CN106243775A - Warm type disperse dye composition in one - Google Patents

Warm type disperse dye composition in one Download PDF

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Publication number
CN106243775A
CN106243775A CN201610581367.6A CN201610581367A CN106243775A CN 106243775 A CN106243775 A CN 106243775A CN 201610581367 A CN201610581367 A CN 201610581367A CN 106243775 A CN106243775 A CN 106243775A
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China
Prior art keywords
dyestuff
dye
content
formula
gross weight
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Application number
CN201610581367.6A
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Chinese (zh)
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CN106243775B (en
Inventor
邱健
牟忠岳
胡效奎
徐叙明
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Leping Safely Pharmaceutical Co ltd
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ZHEJIANG SHANYU DYESTUFF CHEMICAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09BORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B67/00Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
    • C09B67/0033Blends of pigments; Mixtured crystals; Solid solutions
    • C09B67/0046Mixtures of two or more azo dyes
    • C09B67/0051Mixtures of two or more azo dyes mixture of two or more monoazo dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/16General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
    • D06P1/18Azo dyes

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  • Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Abstract

The present invention relates to warm type disperse dye composition in one, mixed by dyestuff and auxiliary agent two parts and form, described dye moiety is at least formed by two or more dye component is compounding, it is widely used in hydrophobic fiber material such as polyester and the dyeing of ultra-fine polyester, and color fastness particularly suitable requires higher to wash the/dyeing of ammonia stockinette.

