CN106242209A - Municipal sewage and mud work in coordination with the method and device of circular treatment - Google Patents

Municipal sewage and mud work in coordination with the method and device of circular treatment Download PDF

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Publication number
CN106242209A
CN106242209A CN201610793186.XA CN201610793186A CN106242209A CN 106242209 A CN106242209 A CN 106242209A CN 201610793186 A CN201610793186 A CN 201610793186A CN 106242209 A CN106242209 A CN 106242209A
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CN
China
Prior art keywords
mud
sewage
sludge
municipal sewage
sludge hot
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610793186.XA
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Chinese (zh)
Inventor
陈剑波
刘思聪
刘思君
刘海鸿
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Hainan Xing Tai Tai Environmental Technology Co Ltd
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Hainan Xing Tai Tai Environmental Technology Co Ltd
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Publication date
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Priority to CN201610793186.XA priority Critical patent/CN106242209A/en
Publication of CN106242209A publication Critical patent/CN106242209A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

Abstract

The invention provides a kind of municipal sewage and mud works in coordination with the method and device of circular treatment, the method includes: the first step: municipal sewage is through processing, and sewage becomes qualified discharge water and mud;Second step: mud preheats through pulp, completes the reaction of mud organic substance pyrohydrolysis in entering into sludge hot hydrolytic reaction pot, in pyrohydrolysis course of reaction, the larger molecular organics in mud is pyrolyzed into little molecule and the most biochemical Organic substance;3rd step: the high temperature mud after pyrolysis is cooled to normal pressure through guanite dephosphorization process dephosphorization and part ammonia nitrogen, cooled device, enters sewage disposal system after being back to Sewage Plant water inlet, and municipal sewage mixing.The invention has the beneficial effects as follows: the sludge treatment technique of the present invention solves a mud supervision and management difficult problem, solve the illegal unrest of mud to fall to pollute a difficult problem for environment, and sewage disposal, Treatment of Sludge and odor treatment are considered by the present invention in the lump, with traditional sewage and mud comparison of item, reduce general item investment expense.

