CN106243846A - A kind of Flexible waterproof paint of highly-breathable and preparation method thereof - Google Patents

A kind of Flexible waterproof paint of highly-breathable and preparation method thereof Download PDF

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Publication number
CN106243846A
CN106243846A CN201610738966.4A CN201610738966A CN106243846A CN 106243846 A CN106243846 A CN 106243846A CN 201610738966 A CN201610738966 A CN 201610738966A CN 106243846 A CN106243846 A CN 106243846A
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CN
China
Prior art keywords
parts
breathable
highly
flexible waterproof
waterproof paint
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610738966.4A
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Chinese (zh)
Inventor
周俊华
王峰
赵国庆
王�华
王治国
孟宪良
于凯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SHANDONG TECWAY WATERPROOF MATERIALS Co Ltd
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SHANDONG TECWAY WATERPROOF MATERIALS Co Ltd
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Application filed by SHANDONG TECWAY WATERPROOF MATERIALS Co Ltd filed Critical SHANDONG TECWAY WATERPROOF MATERIALS Co Ltd
Priority to CN201610738966.4A priority Critical patent/CN106243846A/en
Publication of CN106243846A publication Critical patent/CN106243846A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/08Copolymers of ethene
    • C09D123/0846Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C09D123/0853Vinylacetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to Flexible waterproof paint of a kind of highly-breathable and preparation method thereof, in parts by weight, including: pullulan solution 5 10 parts, silica flour 10 15 parts, rare earth adhesive 35 parts, hydroxyethyl cellulose 24 parts, EVA resin 50 60 parts, acrylic fiber 47 parts, 58 parts of kieselguhr, dispersant 5~10 parts, wetting agent 10~15 parts, thickening agent 5~8 parts, defoamer 1~3 parts, coalescents 10~15 parts and acrylic emulsion 30 40 parts, there is breathability good, pliability is good, adhesion is high, water proofing property is excellent, weatherability is strong, with low cost long with service life.

Description

A kind of Flexible waterproof paint of highly-breathable and preparation method thereof
Technical field
The present invention relates to Flexible waterproof paint of a kind of highly-breathable and preparation method thereof, belong to water-repellent paint field.
Background technology
Building enclosure rainwater to be prevented, snow water and the infiltration of subsoil water of building;Dampness in air to be prevented, steam Erosion with other harmful gass Yu liquid;The seepage of separation structure plumbing to be prevented.These impermeable, seepages and erosion Material is referred to as waterproof material.
Flexible waterproof material is as main waterproof material, and it has the following characteristics that
1: by acrylic emulsion and selected auxiliary agent (liquid material) and high grade cement, join sand and rubber powder (powder) forms in proportion Double-component, tough plastic modified polymer cement-based waterproof slurry.Brush after powder and liquid material are mixed, formed one layer tough and tensile High-elastic waterproof film, this film has good adhesiveness to concrete and cement mortar, is firmly combined with basal plane, thus reaches waterproof Effect.Product highlights flexility, it is possible to resist slight vibrations and a certain degree of displacement, is the novel green of Ministry of Construction's popularization Color environment-friendly products, are mainly adapted to civil engineering construction.
But, in actual applications, too pay close attention to water resistance due to water-repellent paint, in actual use, coating be coated with After overlaying on basic unit, due to day and night relatively big with the temperature difference in season, expand with heat and contract with cold cause be enclosed in the gas within basic unit cannot be with outward Portion's environment circulates, and is expanding with heat and contract with cold lower coating and basic unit often produces cracking phenomena, have a strong impact on coating water resistance, Adhesion and service life.
Summary of the invention
The invention provides Flexible waterproof paint of a kind of highly-breathable and preparation method thereof, have, breathability is good, soft Good toughness, adhesion are high, water proofing property is excellent, weatherability is strong, with low cost and service life is long.
