% of peace promise element, peace promise element indigo plant M-2GE or the black B of peace promise element
150%.
5. Reactive Printing Process as claimed in claim 3, which is characterized in that the dosage of the reactive dyes with double active group, processes
It is 2~4%；
The dosage of the reservehao S is 1%；
And/or the dosage of the sodium alginate paste is 50%；It is molten that the sodium alginate paste is preferably 4~6wt% sodium alginates
The gained in 94~96wt% water.
6. Reactive Printing Process as described in claim 1, which is characterized in that do not include alkaline agent in the print paste
And/or urea.
7. Reactive Printing Process as described in claim 1, which is characterized in that the temperature of the drying is 95~105 DEG C,
Preferably 100 DEG C.
8. Reactive Printing Process as described in claim 1, which is characterized in that in the fixation lye, the sodium carbonate
Dosage be 10%；
In the fixation lye, the dosage of the sodium metasilicate is 8%；
And/or in the fixation lye, the dosage of the sodium hydroxide is 1%.
9. Reactive Printing Process as described in claim 1, which is characterized in that the pick-up rate is 40%.
10. Reactive Printing Process as described in claim 1, which is characterized in that the condition of the vapour steaming colour fixing is：Temperature
125~135 DEG C, 30~60s of time, preferably 130 DEG C of temperature, time 45s.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711462990.0A CN108149494A (en) | 2017-12-28 | 2017-12-28 | A kind of Reactive Printing Process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711462990.0A CN108149494A (en) | 2017-12-28 | 2017-12-28 | A kind of Reactive Printing Process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108149494A true CN108149494A (en) | 2018-06-12 |
Family
ID=62462487
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711462990.0A Withdrawn CN108149494A (en) | 2017-12-28 | 2017-12-28 | A kind of Reactive Printing Process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108149494A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109518487A (en) * | 2018-10-25 | 2019-03-26 | 昌邑富润纺织科技有限公司 | A kind of steam combination ammonia dyeing and printing process |
| CN110747663A (en) * | 2019-10-28 | 2020-02-04 | 湖南特俪洁新材料科技有限公司 | Reactive dye printing paste and printing method thereof |
| CN111500115A (en) * | 2019-01-31 | 2020-08-07 | 南通市墨宝打印科技有限公司 | Double-active-group ink-jet ink and application method thereof |
| CN113668266A (en) * | 2021-09-10 | 2021-11-19 | 天津工业大学 | Urea-free ink-jet printing pretreatment agent and pretreatment method for fibrilia |
| CN114775308A (en) * | 2022-06-07 | 2022-07-22 | 临清三和纺织集团有限公司 | Reactive dye printing method of cellulose fiber fabric based on microwave color fixation |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493055A (en) * | 2011-11-24 | 2012-06-13 | 无锡市天然绿色纤维科技有限公司 | Processing method of alkali-resistant dischargeable mercerized yarns |
| CN102767100A (en) * | 2012-07-30 | 2012-11-07 | 罗莱家纺股份有限公司 | Printing gum composition and printing paste |
| CN103437213A (en) * | 2013-06-19 | 2013-12-11 | 安徽中天印染股份有限公司 | Polyester/cotton interwoven fabric dyeing and fishing process |
| CN103696281A (en) * | 2013-12-18 | 2014-04-02 | 江苏波波熊纺织品有限公司 | Active printing and dyeing method for blended silk |
| CN105970698A (en) * | 2016-05-30 | 2016-09-28 | 山东黄河三角洲纺织科技研究院有限公司 | Reactive dye cold pad-batch printing method |
-
2017
- 2017-12-28 CN CN201711462990.0A patent/CN108149494A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102493055A (en) * | 2011-11-24 | 2012-06-13 | 无锡市天然绿色纤维科技有限公司 | Processing method of alkali-resistant dischargeable mercerized yarns |
| CN102767100A (en) * | 2012-07-30 | 2012-11-07 | 罗莱家纺股份有限公司 | Printing gum composition and printing paste |
| CN103437213A (en) * | 2013-06-19 | 2013-12-11 | 安徽中天印染股份有限公司 | Polyester/cotton interwoven fabric dyeing and fishing process |
| CN103696281A (en) * | 2013-12-18 | 2014-04-02 | 江苏波波熊纺织品有限公司 | Active printing and dyeing method for blended silk |
| CN105970698A (en) * | 2016-05-30 | 2016-09-28 | 山东黄河三角洲纺织科技研究院有限公司 | Reactive dye cold pad-batch printing method |
Non-Patent Citations (1)
| Title |
|---|