Description

Municipal sewage and mud work in coordination with the method and device of circular treatment
Technical field
The present invention relates to municipal wastewater and technical field of sludge treatment, particularly relate to municipal sewage and mud is worked in coordination with at circulation The method and device of reason.
Background technology
China is along with the development of urbanization and improving constantly of living standards of the people, the substantial amounts of city of generation every day, cities and towns now Political affairs sewage and mud, cause the biggest pressure to The Surroundings in Cities and sustainable development, it is achieved the minimizing of mud, harmless Change, stabilisation, resource must change traditional technical method, innovate energetically, constantly adopt new technology and new technique solves This urgent problems.
Summary of the invention
The invention provides a kind of municipal sewage and method that mud works in coordination with circular treatment, comprise the steps:
The first step: municipal sewage is through processing, and sewage becomes qualified discharge water and mud;
Second step: mud preheats through pulp, completes mud organic substance pyrohydrolysis in entering into sludge hot hydrolytic reaction pot Reaction, in pyrohydrolysis course of reaction, the larger molecular organics in mud is pyrolyzed into little molecule and the most biochemical Organic substance;
3rd step: the high temperature mud after pyrolysis is cooled to through guanite dephosphorization process dephosphorization and part ammonia nitrogen, cooled device Normal pressure, enters sewage disposal system after being back to Sewage Plant water inlet, and municipal sewage mixing.
As a further improvement on the present invention, municipal sewage is through the process of grid, setting pot and sewage disposal system, dirty Water becomes qualified discharge water and mud.
As a further improvement on the present invention, the temperature after mud pulp preheats in described second step: 55 DEG C-80 DEG C, mud enters sludge hot hydrolytic reaction pot, injects superheated steam, and final pyrolysis mud temperature is heated to: 140 DEG C-170 DEG C, Mud is the time of staying 13 minutes to 20 minutes in sludge hot hydrolytic reaction pot.
As a further improvement on the present invention, in described second step, mud reacts through sludge hot hydrolytic reaction pot, becomes Having become liquid state mud, solubility COD has accounted for 95%, BOD/COD >=0.6.
As a further improvement on the present invention, in described second step, mud and steam rates are that mud per ton adds 110 To 130 kilogram of steam.
As a further improvement on the present invention, in described second step, when mud stops in sludge hot hydrolytic reaction pot Between 15 minutes or 18 minutes, final pyrolysis mud temperature is heated to 155 DEG C.
As a further improvement on the present invention, in described 3rd step, the chemical feeding quantity of magnesium chloride in guanite dephosphorization process For aqueous 80% raw sewage 1.2/10000ths.
As a further improvement on the present invention, in described 3rd step, guanite dephosphorization process Chinese medicine selects hydroxide Magnesium.
Present invention also offers a kind of municipal sewage and mud works in coordination with the device of circular treatment, including the sewage being sequentially connected Processing system, dirty slurry dewaterer, mud preheating pulp tank, sludge hot hydrolytic reaction pot, guanite dephosphorization system, cooler, should Device also includes the steam generator system providing steam for described sludge hot hydrolytic reaction pot, described steam generator system and described mud hot water Solution reaction kettle is connected.
As a further improvement on the present invention, this device also includes being arranged at municipal sewage outlet and described sewage disposal Grid between system and setting pot, this device also includes that flash tank, condenser, deodoration system, described flash tank connect respectively Described sludge hot hydrolytic reaction pot and described mud preheating pulp tank, described condenser input connects the preheating pulp of described mud Tank, described condenser outfan connects described deodoration system, and described deodoration system connects described dirty slurry dewaterer and described respectively Sewage disposal system.
The invention has the beneficial effects as follows: the sludge treatment technique of the present invention solves a mud supervision and management difficult problem, solves The illegal unrest of mud falls to pollute a difficult problem for environment, and sewage disposal, Treatment of Sludge and odor treatment are considered by the present invention in the lump, Define the solution of a closed loop, and traditional sewage and mud comparison of item, reduce general item investment expense.
Accompanying drawing explanation
Fig. 1 is assembly of the invention theory diagram.
Detailed description of the invention
The invention discloses a kind of municipal sewage and method that mud works in coordination with circular treatment, comprise the steps:
The first step: municipal sewage becomes qualified discharge through the process of grid, setting pot and sewage disposal system, sewage Water and mud;
Second step: mud preheats through pulp, completes mud organic substance pyrohydrolysis in entering into sludge hot hydrolytic reaction pot Reaction, in pyrohydrolysis course of reaction, the larger molecular organics in mud is pyrolyzed into little molecule and the most biochemical Organic substance, the most such as Under: sludge protein hydrolysis of organic matter becomes polypeptide and aminoacid, mud cell wall fiber type organic to be hydrolyzed into fructose and Fructus Vitis viniferae Sugar, mud fats hydrolysis of organic matter becomes fatty acid and triglyceride etc.;
3rd step: the high temperature mud after pyrolysis is cooled to through guanite dephosphorization process dephosphorization and part ammonia nitrogen, cooled device Normal pressure, enters sewage disposal system, successively collaborative place of moving in circles after being back to Sewage Plant water inlet, and municipal sewage mixing Reason.
