CN106281601A - 可生物降解柴油发动机油组合物 - Google Patents

可生物降解柴油发动机油组合物 Download PDF

Info

Publication number
CN106281601A
CN106281601A CN201610620389.9A CN201610620389A CN106281601A CN 106281601 A CN106281601 A CN 106281601A CN 201610620389 A CN201610620389 A CN 201610620389A CN 106281601 A CN106281601 A CN 106281601A
Authority
CN
China
Prior art keywords
diesel engine
engine oil
oil composition
biodegradable
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610620389.9A
Other languages
English (en)
Inventor
卢姗
唐彩珍
雷敬玲
王友东
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangxi Land Renewable Energy Co Ltd
Original Assignee
Guangxi Land Renewable Energy Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangxi Land Renewable Energy Co Ltd filed Critical Guangxi Land Renewable Energy Co Ltd
Priority to CN201610620389.9A priority Critical patent/CN106281601A/zh
Publication of CN106281601A publication Critical patent/CN106281601A/zh
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/048—Mixtures of base-materials and additives the additives being a mixture of compounds of unknown or incompletely defined constitution, non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/02—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers
    • C10M2205/0206—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing acyclic monomers used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/023—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings
    • C10M2207/026—Hydroxy compounds having hydroxy groups bound to carbon atoms of six-membered aromatic rings with tertiary alkyl groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/127—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids polycarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/28—Esters
    • C10M2207/283—Esters of polyhydroxy compounds
    • C10M2207/2835—Esters of polyhydroxy compounds used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
    • C10M2215/064—Di- and triaryl amines
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/086—Imides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/22—Heterocyclic nitrogen compounds
    • C10M2215/223—Five-membered rings containing nitrogen and carbon only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/046—Overbasedsulfonic acid salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C10M2219/106—Thiadiazoles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
    • C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C10M2229/04—Siloxanes with specific structure
    • C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/02—Viscosity; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2020/00—Specified physical or chemical properties or characteristics, i.e. function, of component of lubricating compositions
    • C10N2020/01—Physico-chemical properties
    • C10N2020/081—Biodegradable compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/04—Detergent property or dispersant property
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/14—Metal deactivation
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/25—Internal-combustion engines
    • C10N2040/252—Diesel engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

本发明的可生物降解柴油发动机油组合物，由85.399％～80.470％的复合基础油和添加剂组成，基础油由季戊四醇酯和聚α‑烯烃复合而成。本发明的可生物降解柴油发动机油，具有良好的抗氧化性能，可以有效防止高温造成的发动机油氧化变质或产生沉积物；抗腐蚀性能突出，可以有效中和腐蚀性物质及油品氧化产生的酸性物质，降低发动机腐蚀；具有适当的灰分，其抗磨、减摩性能优良，组分稳定、无毒、无刺激、有良好的可生物降解性能、可以保护发动机、尤其是车用发动机在连续高负载的工况下正常工作。

