CN106223072B - A kind of leaching heap staining method of cheese or beamed yarn - Google Patents

A kind of leaching heap staining method of cheese or beamed yarn Download PDF

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Publication number
CN106223072B
CN106223072B CN201610611293.6A CN201610611293A CN106223072B CN 106223072 B CN106223072 B CN 106223072B CN 201610611293 A CN201610611293 A CN 201610611293A CN 106223072 B CN106223072 B CN 106223072B
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seconds
banking
dyeing
dip dyeing
cycle alternation
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CN106223072A (en
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陈队范
鹿庆福
孙会丰
沈敏举
张本海
崔燕
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TAI'AN COMPANION MACHINERY CO Ltd
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TAI'AN COMPANION MACHINERY CO Ltd
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0004General aspects of dyeing
    • D06P1/002Processing by repeated dyeing, e.g. in different baths
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)

Abstract

The invention discloses a kind of cheeses or the leaching heap staining method of beamed yarn, this method to include the following steps:It scourings and bleaching, once wash, neutralizing, dyeing, secondary washing, soaping and wash three times, dyeing processing is carried out with banking up alternate cycles mode using dip dyeing in the processing stage of each step.It is dyed using dip dyeing with banking up alternate cycles mode, electric energy is greatly saved in main pump no longer continuous work;Simultaneously in entire dyeing course, cheese or beamed yarn, which only enter cylinder and go out cylinder, once just can reach standards for dyeing, and the ectonexine colour-difference effect after cheese or beam dyeing substantially increases the success rate once dyed better than existing colouring method, that is a duplicate sample rate, at the same it is time saving and energy saving.

