CN106263135A - A kind of electromagnetic protection clothes - Google Patents

A kind of electromagnetic protection clothes Download PDF

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Publication number
CN106263135A
CN106263135A CN201510264567.4A CN201510264567A CN106263135A CN 106263135 A CN106263135 A CN 106263135A CN 201510264567 A CN201510264567 A CN 201510264567A CN 106263135 A CN106263135 A CN 106263135A
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China
Prior art keywords
amorphous
fiber
glass
foundry alloy
fabric
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CN201510264567.4A
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Chinese (zh)
Inventor
王诚
陈征
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Beijing Heng Wei Science And Technology Ltd
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Beijing Heng Wei Science And Technology Ltd
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Priority to CN201510264567.4A priority Critical patent/CN106263135A/en
Publication of CN106263135A publication Critical patent/CN106263135A/en
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Abstract

The invention belongs to field of textiles, it is provided that a kind of absorption-type electromagnetic protection clothes, use and inhale the making of ripple fabric, containing amorphous fiber in this suction ripple fabric, incident electromagnetic wave can be converted into heat energy loss and fall so that electromagnetic wave neither transmission, not reflect.

Description

A kind of electromagnetic protection clothes
Technical field
A kind of electromagnetic protection clothes in the present invention belong to field of textiles.
Background technology
Along with developing rapidly of information technology, electromagnetic pollution becomes after water pollution, atmospheric pollution, sound pollution, by generation Boundary is known as the fourth-largest environmental pollution.Result of study shows, electromagnetic pollution works the mischief for the health of human body, electromagnetic radiation pair The influence degree of health is relevant with the time length of its suffered radiant intensity, accumulation, and human body is had latent by electromagnetic radiation In danger.Molecule in Working Life interference the most long, electromagnetic wave makes tissue in the environment of superpower electromagnetic radiation is original Electric field changes so that the molecule electric field in cell is destroyed, and cellularity is damaged.Additionally, real-life electricity Magnetic radiation problem is day by day serious, and the protection to the fetus in anemia of pregnant woman's body is the most necessary.
At present, mainly take the form suppression electromagnetic radiation of electromagnetic shielding, be divided into reflection-type and the big class of absorption-type two.Traditional electricity Magnetic protective garment uses the conductive fibers such as rustless steel, copper, silver to make, and belongs to reflection-type electromagnetic shielding material, it may be assumed that by incident electricity Magnetic wave reflects back, and does not allow Electromgnetically-transparent to the opposite side of fabric.Protective garment is the clothing being through on human body, it is impossible to accomplished Total enclosing, neckline, cuff etc. are all the channels revealing electromagnetic wave.Reflection-type electromagnetic protection clothes can stop the entrance of electromagnetic wave, But once electromagnetic wave is entered inside exposure suit by leak point, is difficult to away too so that protective garment becomes an electromagnetic wave Catcher, may produce secondary pollution.
Absorption-type electromagnetic shielding material is electromagnetic wave to be converted into thermal energy consumption fall, and neither transmission is not reflected, at industrial field Apply quite varied, mainly use the dusty materials such as ferrite, iron-nickel alloy and non-crystaline amorphous metal to make, in suppression electromagnetic radiation It is also possible to prevent the secondary pollution of electromagnetic wave.But, dusty material cannot be spun into Electromagnetically shielding fabrics;It is coated in fabric The reduction of performance can be caused again in surface, and weatherability is poor.
Amorphous fiber employed in the present invention has the features such as good soft magnet performance, high magnetic permeability, high intensity and corrosion resistance, It it is a kind of good absorption-type electromagnetic shielding material;Its fibre morphology is beneficial to it and puts in the middle of fabric.Use amorphous fiber as suction The fabric that ripple agent makes, can prepare the absorption-type electromagnetic protection clothes with good absorbing property and weatherability.
Summary of the invention
The invention aims to develop a kind of absorption-type electromagnetic protection clothes, containing amorphous fiber in this suction ripple fabric, can will enter The electromagnetic wave penetrated is converted into heat energy loss and falls so that electromagnetic wave neither transmission, does not reflects.
Technical characteristic and the scheme of the absorption-type electromagnetic protection clothes proposed in the present invention are as follows:
Absorption-type electromagnetic protection clothes in the present invention, use and can make with the fabric of electromagnetic wave absorption.
