CN106281018A - A kind of fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui and preparation method thereof - Google Patents
A kind of fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui and preparation method thereof Download PDFInfo
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- CN106281018A CN106281018A CN201610713135.1A CN201610713135A CN106281018A CN 106281018 A CN106281018 A CN 106281018A CN 201610713135 A CN201610713135 A CN 201610713135A CN 106281018 A CN106281018 A CN 106281018A
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- resina toxicodendri
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- toxicodendri verniciflui
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D193/00—Coating compositions based on natural resins; Coating compositions based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/06—Artists' paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/206—Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Abstract
The invention discloses a kind of fireproof wear-resisting and synthesize transparent Resina Toxicodendri verniciflui, it is characterised in that: include component A and B component；The raw material of described component A is by Resina Toxicodendri verniciflui resin, solvent, rosin；The raw material of described B component is made up of maleic-modified rosin resin, nano-aluminium oxide, solvent, decabromodiphenyl oxide, defoamer, TDI；Described component A and B component are constituted according to weight ratio 1:0.6 1.2 mixing.The present invention utilizes TDI to add the dry setting rate of Resina Toxicodendri verniciflui, can be good by primer wood tire plate after, rapid draing, improve the cloth paint speed of priming paint；Invention increases maleic-modified rosin resin and nano-aluminium oxide is effectively increased the anti-wear performance of paint film, the convenient transparency controlling Resina Toxicodendri verniciflui simultaneously, convenient make lacquer painting；And in Resina Toxicodendri verniciflui, add decabromodiphenyl oxide, the situation such as naked light preventing from causing because of individual factor that can be good and make lacquer painting cause the infringement that cannot retrieve.
Description
Technical field
The present invention relates to lacquer painting raw material and make field, particularly to a kind of fireproof wear-resisting that accumulator is played sealing function
Synthesize transparent Resina Toxicodendri verniciflui and preparation method thereof.
Background technology
Lacquer painting art is as the important component part of Chinese civilization, the history passed by thousand of years.In China's thousand of year
The long korneforos of history, lacquer painting is that descendant leaves countless art rarity, not only can decorate but also can be realistic, not only can be abstract but also can
With tool as, here it is why lacquer painting develops into an independent the most basic immanent cause drawn kind.
Lacquer painting is with paint as stock, coats with lacquer decorations technique with Chinese tradition and participates in the drafting of external skill and technique, passes on modern idea
Drawing, there is abundant representability.Due to the restriction of processing technology, the yield of lacquer painting is few.Create the cycle of a width lacquer painting,
It is generally required to one or two months, complex process is a little, half a year 1 year.The creation flow process of lacquer painting is complicated, and particularly manufacturing process needs
Will be through the biggest amount of labour ground works of polishing
Lacquer painting is that the one paint various pigment of mediation are depicted on paint plate, and uses the modes such as polishing to make its color gradually presentation layer
The artistic pictures kind of secondary sense and sparkling and crystal-clear sense.Owing to paint plate is plank is closed polishing to form with paint mediation dark grey, can completely cut off acid, alkali,
Oxygen, moisture, lacquer painting is the most denumerable kept its bright feature with thousand.Lacquer painting with paint as raw material has strong color
Sense, visual impact is extremely strong, the material sense that the most promising modern is liked.
Compare with multiple artistic forms such as oil painting, traditional Chinese Painting, etching and gouaches, the characteristic of lacquer painting be it thick and heavy sense,
Stereovision, sparkling and crystal-clear sense, color sense, material sense and nursing are easy, storage life is permanent, and lacquer painting can well realize above art
The effect of form, is fabricated to the lacquer painting of the style such as traditional Chinese Painting, oil painting, and has characteristic and the advantage of lacquer painting concurrently.
The lacquer painting drawing with natural lacquer as main material, outside paint removal, also gold, silver, lead, stannum and eggshell, shell,
Flag, wood chip etc..It is the art work, is again practical ornament, becomes the form of expression of wall ornamentation, screen and mural painting etc..Lacquer painting
Increasingly coming into people's daily life to suffer, it adds artistic feeling.
At present, lacquer painting is in manufacturing process, and it is composite paint that most uses arrive raw material lacquer, but composite paint is the best at present
Good fire protecting performance, is the most also not easy rapid draing simultaneously, and transparent for the anti-wear performance of paint film and Resina Toxicodendri verniciflui
Degree is inconvenient to grasp, it has not been convenient to carry out making and the process of priming paint, it is impossible to meet the market demand.
Summary of the invention
It is an object of the invention to provide and a kind of there is good fire protecting performance, the convenient transparency grasping Resina Toxicodendri verniciflui, increase paint
The anti-wear performance of film, after a procedure can rapid draing, facilitate the advantages such as use a kind of fireproof wear-resisting synthesize transparent Resina Toxicodendri verniciflui and
Its manufacture method.