For solving above-mentioned technical problem, the technical solution used in the present invention is:
. the Flexible waterproof paint of a kind of highly-breathable, in parts by weight, including: pullulan solution 5-10 part, stone English powder 10-15 part, rare earth adhesive 3-5 part, hydroxyethyl cellulose 2-4 part, EVA resin 50-60 part, acrylic fiber 4-7 part, Kieselguhr 5-8 part, dispersant 5~10 parts, wetting agent 10~15 parts, thickening agent 5~8 parts, defoamer 1~3 parts, coalescents 10 ~15 parts and acrylic emulsion 30-40 part.
Preferably: in parts by weight, including pullulan solution 5-6 part, silica flour 10-13 part, rare earth adhesive 3- 5 parts, hydroxyethyl cellulose 2-4 part, EVA resin 50-55 part, acrylic fiber 6-7 part, kieselguhr 5-8 part, dispersant 5~10 Part, wetting agent 10~15 parts, thickening agent 5~8 parts, defoamer 1~3 parts, coalescents 10~15 parts and acrylic emulsion 35-40 Part.
Preferably: described dispersant is the mixture of polyacrylate, poly-methyl acrylate.Polyacrylate, poly- The mixture of methacrylate is the macromolecule hyper-dispersant using particular polymeric technique to prepare, and it has molecular weight low and distribution The characteristic such as narrow, is dispersed with good effect to various inorganic pigments and filler in water-based system, and it has, and consumption is few, foam Less, the advantage such as viscosity stablization, with water-repellent paint and ceramic particle, there is the good compatibility, effectively can improve the resistance to of coating Hou Xing, bin stability and water proofing property.
Preferably: described wetting agent is OT-75 or TECH-278.OT-75 or TECH-278 has ultralow dynamic tension, Outstanding wettability, highly-water-soluble, it is used in conjunction with the mixture of polyacrylate, poly-methyl acrylate, can be effective Ground improves stability and the weatherability of coating.
Preferably: described thickening agent is polyacrylamide thickeners.It is strong that polyacrylamide thickeners has water-retaining property: anti- Only mortar rapid draing;2, instant: cold water stirring can use, and dissolution velocity is quickly;3, environmental protection does not has VOC, formaldehyde etc.;Nothing Abnormal smells from the patient;4, low cost is lower than common water-retaining admixture cost, and consumption is less;5, application property is good: mortar in dry powder and mortar Denseness, sag resistance and water-retaining property, there is the features such as consumption little, good water-retaining property, cohesive strength height, good endurance.Use it to make Thickening agent for the present invention can be mutual with polyacrylate, the mixture of poly-methyl acrylate and OT-75 or TECH-278 Effect, is effectively improved adhesion and the water proofing property of product.
Preferably: described defoamer is the organic silicon defoamer of 1:0.5:1-2 by weight ratio: tributyl phosphate: dioxy SiClx forms.The combination of organic silicon defoamer, tributyl phosphate and silicon dioxide uses as defoamer has good stability, disappears Bubble speed is fast, and consumption is few, nontoxic, have the preferable compatibility.
Preferably: described coalescents is by the alcohol ester 12 that weight ratio is 1:2-3:1-2: diethanol: propylene glycol forms. The coalescents of the present invention has the good compatibility, even if health also will not be caused damage by Long Term Contact, and peace easy to use Entirely.The all-environmentally-friendly film forming auxiliary agent of the present invention is water insoluble, and boiling point is high, and usage amount is few, belongs to VOC free product.
The Flexible waterproof paint of highly-breathable of the present invention obtains preparation method, comprises the following steps: first by hydroxy ethyl fiber Element, EVA resin, acrylic fiber, kieselguhr and dispersant, 600-800r/min, stirs 20-30min;It is subsequently adding and grows sturdily Mould polysaccharide solution, wetting agent, thickening agent, defoamer and coalescents, 800-1000r/min, stirs 10-15min, is eventually adding Acrylic emulsion and silica flour, 800-1000r/min, stirs 25-30min, obtains the Flexible waterproof paint of highly-breathable.