In described second step, the mud of generation, after pulp preheating can 5 processes, enters into sludge hot hydrolysis Completing the reaction of mud organic substance pyrohydrolysis in still 6, in pyrohydrolysis course of reaction, the larger molecular organics in mud is pyrolyzed into little Molecule and the most biochemical Organic substance, the temperature after mud pulp preheating: 55 DEG C-80 DEG C, mud enters sludge hot hydrolytic reaction pot, note Entering superheated steam, final pyrolysis mud temperature is heated to: 140 DEG C-170 DEG C, when mud stops in sludge hot hydrolytic reaction pot Between 13 minutes to 20 minutes, whole process is a continuous print technical process.
In described second step, mud reacts through sludge hot hydrolytic reaction pot 6, becomes liquid state mud, solubility COD has accounted for 95%, BOD/COD >=0.6.
In described second step, mud and steam rates are that mud per ton adds 110 to 130 kilogram of steam.
As the preferred embodiments of the present invention, in described second step, when mud stops in sludge hot hydrolytic reaction pot Between 15 minutes or 18 minutes, final pyrolysis mud temperature is heated to 155 DEG C.
In described 3rd step, in guanite dephosphorization process the chemical feeding quantity of magnesium chloride be aqueous 80% raw sewage ten thousand/ 1.2。
In described 3rd step, guanite dephosphorization process Chinese medicine selects magnesium hydroxide.
As it is shown in figure 1, the invention also discloses a kind of municipal sewage and mud works in coordination with the device of circular treatment, including successively The sewage disposal system 3 being connected, dirty slurry dewaterer 4, mud preheating pulp tank 5, sludge hot hydrolytic reaction pot 6, guanite dephosphorization System 7, cooler 8, this device also includes the steam generator system 9 providing steam for described sludge hot hydrolytic reaction pot 6, described boiler System 9 is connected with described sludge hot hydrolytic reaction pot 6.
This device also includes grid 1 and the sand setting being arranged between municipal sewage outlet and described sewage disposal system 3 Pond 2, this device also includes that flash tank 10, condenser 11, deodoration system 12, described flash tank 10 connect described mud hot water respectively Solution reaction kettle 6 and described mud preheating pulp tank 5, described condenser 11 input connects described mud preheating pulp tank 5, described Condenser 11 outfan connects described deodoration system 12, and described deodoration system 12 connects described dirty slurry dewaterer 4 and described respectively Sewage disposal system 3.
High temperature mud after pyrolysis is cooled to normal pressure through guanite dephosphorization system 7 dephosphorization and part ammonia nitrogen, cooled device 8, Sewage disposal system 3 is entered after being back to Sewage Plant water inlet, and municipal sewage mixing.
This deodoration system 12 processes sewage disposal system 3 and the low concentration foul smell of Dehydrator for Slurry 4 generation, processes dirt simultaneously Mud preheating pulp tank 5 high concentration foul smell out.
The present invention has a following technical advantage:
1. the present invention solves a municipal sewage plant specific resistance to filtration difficult problem, and no matter present specific resistance to filtration is mud Anhydration and incineration or the technique such as Sludge landfill or sludge composting, all can bring secondary pollution to environment, as sludge incineration produces The harmful substances such as dioxin carcinogen and heavy metal gaseous state glue, Sludge landfill produces high concentration penetrating fluid polluted underground water, simultaneously Producing the air ambient that substantial amounts of odor pollution periphery is neighbouring, Treatment of Sludge project all receives the people's around project pick-up point Neck keeps away resistance.
2. the problem that during the present invention solves mud factory sewage disposal process, carbon source is not enough, the pyrolysis mud after pyrohydrolysis is rich Supplement carbon source after carbon source, and municipal sewage mixing, need not separately add methanol etc., reduce operating cost.
In sewage the most of the present invention and mud same system, treatment in situ is disposed, and changes existing sewage disposal and Treatment of Sludge Pattern, solves mud outward transport, a process difficult problem of separately founding the factory, the difficulty that present China is landed by mud project in a lot of city.
4. the sludge treatment technique of the present invention solves a mud supervision and management difficult problem, solves the illegal unrest of mud and pollutes ring The difficult problem in border.
5. the sewage sludge of the present invention process disposing technique than traditional sewage sludge process cost of disposal save 20% with On.
The collaborative process of sewage sludge the most of the present invention circulation disposes the civilization embodying ecology, and mud comes to go back to there more therefrom Going, lattice keep the ecological replacement made the best use of everything.
7. the guanite dephosphorization of the present invention, eliminates the phosphorus in sewage sludge and part ammonia nitrogen, and guanite returns as fertilizer Return Natural Circulation.
8. sewage disposal, Treatment of Sludge and odor treatment are considered by the present invention in the lump, define the solution of a closed loop Certainly scheme, and traditional sewage and mud comparison of item, reduce general item investment expense.
Above content is to combine concrete preferred implementation further description made for the present invention, it is impossible to assert Being embodied as of the present invention is confined to these explanations.For general technical staff of the technical field of the invention, On the premise of present inventive concept, it is also possible to make some simple deduction or replace, all should be considered as belonging to the present invention's Protection domain.