Suction ripple fabric in the present invention is a kind of composite, is made up of matrix material and wave absorbing agent.
Containing amorphous fiber in wave absorbing agent in the present invention.
Amorphous fiber in the present invention is by glass fluxing technique amorphous fiber or amorphous naked fiber or the two mixing.
Glass fluxing technique amorphous fiber in the present invention, uses Taylor's spin processes to prepare.
Amorphous naked fiber in the present invention, uses inner circle water spinning or melt czochralski method to prepare.
The size range of the glass bag amorphous fiber in the present invention is: amorphous inner core diameter 1-30 micron;Glass outer layer thickness 1-15 Micron;Chopped fiber or the employing continuous fibers material of a length of 1-50 millimeter are directly weaved.
The size range of the amorphous naked fiber in the present invention is: diameter 1-50 micron;The chopped fiber of a length of 1-50 millimeter.
The composition of the amorphous fiber in the present invention contains Co, one or more elements in Fe, Mn, Ni;Containing Si, B, C In one or more elements;Rare earth or magnesium-yttrium-transition metal etc. may be added.
In the present invention, the mass percent of amorphous fiber is 0.1%-30%.
Matrix material in the present invention is the tradition fabrics such as cotton, chemical fibre, but is not limited to above-mentioned fabric.
Fabric in the present invention uses traditional blending, felt-cloth, twist thread and sword the method such as is knitted and prepared, but is not limited to said method.
Accompanying drawing explanation
(1 induction coil 6 cooling zone 7, glass tubing 3 foundry alloy 4 thermal treatment zone 5, feed zone 2 is cold for Fig. 1: Taylor's spin processes schematic diagram But liquid 8 glass fluxing technique amorphous wire material 9 winding roller)
Fig. 2: inner circle water spinning schematic diagram (1 nozzle 2 foundry alloy 3 induction coil 4 amorphous naked fiber 5 drum 6 coolant)
Fig. 3: melt czochralski method schematic diagram (1 induction coil 2 foundry alloy bar 3 copper wheel 4 foundry alloy apparatus for feeding)
Fig. 4: glass bag amorphous fiber electromicroscopic photograph
Fig. 5: amorphous naked fiber electromicroscopic photograph
Fig. 6: the fabric photo containing amorphous fiber
The electromagnetic performance test result of Fig. 7: the fabric containing copper fiber
The electromagnetic performance test result of Fig. 8: the fabric containing amorphous fiber
Detailed description of the invention
In the present invention, amorphous fiber uses Taylor's spin processes to prepare, prepared by inner circle water spinning or melt czochralski method
In the present invention, glass bag amorphous fiber uses Taylor's spin processes to prepare, (as shown in Figure 1) specific as follows:
It is first according to required composition and prepares foundry alloy rod, and choose the glass tubing matched, the fusing point of foundry alloy and glass tubing The difference of softening temperature is higher than 50 DEG C and less than 500 DEG C.
1, foundry alloy rod is inserted bottom glass tubing;
2, use bottom Efco-Northrup furnace fusing foundry alloy rod;
Glass tubing is softened by the foundry alloy 3, utilizing fusing;
4, drawing mode is used to be extracted by silk;
5, by the way of rapid solidification, it is in the foundry alloy cooling of molten condition, forms amorphous alloy.
6, being wound on by silk material on receipts roll dies, the coiling speed of silk material keeps linear velocity constant, linear velocity scope 10-100 m/min;
7, by the regulation parameter such as delivery rate, temperature, stablizing of drawing process is kept, it is achieved prepared by the serialization of silk.
Use aforesaid way to prepare continuous print glass bag amorphous wire, then the glass bag amorphous that continuous fibers cut into Len req is fine Dimension.
In the present invention, amorphous naked fiber uses inner circle water spinning to prepare, (as shown in Figure 2) specific as follows:
It is first according to required composition and prepares foundry alloy rod.
1, in the drum of high speed rotating, cooling water is added so that cooling water is at the inwall synchronous rotary of drum;
2, foundry alloy is put in the middle of nozzle, utilize induction heating mode to melt foundry alloy;
3, in nozzle, it is filled with gases at high pressure, the foundry alloy of fusing is sprayed into rapid solidification in water, prepare amorphous naked fiber.
In the present invention, amorphous naked fiber uses melt czochralski method to prepare, (as shown in Figure 3) specific as follows:
It is first according to required composition and prepares foundry alloy rod.
1, the mode utilizing sensing heating or LASER HEATING melts foundry alloy so that foundry alloy upper end forms a stable weld pool;
2, upwards being fed foundry alloy by machinery, foundry alloy is cooled down by the position simultaneously utilizing guider to be connected with foundry alloy, Prevent the part beyond foundry alloy top from melting;
3, the foundry alloy of fusing is cut by the copper wheel of the high speed rotating using edge to be taper, obtains amorphous naked fiber.
In the present invention, glass bag amorphous fiber is as shown in Figure 4, and 1 is glass bag amorphous fiber;2 is the amorphous of glass bag amorphous fiber Inner core;3 is the glass shell of glass bag amorphous fiber.
In the present invention, amorphous naked fiber is as shown in Figure 5.