In the Flexible waterproof paint of a kind of highly-breathable of the present invention, by add pullulan solution and EVA resin, breaks through tradition and is concerned only with the restriction of its water resistance only with acrylic emulsion as Flexible waterproof paint, pass through Pullulan solution matches with EVA resin, acrylic emulsion and reaches air tight purpose, realizes again EVA resin and propylene yogurt The crosslinking mixing of liquid, improves the pliability of water-repellent paint, adhesion;And interacting with each other of other auxiliary agents, mutually promote, Effectively maintain the intrinsic water resistance of water-repellent paint and weatherability, having the beneficial effect that of generation:
The first, breathability is good, and by using coating of the present invention, Air permenbility is 35ml/m224 hours 0.1MPa Above, it is prevented effectively from gas to be sealed in after substrate surface due to the crack initiation phenomenon under high temperature and cold cycle;
The second, pliability is good, and through test, the hot strength of coating of the present invention is up to 2.2MPa, elongation at break Reach more than 115%, there is preferable pliability;
3rd, adhesion is high, and through test, coating of the present invention is bonded in its adhesive strength of wet base and reaches More than 1.2MPa, has higher adhesion;
4th, water resistance is excellent, uses coating of the present invention, can meet 0.3MPa60 minute waterproof and 0.5MPa The test request of permeability resistance;
5th, weatherability is strong, can meet flawless use requirement under-25 DEG C of-60 DEG C of test conditions, meet high/low temperature Use need;
6th, with low cost, coating raw material wide material sources of the present invention, preparation method is simple, effectively reduces product Manufacturing cost;
6th, service life is long, and coating of the present invention is easily constructed, and coating application 5-10 does not has obscission, and And there is not segregation phenomenon, good stability at storing process in coating.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described enforcement Example is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, this area is common The every other embodiment that technical staff is obtained under not making creative work premise, broadly falls into the model of present invention protection Enclose.
Embodiment 1
A kind of Flexible waterproof paint of highly-breathable, in parts by weight, including: pullulan solution 5 parts, silica flour 12 parts, rare earth adhesive 3 parts, hydroxyethyl cellulose 2 parts, EVA resin 50 parts, acrylic fiber 4 parts, 7 parts of kieselguhr, dispersant 8 parts, wetting agent 12 parts, thickening agent 6 parts, defoamer 1 part, coalescents 12 parts and acrylic emulsion 33 parts.
Dispersant is the mixture of polyacrylate, poly-methyl acrylate, and wetting agent is OT-75 or TECH-278, increases Thick dose is polyacrylamide thickeners, and defoamer is the organic silicon defoamer of 1:0.5:1 by weight ratio: tributyl phosphate: dioxy SiClx forms, and coalescents is by the alcohol ester 12 that weight ratio is 1:2:1: diethanol: propylene glycol.
The preparation method of the Flexible waterproof paint of highly-breathable of the present invention, comprises the following steps: first by hydroxy ethyl fiber Element, EVA resin, acrylic fiber, kieselguhr and dispersant, 600-800r/min, stirs 20-30min;It is subsequently adding and grows sturdily Mould polysaccharide solution, wetting agent, thickening agent, defoamer and coalescents, 800-1000r/min, stirs 10-15min, is eventually adding Acrylic emulsion and silica flour, 800-1000r/min, stirs 25-30min, obtains the Flexible waterproof paint of highly-breathable.
Embodiment 2
A kind of Flexible waterproof paint of highly-breathable, in parts by weight, including: pullulan solution 6 parts, silica flour 13 parts, rare earth adhesive 4 parts, hydroxyethyl cellulose 3 parts, EVA resin 55 parts, acrylic fiber 6 parts, 6 parts of kieselguhr, dispersant 6 parts, wetting agent 14 parts, thickening agent 8 parts, defoamer 2 parts, coalescents 13 parts and acrylic emulsion 35 parts.