Description

A kind of leaching heap staining method of cheese or beamed yarn
Technical field
The present invention relates to textile industry colouring art, the leaching heap staining method of specially a kind of cheese or beamed yarn.
Background technology
Cheese or beamed yarn are because dye bath ratio is small, dye material input amount is relatively fewer, technological process is shorter and with can Developing the features such as wide in variety, development scheme is flexible and industrialization level is high has been widely used in textile printing and dyeing field, with work Industry is horizontal to be constantly progressive, and cheese or beamed yarn dyeing also continue to develop, and is endowed update, in more rich technology Contain, technical guarantee caused by new method, the commercial application of new process, enhance the market competitiveness of enterprise, be that creation is good The necessary condition of good economic benefit.
However, as other industry, the higher fast-developing course of industrialization degree is along with high energy anxious to be resolved Consumption, high pollution current problem, than if desired for reduce industrialization process in water, steam, electricity, contaminate material consumption, and then It realizes and finds an adaptation china textile dyeing characteristic while meeting printing and dyeing parameters performance, ensureing printing quality Using energy-saving and emission-reduction and sustainable development as the effective development approach of important reference index.
In the prior art, to solve the above problems, generally being solved by several methods, such as:First, adjustment bath raio and Specific discharge;Second, adjust the relative motion degree for exchanging both frequency namely adjustment of dye liquor or working solution with such as yarn; Third, adjustment dye liquor cycle operation mode etc.;The above method approximately through scouring and bleaching, once wash, neutralize, dyeing, it is secondary washing, Soap, three times washing and etc. complete dyeing processing, each step is divided into according to technological requirement to enter water stage, charging and heating Stage cools down and holds the stages such as thermophase, however the above method dye liquor or working solution during industrialization production need to continue From cheese or beamed yarn leaching across, in order to ensure that working solution circulates, main pump cannot be shut down, can only continuous firing, dyeing Water consumption, electric energy consumption, hot steam energy consumption are higher in the process, and production cost is higher and unit source utilization rate is not high, and companion often Happening for product quality is influenced with there is yam surface to generate filoplume etc..
Invention content
The present invention is directed to more than shortcoming, the leaching heap staining method of a kind of cheese or beamed yarn is provided, using dip dyeing It is dyed with banking up alternate cycles mode, electric energy is greatly saved in main pump no longer continuous work;Entire dyeing course simultaneously In, cheese or beamed yarn, which only enter cylinder and go out cylinder, once just can reach standards for dyeing, inside and outside after cheese or warp beam dyeing yarn Layer colour-difference effect substantially increases the success rate once dyed, i.e. a duplicate sample rate, while time saving better than existing colouring method It is laborsaving.
The technical solution adopted by the present invention to solve the technical problems is:This method includes the following steps:It scourings and bleaching, a water It washes, neutralize, dyeing, secondary washing, soaping and wash three times, using dip dyeing and friendship is banked up in the processing stage of each step Dyeing processing is carried out for endless form.
Dip dyeing mode:Working solution or water continue to pass through the cheese being placed in staining jar or warp beam under the action of main pump Yarn, which cannot shut down and uninterrupted pumping working solution or water.
Stacked configuration:Main pump is shut down, and contaminates cheese or beamed yarn is in static working solution or water, technological requirement master Pump is shut down, no longer pumping work liquid or water.
It disseminates and banks up alternate cycles mode:To the cheese in staining jar or beamed yarn using dip dyeing mode and the side of banking up The mode of formula alternate cycles.
It is contaminated in the processing stage of each step using dip dyeing with banking up alternate cycles mode due to devising Color is handled, main pump no longer continuous work, greatly reduces the consumption of electric energy;Simultaneously in entire dyeing course, due to using Dip dyeing only enters cylinder and goes out cylinder once with regard to that can reach standards for dyeing with banking up alternating cyclical process, cheese or beamed yarn, no longer The cylinder that repeatedly to come in and go out as other techniques can be only achieved standards for dyeing, substantially increase production efficiency;Cheese or warp beam are led to The ectonexine colour-difference effect after colouring method dyeing is crossed better than existing colouring method, substantially increases the success once dyed Rate, i.e. a duplicate sample rate.
The present invention devises, and disseminates and is replaced with banking up alternate cycles mode using dip dyeing with banking up 6-300 seconds within 6-300 seconds Endless form carries out dyeing processing.
The present invention devises, it enters the water stage using the 60-300 seconds cycle alternations with banking up 6-60 seconds of dip dyeing in scouringing and bleaching Mode, charging, temperature rise period using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing, hold thermophase use Disseminate the 6-300 seconds cycle alternation modes with banking up 6-300 seconds;
It enters the water stage using the 60-300 seconds cycle alternation patterns with banking up 6-60 seconds of dip dyeing in primary washing, rises Temperature holds thermophase using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing;
In and in its enter the water stage using dip dyeing the 60-300 second cycle alternation modes with banking up 6-60 seconds, feed, Temperature rise period using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing, holds thermophase using dip dyeing 6-300 seconds Cycle alternation mode with banking up 6-300 seconds;
