CN104230240A - Flexible cement-base waterproof coating and preparation and application methods thereof - Google Patents

Flexible cement-base waterproof coating and preparation and application methods thereof Download PDF

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Publication number
CN104230240A
CN104230240A CN201410460615.2A CN201410460615A CN104230240A CN 104230240 A CN104230240 A CN 104230240A CN 201410460615 A CN201410460615 A CN 201410460615A CN 104230240 A CN104230240 A CN 104230240A
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Prior art keywords
waterproof coating
cement
base waterproof
powder
flexible cement
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CN201410460615.2A
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CN104230240B (en
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黄凯
王会元
熊卫锋
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Oriental Yuhong civil building materials limited liability company
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YUEYANG ORIENTAL YUHONG WATERPROOF TECHNOLOGY Co Ltd
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Abstract

The invention discloses a flexible cement-base waterproof coating, comprising a liquid material and powder, wherein the liquid material is composed of a styrene-acrylic emulsion and matched assistants, and the powder is composed of cement, silica sand, quartz powder, kaolin and matched assistants. The flexible cement-base waterproof coating disclosed by the invention has good water tolerance, weather fastness and durability due to mixed use of the liquid material and the powder, and has excellent binding power to outer cement mortar and various binding materials. The waterproof coating disclosed by the invention has good flexibility and strong tracing ability for microcracks of the coating.

