CN106269819A - A kind of electronic waste processing means and electronic waste process technique - Google Patents

A kind of electronic waste processing means and electronic waste process technique Download PDF

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Publication number
CN106269819A
CN106269819A CN201611000586.7A CN201611000586A CN106269819A CN 106269819 A CN106269819 A CN 106269819A CN 201611000586 A CN201611000586 A CN 201611000586A CN 106269819 A CN106269819 A CN 106269819A
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gas
rotating cylinder
expansion chamber
electronic waste
air
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CN201611000586.7A
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CN106269819B (en
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廖振宏
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Chenzhou Wanmo Environmental Protection Technology Co ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Treating Waste Gases (AREA)
  • Gasification And Melting Of Waste (AREA)

Abstract

The present invention relates to pyrolysis treatment apparatus, the first air-introduced machine, expansion chamber group, waste heat boiler, U-shaped air cooling pipe, pulse bag dust-precipitator, the second air-introduced machine and desulfurization taste removal tower system that a kind of electronic waste processing means includes being sequentially connected with;Described pyrolysis treatment apparatus is made up of rotating cylinder, deslagging storehouse, drive mechanism and tunnel gas furnace, the invention still further relates to the technique that electronic waste processes.The present invention processes electronic waste can solve the technical problem of the rotary kiln easy coking of stove wall, the most recyclable gasoline, diesel oil, metallics and glass fibre.The tail gas separated, a part enter waste heat boiler make produce superheated vapour drive turbine unit generation, another part tail gas be provide pyrolysis treatment apparatus thermal source fuel;The most not only improve economic benefit but also prevent secondary pollution, turn waste into wealth, really complete innoxious, recycling treatment to electronic waste.