In the present invention using amorphous fiber as wave absorbing agent according to required ratio, use traditional blending, felt-cloth, twist thread and sword is knitted Method, is spun in the middle of the tradition fabric such as cotton, chemical fibre, makes suction ripple fabric (as shown in Figure 6).
The present invention uses above-mentioned suction ripple fabric to make absorption-type electromagnetic protection clothes.
Comparative example 1
Comparative example 1 use copper fiber prepare loomage.
The copper fiber using a length of 15 millimeters in comparative example 1 is mixed into matrix material as wave absorbing agent according to the mass percent of 5%, Make felt-cloth.
The electromagnetic performance test result of the absorption-type loomage in comparative example 1 is as shown in Figure 7.
Embodiment 1:
In embodiment 1, amorphous fiber uses the preparation preparation of Taylor's spin processes
In embodiment 1, glass bag amorphous fiber uses Taylor's spin processes to prepare, specific as follows:
First embodiment 1 is prepared Co base foundry alloy rod, 1025 DEG C of diameter 7mm of fusing point;The glass selecting operating temperature to be 825 DEG C Glass pipe, external diameter 12mm, wall thickness 1mm.
1, foundry alloy rod is inserted bottom glass tubing;
2, use Efco-Northrup furnace fusing foundry alloy, and be heated to 1200 DEG C;
Glass tubing is softened by the foundry alloy 3, utilizing fusing;
4, drawing mode is used to be extracted by silk;
5, logical supercooled water, cools down the foundry alloy being in molten condition, forms amorphous alloy;
6, it is wound on receipts roll dies, receives silk speed 30 ms/min;
7, by the regulation parameter such as delivery rate, temperature, stablizing of drawing process is kept, it is achieved prepared by the serialization of silk.
Aforesaid way is used to prepare continuous print glass bag amorphous wire, amorphous inner core diameter 15 ± 2 microns;Glass outer layer thickness 5 ± 1 micron.
Continuous fibers are cut into the glass bag amorphous fiber of a length of 15 millimeters again.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 5% by embodiment 1, makes felt Cloth.
As shown in Figure 8, electromagnetic consumable is fine apparently higher than copper for the electromagnetic performance test result of the absorption-type loomage in embodiment 1 The loomage that dimension is made.
Embodiment 2:
In embodiment 2, amorphous fiber uses the preparation preparation of Taylor's spin processes
In embodiment 2, glass bag amorphous fiber uses Taylor's spin processes to prepare, specific as follows:
First embodiment 2 is prepared Fe base foundry alloy rod, 1055 DEG C of diameter 7mm of fusing point;The glass selecting operating temperature to be 825 DEG C Glass pipe, external diameter 12mm, wall thickness 1mm.
1, foundry alloy rod is inserted bottom glass tubing;
2, use Efco-Northrup furnace fusing foundry alloy, and be heated to 1250 DEG C;
Glass tubing is softened by the foundry alloy 3, utilizing fusing;
4, drawing mode is used to be extracted by silk;
5, logical supercooled water, cools down the foundry alloy being in molten condition, forms amorphous alloy;
6, it is wound on receipts roll dies, receives silk speed 50 ms/min;
7, by the regulation parameter such as delivery rate, temperature, stablizing of drawing process is kept, it is achieved prepared by the serialization of silk.
Aforesaid way is used to prepare continuous print glass bag amorphous wire, amorphous inner core diameter 12 ± 2 microns;Glass outer layer thickness 6 ± 1 micron.
Continuous fibers are cut into the glass bag amorphous fiber of a length of 15 millimeters again.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 5% by embodiment 2, makes felt Cloth.
Embodiment 3:
In embodiment 3, amorphous fiber uses the preparation preparation of Taylor's spin processes
In embodiment 3, glass bag amorphous fiber uses Taylor's spin processes to prepare, specific as follows:
First embodiment 3 is prepared Co base foundry alloy rod, 1025 DEG C of diameter 7mm of fusing point;The glass selecting operating temperature to be 825 DEG C Glass pipe, external diameter 12mm, wall thickness 1mm.
1, foundry alloy rod is inserted bottom glass tubing;
2, use Efco-Northrup furnace fusing foundry alloy, and be heated to 1200 DEG C;
Glass tubing is softened by the foundry alloy 3, utilizing fusing;
4, drawing mode is used to be extracted by silk;
5, logical supercooled water, cools down the foundry alloy being in molten condition, forms amorphous alloy;
6, it is wound on receipts roll dies, receives silk speed 30 ms/min;
7, by the regulation parameter such as delivery rate, temperature, stablizing of drawing process is kept, it is achieved prepared by the serialization of silk.
Aforesaid way is used to prepare continuous print glass bag amorphous wire, amorphous inner core diameter 15 ± 2 microns;Glass outer layer thickness 5 ± 1 micron.
Continuous fibers are cut into the glass bag amorphous fiber of a length of 15 millimeters again.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 2% by embodiment 3, makes felt Cloth.
Embodiment 4:
In embodiment 4, amorphous fiber uses the preparation preparation of Taylor's spin processes
In embodiment 4, glass bag amorphous fiber uses Taylor's spin processes to prepare, specific as follows:
First embodiment 4 is prepared Co base foundry alloy rod, 1025 DEG C of diameter 7mm of fusing point;The glass selecting operating temperature to be 825 DEG C Glass pipe, external diameter 12mm, wall thickness 1mm.