Dispersant is the mixture of polyacrylate, poly-methyl acrylate, and wetting agent is OT-75 or TECH-278, increases Thick dose is polyacrylamide thickeners, and defoamer is the organic silicon defoamer of 1:0.5:2 by weight ratio: tributyl phosphate: dioxy SiClx forms, and coalescents is by the alcohol ester 12 that weight ratio is 1:3:2: diethanol: propylene glycol.
The preparation method of the Flexible waterproof paint of highly-breathable of the present invention, comprises the following steps: first by hydroxy ethyl fiber Element, EVA resin, acrylic fiber, kieselguhr and dispersant, 600-800r/min, stirs 20-30min;It is subsequently adding and grows sturdily Mould polysaccharide solution, wetting agent, thickening agent, defoamer and coalescents, 800-1000r/min, stirs 10-15min, is eventually adding Acrylic emulsion and silica flour, 800-1000r/min, stirs 25-30min, obtains the Flexible waterproof paint of highly-breathable.
The preparation method of the Flexible waterproof paint of highly-breathable in the same manner as in Example 1, is not describing.
Embodiment 3
A kind of Flexible waterproof paint of highly-breathable, in parts by weight, including: pullulan solution 8 parts, silica flour 10 parts, rare earth adhesive 5 parts, hydroxyethyl cellulose 4 parts, EVA resin 60 parts, acrylic fiber 7 parts, 8 parts of kieselguhr, dispersant 5 parts, wetting agent 10 parts, thickening agent 5 parts, defoamer 3 parts, coalescents 14 parts and acrylic emulsion 30 parts.
Dispersant is the mixture of polyacrylate, poly-methyl acrylate, and wetting agent is OT-75 or TECH-278, increases Thick dose is polyacrylamide thickeners, and defoamer is the organic silicon defoamer of 1:0.5:1.5 by weight ratio: tributyl phosphate: two Silicon oxide forms, and coalescents is by the alcohol ester 12 that weight ratio is 1:2.5:1.5: diethanol: propylene glycol.
The preparation method of the Flexible waterproof paint of highly-breathable of the present invention, comprises the following steps: first by hydroxy ethyl fiber Element, EVA resin, acrylic fiber, kieselguhr and dispersant, 600-800r/min, stirs 20-30min;It is subsequently adding and grows sturdily Mould polysaccharide solution, wetting agent, thickening agent, defoamer and coalescents, 800-1000r/min, stirs 10-15min, is eventually adding Acrylic emulsion and silica flour, 800-1000r/min, stirs 25-30min, obtains the Flexible waterproof paint of highly-breathable.
The preparation method of the Flexible waterproof paint of highly-breathable in the same manner as in Example 1, is not describing.
Embodiment 4
A kind of Flexible waterproof paint of highly-breathable, in parts by weight, including: pullulan solution 10 parts, quartz 11 parts of powder, rare earth adhesive 4 parts, hydroxyethyl cellulose 4 parts, EVA resin 50 parts, acrylic fiber 5 parts, 5 parts of kieselguhr, dispersion Agent 10 parts, wetting agent 15 parts, thickening agent 7 parts, defoamer 2 parts, coalescents 10 parts and acrylic emulsion 38 parts.
Dispersant is the mixture of polyacrylate, poly-methyl acrylate, and wetting agent is OT-75 or TECH-278, increases Thick dose is polyacrylamide thickeners, and defoamer is the organic silicon defoamer of 1:0.5:42 by weight ratio: tributyl phosphate: dioxy SiClx forms, and coalescents is by the alcohol ester 12 that weight ratio is 1:3:1: diethanol: propylene glycol.
The preparation method of the Flexible waterproof paint of highly-breathable of the present invention, comprises the following steps: first by hydroxy ethyl fiber Element, EVA resin, acrylic fiber, kieselguhr and dispersant, 600-800r/min, stirs 20-30min;It is subsequently adding and grows sturdily Mould polysaccharide solution, wetting agent, thickening agent, defoamer and coalescents, 800-1000r/min, stirs 10-15min, is eventually adding Acrylic emulsion and silica flour, 800-1000r/min, stirs 25-30min, obtains the Flexible waterproof paint of highly-breathable.