Description

A kind of electronic waste processing means and electronic waste process technique
Technical field
The present invention relates to the process of rubbish, be specifically related to a kind of electronic waste processing means and electronic waste processes technique.
Background technology
Along with the fast development of new and high technology, the cycle that electronic product updates is shorter and shorter, the electricity produced therefrom Sub-garbage annual the most especially with 18% speed increment, become the most fastest-rising rubbish.And as a kind of electronics unit device Part printed substrate (Printed Circuit Boards is called for short PCB), is widely used in the middle of various electronic product, Its recycling and Resource analysis are had become as the hot issue of Current electronic garbage disposal.Old circuit board main source The substandard products, leftover pieces and the waste electric products that produce in electronic circuit board manufacturing process remove the electronic circuit board of assembly element Substrate.At present, the method for disposal of old circuit board substantially can be divided into 5 kinds, i.e. landfill method, burning method, Mechanical Crushing one The multiple methods such as physical partition method, wet chemistry method, pyrolysismethod.These methods cut both ways, electronic waste processing equipment cost Costliness, processing cost is high, and particularly pyrolysismethod uses the kiln high-temperature process old circuit board easy coking of kiln wall, processes skill Art is the most immature, it is impossible to promote.
Summary of the invention
It is an object of the invention to overcome deficiency of the prior art, it is provided that a kind of electronic waste processing means and electronics rubbish Rubbish processes technique, it is intended to reclaim metallics and glass fibre, improves efficiency of combustion, reduces secondary pollution, it is possible to solve back The technical problem of the easy coking of rotary kiln stove wall.
For reaching above-mentioned purpose, a kind of electronic waste processing means of the present invention, set including the pyrolysis processing being sequentially connected with Standby, the first air-introduced machine, expansion chamber group, waste heat boiler, U-shaped air cooling pipe, pulse bag dust-precipitator, the second air-introduced machine and desulfurization taste removal Tower system;Described pyrolysis treatment apparatus is made up of rotating cylinder, deslagging storehouse, drive mechanism and tunnel gas furnace, rotating cylinder Middle part is horizontal through tunnel gas furnace, and by surrounding hearth, two ends, rotating cylinder left and right are shelved on the carrying roller of support by rolling ring On;Described rotating cylinder left port is stretched and is packed in deslagging storehouse, is flexibly connected by the upper box of the first sealing ring with deslagging storehouse, row Slag notch is arranged at the bottom in slag storehouse;A hollow spindle is connected also by the spoke of more than three in rotating cylinder left port;This is hollow Main shaft passes through the external drive mechanism of upper box in deslagging storehouse by sealing device;Described rotating cylinder right output port is stretched and is packed into gas skirt In, it is flexibly connected with gas skirt by the second sealing ring;Rotating cylinder is led to equipped with sealing spiral conveyer in gas skirt side In;There is airway to connect the air inlet of expansion chamber group through the first air-introduced machine, from expansion chamber group row out at the top of gas skirt Trachea divides two-way by branched pipe, and wherein a road connects waste heat boiler, another connection tunnel, road gas furnace;Described waste heat boiler Superheated vapour outlet connects turbine unit by pipeline and drives electrical power generators.
A kind of electronic waste processes technique:
1. after electronic waste transports factory back, store in a warehouse, it is impossible to air storage drenches with rain, fire prevention;
2. by environmental protection cyclopentane gas detector, electronic waste is torn up;Control to tear up thing particle diameter 1mm particles below and account for 40%, grain Footpath 1-10mm granule accounts for 40%, and particle diameter 20mm granule accounts for 20%;
3. by the revolving drum tearing up thing sealing spiral conveyer feeding pyrolysis treatment apparatus, sealing spiral conveyer is controlled Charging rate is 15-20kg/min;The rotating speed of revolving drum is 1-2r/min;Through the carbonization slag that revolving drum slagging device ejects Material is containing glass fibre, valuable metal and white carbon black, through dispensing, send smelting shop to reclaim glass fibre, valuable metal and white carbon black;
4. thing is torn up by mixed gas produced after pyrolysis, containing CO2, CO, methane, HBr, lower aliphatic hydrocarbon, relatively low The aromatic hydrocarbons of molecular mass, phenol, methylphenol, bisphenol-A, bromophenol and two English;Under the effect of the first air-introduced machine, it is introduced into Expansion chamber group heavy oil separation;Gained heavy oil pass through air-distillation pyrolysis oil, obtain light naphthar, heavy naphtha, light petroleum gas and 4 kinds of fractions of heavy oil gas;The high-temperature fraction with higher thermal value is sold as lower grade fuel oil;Through appropriateness hydrogenation and deoxidation, take off Low temperature fraction Petroleum and light petroleum gas that water processes can reclaim as gasoline and bavin main body of oil and use;