Description

Warm type disperse dye composition in one
Technical field
The invention belongs to dye composite field, be specifically related to one and be applicable to textile fiber material particularly hydrophobicity fibre The disperse dye composition of dimension material printing and dyeing.
Background technology
In recent years, owing to the fabric containing spandex has the rebound performance of excellence, soft, wear comfortable, thus obtain / ammonia stockinette is washed in increasing application, such as make compound with terylene.At present ,/main the employing of ammonia stockinette dyeing is washed Disperse dyes, due to the construction features of spandex, disperse dyes easily on contaminate spandex, the most easily desorbing, so reducing this Every color fastness of series products.Further, since the existence of spandex, in order to avoid spandex performance is injury-free, the high temperature dye of terylene Color is restricted, and low temperature dyeing often makes disperse dyes can not the most thoroughly contaminate terylene, the dye-uptake of terylene component and lifting Rate can not sufficiently be embodied, particularly upper dye dark blue to black etc. dark time, serious to spandex contamination, color fastness is the most not Ideal, is extremely difficult to the 3-4 level of market demands, so that color fastness being required, high product exists bigger in Colour Difference Problem.
Summary of the invention
For solving the above-mentioned problems in the prior art, the present invention provides the dispersion that a kind of color fastness is good, enhancing is good Blue dye composition, it is widely used in hydrophobic fiber material such as polyester and the dyeing of ultra-fine polyester, particularly suitable jail of checking colors Degree requires higher to wash/dyeing of ammonia stockinette.
In order to achieve the above object, the technical solution used in the present invention is: warm type disperse dye composition in one, by Dyestuff and auxiliary agent two parts mixing composition, described dye moiety is at least by the dyestuff mixing group of following two or two or more structure Become:
One is the dyestuff meeting chemical constitution formula I, and content is the 5%~95% of dye moiety gross weight,
R in above formula1For nitro, cyano group, halogen, R2And R3For C1-4 alkyl, R4For C1-4 alkyl, hydroxyl;
It two is C.I disperse blue 165 dyestuff, the i.e. dyestuff of chemical constitution formula II, and content is dye moiety gross weight 5%~95%,
In a preferred embodiment of the present invention, R in chemical structure of general formula (I)1For NO2, R2、R3For-CH2CH3, R4For CH3, it being C.I. disperse blue 360, chemical structural formula (I-1) is as follows:
In a preferred embodiment of the present invention, R in chemical structure of general formula (I)1For NO2, R2、R3For-CH2CH3, R4For OH, is C.I. disperse blue 360:1, and chemical structural formula (I-2) is as follows:
In a preferred embodiment of the present invention, the content of the dyestuff of chemical constitution formula I is dye moiety gross weight 70%~90%, the content of the dyestuff of chemical constitution formula II is the 10%~32% of dye moiety gross weight.
It is furthermore preferred that the content of the dyestuff of chemical constitution formula I is dye moiety gross weight 71%~86%, chemistry knot The content of the dyestuff of structure formula II is the 14%~29% of dye moiety gross weight.
In a preferred embodiment of the present invention, described auxiliary agent comprises diffusant and dispersant, diffusant selected from MF and/ Or NNO, dispersant be selected from sodium lignin sulfonate class, the consumption of diffusant and dispersant be deduction dye moiety gross weight after remaining Amount.
In a preferred embodiment of the present invention, the content of auxiliary agent is less than disperse dye composition gross weight 30%.
The present invention also protects the preparation method of above-mentioned disperse dye composition, after blending that each component and auxiliary agent are added water, Use grinder grinding distribution, be spray-dried, get product.
In such scheme, described " dye moiety " refers to the material of pure dye in the dye mixture of the present invention, does not includes Aid Portions.It is known that during the former dyestuff of synthetic disperse dyes is processed into commodity disperse dyes, need to add Enter substantial amounts of auxiliary agent, such as dispersant sodium lignin sulfonate B (Anyang product) or sodium lignin sulfonate 85A (import), dispersing agent MF Or NNO and a small amount of dust-proofing agent (JH2112).Obviously, part by weight between each dyestuff of the dye mixture of the invention described above On the basis of, the product that interpolation auxiliary agent dilution obtains remains within the protection of this patent.Even if auxiliary agent kind used is at this Do not mention in patent specification, as long as its dye moiety proportioning is within the scope of the present invention, remain the protection at this patent Within the scope of.
In such scheme, the percentage composition of described " dye moiety " refers to remove auxiliary agent and the percentage of outer pure dye dry product Content.And general industry formula is to use former dyestuff dry product content, owing to former dyestuff dry product containing a small amount of impurity, the most former dye The numeral of material dry product content is that approximation replaces pure dye dry product content.The former dyestuff wet cake being synthesized can be converted to former dye Material dry product measures.Some commercial formulations also (such as dye with the sample of certain trade mark commodity disperse dyes containing a large amount of auxiliary agents The sample of intensity 100% or 200%) weight calculate content, this content can be scaled pure dye dry product content.
In this article, the C.I. labelling of dyestuff title head is English Color Index abbreviation, i.e. Colour Index is middle Part represents color type, and afterbody is dyestuff numbering.This name form is the most general.This Colour Index is dyeed by Britain Family association (Society of Dyers and Colorists;And AATCC SDC) (American Association of Textile Chemists and Colorists;AATCC) compile in collaboration with.As for those heads Portion does not has the dyestuff title of C.I. labelling to be not yet to be announced the dye species title of structure by Colour Index.
Need special instruction: in following example formula, the content of each component refers to disperse dye composition gross weight On the basis of weight percentage, wherein, disperse dye composition gross weight is all each dyestuff weight and all each auxiliary agents Weight sum.And be above with dye moiety gross weight outer except auxiliary agent at the percentage composition described in the technical scheme of summary of the invention Weight percentage on the basis of amount.There is conversion relation between the two.
Compared with prior art, the beneficial effects are mainly as follows: use the dispersed blue dye of inventive formulation During upper dye hydrophobic fiber material, dyeing residual liquid is clear, loose colour is few;By adjusting the ratio between different component, enhancing can be obtained Good, washing fastness, crock fastness and the good blue dyeing and weaving thing of sublimation reliability, be highly suitable for medium-to-high grade fabric such as super fine denier and knit Thing, polyester cotton, wash/the printing and dyeing of the blend fabric such as ammonia.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with specific embodiment, to this Invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, and not structure Become limitation of the present invention.
Embodiment 1: middle warm type disperse dye composition A
1, formula
2, preparation
By the wet cake of above-mentioned dyestuff and auxiliary agent according to the above ratio, sand milling together, it is spray-dried the most again, prepares dyestuff Finished product.
Embodiment 2: middle warm type disperse dye composition B
1, formula
2, preparation
By the wet cake of above-mentioned dyestuff and auxiliary agent according to the above ratio, sand milling together, it is spray-dried the most again, prepares dyestuff Finished product.
Embodiment 3: middle warm type disperse dye composition C
1, formula
2, preparation
By the wet cake of above-mentioned dyestuff and auxiliary agent according to the above ratio, sand milling together, it is spray-dried the most again, prepares dyestuff Finished product.
Embodiment 4: middle warm type disperse dye composition D
1, formula
2, preparation
By the wet cake of above-mentioned dyestuff and auxiliary agent according to the above ratio, sand milling together, it is spray-dried the most again, prepares dyestuff Finished product.
Weighing disperse dye composition A and B that embodiment 1~2 prepares respectively, quality consumption is the 4% of fabric quality, Bath raio is 50: 1, and selection of fabric, for washing/ammonia stretch fabric, is adjusted dye bath pH to be 4~5 with acetic acid, was warmed up to by 70 DEG C in 50 minutes 125 DEG C, it is incubated 40 minutes, is cooled to reduction cleaning when 90 DEG C.
Observing sample cloth coloured light, use GB/T3921, GB/T3920, GB/T5718 to test respectively, result shows its washable jail Degree (60 DEG C) >=6 grades, fastness to rubbing >=6 grade, fastness to sublimation >=5 grade.The disperse dye composition of the visible present invention Color fastness exceeds well over washs/polyurethane fabric 3~the high standard requirement of 4 grades on market, the results are shown in Table 1.
Table 1
Above detailed description of the invention describes ultimate principle and the principal character of the present invention.The technical staff of the industry should Understand, protection scope of the present invention is not restricted to the described embodiments, any change expected without creative work or Replace, all should contain within protection scope of the present invention.Therefore, protection scope of the present invention should be with claims institute The protection domain limited is as the criterion.