Description

Flexible cement-base waterproof coating and preparation and application thereof
Technical field
The present invention relates to one and there is good flexible cement-base waterproof coating, belong to building material field.
Background technology
The waterproof paint major part that existing market uses is polyurethane-type mono-component waterproofing paint, although it has good water resistance, operational procedure is loaded down with trivial details, needs repeatedly to brush; And after finishing waterproof layer, also to do protective layer, water-proof function cannot be realized fast; Simultaneously the film formation time of coating is long, and coating and concrete base layer cohesive strength on the low side.
Summary of the invention
For the needs of prior art, the invention discloses a kind of cement-base waterproof coating, have construction technology simple, waterproof layer and protective layer unite two into one, and save the advantage of engineering time, and have good snappiness, cohesive strength is large.
For achieving the above object, the present invention is achieved through the following technical solutions:
A kind of flexible cement-base waterproof coating, be made up of liquid material and powder, wherein liquid material comprises benzene emulsion 600-1000 part, dispersion agent 1-3 part, defoamer 3-7 part, water 50-100 part composition, and powder comprises cement 300-600 part, 80-120 order quartz sand 300-500 part, 200-400 order silica powder 20-80 part, kaolin 40-80 part, water reducer 3-6 part.
According to the needs of application, usually can also add 0-2 part sanitas to improve its shelf time in liquid material, consider that liquid material component of the present invention at room temperature can long-term storage, sanitas generally need not add.
Meanwhile, Mierocrystalline cellulose 0-1 part, hardening accelerator 0-2 part, water-holding agent 0-2 part can also be added in powder as required, to improve its performance.
In the present invention, benzene emulsion specification used is: second-order transition temperature 8 ~ 12 DEG C.
In the present invention, dispersion agent used can be traditional sodium acrylate dipersant, polyurethane dispersant etc., preferably, in order to have good dispersion and mixed type energy, dispersion agent used is carboxylic acid sodium salt form dispersion agent PS-5000, and it consists of the mixture of poly carboxylic acid sodium and water (44: 56).
In the present invention, described defoamer is silicone antifoam agent, and its defoaming capacity is strong, and surface tension is low, and chemical stability is good, is conducive to the stability of liquid powder mixing.
In the present invention, cement used is ash concrete, is preferably 42.5 ash concretes, has good cohesive strength; Described kaolin is the high-activity nano kaolin of 200-325nm particle diameter, not only there is good electrical insulating property and resistant to chemical media, and improve the reactive behavior of powder, simultaneously due to its special microtexture, make liquid material component can enter into the microtexture of powder, increase the intersection compound between liquid material and powder, form inierpeneirating network structure, increased substantially product comprehensive mechanical property.
In the present invention, described water reducer is naphthalene system or poly carboxylic acid series water reducer.
In the present invention, described hardening accelerator is calcium formiate, is preferably commercially available high purity (being not less than 95%) calcium formiate; Described water-holding agent is high viscosity methylhydroxypropylcellulose ether HPMC, and its viscosity profile is 10000-20000, preferred viscosities 15000.
Accordingly, the invention also discloses the preparation method of flexible cement-base waterproof coating, comprise the following steps:
1. by benzene emulsion, dispersion agent, defoamer, water, stirs and obtains liquid material component;
2. cement, quartz sand, silica powder, kaolin, water reducer etc. are stirred and obtain powder component.
Above-mentioned preparation process is at room temperature carried out, and is uniformly mixed time controling at 0.5-1 hour.
On this basis, the invention also discloses the using method of flexible cement-base waterproof coating, by liquid material component and powder component used in combination, mixing match is 1: 2-3, in mass.
Preferably, the blending ratio of the two is 1: 2.5.
The experiment display that applicant carries out, cement group water-proofing material of the present invention has good tensile strength and cohesive strength, and has good snappiness.
Embodiment
In order to implementation of the present invention is described, in the following embodiments, applicant provides specific embodiments of the invention, be only signal.
Embodiment 1
Component A: get 600 parts of benzene emulsions, 1 part of dispersion agent and 3 parts of defoamers, add 50 parts of water, stirs 30 minutes, mix, for subsequent use.
B component: get 400 parts of cement, adds 300 parts of quartz sands, 40 parts of silica powders, 40 parts of kaolin, 4 parts of water reducers, 1 part of hardening accelerator, stirs 1 hour, mixes.
B component joins in component A by the ratio according to A: B=10: 25, stirs 5 minutes, stirs, measure its performance according to standard GB/T23445-2009.Testing its tension set is 60%; Tensile strength is 2.0MPa, its bonding strength reaches about 1.1MPa.
Embodiment 2
Component A: get 800 parts of benzene emulsions, 2 parts of dispersion agents and 4 parts of defoamers, add 80 parts of water, stirs 30 minutes, mix, for subsequent use.
B component: get 500 parts of cement, adds 400 parts of quartz sands, and 50 parts of silica powders, 60 parts of kaolin, 5 parts of water reducers, 1 part of hardening accelerator, 0.5 part of water-holding agent, stir 1 hour, mix.
B component joins in component A by the ratio according to A: B=10: 25, stirs 5 minutes, stirs, measure its performance according to standard GB/T23445-2009.Testing its tension set is 72%; Tensile strength is 2.1MPa, its bonding strength reaches about 1.2MPa.
Embodiment 3
Component A: get 1000 parts of benzene emulsions, 2 parts of dispersion agents and 6 parts of defoamers, add 100 parts of water, stirs 30 minutes, mix, for subsequent use.
B component: get 300 parts of cement, adds 400 parts of quartz sands, and 80 parts of silica powders, 60 parts of kaolin, 3 parts of water reducers, 0.5 part of hardening accelerator, 1 part of water-holding agent, stir 1 hour, mix.
B component joins in component A by the ratio according to A: B=10: 25, stirs 5 minutes, stirs, measure its performance according to standard GB/T23445-2009.Testing its tension set is 75%; Tensile strength is 1.9MPa, its bonding strength reaches about 1.0MPa.
Embodiment 4
Component A: get 600 parts of benzene emulsions, 3 parts of dispersion agents and 6 parts of defoamers, add 100 parts of water, stirs 30 minutes, mix, for subsequent use.
B component: get 400 parts of cement, adds 500 parts of quartz sands, and 40 parts of silica powders, 40 parts of kaolin, 3 parts of water reducers, 1 part of hardening accelerator, 1 part of water-holding agent, stir 1 hour, mix.
B component joins in component A by the ratio according to A: B=10: 25, stirs 5 minutes, stirs, measure its performance according to standard GB/T23445-2009.Testing its tension set is 55%; Tensile strength is 2.25MPa, its bonding strength reaches about 1.3MPa.

Claims (10)