5. from afterbody expansion chamber gas out containing CO, methane and two English, a part is entered waste heat boiler and is fired as gas Material burning;Another part is as the fuel providing pyrolysis treatment apparatus thermal source;In waste heat boiler, gas is abundant at combustor oxygenation Burning, falls two English burn processing, and furnace temperature is up to 1000 DEG C-1300 DEG C;Produce superheated vapour by moisture film heat exchange to drive Take offence wheel unit generation;
6. from waste heat boiler discharge flue gas, through U-shaped air cooling pipe naturally cool to 180 DEG C flue gas enter pulse bag gather dust; Cool down taste removal in flue gas sends into desulfurization taste removal tower in the two poles of the earth under the effect of the second air-introduced machine after gathering dust, taken off by water wash in tower Sulfur, cool down, add sheet alkali arsenic removal, reach national environmental standard discharge;Washing water recycles.
Compared with the prior art, the present invention can process electronic waste, reclaims metallics and glass fibre, improves burning effect Rate, reduce secondary pollution, it is possible to solve the rotary kiln easy coking of stove wall technical problem, its key technology is: 1. due to Before pyrolysis, electronic waste is first carried out special handling, controls to tear up the proportioning of thing different-grain diameter, both met and needed fine powder The requirement that the factor of created gase of shape granule is higher, make use of the rolling of larger particles the most dexterously, solves fine powder and is easily detained knot The problem of block;This is fully and completely one of key technology being pyrolyzed electronic waste.2. special electronic waste pyrolysis processing is utilized Equipment, omnidistance laying spiral stream guidance device in using revolving drum body wall;Utilize guide vane to reverse in rotating cylinder dexterously to sweep Scrape rotating cylinder;Both achieved the guide conveying function that spiral stream guidance device itself is had, and created again and make electronic waste uniform The New function of pyrolysis noncoking.This is the two of the key technology being fully and completely pyrolyzed electronic waste, is also the innovative point of the present invention. 3. expansion chamber group heavy oil separation is utilized;Can reclaim as gasoline and bavin main body of oil and use.4. expansion chamber group is utilized to separate After tail gas, a part is entered waste heat boiler as gas fuel combustion, is produced superheated vapour by moisture film heat exchange and drive turbine Unit generation;Through field test, the present invention processes waste and old electric rubbish 5-6 ton per hour, can be with unit generated energy 3 megawatts Electricity/hour, as calculated by the 0.5 yuan/electricity price often spent, the economic benefit of 36000 yuan can be obtained every day;After expansion chamber group separates Another part tail gas, as provide pyrolysis treatment apparatus thermal source fuel;Make tail gas more be made full use of, improve economy effect Benefit, will not give off dioxin contamination environment.Waste residue the most of the present invention is sent smelting shop to reclaim glass fibre, valuable metal and charcoal Black.The most not only improve economic benefit but also prevent secondary pollution, turn waste into wealth, really complete electronic waste is harmless Change, recycling treatment.
Accompanying drawing explanation
Fig. 1 is the structural representation of electronic waste processing means of the present invention.
Being labeled as in figure: 1 pyrolysis treatment apparatus;1.1 rotating cylinder;1.2 deslagging storehouses;1.3 drive mechanism;1.4 tunnel Gas furnace;1.5 rolling ring;1.6 support;1.7 slag notch;1.8 spoke;1.9 hollow spindle;1.10 gas skirt;1.11 sealing screw Conveyer;1.12 spiral stream guidance device;1.13 drive shaft;1.14 commutating tooth wheel set;2 first air-introduced machines;3 expansion chamber groups;3.1 air inlet Mouthful;3.2 exhaustor;4 waste heat boilers;5 U-shaped air cooling pipes;6 pulse bag dust-precipitators;7 second air-introduced machines;8 desulfurization taste removal tower system; 9 turbine units;10 electromotors.
Detailed description of the invention
The present invention will be further described with embodiment below in conjunction with the accompanying drawings.
