CN106223016A - A kind of autumn and winter automotive trim antibacterial rabbit hair fabric - Google Patents
A kind of autumn and winter automotive trim antibacterial rabbit hair fabric Download PDFInfo
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- CN106223016A CN106223016A CN201610607727.5A CN201610607727A CN106223016A CN 106223016 A CN106223016 A CN 106223016A CN 201610607727 A CN201610607727 A CN 201610607727A CN 106223016 A CN106223016 A CN 106223016A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/11—Compounds containing epoxy groups or precursors thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/342—Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/13—Alginic acid or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
- D06M16/003—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic with enzymes or microorganisms
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
- D06M2101/12—Keratin fibres or silk
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Biochemistry (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the preparation method of a kind of autumn and winter automotive trim antibacterial rabbit hair fabric, its step is as follows: (1) pretreatment: with preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.2 0.4g/L;Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 35 38 DEG C to process 30 35min, then uses clear water rinsed clean, 50 DEG C of drying;(2) antibiotic finish: with antibiotic finishing solution: stachyose 1.5g/L, mangrove bark extracting solution;3 5g/L, Aloe juice 0.3g/L, Algin 2 5g/L;Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C to process 25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
Description
Technical field
The present invention relates to a kind of autumn and winter automotive trim antibacterial rabbit hair fabric, belong to field of textiles.
Background technology
Along with progress and the development of technology, the demand that internal decoration textile of automobile is worth by consumer is also stepping up.Pass
On system, its demand is concentrated mainly on Comfortable attractive, economy and durability, is prone to the aspects such as maintenance.Nowadays, also require that some are special
Processing performance, such as anti-ultraviolet, antibacterial deodourizing, radioprotective etc., and needs to meet various standards etc..Functional fiber can be expired
These particular/special requirements of foot, such as: the fiber with anti-bacterial anti-foul function can control the breeding of antibacterial to a certain extent, prevents smelly
The generation of taste;Seat-cover fabric that ultraviolet prevention fiber is made, carpet, car blinds fabric etc., be unlikely and fade and brittle.
Be in the environment of a relative closure in automobile, be the hotbed that grows of bacterial virus, dust, human sweat, sebum,
The dirt of the material such as grease, crock and outside easily sticks on the fiber of interior material, on these pollutant and skin
The lower fatty acid (such as n-nonanoic acid, capric acid) and the volatile compound that often produce after the effect of bacterium and external microorganism distribute evil
Smelly.The anti-bacterial purifying finish of automotive interior material is gradually paid close attention in recent years, by fiber or surface introduce antibacterial,
The generation of suppression antibacterial or breeding, prevent stench from producing, make fabric have good antibiotic property.Natural antibacterial agent is mainly derived from
Natural materials extract, can be divided into animal class, plant, mineral substance from source.Its advantage is that product carries from natural materials
Taking or directly use, environment typically will not produce pollution, safety and environmental protection, shortcoming is to begin to carbonization when 160~180 DEG C divide
Solving, range of application is extremely restricted.
The rabbit hair is soft, light weight is fluffy, novel in style, warmth retention property and good hygroscopicity, but owing to rabbit fur fibre surface is deposited
At unipolarity scale, fibre strength is low, and surface friction property is poor, and crimpness is little, and obvolvent poor performance uses easily to fall in textile
Hair, shrink, pilling.
Fibre property is the basic reason affecting rabbit hair knitted fabrics pilling performance, and the scale on rabbit fur fibre surface is most
In tiles oblique strip shaped, subtended angle is less, the least along reverse friction factor, and the crimpness of single fiber is little, with surrounding annulus
Frictional force, cohesive force little, easily from yarn slip;Rabbit fur fibre is relatively soft, and the fiber head end exposing fabric face is easy
Tangle balling-up.Spinning process is also the key factor affecting rabbit hair knitted fabrics pilling.
The disadvantages mentioned above of the rabbit hair constrains rabbit hair fabric application on automotive trim, improves rabbit hair fabric anti-fluffing and anti-pilling
Performance, increases its anti-microbial property and rabbit hair fabric just can be made for automotive trim.
It is desirable to provide a kind of autumn and winter automotive trim antibacterial rabbit hair fabric, the technique native annulus that the present invention provides
Protecting, the rabbit hair fabric anti-microbial property after process is good, and feel is more soft, fine and smooth, is difficult to balling-up.
Summary of the invention
The technical problem existed based on background technology, the present invention is directed to the problem that background technology exists, it is provided that a kind of autumn and winter
Automotive trim antibacterial rabbit hair fabric, the technique natural environmental-protective that the present invention provides, the rabbit hair fabric anti-microbial property after process is good, and
And feel is more soft, fine and smooth, it is difficult to balling-up.