1. a flexible cement-base waterproof coating, it is characterized in that being made up of liquid material and powder, wherein liquid material comprises benzene emulsion 600-1000 part, dispersion agent 1-3 part, defoamer 3-7 part, water 50-100 part composition, and powder comprises cement 300-600 part, 80-120 order quartz sand 300-500 part, 200-400 order silica powder 20-80 part, kaolin 40-80 part, water reducer 3-6 part.
2. flexible cement-base waterproof coating according to claim 1, is characterized in that in powder also containing Mierocrystalline cellulose 0-1 part, hardening accelerator 0-2 part, water-holding agent 0-2 part.
3. flexible cement-base waterproof coating according to claim 1, is characterized in that the second-order transition temperature of described benzene emulsion is 8 ~ 12 DEG C.
4. flexible cement-base waterproof coating according to claim 1, is characterized in that described dispersion agent is PS-5000.
5. flexible cement-base waterproof coating according to claim 1, is characterized in that described defoamer is silicone antifoam agent.
6. flexible cement-base waterproof coating according to claim 1, is characterized in that described cement is ash concrete, and described kaolin is the high-activity nano kaolin of 200-325nm particle diameter.
7. flexible cement-base waterproof coating according to claim 1, is characterized in that described water reducer is naphthalene system or poly carboxylic acid series water reducer.
8. flexible cement-base waterproof coating according to claim 1, is characterized in that described hardening accelerator is calcium formiate, and described water-holding agent is high viscosity methylhydroxypropylcellulose ether.
9. the preparation method of the flexible cement-base waterproof coating of claim 1, is characterized in that comprising the following steps:
1. by benzene emulsion, dispersion agent, defoamer, water, stirs and obtains liquid material component; 2. cement, quartz sand, silica powder, kaolin, water reducer etc. are stirred and obtain powder component.
10. the using method of the flexible cement-base waterproof coating of claim 1, it is characterized in that liquid material component and powder component used in combination, mixing match is 1: 2-3, in mass.
CN201410460615.2A 2014-09-11 2014-09-11 Flexible cement-base waterproof coating and preparation and application thereof Active CN104230240B (en)

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Cited By (18)

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Publication number Priority date Publication date Assignee Title
CN104860591A (en) * 2015-05-12 2015-08-26 惠州东方雨虹建筑材料有限责任公司 Thick-painted cement-based waterproof coating
CN105110737A (en) * 2015-09-06 2015-12-02 东莞市伟业水泥有限公司 Flexible waterproof slurry
CN105218019A (en) * 2015-09-16 2016-01-06 北京东方雨虹防水技术股份有限公司 A kind of environmental protection polymer cement waterproof paint
CN105236885A (en) * 2015-09-16 2016-01-13 岳阳东方雨虹防水技术有限责任公司 Easily-coating type flexible waterproof slurry and preparation method thereof
CN105753383A (en) * 2015-11-09 2016-07-13 派丽(上海)管理有限公司 Deodorizing waterproof size with self-repairing function
CN106145823A (en) * 2016-07-05 2016-11-23 唐山东方雨虹防水技术有限责任公司 A kind of self-healing polymer-modified cement-based waterproofing slurry of environmental protection osmosis type
CN106433361A (en) * 2016-09-13 2017-02-22 东华大学 Cement-based waterproof coating applied to large open fine ore heap and preparation method of cement-based waterproof coating
CN106634250A (en) * 2015-10-30 2017-05-10 丹阳市海信涂料化工厂 Elastic waterproof coating
CN107129225A (en) * 2017-04-14 2017-09-05 河南工业大学 A kind of special cement base energy-saving exterior wall coating of external wall and preparation method
CN107418312A (en) * 2017-05-27 2017-12-01 青岛东方雨虹建筑材料有限公司 A kind of hydrophobic type polymer cement waterproof paint and preparation method thereof
CN107555890A (en) * 2017-08-15 2018-01-09 东方雨虹民用建材有限责任公司 Silica suspension, polymer cement waterproof slurry and preparation method thereof
CN107555891A (en) * 2017-08-15 2018-01-09 东方雨虹民用建材有限责任公司 A kind of environment-friendly waterproof paint and preparation method thereof
CN109095829A (en) * 2018-10-30 2018-12-28 湖北汇林建材有限公司 A kind of flute profile waterproof material of anti-ceramic tile hollowing and its use tool
CN111171637A (en) * 2020-03-20 2020-05-19 广州维施克建材有限公司 Waterproof coating formula and preparation method thereof
CN111574864A (en) * 2020-04-30 2020-08-25 深圳市卓宝科技股份有限公司 Asphalt-based coating for pre-paved waterproof system
CN112552773A (en) * 2021-01-15 2021-03-26 赵朵 Preparation method of high-flexibility polymer cement-based waterproof coating
CN114046004A (en) * 2021-12-03 2022-02-15 瑞宇建设有限公司 Construction process of building coating for building construction
CN115477879A (en) * 2022-10-11 2022-12-16 河北化工医药职业技术学院 Anti-permeable polymer cement-based waterproof coating and preparation method thereof