1, foundry alloy rod is inserted bottom glass tubing;
2, use Efco-Northrup furnace fusing foundry alloy, and be heated to 1200 DEG C;
Glass tubing is softened by the foundry alloy 3, utilizing fusing;
4, drawing mode is used to be extracted by silk;
5, logical supercooled water, cools down the foundry alloy being in molten condition, forms amorphous alloy;
6, it is wound on receipts roll dies, receives silk speed 30 ms/min;
7, by the regulation parameter such as delivery rate, temperature, stablizing of drawing process is kept, it is achieved prepared by the serialization of silk.
Aforesaid way is used to prepare continuous print glass bag amorphous wire, amorphous inner core diameter 15 ± 2 microns;Glass outer layer thickness 5 ± 1 micron.
Continuous fibers are cut into the glass bag amorphous fiber of a length of 15 millimeters again.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 25% by embodiment 4, makes felt Cloth.
Embodiment 5:
In embodiment 5, amorphous fiber uses the preparation preparation of Taylor's spin processes
In embodiment 5, glass bag amorphous fiber uses Taylor's spin processes to prepare, specific as follows:
First embodiment 5 is prepared Co base foundry alloy rod, 1025 DEG C of diameter 7mm of fusing point;The glass selecting operating temperature to be 825 DEG C Glass pipe, external diameter 12mm, wall thickness 1mm.
1, foundry alloy rod is inserted bottom glass tubing;
2, use Efco-Northrup furnace fusing foundry alloy, and be heated to 1200 DEG C;
Glass tubing is softened by the foundry alloy 3, utilizing fusing;
4, drawing mode is used to be extracted by silk;
5, logical supercooled water, cools down the foundry alloy being in molten condition, forms amorphous alloy;
6, it is wound on receipts roll dies, receives silk speed 30 ms/min;
7, by the regulation parameter such as delivery rate, temperature, stablizing of drawing process is kept, it is achieved prepared by the serialization of silk.
Aforesaid way is used to prepare continuous print glass bag amorphous wire, amorphous inner core diameter 15 ± 2 microns;Glass outer layer thickness 5 ± 1 micron.
Continuous fibers are cut into the glass bag amorphous fiber of a length of 15 millimeters again.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 5% by embodiment 5, uses and twist with the fingers After line, the method for weaving makes fabric.
Embodiment 6:
In embodiment 6, amorphous fiber uses the preparation preparation of Taylor's spin processes
In embodiment 6, glass bag amorphous fiber uses Taylor's spin processes to prepare, specific as follows:
First embodiment 6 is prepared Co base foundry alloy rod, 1025 DEG C of diameter 7mm of fusing point;The glass selecting operating temperature to be 825 DEG C Glass pipe, external diameter 12mm, wall thickness 1mm.
1, foundry alloy rod is inserted bottom glass tubing;
2, use Efco-Northrup furnace fusing foundry alloy, and be heated to 1200 DEG C;
Glass tubing is softened by the foundry alloy 3, utilizing fusing;
4, drawing mode is used to be extracted by silk;
5, logical supercooled water, cools down the foundry alloy being in molten condition, forms amorphous alloy;
6, it is wound on receipts roll dies, receives silk speed 30 ms/min;
7, by the regulation parameter such as delivery rate, temperature, stablizing of drawing process is kept, it is achieved prepared by the serialization of silk.
Aforesaid way is used to prepare continuous print glass bag amorphous wire, amorphous inner core diameter 15 ± 2 microns;Glass outer layer thickness 5 ± 1 micron.
Continuous fibers are cut into the glass bag amorphous fiber of a length of 15 millimeters again.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 5% by embodiment 6, uses sword The mode knitted makes fabric.
Embodiment 7:
In embodiment 7, amorphous fiber uses inner circle water spinning to prepare, and chooses Co base foundry alloy as raw material.
1, in the drum of the high speed rotating that rotating speed is 150 meter per seconds, cooling water is added so that cooling water is at the inwall synchronous rotary of drum;
2, foundry alloy is put in the middle of nozzle, utilize induction heating mode to melt foundry alloy, be heated to 1200 degree;
3, in nozzle, it is filled with gases at high pressure, the foundry alloy of fusing is sprayed into rapid solidification in water, prepare amorphous naked fiber.
Amorphous naked fiber cuts into length 15 millimeters.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 5% by embodiment 7, makes felt Cloth.
Embodiment 8:
In embodiment 8 prepared by amorphous fiber melt czochralski method, chooses Co base foundry alloy as raw material.
1, the mode utilizing sensing heating melts foundry alloy, is heated to 1200 degree so that foundry alloy upper end forms a stable weld pool;
2, upwards fed foundry alloy by the speed of the machinery second of 2mm/, utilize the position pair that guider is connected with foundry alloy simultaneously Foundry alloy cools down, and prevents the part beyond foundry alloy top from melting;
3, the foundry alloy of fusing is cut by the copper wheel of the high speed rotating using edge to be taper, obtains amorphous naked fiber.
Amorphous naked fiber cuts into length 15 millimeters.
Glass bag amorphous fiber is mixed into matrix material as wave absorbing agent according to the mass percent of 5% by embodiment 8, makes felt Cloth.