Claims (7)

1. a warm type disperse dye composition in, is mixed by dyestuff and auxiliary agent two parts and forms, it is characterised in that described dye Material part is at least mixed by the dyestuff of following two or two or more structure and forms:
One is the dyestuff meeting chemical constitution formula I, and content is the 5%~95% of dye moiety gross weight,
R in above formula1For nitro, cyano group, halogen, R2And R3For C1-4 alkyl, R4For C1-4 alkyl, hydroxyl;
It two is C.I disperse blue 165 dyestuff, the i.e. dyestuff of chemical constitution formula II, content be dye moiety gross weight 5%~ 95%,
Compositions the most according to claim 1, it is characterised in that in chemical structure of general formula (I), R1 is NO2, R2、R3For- CH2CH3, R4For CH3, it being C.I. disperse blue 360, chemical structural formula (I-1) is as follows:
Compositions the most according to claim 1, it is characterised in that R in chemical structure of general formula (I)1For NO2, R2、R3For- CH2CH3, R4For OH, being C.I. disperse blue 360:1, chemical structural formula (I-2) is as follows:
Compositions the most according to claim 1, it is characterised in that the content of the dyestuff of chemical constitution formula I is dye portion Dividing the 70%~90% of gross weight, the content of the dyestuff of chemical constitution formula II is the 10%~32% of dye moiety gross weight; It is furthermore preferred that the content of the dyestuff of chemical constitution formula I is dye moiety gross weight 71%~86%, chemical constitution formula II Dyestuff content is dye moiety gross weight 14%~29%.
Compositions the most according to claim 1, it is characterised in that described auxiliary agent comprises diffusant and dispersant, diffusant Selected from MF and/or NNO, dispersant is selected from sodium lignin sulfonate class, and the consumption of diffusant and dispersant is total for deduction dye moiety Surplus after weight.
Compositions the most according to claim 5, it is characterised in that the content of auxiliary agent is less than disperse dye composition The 30% of gross weight.
7. according to the preparation method of the compositions one of claim 1-6 Suo Shu, it is characterised in that each component is added water with auxiliary agent After blending, use grinder grinding distribution, be spray-dried, get product.
CN201610581367.6A 2016-07-20 2016-07-20 A kind of middle warm type disperse dye composition Active CN106243775B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106977979A (en) * 2017-03-24 2017-07-25 江苏迪安化工有限公司 A kind of high water-washing type disperse black dye composition
WO2022080430A1 (en) * 2020-10-14 2022-04-21 富士フイルム株式会社 Compound, tautomer of same or salt of said compound or tautomer, method for producing same, coloring composition, dyeing method and dyed article
CN116490574A (en) * 2020-10-14 2023-07-25 富士胶片株式会社 Compound, tautomer thereof or salt thereof, process for producing the same, coloring composition, method for dyeing, and dyed article