The preparation method of the Flexible waterproof paint of highly-breathable in the same manner as in Example 1, is not describing.
Embodiment 5
A kind of Flexible waterproof paint of highly-breathable, in parts by weight, including: pullulan solution 7 parts, silica flour 15 parts, rare earth adhesive 5 parts, hydroxyethyl cellulose 2.5 parts, EVA resin 58 parts, acrylic fiber 5 parts, 6 parts of kieselguhr, dispersion Agent 6 parts, wetting agent 13 parts, thickening agent 6 parts, defoamer 2.5 parts, coalescents 15 parts and acrylic emulsion 40 parts.
Dispersant is the mixture of polyacrylate, poly-methyl acrylate, and wetting agent is OT-75 or TECH-278, increases Thick dose is polyacrylamide thickeners, and defoamer is the organic silicon defoamer of 1:0.5:1-2 by weight ratio: tributyl phosphate: two Silicon oxide forms, and coalescents is by the alcohol ester 12 that weight ratio is 1:2:2: diethanol: propylene glycol.
The preparation method of the Flexible waterproof paint of highly-breathable of the present invention, comprises the following steps: first by hydroxy ethyl fiber Element, EVA resin, acrylic fiber, kieselguhr and dispersant, 600-800r/min, stirs 20-30min;It is subsequently adding and grows sturdily Mould polysaccharide solution, wetting agent, thickening agent, defoamer and coalescents, 800-1000r/min, stirs 10-15min, is eventually adding Acrylic emulsion and silica flour, 800-1000r/min, stirs 25-30min, obtains the Flexible waterproof paint of highly-breathable.
The preparation method of the Flexible waterproof paint of highly-breathable in the same manner as in Example 1, is not describing.
Comparative example 1
Comparative example 1 is with the difference of embodiment 1: comparative example 1 does not include pullulan solution.
Comparative example 2
Comparative example 2 is with the difference of embodiment 1: comparative example 2 does not include EVA resin.
Comparative example 3
Comparative example 1 is with the difference of embodiment 1: comparative example 3 does not include pullulan solution and EVA resin.
In order to assess the experiment effect of the present invention, comparative example 1-5 and comparative example 1-3 are carried out performance contrast test, specifically Result is as shown in table 1: table 1 performance comparison testing result
From table 1 result it will be seen that the present invention prepare the water-repellent paint of gained have good, breathability, pliability and Water proofing property, has a extensive future.
The above, only presently preferred embodiments of the present invention, not the present invention is made any pro forma restriction;All The those of ordinary skill of the industry all can shown in by specification and the above and implement the present invention swimmingly;But, all familiar Professional and technical personnel, in the range of without departing from technical solution of the present invention, may utilize disclosed above technology contents and makes A little change, the equivalent variations modifying and develop, be the Equivalent embodiments of the present invention;Meanwhile, all realities according to the present invention The change of any equivalent variations that above example is made by matter technology, modify and differentiation etc., all still fall within the technology of the present invention Within the protection domain of scheme.

Claims (8)

1. the Flexible waterproof paint of a highly-breathable, it is characterised in that: in parts by weight, including: pullulan solution 5-10 part, silica flour 10-15 part, rare earth adhesive 3-5 part, hydroxyethyl cellulose 2-4 part, EVA resin 50-60 part, acrylic acid Fiber 4-7 part, kieselguhr 5-8 part, dispersant 5~10 parts, wetting agent 10~15 parts, thickening agent 5~8 parts, defoamer 1~3 parts, Coalescents 10~15 parts and acrylic emulsion 30-40 part.