Claims (13)

1. absorption-type electromagnetic protection clothes, containing amorphous fiber in this suction ripple fabric, can be converted into heat energy loss by incident electromagnetic wave and fall so that electromagnetic wave neither transmission, not reflect.
2. the clothes of the absorption-type electromagnetic protection in claim 1, use and can make with the suction ripple fabric of electromagnetic wave absorption.
3. the suction ripple fabric in claim 2 is a kind of composite, is made up of matrix material and wave absorbing agent.
4. the matrix material in claim 3 is the tradition fabrics such as cotton, chemical fibre, but is not limited to above-mentioned fabric.
5. containing amorphous fiber in the wave absorbing agent in claim 3.
6. the amorphous fiber in claim 5 is by glass fluxing technique amorphous fiber or amorphous naked fiber or the two mixing.
7. the glass fluxing technique amorphous fiber in claim 6, uses Taylor's spin processes to prepare.
8. the amorphous naked fiber in claim 6, uses inner circle water spinning or melt czochralski method to prepare.
9. the size range of the glass bag amorphous fiber in claim 6 is: amorphous inner core diameter 1-30 micron;Glass outer layer thickness 1-15 micron;Chopped fiber or the employing continuous fibers material of a length of 1-50 millimeter are directly weaved.
10. the size range of the amorphous naked fiber in claim 6 is: diameter 1-50 micron;The chopped fiber of a length of 1-50 millimeter.
The composition of the amorphous fiber in 11. claim 5 contains Co, one or more elements in Fe, Mn, Ni;Containing Si, one or more elements in B, C;Rare earth or magnesium-yttrium-transition metal etc. may be added.
The mass percent of the amorphous fiber in 12. claim 5 is 0.1%-30%.
Ripple fabric of inhaling in 13. claim 2 uses traditional blending, felt-cloth, twists thread and sword the method such as is knitted and prepared, but is not limited to said method.
CN201510264567.4A 2015-05-22 2015-05-22 A kind of electromagnetic protection clothes Pending CN106263135A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107736656A (en) * 2017-09-29 2018-02-27 安徽瓦尔特机械贸易有限公司 A kind of wireless heating garment