Description

可生物降解柴油发动机油组合物
技术领域
本发明涉及一种发动机油组合物，特别是可生物降解柴油发动机油组合物。
背景技术
柴油发动机油发展的推动力主要是节省自然资源和保护环境方面的要求，因此可生物降解性柴油机油仍是汽车研究重要的课题。发动机油的主要作用是降低发动机运动副摩擦和减少磨损，防止在发动机中形成沉积物，提高油品的润滑性能，延缓发动机油氧化，延长发动机油的使用寿命。这就要求发动机油既要有性能好的基础油又同时加有相应功能的添加剂，以满足发动机油的各项性能要求。随着发动机系统的不断升级，发动机油品质的更新换代，传统的矿物型润滑油已不能满足人们对润滑油综合性能及环境友好性能的要求，可生物降解发动机油越来越受到重视。季戊四醇酯具有良好的可生物降解性能，现今已被运用于航空发动机油、燃气透平油等领域。此外，季戊四醇酯型基础油粘度随温度的变化小，在相同条件下的凝点比矿物油的凝点低，低温粘度小，这对发动机的低温泵送能力降低了要求，从而保护发动机，延长发动机的使用寿命。季戊四醇酯在高温下也较难分解，且不易产生积碳和油泥，抑制了油品氧化衰败，从而对油品起到了保护作用，延长油品的使用期。
发明内容
本发明要解决的技术问题是提供一种具有良好的抗氧化性能，有效防止高温造成的发动机油氧化变质或产生沉积物、抗腐蚀性能突出、灰分适当、抗磨、减摩性能优良、组分稳定、无毒、无刺激、可生物降解性能良好、可保护发动机在连续高负载的工况下正常工作的可生物降解柴油发动机油组合物。
本发明以如下技术方案解决上述技术问题
本发明的润滑油组合物各组分及其质量百分数为：
以上组分质量百分数之和为100％。
基础油由质量比40％～60％季戊四醇酯和60％～40％聚α-烯烃PAO复合而成。
制备季戊四醇酯的主要原料来自地沟油，制得的季戊四醇酯的理化性质为：运动粘度(100℃)9.37mm2/s，密度(20℃)0.8kg/m3，酸值0.11mgKOH/g，凝点-22℃，闪点216℃。
清净剂由质量比40％～60％低碱值石油磺酸钠与60％～40％高碱值石油磺酸钠复合。
分散剂是双烯基丁二酰亚胺。
抗氧防腐剂是硫磷双辛基碱性锌盐。
抗氧剂由质量比30％～70％2.6-二叔丁基对甲酚与70％～30％二烷基二苯胺复合。
油性剂是磷酸酯。
金属钝化剂是噻二唑衍生物。
防锈剂由质量比50％有机磷型咪唑啉化合物和50％十二烯基丁二酸复合。
抗泡剂是二甲基硅油。
本发明的可生物降解柴油发动机油，具有良好的抗氧化性能，可以有效防止高温造成的发动机油氧化变质或产生沉积物；抗腐蚀性能突出，可以有效中和腐蚀性物质及油品氧化产生的酸性物质，降低发动机腐蚀；具有适当的灰分，其抗磨、减摩性能优良，组分稳定、无毒、无刺激、有良好的可生物降解性能、可以保护发动机、尤其是车用发动机在连续高负载的工况下正常工作。
具体实施方式
季戊四醇酯具有大极性集团酯基，能使其在金属表面形成一个稳定的油膜，提高油品的润滑性，且在基础油组分中加入聚α-烯烃能显著降低基础油的摩擦系数。季戊四醇酯和聚α-烯烃复合的基础油结焦少、生成油泥倾向性小，在基础油中添加少量的清净剂和分散剂可避免油品出现积碳、油泥等沉积物，确保发动机油的安全使用。低碱值石油磺酸钠与高碱值石油磺酸钠复合作为清净剂，可以避免油品的碱值过高，损坏发动机部件。硫磷双辛基碱性锌盐是一种优良的抗氧防腐剂，发动机工作时，活性硫、磷元素可以与发动机元件表面金属发生化学反应，形成致密的化学膜牢牢附着在元件表面，从而达到保护的目的。
餐厨垃圾是指除居民日常生活以外的食品加工、饮食服务、单位供餐等活动中产生的厨余废弃物和废弃食用油脂，占居民生活垃圾的30％～40％。据调研，餐厨垃圾约含有3.0％～5.0％废弃油脂，不法商贩将餐厨垃圾中的油脂加工炼制成食用油。这种油含有黄曲霉素、苯等有毒物质，对人们的健康饮食造成严重影响。规范处理餐厨废弃油脂，受到了环保部门以及人们的重视与关注。本发明采用由餐厨废弃油脂研制得到的季戊四醇酯作为柴油发动机油的基础油组分之一，与矿物型基础油相比，不仅可生物降解性能优异，而且赋予油品良好润滑性、低温流动性能以及不易形成积碳和油泥等性能，满足发动机润滑要求的同时，还避免了环境污染。
季戊四醇酯制取过程为：餐厨废弃油脂经过除杂、脱水、脱酸、脱色等精制处理，在酸性条件下发生水解得到游离脂肪酸，将游离脂肪酸与季戊四醇进行酯化反应，并经过一系列精制得到季戊四醇酯。表1为本发明所用的季戊四醇酯的理化性质。
表1季戊四醇酯的理化性质
本发明采用季戊四醇酯和聚α-烯烃调合得到的油品属于全合成型，加之多种功能型添加剂的协同增效作用，使油品具有良好的综合性能，不仅延长了油品换油期、节省能耗，同时保护发动机系统、延长发动机的使用寿命。
实施例1
将以下各组分按其质量百分数调和而成：
实施例2
将以下各组分按其质量百分数调和而成：
实施例3
将以下各组分按其质量百分数调和而成：
以下是实施例2的可生物降解柴油发动机油技术参数测定结果：
可生物降解柴油发动机油典型数据
经实验测定，可以发现：本发明柴油机油粘温性能较好，在较高的工作温度下，也可保证较好的润滑性能；油品的灰分较低，减少了发动机燃烧室和活塞机排气阀等部位的沉积物增加，延长发动机易损件的使用寿命；油品抗泡性能优良，在发动机运转过程中及时消泡，避免因泡沫存在而导致部件的润滑不良，从而达到保护发动机的目的。

Claims (10)