A kind of electronic waste processing means, including pyrolysis treatment apparatus the 1, first air-introduced machine 2 being sequentially connected with, expansion chamber group 3, waste heat boiler 4, U-shaped air cooling pipe 5, pulse bag dust-precipitator the 6, second air-introduced machine 7 and desulfurization taste removal tower system 8;Described pyrolysis Processing equipment 1 is made up of rotating cylinder 1.1, deslagging storehouse 1.2, drive mechanism 1.3 and tunnel gas furnace 1.4, rotating cylinder 1.1 Middle part is horizontal through tunnel gas furnace 1.4, and by surrounding hearth, rotating cylinder about 1.1 two ends are shelved on by rolling ring 1.5 and prop up On the carrying roller of support 1.6;Described rotating cylinder 1.1 left port is stretched and is packed in deslagging storehouse 1.2, by the first sealing ring and deslagging storehouse The upper box of 1.2 is flexibly connected, and slag notch 1.7 is arranged at the bottom in deslagging storehouse 1.2;In rotating cylinder 1.1 left port also by three Above spoke 1.8 connects a hollow spindle 1.9;This hollow spindle 1.9 passes through the upper box in deslagging storehouse 1.2 by sealing device External drive mechanism 1.3;Described rotating cylinder 1.1 right output port is stretched and is packed in gas skirt 1.10, by the second sealing ring and gas collection Cover 1.10 flexible connection;Lead in rotating cylinder 1.1 equipped with sealing spiral conveyer 1.11 in gas skirt 1.10 side;At gas collection The top of cover 1.10 has airway to connect the air inlet 3.1 of expansion chamber group 3 through the first air-introduced machine 2, from expansion chamber group 3 row out Trachea 3.2 divides two-way by branched pipe, and wherein a road connects waste heat boiler 4, another connection tunnel, road gas furnace 1.4;Described remaining The superheated vapour outlet of heat boiler 4 connects turbine unit 9 by pipeline and drives electromotor 10 to generate electricity.
Also whole process lays a spiral stream guidance device 1.12 in described rotating cylinder 1.1 wall, and the leading of spiral stream guidance device 1.12 Stream blade matches with cylinder internal diameter;The drive shaft 1.13 of spiral stream guidance device 1.12 passes described hollow spindle 1.9 through commutation Gear pair 1.14 is also connected with drive mechanism 1.3;When making rotating cylinder 1.1 rotate, the guide vane of spiral stream guidance device 1.12 exists Reverse and sweep in rotating cylinder 1.1 and scrape rotating cylinder 1.1 inwall.
Described expansion chamber group 3 has two groups of series connection, and the exhaustor of the i.e. first expansion chamber connects the air inlet of the second expansion chamber;Each Exhaustor in expansion chamber inserts the middle and lower part of expansion chamber from expansion chamber upper straight.
Described desulfurization taste removal tower system 8 has two groups of series connection, the smoke exhaust pipe of the i.e. first desulfurization taste removal tower to connect the second desulfurization taste removal tower Smoke inlet.
Described pyrolysis treatment apparatus 1, expansion chamber group 3, waste heat boiler 4, U-shaped air cooling pipe 5, pulse bag dust-precipitator 6 and de- Each position of sulfur taste removal tower system 8, is equipped with corresponding alarm.
A kind of electronic waste processes technique, and processing step is as follows:
1. after electronic waste transports factory back, store in a warehouse, it is impossible to air storage drenches with rain, fire prevention;
2. by environmental protection cyclopentane gas detector, electronic waste is torn up;Control to tear up thing particle diameter 1mm particles below and account for 40%, grain Footpath 1-10mm granule accounts for 40%, and particle diameter 20mm granule accounts for 20%;
3. by the revolving drum tearing up thing sealing spiral conveyer 1.11 and sending into pyrolysis treatment apparatus 1, sealing screw is controlled defeated The charging rate sending machine 1.11 is 15-20kg/min;The rotating speed of revolving drum is 1-2r/min;Discharge through revolving drum slagging device The carbonization slag charge come is containing glass fibre, valuable metal and white carbon black, through dispensing, send smelting shop to reclaim glass fibre, have valency gold Belong to and white carbon black;
4. thing is torn up by mixed gas produced after pyrolysis, containing CO2, CO, methane, HBr, lower aliphatic hydrocarbon, relatively low The aromatic hydrocarbons of molecular mass, phenol, methylphenol, bisphenol-A, bromophenol and two English;Under the effect of the first air-introduced machine 2, advanced Enter expansion chamber group 3 heavy oil separation;Gained heavy oil passes through air-distillation pyrolysis oil, obtains light naphthar, heavy naphtha, light petroleum gas With 4 kinds of fractions of heavy oil gas;The high-temperature fraction with higher thermal value is sold as lower grade fuel oil;Through appropriateness hydrogenation and deoxidation, The low temperature fraction Petroleum of processed and light petroleum gas can reclaim as gasoline and bavin main body of oil and use;
5. from afterbody expansion chamber gas out containing CO, methane and two English, a part is entered waste heat boiler 4 and is fired as gas Material burning;Another part is as the fuel providing pyrolysis treatment apparatus 1 thermal source;In waste heat boiler 4, gas fills at combustor oxygenation Divided combustion, falls two English burn processing, and furnace temperature is up to 1000 DEG C-1300 DEG C;Superheated vapour is produced by moisture film heat exchange Turbine unit 10 is driven to generate electricity;
6. the flue gas discharged from waste heat boiler 4, the flue gas naturally cooling to 180 DEG C through U-shaped air cooling pipe 5 enters pulse bag receipts Dirt;Cool down taste removal in flue gas sends into desulfurization taste removal tower in the two poles of the earth under the effect of the second air-introduced machine 7 after gathering dust, drenched by water in tower Eluting sulfur, cool down, add sheet alkali arsenic removal, reach national environmental standard discharge;Washing water recycles.