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Publication number Priority date Publication date Assignee Title
US5103504A (en) * 1989-02-15 1992-04-14 Finex Handels-Gmbh Textile fabric shielding electromagnetic radiation, and clothing made thereof
CN1091484A (en) * 1989-02-15 1994-08-31 芬耐克斯贸易有限公司 The clothes of making of the fabric of electromagnetic radiation shielding
CN101302732A (en) * 2007-05-09 2008-11-12 中国印钞造币总公司 Composite anti-counterfeiting fiber and manufacturing method thereof
CN201468062U (en) * 2009-05-22 2010-05-19 王丛乐 Radiation-proof anti-bacterial and anti-static maternity clothes
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Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5103504A (en) * 1989-02-15 1992-04-14 Finex Handels-Gmbh Textile fabric shielding electromagnetic radiation, and clothing made thereof
CN1091484A (en) * 1989-02-15 1994-08-31 芬耐克斯贸易有限公司 The clothes of making of the fabric of electromagnetic radiation shielding
CN101302732A (en) * 2007-05-09 2008-11-12 中国印钞造币总公司 Composite anti-counterfeiting fiber and manufacturing method thereof
CN201468062U (en) * 2009-05-22 2010-05-19 王丛乐 Radiation-proof anti-bacterial and anti-static maternity clothes
CN101740143A (en) * 2009-12-02 2010-06-16 安泰科技股份有限公司 Amorphous fiber-containing electromagnetic wave absorbing material and method for preparing same

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何璞祯等: "非晶玻璃包裹细丝的制备与铁磁共振性能的应用", 《铸造技术》 *

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107736656A (en) * 2017-09-29 2018-02-27 安徽瓦尔特机械贸易有限公司 A kind of wireless heating garment

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