The Flexible waterproof paint of a kind of highly-breathable the most according to claim 1, it is characterised in that: according to weight portion Meter, including: pullulan solution 5-6 part, silica flour 10-13 part, rare earth adhesive 3-5 part, hydroxyethyl cellulose 2-4 part, EVA Resin 50-55 part, acrylic fiber 6-7 part, kieselguhr 5-8 part, dispersant 5~10 parts, wetting agent 10~15 parts, thickening agent 5 ~8 parts, defoamer 1~3 parts, coalescents 10~15 parts and acrylic emulsion 35-40 part.
The Flexible waterproof paint of a kind of highly-breathable the most according to claim 2, it is characterised in that: described dispersant For polyacrylate, the mixture of poly-methyl acrylate.
4. according to the Flexible waterproof paint of a kind of highly-breathable described in Claims 2 or 3, it is characterised in that: described profit Humectant is OT-75 or TECH-278.
The Flexible waterproof paint of a kind of highly-breathable the most according to claim 4, it is characterised in that: described thickening agent For polyacrylamide thickeners.
The Flexible waterproof paint of a kind of highly-breathable the most according to claim 5, it is characterised in that: described defoamer It it is the organic silicon defoamer of 1:0.5:1-2 by weight ratio: tributyl phosphate: silicon dioxide forms.
The Flexible waterproof paint of a kind of highly-breathable the most according to claim 6, it is characterised in that: described film forming helps Agent is by the alcohol ester 12 that weight ratio is 1:2-3:1-2: diethanol: propylene glycol forms.
8. the Flexible waterproof paint of a highly-breathable as claimed in claim 1 obtains preparation method, it is characterised in that: include Following steps: first by hydroxyethyl cellulose, EVA resin, acrylic fiber, kieselguhr and dispersant, 600-800r/min, Stirring 20-30min;It is subsequently adding pullulan solution, wetting agent, thickening agent, defoamer and coalescents, 800-1000r/ Min, stirs 10-15min, is eventually adding acrylic emulsion and silica flour, 800-1000r/min, stirs 25-30min, obtain high The Flexible waterproof paint of breathability.
CN201610738966.4A 2016-08-26 2016-08-26 A kind of Flexible waterproof paint of highly-breathable and preparation method thereof Pending CN106243846A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337967A (en) * 2017-07-12 2017-11-10 合肥梵腾环保科技有限公司 A kind of environment-friendlyweather-proof weather-proof water-repellent paint and preparation method thereof
CN107699126A (en) * 2017-09-30 2018-02-16 合肥禾盛新型材料有限公司 A kind of anti-aging Coil Coating Products

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104059454A (en) * 2014-06-23 2014-09-24 蓝星(成都)新材料有限公司 Waterproof paint and preparation method thereof
CN104355565A (en) * 2014-09-30 2015-02-18 青岛桐晟桐橡塑科技有限公司 Formula for natural waterproof coating
CN104479467A (en) * 2014-12-25 2015-04-01 上海奇想青晨新材料科技股份有限公司 Water-based non-breathable water-resistant paint and preparation method thereof
CN105295574A (en) * 2015-11-19 2016-02-03 广州聚注专利研发有限公司 Reflective heat-insulating paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104059454A (en) * 2014-06-23 2014-09-24 蓝星(成都)新材料有限公司 Waterproof paint and preparation method thereof
CN104355565A (en) * 2014-09-30 2015-02-18 青岛桐晟桐橡塑科技有限公司 Formula for natural waterproof coating
CN104479467A (en) * 2014-12-25 2015-04-01 上海奇想青晨新材料科技股份有限公司 Water-based non-breathable water-resistant paint and preparation method thereof
CN105295574A (en) * 2015-11-19 2016-02-03 广州聚注专利研发有限公司 Reflective heat-insulating paint and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107337967A (en) * 2017-07-12 2017-11-10 合肥梵腾环保科技有限公司 A kind of environment-friendlyweather-proof weather-proof water-repellent paint and preparation method thereof
CN107699126A (en) * 2017-09-30 2018-02-16 合肥禾盛新型材料有限公司 A kind of anti-aging Coil Coating Products

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