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6233688A (en) * 1985-08-07 1987-02-13 Mitsubishi Chem Ind Ltd Dyestuff for thermal transfer recording
US4874392A (en) * 1986-08-01 1989-10-17 Sandoz Ltd. Monoazo dyes having a substituted 1,4-phenylene coupling component radical having one C8-14 alkyl group or moiety
WO2006045375A1 (en) * 2004-09-23 2006-05-04 Unilever Plc Laundry treatment compositions
CN103571229A (en) * 2013-10-18 2014-02-12 浙江山峪染料化工有限公司 Intermediate temperate type high-fastness dispersed orange dye
CN104031412A (en) * 2014-06-26 2014-09-10 上海贝通色彩科技有限公司 Disperse dischargeable black dye mixture as well as preparation method and application thereof
CN104861690A (en) * 2014-02-21 2015-08-26 江苏道博化工有限公司 Method used for preparing disperse blue 360
CN105176140A (en) * 2015-08-15 2015-12-23 上海贝通色彩科技有限公司 Alkaline discharge printing disperse dye, preparation method and applications

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6233688A (en) * 1985-08-07 1987-02-13 Mitsubishi Chem Ind Ltd Dyestuff for thermal transfer recording
US4874392A (en) * 1986-08-01 1989-10-17 Sandoz Ltd. Monoazo dyes having a substituted 1,4-phenylene coupling component radical having one C8-14 alkyl group or moiety
WO2006045375A1 (en) * 2004-09-23 2006-05-04 Unilever Plc Laundry treatment compositions
CN103571229A (en) * 2013-10-18 2014-02-12 浙江山峪染料化工有限公司 Intermediate temperate type high-fastness dispersed orange dye
CN104861690A (en) * 2014-02-21 2015-08-26 江苏道博化工有限公司 Method used for preparing disperse blue 360
CN104031412A (en) * 2014-06-26 2014-09-10 上海贝通色彩科技有限公司 Disperse dischargeable black dye mixture as well as preparation method and application thereof
CN105176140A (en) * 2015-08-15 2015-12-23 上海贝通色彩科技有限公司 Alkaline discharge printing disperse dye, preparation method and applications

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106977979A (en) * 2017-03-24 2017-07-25 江苏迪安化工有限公司 A kind of high water-washing type disperse black dye composition
CN106977979B (en) * 2017-03-24 2019-03-05 江苏迪安化工有限公司 A kind of high water-washing type disperse black dye composition
WO2022080430A1 (en) * 2020-10-14 2022-04-21 富士フイルム株式会社 Compound, tautomer of same or salt of said compound or tautomer, method for producing same, coloring composition, dyeing method and dyed article
CN116490574A (en) * 2020-10-14 2023-07-25 富士胶片株式会社 Compound, tautomer thereof or salt thereof, process for producing the same, coloring composition, method for dyeing, and dyed article

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Address after: Three, 318000 mountain village, Jiaojiang District, Zhejiang, Taizhou

Applicant after: ZHEJIANG SHANYU TECHNOLOGY CO.,LTD.

Address before: Three, 318000 mountain village, Jiaojiang District, Zhejiang, Taizhou

Applicant before: ZHEJIANG SHANYU DYESTUFF CHEMICAL Co.,Ltd.

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Address after: Three, 318000 mountain village, Jiaojiang District, Zhejiang, Taizhou

Patentee after: Zhejiang Shanyu Group Co.,Ltd.

Address before: Three, 318000 mountain village, Jiaojiang District, Zhejiang, Taizhou

Patentee before: ZHEJIANG SHANYU TECHNOLOGY CO.,LTD.

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Effective date of registration: 20231010

Address after: 333300 Tashan Industrial Zone, Leping Industrial Park, Jingdezhen City, Jiangxi Province

Patentee after: LEPING SAFELY PHARMACEUTICAL Co.,Ltd.

Address before: 318000 three mountain village, Jiaojiang District, Taizhou, Zhejiang

Patentee before: Zhejiang Shanyu Group Co.,Ltd.

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Denomination of invention: A medium temperature dispersed blue dye composition

Effective date of registration: 20231117

Granted publication date: 20180629

Pledgee: Agricultural Bank of China Limited Leping sub branch

Pledgor: LEPING SAFELY PHARMACEUTICAL Co.,Ltd.

Registration number: Y2023980066395