Claims (10)

1. the method that a municipal sewage and mud work in coordination with circular treatment, it is characterised in that comprise the steps:
The first step: municipal sewage is through processing, and sewage becomes qualified discharge water and mud;
Second step: mud preheats through pulp, completes the reaction of mud organic substance pyrohydrolysis in entering into sludge hot hydrolytic reaction pot, In pyrohydrolysis course of reaction, the larger molecular organics in mud is pyrolyzed into little molecule and the most biochemical Organic substance;
3rd step: the high temperature mud after pyrolysis is cooled to normal pressure through guanite dephosphorization process dephosphorization and part ammonia nitrogen, cooled device, Sewage disposal system is entered after being back to Sewage Plant water inlet, and municipal sewage mixing.
Method the most according to claim 1, it is characterised in that in the first step, municipal sewage through grid, setting pot and The process of sewage disposal system, sewage becomes qualified discharge water and mud.
Method the most according to claim 1, it is characterised in that the temperature after mud pulp preheats in described second step Degree: 55 DEG C-80 DEG C, mud enters sludge hot hydrolytic reaction pot, injects superheated steam, and final pyrolysis mud temperature is heated to: 140 DEG C-170 DEG C, mud is the time of staying 13 minutes to 20 minutes in sludge hot hydrolytic reaction pot.
Method the most according to claim 1, it is characterised in that in described second step, mud is anti-through sludge hot hydrolysis Answering still to react, become liquid state mud, solubility COD has accounted for 95%, BOD/COD >=0.6.
Method the most according to claim 1, it is characterised in that in described second step, mud and steam rates are per ton Mud adds 110 to 130 kilogram of steam.
Method the most according to claim 3, it is characterised in that in described second step, mud is at sludge hot hydrolysis 15 minutes time of staying or 18 minutes in still, final pyrolysis mud temperature is heated to 155 DEG C.
Method the most according to claim 1, it is characterised in that in described 3rd step, chlorination in guanite dephosphorization process The chemical feeding quantity of magnesium is 1.2/10000ths of aqueous 80% raw sewage.
Method the most according to claim 1, it is characterised in that in described 3rd step, guanite dephosphorization process Chinese medicine Select magnesium hydroxide.
9. a municipal sewage and mud work in coordination with the device of circular treatment, it is characterised in that include the sewage disposal being sequentially connected System, dirty slurry dewaterer, mud preheating pulp tank, sludge hot hydrolytic reaction pot, guanite dephosphorization system, cooler, this device Also including the steam generator system providing steam for described sludge hot hydrolytic reaction pot, described steam generator system is anti-with the hydrolysis of described sludge hot Still is answered to be connected.
Device the most according to claim 9, it is characterised in that this device also include being arranged at municipal sewage outlet with Grid between described sewage disposal system and setting pot, this device also includes flash tank, condenser, deodoration system, described sudden strain of a muscle Steaming pot connects described sludge hot hydrolytic reaction pot and described mud preheating pulp tank respectively, and described condenser input connects described Mud preheating pulp tank, described condenser outfan connects described deodoration system, and described deodoration system connects described dirty slurry respectively Dewaterer and described sewage disposal system.
CN201610793186.XA 2016-08-31 2016-08-31 Municipal sewage and mud work in coordination with the method and device of circular treatment Pending CN106242209A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106630526A (en) * 2017-03-06 2017-05-10 东方电气集团东方锅炉股份有限公司 Sludge hydrothermal oxidization reaction system and method with function of product reflux pretreatment
CN106746467A (en) * 2017-01-25 2017-05-31 同济大学 A kind of sludge resource recovery method based on digested sludge hydro-thermal process
CN106830587A (en) * 2017-01-19 2017-06-13 同济大学 It is a kind of to strengthen the method for explaining phosphorus containing solid sludge high temperature hot water high
CN106904807A (en) * 2017-03-31 2017-06-30 同济大学 A kind of method that phosphorus is reclaimed from dewatered sludge
CN107417062A (en) * 2017-09-08 2017-12-01 复旦大学 A kind of method that phosphorus is reclaimed from sludge from wastewater treatment plant

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106830587A (en) * 2017-01-19 2017-06-13 同济大学 It is a kind of to strengthen the method for explaining phosphorus containing solid sludge high temperature hot water high
CN106746467A (en) * 2017-01-25 2017-05-31 同济大学 A kind of sludge resource recovery method based on digested sludge hydro-thermal process
CN106630526A (en) * 2017-03-06 2017-05-10 东方电气集团东方锅炉股份有限公司 Sludge hydrothermal oxidization reaction system and method with function of product reflux pretreatment
CN106904807A (en) * 2017-03-31 2017-06-30 同济大学 A kind of method that phosphorus is reclaimed from dewatered sludge
CN107417062A (en) * 2017-09-08 2017-12-01 复旦大学 A kind of method that phosphorus is reclaimed from sludge from wastewater treatment plant

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