1.一种可生物降解柴油发动机油组合物，包括复合基础油和添加剂，其特征是各组分及其质量百分数为：
以上各组分质量百分比之和为100％。
2.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是基础油由质量比40％～60％季戊四醇酯与60％～40％聚α-烯烃PAO复合而成。
3.如权利要求2所述的可生物降解柴油发动机油组合物，其特征是制备季戊四醇酯的主要原料来自地沟油，制得的季戊四醇酯理化性质为：100℃运动粘度9.37mm2/s，20℃密度kg/m3，酸值0.11mgKOH/g，凝点-22℃，闪点216℃。
4.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是清净剂由质量比40％～60％低碱值石油磺酸钠与60％～40％高碱值石油磺酸钠复合。
5.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是分散剂是双烯基丁二酰亚胺。
6.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是抗氧防腐剂是硫磷双辛基碱性锌盐。
7.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是抗氧剂由质量比30％～70％2、6-二叔丁基对甲酚与70％～30％二烷基二苯胺复合。
8.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是油性剂是磷酸酯。
9.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是金属钝化剂是噻二唑衍生物。
10.如权利要求1所述的可生物降解柴油发动机油组合物，其特征是防锈剂由质量比50％有机磷型咪唑啉化合物和50％十二烯基丁二酸复合；抗泡剂是二甲基硅油。
CN201610620389.9A 2016-07-29 2016-07-29 可生物降解柴油发动机油组合物 Pending CN106281601A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610620389.9A CN106281601A (zh) 2016-07-29 2016-07-29 可生物降解柴油发动机油组合物

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610620389.9A CN106281601A (zh) 2016-07-29 2016-07-29 可生物降解柴油发动机油组合物

Publications (1)

Publication Number Publication Date
CN106281601A true CN106281601A (zh) 2017-01-04

Family

ID=57663824

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201610620389.9A Pending CN106281601A (zh) 2016-07-29 2016-07-29 可生物降解柴油发动机油组合物

Country Status (1)

Country Link
CN (1) CN106281601A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690454A (zh) * 2019-03-12 2020-09-22 赫因道夫润滑科技(上海)有限公司 一种环保型汽车动力增强剂及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205307A (zh) * 2013-04-12 2013-07-17 广西大学 环境友好节能型柴油发动机油
CN103525523A (zh) * 2013-10-21 2014-01-22 广西大学 一种适用于闭式循环柴油机的润滑剂
CN104498144A (zh) * 2014-12-01 2015-04-08 新疆福克油品股份有限公司 一种通用型合成汽柴油润滑油及其制备方法
CN104745278A (zh) * 2015-02-15 2015-07-01 上海应用技术学院 一种环保节能的柴油机油及其制备方法
CN105542922A (zh) * 2016-01-07 2016-05-04 北京雅士科莱恩石油化工有限公司 一种超长换油里程的节能柴油机油及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205307A (zh) * 2013-04-12 2013-07-17 广西大学 环境友好节能型柴油发动机油
CN103525523A (zh) * 2013-10-21 2014-01-22 广西大学 一种适用于闭式循环柴油机的润滑剂
CN104498144A (zh) * 2014-12-01 2015-04-08 新疆福克油品股份有限公司 一种通用型合成汽柴油润滑油及其制备方法
CN104745278A (zh) * 2015-02-15 2015-07-01 上海应用技术学院 一种环保节能的柴油机油及其制备方法
CN105542922A (zh) * 2016-01-07 2016-05-04 北京雅士科莱恩石油化工有限公司 一种超长换油里程的节能柴油机油及其制备方法

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111690454A (zh) * 2019-03-12 2020-09-22 赫因道夫润滑科技(上海)有限公司 一种环保型汽车动力增强剂及其制备方法

Similar Documents

Publication Publication Date Title
Salimon et al. Biolubricants: Raw materials, chemical modifications and environmental benefits
Mobarak et al. The prospects of biolubricants as alternatives in automotive applications
CN102031190A (zh) 一种切削油及其制备方法
CN106590877B (zh) 一种全合成重负荷螺杆空气压缩机油及其制备方法
CN104087383A (zh) 一种以二异丙基醚为燃料的发动机油组合物
CN104130845A (zh) 一种船用齿轮箱油组合物
CN104087384A (zh) 一种煤浆油燃料发动机油组合物
CN105733765A (zh) 环保免清洗的防锈冲压油
CN105132098A (zh) 内燃机润滑油添加剂组合物及其制备方法和应用
CN108913311A (zh) 柴油发动机的润滑油组合物
CN115992021A (zh) 含硼添加剂作为铅腐蚀抑制剂的用途
CN104194891A (zh) 一种二丁氧基甲烷发动机油组合物
CN104087373B (zh) 一种洗油燃料发动机油组合物
CN103254986A (zh) 一种双燃料发动机润滑油及其制备方法
CN104087375B (zh) 一种水煤浆混合燃料发动机油组合物
CN103265999A (zh) 可生物降解润滑脂
CN106281601A (zh) 可生物降解柴油发动机油组合物
CN104087381A (zh) 一种二正戊基醚柴油发动机油组合物
CN104087371B (zh) 一种煤焦油柴油发动机油组合物
Igartua et al. Biolubricants and triboreactive materials for automotive applications
CN103525523B (zh) 一种适用于闭式循环柴油机的润滑剂
CN104152212A (zh) 一种润滑油及其制备方法
CN104087372B (zh) 一种乙二醇二甲基醚燃料发动机油组合物
CN104087377A (zh) 一种二乙二醇二甲醚发动机油组合物
CN106244307A (zh) 可生物降解汽油发动机油组合物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170104

WD01 Invention patent application deemed withdrawn after publication