In order to achieve the above object, the present invention provides following technical scheme:
A kind of fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui, it is characterised in that: include component A and B component；The raw material of described component A is by giving birth to
Coating resins, solvent, rosin；The raw material of described B component by maleic-modified rosin resin, nano-aluminium oxide,
Solvent, decabromodiphenyl oxide, defoamer, TDI forms；Described component A and B component are constituted according to the mixing of weight ratio 1:0.6-1.2；Press
Ratio of weight and number, in wherein said component A, including: Resina Toxicodendri verniciflui resin 70 85 parts, solvent 16 30 parts, 8 18 parts of rosin；
In described B component, including: maleic-modified rosin resin 10 20 parts, nano-aluminium oxide 10 20 parts, solvent
35 45 parts, decabromodiphenyl oxide 16 28 parts, defoamer 16 parts, TDI:3-8 part.
The preferred weight proportioning that described fireproof wear-resisting synthesizes in transparent Resina Toxicodendri verniciflui is: in component A: Resina Toxicodendri verniciflui resin 80 parts, solvent
25 parts, 16 parts of rosin；In described B component, including: maleic-modified rosin resin 16 parts, nano-aluminium oxide
15 parts, solvent 40 parts, decabromodiphenyl oxide 25 parts, defoamer 4 parts, TDI:5 part.
Described solvent is fat, ketones solvent.
Described defoamer be silicone and polyacrylate apoplexy due to endogenous wind BYK-065, BYK-066N, BYK-354,
Any one in DEUCHEM2700.
Specific make step is:
1, the making of component A: under aerobic conditions, adds fungal laccase, then by Resina Toxicodendri verniciflui resin through 200 mesh silk screen filter,
To refined raw coating resins, then according to above-mentioned ratio of weight and number adds solvent, reach regulation fineness through physical dispersion, use diluent
Adjust viscosity, prepare component A preparation；
2, the making of B component: according to above-mentioned ratio of weight and number, by solvent, decabromodiphenyl oxide, TDI adds in reactor together,
It is slowly stirred under room temperature, then after internal mix thing is stable, is sequentially added into maleic-modified rosin resin, receives
Rice aluminium sesquioxide, defoamer carries out mix and blend, stops, preparing B component preparation when no longer producing bubble in thing to be mixed；
3, mixing finished product: above-mentioned A, B component mixture are put in reactor according to above-mentioned ratio of weight and number and mixes, wait to fill
Take out after dividing mixing, seal up for safekeeping after adding appropriate Oleum Camphora.
Beneficial effects of the present invention: the present invention utilizes TDI to add the dry setting rate of Resina Toxicodendri verniciflui, can be good by priming paint
After spreading upon wood tire plate, rapid draing, improve the cloth paint speed of priming paint；Invention increases maleic-modified rosin
Resin and nano-aluminium oxide are effectively increased the anti-wear performance of paint film, and the convenient transparency controlling Resina Toxicodendri verniciflui, convenient simultaneously
Make lacquer painting；And in Resina Toxicodendri verniciflui, add decabromodiphenyl oxide, the situation such as naked light preventing from causing because of individual factor that can be good and
Lacquer painting is made to cause the infringement that cannot retrieve.
Detailed description of the invention
Below in conjunction with embodiment, technical scheme is clearly and completely described, it is clear that described
Embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area
The every other embodiment that those of ordinary skill is obtained under not making creative work premise, broadly falls into present invention protection
Scope.
Embodiment 1:
A kind of fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui, it is characterised in that: include component A and B component；The raw material of described component A is by giving birth to
Coating resins, solvent, rosin；The raw material of described B component by maleic-modified rosin resin, nano-aluminium oxide,
Solvent, decabromodiphenyl oxide, defoamer, TDI forms；Described component A and B component are constituted according to the mixing of weight ratio 1:0.6-1.2；Press
Ratio of weight and number, in wherein said component A, including: Resina Toxicodendri verniciflui resin 70 85 parts, solvent 16 30 parts, 8 18 parts of rosin；
In described B component, including: maleic-modified rosin resin 10 20 parts, nano-aluminium oxide 10 20 parts, solvent
35 45 parts, decabromodiphenyl oxide 16 28 parts, defoamer 16 parts, TDI:3-8 part.
Embodiment 2:
The preferred weight proportioning that described fireproof wear-resisting synthesizes in transparent Resina Toxicodendri verniciflui is: in component A: Resina Toxicodendri verniciflui resin 80 parts, solvent 25 parts,
16 parts of rosin；In described B component, including: maleic-modified rosin resin 16 parts, nano-aluminium oxide 15 parts,
Solvent 40 parts, decabromodiphenyl oxide 25 parts, defoamer 4 parts, TDI:5 part.
Embodiment 3:
Described solvent is fat, ketones solvent.
Embodiment 4:
Described defoamer is silicone and polyacrylate apoplexy due to endogenous wind BYK-065, BYK-066N, BYK-354, DEUCHEM2700
In any one.