| 潘云芳: "《染整技术（印花分册）》", 31 January 2017, 中国纺织出版社 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109518487A (en) * | 2018-10-25 | 2019-03-26 | 昌邑富润纺织科技有限公司 | A kind of steam combination ammonia dyeing and printing process |
| CN111500115A (en) * | 2019-01-31 | 2020-08-07 | 南通市墨宝打印科技有限公司 | Double-active-group ink-jet ink and application method thereof |
| CN110747663A (en) * | 2019-10-28 | 2020-02-04 | 湖南特俪洁新材料科技有限公司 | Reactive dye printing paste and printing method thereof |
| CN113668266A (en) * | 2021-09-10 | 2021-11-19 | 天津工业大学 | Urea-free ink-jet printing pretreatment agent and pretreatment method for fibrilia |
| CN113668266B (en) * | 2021-09-10 | 2023-09-15 | 天津工业大学 | Urea-free inkjet printing pretreatment agent and pretreatment method for fibrilia |
| CN114775308A (en) * | 2022-06-07 | 2022-07-22 | 临清三和纺织集团有限公司 | Reactive dye printing method of cellulose fiber fabric based on microwave color fixation |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108149494A (en) | A kind of Reactive Printing Process | |
| CN101381934B (en) | Fixation method and apparatus for inking and printing on cotton with active ink | |
| CN105755861B (en) | A kind of preparation method of transfer discharge printing fabric | |
| CN104975518A (en) | Textile printing and dyeing technology | |
| CN103194918B (en) | Preprocessing size for textile printing as well as preparation method and applications thereof | |
| CN109056379A (en) | A kind of wool fabric reactive dye digit printing pretreatment slurry and printing technology | |
| CN103224729A (en) | Active dye gravure printing ink and preparation method thereof, and method for applying active dye gravure printing ink for printing | |
| CN104278588A (en) | Digital ink jet printing process of mulberry silk fabric | |
| CN107604705A (en) | One kind pretreatment slurry and a kind of digital printing process | |
| CN109853262A (en) | A kind of ink-jet printed method of the method for enzymatically treating and wool fabric of wool fabric | |
| CN105507031B (en) | It is a kind of for slurry of digit printing and its preparation method and application | |
| CN106930118B (en) | A kind of printing with reactive dye method of no dyeing waste water | |
| CN101935466A (en) | Active red dye composition | |
| CN106638039B (en) | A kind of the acid dyes foam printing liquid and foam printing method of polyamide fibre flimsy material | |
| CN101880473B (en) | Active orange dye composition | |
| CN102787514B (en) | Method for producing acid dye flat screen or rotary screen printing of protein fiber fabric and nylon fabric | |
| CN106544909A (en) | A kind of fleece fabrics digit printing pre-treatment slurry and printing technology | |
| CN101880474B (en) | Orange red reactive dyestuff composition | |
| CN108166283A (en) | A kind of reactive dye discharge printing process | |
| CN106120408B (en) | A kind of digital printing process of silk fabric | |
| CN101942774A (en) | Wash flower process | |
| CN107059435A (en) | A kind of pure cotton fabric exempts from decatize printing method | |
| CN111334086B (en) | Maotai-red reactive dye composition and preparation method and application thereof | |
| CN108264779B (en) | A kind of active black dye composition and its application | |
| CN103243577B (en) | A kind of high mesh fine flower pattern printing technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20190812 Address after: 201703 Shanghai city Qingpu District Songhua Road No. 881 Applicant after: SHANGHAI ANOKY GROUP CO., LTD. Applicant after: Yantai Anoky Fine Chemical Co., Ltd. Applicant after: SHANGHAI ANOKY DIGITAL TECHNOLOGY CO., LTD. Applicant after: Dongying Annuoqi Textile Material Co., Ltd. Applicant after: Shanghai Shangyu Digital Technology Co., Ltd. Applicant after: Yantai Shangyu Digital Technology Co., Ltd. Address before: 224631 North of Weiliu Road, Chenjiagang Town, Xiangshui County, Yancheng City, Jiangsu Province Applicant before: JIANGSU ANOKY CHEMICAL CO., LTD. Applicant before: SHANGHAI ANOKY GROUP CO., LTD. Applicant before: SHANGHAI ANOKY DIGITAL TECHNOLOGY CO., LTD. Applicant before: Yantai Anoky Fine Chemical Co., Ltd. Applicant before: Dongying Annuoqi Textile Material Co., Ltd. |
|
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180612 |