The purpose of the present invention is achieved through the following technical solutions:
A kind of preparation method of autumn and winter automotive trim antibacterial rabbit hair fabric, its step is as follows:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.2-0.4g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 35-38 DEG C to process 30-35min,
Then clear water rinsed clean, 50 DEG C of drying are used;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, mangrove bark extracting solution;3-5g/L, Aloe juice 0.3g/L, Algin 2-5g/L;
The preparation method of described mangrove bark extracting solution is: weigh fresh mango skin, and amount of water is 3 times of squeezinges of mangrove bark weight
Becoming juice, 4 DEG C save backup;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
It has been generally acknowledged that Algin and Aloe juice have certain antibacterial effect, but antibacterial ability is the most very well, the present invention
Have been surprisingly found that the mangrove bark extracting solution that addition is certain, their antibacterial effect can have been significantly improved, play synergism, and
More water-fastness.
The invention have benefit that:
(1) present invention provides a kind of autumn and winter automotive trim antibacterial rabbit hair fabric, the technique natural environmental-protective that the present invention provides,
Rabbit hair fabric anti-microbial property after process is good, and feel is more soft, fine and smooth, is difficult to balling-up.
(2) present inventors have unexpectedly found that the mangrove bark extracting solution that addition is certain, their antibacterial effect can have been significantly improved,
Play synergism, and more water-fastness.
Detailed description of the invention
Experiment material used by the present invention: pure rabbit hair knitted fabrics (45tex × 2).
Embodiment 1:
A kind of preparation method of autumn and winter automotive trim antibacterial rabbit hair fabric, its step is as follows:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.2g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 38 DEG C to process 30min, then uses
Clear water rinsed clean, 50 DEG C of drying;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, mangrove bark extracting solution;5g/L, Aloe juice 0.3g/L, Algin 2g/L;
The preparation method of described mangrove bark extracting solution is: weigh fresh mango skin, and amount of water is 3 times of squeezinges of mangrove bark weight
Becoming juice, 4 DEG C save backup;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
Embodiment 2:
A kind of preparation method of autumn and winter automotive trim antibacterial rabbit hair fabric, its step is as follows:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.4g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 35 DEG C to process 35min, then uses
Clear water rinsed clean, 50 DEG C of drying;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, mangrove bark extracting solution;3g/L, Aloe juice 0.3g/L, Algin 5g/L;
The preparation method of described mangrove bark extracting solution is: weigh fresh mango skin, and amount of water is 3 times of squeezinges of mangrove bark weight
Becoming juice, 4 DEG C save backup;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
Embodiment 3:
A kind of preparation method of autumn and winter automotive trim antibacterial rabbit hair fabric, its step is as follows:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.3g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 37 DEG C to process 31min, then uses
Clear water rinsed clean, 50 DEG C of drying;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, mangrove bark extracting solution;4g/L, Aloe juice 0.3g/L, Algin 3g/L;
The preparation method of described mangrove bark extracting solution is: weigh fresh mango skin, and amount of water is 3 times of squeezinges of mangrove bark weight
Becoming juice, 4 DEG C save backup;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
Embodiment 4:
A kind of preparation method of autumn and winter automotive trim antibacterial rabbit hair fabric, its step is as follows:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.2g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 36 DEG C to process 34min, then uses
Clear water rinsed clean, 50 DEG C of drying;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, mangrove bark extracting solution;5g/L, Aloe juice 0.3g/L, Algin 4g/L;
The preparation method of described mangrove bark extracting solution is: weigh fresh mango skin, and amount of water is 3 times of squeezinges of mangrove bark weight
Becoming juice, 4 DEG C save backup;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
Embodiment 5:
A kind of preparation method of autumn and winter automotive trim antibacterial rabbit hair fabric, its step is as follows:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.4g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 38 DEG C to process 32min, then uses
Clear water rinsed clean, 50 DEG C of drying;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, mangrove bark extracting solution;3g/L, Aloe juice 0.3g/L, Algin 5g/L;
The preparation method of described mangrove bark extracting solution is: weigh fresh mango skin, and amount of water is 3 times of squeezinges of mangrove bark weight
Becoming juice, 4 DEG C save backup;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
Embodiment 6:
Matched group is added without mangrove bark extracting solution:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.3g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, and bath raio 1:20 keeps constant temperature 35 DEG C to process 33min, then uses
Clear water rinsed clean, 50 DEG C of drying;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, Aloe juice 0.3g/L, Algin 2g/L;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
Evaluate the persistency of antibacterial fabric performance, mainly antibiotic fabric is carried out the wash durability test of anti-microbial property.Anti-
Bacterium fabric washing tests simplification wash conditions and the program of appendix C in reference " FZ/T 73,023 2006 antibiosis knitting product ", right
Fabric washing to be measured 50 times.
Antibiotic fabric performance test methods is with reference to the succusion of Appendix D in " FZ/T 73,023 2006 antibiosis knitting product ".
Succusion be imitate human body wear condition, make antibacterial under oscillating condition with anti-microbial agent in clothing, by calculate antibacterial
Slip, determines a kind of method of anti-microbial property size.Succusion testing procedure is: put into sample to be tested containing finite concentration
Antibacterial (staphylococcus aureus strain) culture fluid in, then sample is placed on reciprocating agitator, in (24 ± 1) DEG C
Under, with the velocity fluctuation 18h of 150r/min, after making sample fabric and bacterium solution be fully contacted by vibration, at (37 ± 1) DEG C biochemistry
Incubator is cultivated 24h, measures the clump count of antibacterial before and after vibrating, carry out quantitative assessment antibacterial effect by method for counting colonies.