Embodiment 5:
Specific make step is:
1, the making of component A: under aerobic conditions, adds fungal laccase, then by Resina Toxicodendri verniciflui resin through 200 mesh silk screen filter,
To refined raw coating resins, then according to above-mentioned ratio of weight and number adds solvent, reach regulation fineness through physical dispersion, use diluent
Adjust viscosity, prepare component A preparation；
2, the making of B component: according to above-mentioned ratio of weight and number, by solvent, decabromodiphenyl oxide, TDI adds in reactor together,
It is slowly stirred under room temperature, then after internal mix thing is stable, is sequentially added into maleic-modified rosin resin, receives
Rice aluminium sesquioxide, defoamer carries out mix and blend, stops, preparing B component preparation when no longer producing bubble in thing to be mixed；
3, mixing finished product: above-mentioned A, B component mixture are put in reactor according to above-mentioned ratio of weight and number and mixes, wait to fill
Take out after dividing mixing, seal up for safekeeping after adding appropriate Oleum Camphora.
Claims (5)
1. a fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui, it is characterised in that: include component A and B component；The raw material of described component A by
Resina Toxicodendri verniciflui resin, solvent, rosin；The raw material of described B component is aoxidized two by maleic-modified rosin resin, nanometer three
Aluminum, solvent, decabromodiphenyl oxide, defoamer, TDI forms；Described component A and B component are according to weight ratio 1:0.6-1.2 mixing structure
Become；By ratio of weight and the number of copies, in wherein said component A, including: Resina Toxicodendri verniciflui resin 70 85 parts, solvent 16 30 parts, rosin 8
18 parts；In described B component, including: maleic-modified rosin resin 10 20 parts, nano-aluminium oxide 10 20
Part, solvent 35 45 parts, decabromodiphenyl oxide 16 28 parts, defoamer 16 parts, TDI:3-8 part.
A kind of fireproof wear-resisting the most according to claim 1 synthesizes transparent Resina Toxicodendri verniciflui, it is characterised in that: described fireproof wear-resisting synthesizes
Preferred weight proportioning in transparent Resina Toxicodendri verniciflui is: in component A: Resina Toxicodendri verniciflui resin 80 parts, solvent 25 parts, 16 parts of rosin；Described B component
In, including: maleic-modified rosin resin 16 parts, nano-aluminium oxide 15 parts, solvent 40 parts, decabromodiphenyl oxide 25
Part, defoamer 4 parts, TDI:5 part.
3. synthesize transparent Resina Toxicodendri verniciflui according to a kind of fireproof wear-resisting described in any one in claim 1-2, it is characterised in that: institute
Stating solvent is fat, ketones solvent.
4. synthesize transparent Resina Toxicodendri verniciflui according to a kind of fireproof wear-resisting described in any one in claim 1-2, it is characterised in that: institute
Stating defoamer is appointing in silicone and polyacrylate apoplexy due to endogenous wind BYK-065, BYK-066N, BYK-354, DEUCHEM2700
Meaning one.
5. the manufacture method of transparent Resina Toxicodendri verniciflui is synthesized according to a kind of fireproof wear-resisting described in any one in claim 1-4, its
It is characterised by: specific make step is:
The making of component A: under aerobic conditions, adds fungal laccase, then by Resina Toxicodendri verniciflui resin through 200 mesh silk screen filter, obtains
Refined raw coating resins, then according to above-mentioned ratio of weight and number adds solvent, reaches regulation fineness through physical dispersion, adjusts with diluent
Whole viscosity, prepares component A preparation；
The making of B component: according to above-mentioned ratio of weight and number, by solvent, decabromodiphenyl oxide, TDI adds in reactor together, in room
It is slowly stirred under temperature, then after internal mix thing is stable, is sequentially added into maleic-modified rosin resin, nanometer
Aluminium sesquioxide, defoamer carries out mix and blend, stops, preparing B component preparation when no longer producing bubble in thing to be mixed；
Mixing finished product: above-mentioned A, B component mixture are put in reactor according to above-mentioned ratio of weight and number and mix, treats fully
Take out after mixing, seal up for safekeeping after adding appropriate Oleum Camphora.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610713135.1A CN106281018A (en) | 2016-08-24 | 2016-08-24 | A kind of fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610713135.1A CN106281018A (en) | 2016-08-24 | 2016-08-24 | A kind of fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui and preparation method thereof |
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| Publication Number | Publication Date |
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| CN106281018A true CN106281018A (en) | 2017-01-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610713135.1A Pending CN106281018A (en) | 2016-08-24 | 2016-08-24 | A kind of fireproof wear-resisting synthesizes transparent Resina Toxicodendri verniciflui and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110408319A (en) * | 2019-08-20 | 2019-11-05 | 闽江学院 | Fire-retardant raw lacquer film and preparation method thereof |
-
2016
- 2016-08-24 CN CN201610713135.1A patent/CN106281018A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110408319A (en) * | 2019-08-20 | 2019-11-05 | 闽江学院 | Fire-retardant raw lacquer film and preparation method thereof |
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Application publication date: 20170104 |