Claims (6)

1. an electronic waste processing means, including the pyrolysis treatment apparatus (1) being sequentially connected with, the first air-introduced machine (2), expansion chamber Group (3), waste heat boiler (4), U-shaped air cooling pipe (5), pulse bag dust-precipitator (6), the second air-introduced machine (7) and desulfurization taste removal tower system (8);It is characterized in that: described pyrolysis treatment apparatus (1) is by rotating cylinder (1.1), deslagging storehouse (1.2), drive mechanism (1.3) Formed with tunnel gas furnace (1.4), horizontal through tunnel gas furnace (1.4) in the middle part of rotating cylinder (1.1), and by burner hearth bag Enclosing, rotating cylinder (1.1) two ends, left and right are shelved on the carrying roller of support (1.6) by rolling ring (1.5);Described rotating cylinder (1.1) left port is stretched and is packed in deslagging storehouse (1.2), is flexibly connected by the upper box of the first sealing ring with deslagging storehouse (1.2), row Slag notch (1.7) is arranged at the bottom in slag storehouse (1.2);Connect also by the spoke (1.8) of more than three in rotating cylinder (1.1) left port Connect a hollow spindle (1.9);This hollow spindle (1.9) passes through the external driving of upper box in deslagging storehouse (1.2) by sealing device Mechanism (1.3);Described rotating cylinder (1.1) right output port is stretched and is packed in gas skirt (1.10), by the second sealing ring and gas skirt (1.10) it is flexibly connected;Lead in rotating cylinder (1.1) equipped with sealing spiral conveyer (1.11) in gas skirt (1.10) side; Airway is had to connect the air inlet (3.1) of expansion chamber group (3) through the first air-introduced machine (2) at the top of gas skirt (1.10), from heavy Fall room group (3) exhaustor (3.2) out divides two-way by branched pipe, and wherein a road connects waste heat boiler (4), and another road connects Tunnel gas furnace (1.4);The superheated vapour outlet of described waste heat boiler (4) connects turbine unit (9) driving by pipeline and sends out Motor (10) generates electricity.
Electronic waste processing means the most according to claim 1, it is characterised in that: in described rotating cylinder (1.1) wall Also omnidistance laying one spiral stream guidance device (1.12), and the guide vane of spiral stream guidance device (1.12) matches with cylinder internal diameter;Spiral shell The drive shaft (1.13) of rotation air deflector (1.12) through described hollow spindle (1.9) through commutating tooth wheel set (1.14) also with driving Mechanism (1.3) is connected;When making rotating cylinder (1.1) rotate, the guide vane of spiral stream guidance device (1.12) is in rotating cylinder (1.1) Interior reverse is also swept and is scraped rotating cylinder (1.1) inwall.
Electronic waste processing means the most according to claim 1, it is characterised in that: described expansion chamber group (3) has two groups of strings Connection, the exhaustor of the i.e. first expansion chamber connects the air inlet of the second expansion chamber;Exhaustor in each expansion chamber is from expansion chamber top Straight cutting enters the middle and lower part of expansion chamber.
Electronic waste processing means the most according to claim 1, it is characterised in that: described desulfurization taste removal tower system (8) has two Group series connection, the smoke exhaust pipe of the i.e. first desulfurization taste removal tower connects the smoke inlet of the second desulfurization taste removal tower.
Electronic waste processing means the most according to claim 1, it is characterised in that: described pyrolysis treatment apparatus (1), sedimentation Room group (3), waste heat boiler (4), U-shaped air cooling pipe (5), pulse bag dust-precipitator (6) and each portion of desulfurization taste removal tower system (8) Position, is equipped with corresponding alarm.
6. electronic waste processes a technique, it is characterized in that processing step is as follows:
1. after electronic waste transports factory back, store in a warehouse, it is impossible to air storage drenches with rain, fire prevention;