The calculating of succusion test anti-microbial property:
Bacteriostasis rate (%)=(A-B)/A × 100%
In formula: A is clump count after standard blank sample vibration 18h;B is clump count after sample to be tested vibration 18h.With reference to mark
Quasi-FZ/T 01,046 1996 mensuration of gross weight " rabbit hair product fall ", uses YG (B) 401D type full-automatic textile fabric plain grinding instrument, simulation
A mao environment is fallen residing for fabric.According to the round rail in GB/T 4802.1-2008 " mensuration of textile fabric pilling performance "
The content of mark method, unit are ball top number and unit are ball top weighing method is carried out.
Effect is tested and assessed:
Experimental result is as shown in the table:
Table 1
These detection data are just for above-mentioned detection sample.
As can be seen here, the present invention provides a kind of autumn and winter automotive trim antibacterial rabbit hair fabric, the technique sky that the present invention provides
So environmental protection, the rabbit hair fabric anti-microbial property after process is good, and feel is more soft, fine and smooth, is difficult to balling-up.And present invention meaning
It is found that outward and adds certain mangrove bark extracting solution, their antibacterial effect can be significantly improved, play synergism, Er Qiegeng
Add water-fastness.
The above, the only present invention preferably detailed description of the invention, but protection scope of the present invention is not limited thereto,
Any those familiar with the art in the technical scope that the invention discloses, according to technical scheme and
Inventive concept equivalent or change in addition, all should contain within protection scope of the present invention.
Claims (3)
1. an autumn and winter automotive trim preparation method for antibacterial rabbit hair fabric, its step is as follows:
(1) pretreatment:
Outfit preprocessing solution: polyphenol oxidase 0.5g/L, sodium taurocholate 0.2-0.4g/L;
Pretreating process is: takes rabbit hair fabric water-bath and soaks, bath raio 1:20, keeps constant temperature 35-38 DEG C to process 30-35min, then
Use clear water rinsed clean, 50 DEG C of drying;
(2) antibiotic finish:
Outfit antibiotic finishing solution:
Stachyose 1.5g/L, mangrove bark extracting solution;3-5g/L, Aloe juice 0.3g/L, Algin 2-5g/L;
Technological process is: the water-bath again of pretreated rabbit hair fabric soaked, bath raio 1:30, keeps constant temperature 60 DEG C process
25min;Process latter 80 DEG C and bakee 10s, then wash, 30 DEG C of drying.
2. the preparation method of antibacterial rabbit hair fabric of the autumn and winter automotive trim described in claim 1, it is characterised in that:
The preparation method of described mangrove bark extracting solution is: weigh fresh mango skin, and amount of water is 3 times of mangrove bark weight and is squeezed into
Juice, 4 DEG C save backup.
3. the rabbit hair that the preparation method of the autumn and winter automotive trim antibacterial rabbit hair fabric described in claim 1-2 prepares is knitted
Thing.
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CN201610607727.5A CN106223016A (en) | 2016-07-27 | 2016-07-27 | A kind of autumn and winter automotive trim antibacterial rabbit hair fabric |
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CN201610607727.5A CN106223016A (en) | 2016-07-27 | 2016-07-27 | A kind of autumn and winter automotive trim antibacterial rabbit hair fabric |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103668941A (en) * | 2013-11-06 | 2014-03-26 | 天津工业大学 | Rabbit hair textile anti-static nano-finishing agent and finishing process |
CN104889419A (en) * | 2015-05-18 | 2015-09-09 | 湖州品创孵化器有限公司 | Biological synthesis method for spherical silver nanoparticle |
CN105239413A (en) * | 2015-11-12 | 2016-01-13 | 长兴千尺度纺织品有限公司 | Application of ecological auxiliary in finishing of cashmere sweater |
CN105455263A (en) * | 2015-11-13 | 2016-04-06 | 长兴华海纺织有限公司 | Anti-pilling and antibacterial woolen sweater |
-
2016
- 2016-07-27 CN CN201610607727.5A patent/CN106223016A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103668941A (en) * | 2013-11-06 | 2014-03-26 | 天津工业大学 | Rabbit hair textile anti-static nano-finishing agent and finishing process |
CN104889419A (en) * | 2015-05-18 | 2015-09-09 | 湖州品创孵化器有限公司 | Biological synthesis method for spherical silver nanoparticle |
CN105239413A (en) * | 2015-11-12 | 2016-01-13 | 长兴千尺度纺织品有限公司 | Application of ecological auxiliary in finishing of cashmere sweater |
CN105455263A (en) * | 2015-11-13 | 2016-04-06 | 长兴华海纺织有限公司 | Anti-pilling and antibacterial woolen sweater |
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Application publication date: 20161214 |