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Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104860591A (en) * 2015-05-12 2015-08-26 惠州东方雨虹建筑材料有限责任公司 Thick-painted cement-based waterproof coating
CN105110737A (en) * 2015-09-06 2015-12-02 东莞市伟业水泥有限公司 Flexible waterproof slurry
CN105218019A (en) * 2015-09-16 2016-01-06 北京东方雨虹防水技术股份有限公司 A kind of environmental protection polymer cement waterproof paint
CN105236885A (en) * 2015-09-16 2016-01-13 岳阳东方雨虹防水技术有限责任公司 Easily-coating type flexible waterproof slurry and preparation method thereof
CN106634250A (en) * 2015-10-30 2017-05-10 丹阳市海信涂料化工厂 Elastic waterproof coating
CN105753383A (en) * 2015-11-09 2016-07-13 派丽(上海)管理有限公司 Deodorizing waterproof size with self-repairing function
CN106145823B (en) * 2016-07-05 2018-07-27 唐山东方雨虹防水技术有限责任公司 A kind of polymer-modified cement-based waterproofing slurry of self-healing environmental protection osmosis type
CN106145823A (en) * 2016-07-05 2016-11-23 唐山东方雨虹防水技术有限责任公司 A kind of self-healing polymer-modified cement-based waterproofing slurry of environmental protection osmosis type
CN106433361A (en) * 2016-09-13 2017-02-22 东华大学 Cement-based waterproof coating applied to large open fine ore heap and preparation method of cement-based waterproof coating
CN107129225A (en) * 2017-04-14 2017-09-05 河南工业大学 A kind of special cement base energy-saving exterior wall coating of external wall and preparation method
CN107129225B (en) * 2017-04-14 2019-07-02 河南工业大学 A kind of dedicated cement base energy-saving exterior wall coating of external wall and preparation method
CN107418312A (en) * 2017-05-27 2017-12-01 青岛东方雨虹建筑材料有限公司 A kind of hydrophobic type polymer cement waterproof paint and preparation method thereof
CN107418312B (en) * 2017-05-27 2019-08-27 青岛东方雨虹建筑材料有限公司 A kind of hydrophobic type polymer cement waterproof paint and preparation method thereof
CN107555891B (en) * 2017-08-15 2020-06-02 东方雨虹民用建材有限责任公司 Environment-friendly waterproof coating and preparation method thereof
CN107555890A (en) * 2017-08-15 2018-01-09 东方雨虹民用建材有限责任公司 Silica suspension, polymer cement waterproof slurry and preparation method thereof
CN107555891A (en) * 2017-08-15 2018-01-09 东方雨虹民用建材有限责任公司 A kind of environment-friendly waterproof paint and preparation method thereof
CN107555890B (en) * 2017-08-15 2020-06-02 东方雨虹民用建材有限责任公司 Silica suspension, polymer cement waterproof slurry and preparation method thereof
CN109095829A (en) * 2018-10-30 2018-12-28 湖北汇林建材有限公司 A kind of flute profile waterproof material of anti-ceramic tile hollowing and its use tool
CN111171637A (en) * 2020-03-20 2020-05-19 广州维施克建材有限公司 Waterproof coating formula and preparation method thereof
CN111574864A (en) * 2020-04-30 2020-08-25 深圳市卓宝科技股份有限公司 Asphalt-based coating for pre-paved waterproof system
CN111574864B (en) * 2020-04-30 2022-03-11 深圳市卓宝科技股份有限公司 Asphalt-based coating for pre-paved waterproof system
CN112552773A (en) * 2021-01-15 2021-03-26 赵朵 Preparation method of high-flexibility polymer cement-based waterproof coating
CN114046004A (en) * 2021-12-03 2022-02-15 瑞宇建设有限公司 Construction process of building coating for building construction
CN114046004B (en) * 2021-12-03 2023-02-03 瑞宇建设有限公司 Construction process of building coating for building construction
CN115477879A (en) * 2022-10-11 2022-12-16 河北化工医药职业技术学院 Anti-permeable polymer cement-based waterproof coating and preparation method thereof

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Effective date of registration: 20170602

Address after: 100176, Beijing economic and Technological Development Zone, Beijing Garden North Street, No. 27, 2, 4

Patentee after: Oriental Yuhong civil building materials limited liability company

Address before: 414000 Industrial Park, Yunxi District, Hunan, Yueyang

Patentee before: Yueyang Oriental Yuhong Waterproof Technology Co., Ltd.