2. by environmental protection cyclopentane gas detector, electronic waste is torn up;Control to tear up thing particle diameter 1mm particles below and account for 40%, grain Footpath 1-10mm granule accounts for 40%, and particle diameter 20mm granule accounts for 20%;
3. will tear up in the revolving drum that thing sealing spiral conveyer (1.11) sends into pyrolysis treatment apparatus (1), and control to seal spiral shell The charging rate of rotation conveyer (1.11) is 15-20kg/min;The rotating speed of revolving drum is 1-2r/min;Through revolving drum slag extractor The carbonization slag charge that structure ejects is containing glass fibre, valuable metal and white carbon black, through dispensing, send smelting shop reclaim glass fibre, Valuable metal and white carbon black;
4. thing is torn up by mixed gas produced after pyrolysis, containing CO2, CO, methane, HBr, lower aliphatic hydrocarbon, relatively low point The aromatic hydrocarbons of protonatomic mass, phenol, methylphenol, bisphenol-A, bromophenol and two English;Under the effect of the first air-introduced machine (2), advanced Enter expansion chamber group (3) heavy oil separation;Gained heavy oil passes through air-distillation pyrolysis oil, obtains light naphthar, heavy naphtha, light oil Gas and 4 kinds of fractions of heavy oil gas;The high-temperature fraction with higher thermal value is sold as lower grade fuel oil;Hydrogenate and de-through appropriateness Oxygen, the low temperature fraction Petroleum of processed and light petroleum gas can reclaim as gasoline and bavin main body of oil and use;
5. from afterbody expansion chamber gas out containing CO, methane and two English, a part enters waste heat boiler (4) as gas Fuel combustion;Another part is as the fuel providing pyrolysis treatment apparatus (1) thermal source;In waste heat boiler (4), gas is at combustor Oxygenation fully burns, and two English burn processing are fallen, and furnace temperature is up to 1000 DEG C-1300 DEG C;It is overheated to be produced by moisture film heat exchange Water vapour drives turbine unit (10) generating;
6. the flue gas discharged from waste heat boiler (4), the flue gas naturally cooling to 180 DEG C through U-shaped air cooling pipe (5) enters pulse bag Gather dust;Cool down taste removal in flue gas sends into desulfurization taste removal tower in the two poles of the earth under the effect of the second air-introduced machine (7) after gathering dust, pass through in tower Water wash desulfurization, cool down, add sheet alkali arsenic removal, reach national environmental standard discharge;Washing water recycles.
CN201611000586.7A 2016-11-14 2016-11-14 A kind of electronic waste processing unit and electronic waste treatment process Active CN106269819B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113020215A (en) * 2021-03-09 2021-06-25 中国华能集团清洁能源技术研究院有限公司 System for extracting glass fibers and pyrolysis oil from fan blade and working method thereof

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CN105817462A (en) * 2016-03-23 2016-08-03 中山大学 Technical method for high-added-value resource utilization of waste circuit board electronic components
CN206199865U (en) * 2016-11-14 2017-05-31 廖振宏 A kind of electronic waste processing unit

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Publication number Priority date Publication date Assignee Title
CN1483963A (en) * 2002-09-18 2004-03-24 宋纪元 Refuse gasifying incineration treatment method of rotary furnace siege
JP2004270962A (en) * 2003-03-05 2004-09-30 Babcock Hitachi Kk Waste treatment device
CN104128349A (en) * 2013-05-02 2014-11-05 周鼎力 Device for production of fuel oil and fuel gas and/or flue gas power generation through household garbage
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113020215A (en) * 2021-03-09 2021-06-25 中国华能集团清洁能源技术研究院有限公司 System for extracting glass fibers and pyrolysis oil from fan blade and working method thereof

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Address after: 423000 Chenzhou City, Hunan Province, 1779 Nanling Avenue, Beihu District, Chenzhou City, Chenzhou Economic Development Zone, Changchong District, Chenzhou Road Building Machinery Factory 101

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