It enters the water stage using the 60-300 seconds cycle alternation modes with banking up 6-60 seconds are disseminated in dyeing, feed, Temperature rise period using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing, holds thermophase using dip dyeing 6-300 seconds Cycle alternation mode with banking up 6-300 seconds;
It enters the water stage using the 60-300 seconds cycle alternation patterns with banking up 6-60 seconds of dip dyeing in secondary washing, rises Temperature holds thermophase using the 10-60 seconds cycle alternation patterns with banking up 10-30 seconds of dip dyeing;
It enters the water stage using the 60-300 seconds cycle alternation modes with banking up 6-60 seconds are disseminated in soaping, heat up, Thermophase is held using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing;
It enters the water stage using the 60-300 seconds cycle alternation modes with banking up 6-60 seconds of dip dyeing in washing three times, rises Temperature holds thermophase using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing.
Specific embodiment
Embodiment 1:Include the following steps:It scourings and bleaching, once wash, neutralizing, dyeing, secondary washing, soaping and wash three times;
Following table is shown in the different step of the present embodiment, and the dip dyeing in each stage is with banking up alternate circulation time(Unit: Second):
240Kg cheeses are put into overflow dyeing machine, that is, enter cylinder, later using following steps:
Step 1:It scourings and bleaching, enters the water stage using 250 seconds cycle alternation modes with banking up 12 seconds of dip dyeing, 25 DEG C processing 11 minutes, its charging later, temperature rise period are using 38 seconds cycle alternation modes with banking up 27 seconds of dip dyeing and by temperature 112 DEG C are risen to, it is held thermophase and handles 35 using 70 seconds cycle alternation modes with banking up 280 seconds of dip dyeing, and at 112 DEG C later Minute, it discharges later;
Step 2:It is once washed, enters water stage use 220 seconds cycle alternation modes with banking up 57 seconds of dip dyeing, Later its heating, hold thermophase using dip dyeing 10 seconds with the heap cycle alternation mode of 10 seconds, and 88 DEG C processing 12 minutes, later Discharge;
Step 3:It is neutralized, enters the water stage using 60 seconds cycle alternation modes with banking up 47 seconds of dip dyeing, Zhi Houqi Charging, temperature rise period, it held warm rank later using 60 seconds and the heap cycle alternation mode of 30 seconds are disseminated, and temperature is risen to 56 DEG C Duan Caiyong disseminates 66 seconds cycle alternation patterns with banking up 249 seconds, and is handled 14 minutes at 56 DEG C, discharges later;
Step 4:It is dyed, adds in reactive dye in this process, enter the use dip dyeing of water stage 225 seconds with banking up The cycle alternation mode of 28 seconds, and handled at 38 DEG C 30 minutes, its charging later, temperature rise period use dip dyeing 30 seconds with banking up 30 Second cycle alternation mode, and handle 40 minutes at 55 DEG C, it is held thermophase and is followed using dip dyeing with banking up 300 seconds within 60 seconds later Ring alternation method, and handled 50 minutes at 55 DEG C, it discharges later;
Step 5:Secondary washing is carried out, enters water stage use 220 seconds cycle alternation modes with banking up 21 seconds of dip dyeing, Its heating later is held thermophase use 60 seconds cycle alternation modes with banking up 30 seconds of dip dyeing, and is handled 20 minutes at 45 DEG C, it After discharge;
Step 6:It soaps, enters the water stage using 180 seconds cycle alternation modes with banking up 47 seconds are disseminated, later Its heat up, hold thermophase using dip dyeing 10 seconds cycle alternation modes with banking up 10 seconds, and 87 DEG C processing 20 minutes, heel row Go out;
Step 7:It is washed three times, enters water stage use 200 seconds cycle alternation modes with banking up 20 seconds of dip dyeing, Its heating later is held thermophase use 60 seconds cycle alternation modes with banking up 30 seconds of dip dyeing, and is handled 3 minutes at 88 DEG C, it After discharge, finally go out cylinder, that is, take out the cheese in overflow dyeing machine.
It is demonstrated experimentally that if above-mentioned cheese carries out dyeing processing a length of 7.5 hours at that time, electricity consumption using prior art 195 degree, ectonexine color distortion is 4 grades;If dyed using above-mentioned operation, a length of 6.5 hours during technique, electricity consumption 101 degree, ectonexine color distortion is 4-4.5 grade, and power saving while also improves a duplicate sample rate, while entirely dyeing course is only It need to enter that cylinder, to go out cylinder each primary, not need to the cylinder that repeatedly comes in and goes out, improve production efficiency, and saved water consumption.
Embodiment 2:Include the following steps:It scourings and bleaching, once wash, neutralizing, dyeing, secondary washing, soaping and wash three times;
Following table is shown in the different step of the present embodiment, and the dip dyeing in each stage is with banking up alternate circulation time(Unit: Second):
200Kg beamed yarns are put into overflow dyeing machine, that is, enter cylinder, later using following steps:
Step 1:It scourings and bleaching, enters the water stage using 60 seconds cycle alternation modes with banking up 6 seconds of dip dyeing, at 20 DEG C Processing 10 minutes, its charging later, temperature rise period are using 10 seconds cycle alternation modes with banking up 10 seconds of dip dyeing and by temperature liter To 110 DEG C, it is held thermophase and handles 30 points using 6 seconds cycle alternation modes with banking up 300 seconds of dip dyeing, and at 110 DEG C later Clock discharges later;
Step 2:It is once washed, enters water stage use 300 seconds cycle alternation modes with banking up 60 seconds of dip dyeing, Later its heating, hold thermophase using dip dyeing 60 seconds with the heap cycle alternation mode of 30 seconds, and 85 DEG C processing 10 minutes, later Discharge;
Step 3:It is neutralized, enters the water stage using 90 seconds cycle alternation modes with banking up 20 seconds of dip dyeing, Zhi Houqi Temperature is risen to 55 DEG C by charging, temperature rise period using 50 seconds cycle alternation modes with banking up 20 seconds of dip dyeing, it holds temperature later Stage is handled 15 minutes using 150 seconds cycle alternation patterns with banking up 200 seconds of dip dyeing, and at 55 DEG C, is discharged later;
Step 4:It is dyed, adds in reactive dye in this process, enter the use dip dyeing of water stage 150 seconds with banking up The cycle alternation mode of 30 seconds, and handled at 35 DEG C 28 minutes, its charging later, temperature rise period use dip dyeing 60 seconds with banking up 30 The cycle alternation mode of second, and handled at 56 DEG C 35 minutes, it, which is held thermophase and uses, later disseminates 300 seconds with banking up 200 seconds Cycle alternation mode, and handled 40 minutes at 56 DEG C, it discharges later;
Step 5:Secondary washing is carried out, enters water stage use 200 seconds cycle alternation modes with banking up 40 seconds of dip dyeing, Its heating later is held thermophase use 50 seconds cycle alternation modes with banking up 25 seconds of dip dyeing, and is handled 18 minutes at 48 DEG C, it After discharge;
Step 6:It soaps, enters the water stage using 250 seconds cycle alternation modes with banking up 50 seconds are disseminated, later Its heat up, hold thermophase using dip dyeing 40 seconds cycle alternation modes with banking up 27 seconds, and 88 DEG C processing 19 minutes, heel row Go out;
Step 7:It is washed three times, enters water stage use 80 seconds cycle alternation modes with banking up 58 seconds of dip dyeing, it Afterwards its heating, hold thermophase using dip dyeing 35 seconds cycle alternation modes with banking up 30 seconds, and 90 DEG C processing 4 minutes, later Discharge finally goes out cylinder, that is, takes out the cheese in overflow dyeing machine.
It is demonstrated experimentally that if above-mentioned cheese carries out dyeing processing a length of 7 hours at that time, electricity consumption 185 using prior art Degree, ectonexine color distortion are 4 grades;If dyed using above-mentioned operation, a length of 5.5 hours during technique, 90 degree of electricity consumption, Ectonexine color distortion is 4.2-4.6 grade, and power saving while also improves a duplicate sample rate, at the same entirely dyeing course only need into Cylinder, to go out cylinder each primary, does not need to the cylinder that repeatedly comes in and goes out, improves production efficiency, and saved water consumption.
Embodiment 3:Include the following steps:It scourings and bleaching, once wash, neutralizing, dyeing, secondary washing, soaping and wash three times;
Following table is shown in the different step of the present embodiment, and the dip dyeing in each stage is with banking up alternate circulation time(Unit: Second):
170Kg cheeses are put into overflow dyeing machine, that is, enter cylinder, later using following steps:
Step 1:It scourings and bleaching, enters the water stage using 45 seconds cycle alternation modes with banking up 10 seconds of dip dyeing, at 26 DEG C Processing 12 minutes, its charging later, temperature rise period are using 18 seconds cycle alternation modes with banking up 12 seconds of dip dyeing and by temperature liter To 112 DEG C, it is held thermophase and handles 34 points using 300 seconds cycle alternation modes with banking up 6 seconds of dip dyeing, and at 111 DEG C later Clock discharges later;
Step 2:It is once washed, enters water stage use 100 seconds cycle alternation modes with banking up 7 seconds of dip dyeing, it Afterwards its heating, hold thermophase using dip dyeing 30 seconds with the heap cycle alternation mode of 10 seconds, and 90 DEG C processing 13 minutes, heel row It puts;
Step 3:It is neutralized, enters the water stage using 140 seconds cycle alternation modes with banking up 28 seconds are disseminated, later It feeds, temperature is risen to 58 DEG C by the temperature rise period using 15 seconds cycle alternation modes with banking up 26 seconds of dip dyeing, it is held later Thermophase is handled 15 minutes using 200 seconds cycle alternation patterns with banking up 170 seconds of dip dyeing, and at 60 DEG C, is discharged later;
Step 4:It is dyed, adds in reactive dye in this process, enter the use dip dyeing of water stage 170 seconds with banking up The cycle alternation mode of 50 seconds, and handled at 38 DEG C 30 minutes, its charging later, temperature rise period use dip dyeing 40 seconds with banking up 27 The cycle alternation mode of second, and handled at 55 DEG C 40 minutes, it, which is held thermophase and uses, later disseminates 100 seconds with banking up 170 seconds Cycle alternation mode, and handled 55 minutes at 55 DEG C, it discharges later;
Step 5:Secondary washing is carried out, enters water stage use 220 seconds cycle alternation modes with banking up 45 seconds of dip dyeing, Its heating later is held thermophase use 10 seconds cycle alternation modes with banking up 10 seconds of dip dyeing, and is handled 17 minutes at 46 DEG C, it After discharge;
Step 6:It soaps, enters the water stage using 250 seconds cycle alternation modes with banking up 55 seconds are disseminated, later Its heat up, hold thermophase using dip dyeing 60 seconds cycle alternation modes with banking up 30 seconds, and 88 DEG C processing 19 minutes, heel row Go out;
Step 7:It is washed three times, enters water stage use 300 seconds cycle alternation modes with banking up 60 seconds of dip dyeing, Its heating later is held thermophase use 10 seconds cycle alternation modes with banking up 10 seconds of dip dyeing, and is handled 4 minutes at 85 DEG C, it After discharge, finally go out cylinder, that is, take out the cheese in overflow dyeing machine.
It is demonstrated experimentally that if above-mentioned cheese carries out dyeing processing a length of 6.8 hours at that time, electricity consumption using prior art 180 degree, ectonexine color distortion are 4 grades;If dyed using above-mentioned operation, a length of 5.3 hours during technique, electricity consumption 85 Degree, ectonexine color distortion are 4.3-4.7 grade, and power saving while also improves a duplicate sample rate, while entirely dyeing course is only It need to enter that cylinder, to go out cylinder each primary, not need to the cylinder that repeatedly comes in and goes out, improve production efficiency, and saved water consumption.

Claims (1)

1. the leaching heap staining method of a kind of cheese or beamed yarn, this method include the following steps:Scouring and bleaching, once wash, neutralizing, Dyeing, is soaped and is washed three times at secondary washing, and using dip dyeing and alternate cycles side is banked up in the processing stage of each step Formula carries out dyeing processing, and the dip dyeing mode is:Working solution or water continue to pass through under the action of main pump to be placed in staining jar Cheese or beamed yarn, which cannot shut down and uninterrupted pumping working solution or water, the stacked configuration are:Main pump It shuts down, contaminates cheese or beamed yarn is in static working solution or water, which shuts down, no longer pumping work liquid Or water;It disseminates and banks up alternate cycles mode and dyed using dip dyeing with the alternate cycles mode banked up 6-300 seconds within 6-300 seconds Processing;It enters the water stage using the 60-300 seconds cycle alternation modes with banking up 6-60 seconds of dip dyeing, charging, heating in scouringing and bleaching Stage using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing, holds thermophase using dip dyeing 6-300 seconds and heap Put the cycle alternation mode of 6-300 seconds;
It enters the water stage using the 60-300 seconds cycle alternation patterns with banking up 6-60 seconds are disseminated in primary washing, heat up, Thermophase is held using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing;
In and in its enter the water stage using dip dyeing the 60-300 second cycle alternation modes with banking up 6-60 seconds, feed, heat up Stage using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing, holds thermophase using dip dyeing 6-300 seconds and heap Put the cycle alternation mode of 6-300 seconds;
It enters the water stage using the 60-300 seconds cycle alternation modes with banking up 6-60 seconds of dip dyeing, charging, heating in dyeing Stage using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing, holds thermophase using dip dyeing 6-300 seconds and heap Put the cycle alternation mode of 6-300 seconds;
It enters the water stage using the 60-300 seconds cycle alternation patterns with banking up 6-60 seconds are disseminated in secondary washing, heat up, Thermophase is held using the 10-60 seconds cycle alternation patterns with banking up 10-30 seconds of dip dyeing;
It enters the water stage using the 60-300 seconds cycle alternation modes with banking up 6-60 seconds of dip dyeing in soaping, and temperature is held in heating Stage is using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing;
It enters the water stage using the 60-300 seconds cycle alternation modes with banking up 6-60 seconds are disseminated in washing three times, heat up, Thermophase is held using the 10-60 seconds cycle alternation modes with banking up 10-30 seconds of dip dyeing.
CN201610611293.6A 2016-07-30 2016-07-30 A kind of leaching heap staining method of cheese or beamed yarn Active CN106223072B (en)

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CN113638160B (en) * 2021-08-11 2023-10-03 湖州新仲湖针织制衣有限公司 Short-flow quick bleaching and dyeing process for cheese

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CN2654647Y (en) * 2003-07-14 2004-11-10 王陈建 Spray steaming box for printing and dyeing
CN201024310Y (en) * 2007-04-17 2008-02-20 张琦 Knitting tubular open width combination machine for boiling off and bleaching
CN101555654A (en) * 2009-03-25 2009-10-14 稳健实业(深圳)有限公司 Non-woven fabric dyeing method
CN105177887A (en) * 2015-08-07 2015-12-23 泉州市新宏化工贸易有限公司 Knitted fabric cold pad-batch pretreatment process and cold pad-batch pretreatment agent

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KR200373743Y1 (en) * 2004-10-13 2005-01-27 김형조 Cata pult type glider

Patent Citations (4)

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Publication number Priority date Publication date Assignee Title
CN2654647Y (en) * 2003-07-14 2004-11-10 王陈建 Spray steaming box for printing and dyeing
CN201024310Y (en) * 2007-04-17 2008-02-20 张琦 Knitting tubular open width combination machine for boiling off and bleaching
CN101555654A (en) * 2009-03-25 2009-10-14 稳健实业(深圳)有限公司 Non-woven fabric dyeing method
CN105177887A (en) * 2015-08-07 2015-12-23 泉州市新宏化工贸易有限公司 Knitted fabric cold pad-batch pretreatment process and cold pad-batch pretreatment agent

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