CN106223011A - A kind of real silk softness crease-shedding finishing agent and preparation method thereof - Google Patents
A kind of real silk softness crease-shedding finishing agent and preparation method thereof Download PDFInfo
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- CN106223011A CN106223011A CN201610719286.8A CN201610719286A CN106223011A CN 106223011 A CN106223011 A CN 106223011A CN 201610719286 A CN201610719286 A CN 201610719286A CN 106223011 A CN106223011 A CN 106223011A
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
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- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
The invention provides a kind of real silk softness crease-shedding finishing agent and preparation method thereof.Preparation method is as follows: (1) is by tartaric acid, citric acid, pungent capramidopropyl betaine, sorbitan trioleate, sodium hypophosphite, Polyethylene Glycol, water, stirring at normal temperature 30 60 minutes；(2) sodium hydroxide is added regulation pH in above-mentioned solution, stirs 10 20 minutes；(3) acylamidopropyldimethyl tertiary amine, N cocoyl L glutamic acid triethanolamine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether are added in above-mentioned solution; at temperature is 20 60 DEG C, supersonic oscillations 20 40 minutes, obtain finishing agent.The soft anti-wrinkle agent of the present invention is nontoxic and the binding strength of fabric is high, intensity fastness, good hand touch to fabric after arrangement.
Description
Technical field
The present invention relates to the soft crease-resistant field of real silk fabric, be specifically related to a kind of real silk softness crease-shedding finishing agent and preparation thereof
Method.
Background technology
Real silk fabric has that gloss is soft, feel is smooth, plentiful slim and graceful feature and the scroop of uniqueness, not only takes attractive in appearance
Comfortable, and there is plurality of health care functions.But, its resilience is poor, and wet crease recovery angle is little, daily washing and in taking easily
Wrinkling deformation, causes inconvenience.At present crease-resistant many on fabric are realized by anti-wrinkle agent, but more or less exist
Shortcoming.Typically after adding anti-wrinkle agent, its resistance to persistence is poor, and feel is poor, but the interpolation of silicone softening agent can make real silk
Slippage, Tear strength declines.Also need to further study and improve it is thus desirable to reach preferable state.At present, anti-wrinkle agent
It is broadly divided into the big class of " low formaldehyde " and " formaldehydeless " two: the former mostly is modified resin, is main product in the market, arranges
Rear fabric anti-wrinkle effect is good, but because of its release formaldehyde during depositing and using, has been not suitable with the development of current ecological textile
Requirement.In recent years, formaldehydeless class anti-wrinkle agent is just becoming the research emphasis of anti-wrinkle agent.In actual applications, find this kind of crease-resistant
Agent can cause the crease-resistant persistency of real silk fabric poor, and Boardy Feeling easily causes real silk slippage.Mechanical properties decrease.It is therefore desirable to
Exploitation has durable anti-wrinkle effect and ensures the soft crease-shedding finishing agent of real silk fabric feel and mechanical property.
Summary of the invention
Solving the technical problem that: it is an object of the invention to provide a kind of real silk softness crease-shedding finishing agent, this real silk is soft
Anti-wrinkle agent finishing agent molecule occurs between effective active group and cocoon fiber macromole chemical reaction, stops fiber macromole
Between sliding, thus while reaching to improve the pliability of silk broadcloth, strength does not decline, and has good anti-wrinkle effect
Purpose, this softness anti-wrinkle agent is nontoxic and the binding strength of fabric is high, intensity fastness, good hand touch to fabric after arrangement.
Technical scheme: a kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: tartaric acid 10-
20 parts, citric acid 5-15 part, pungent capramidopropyl betaine 7-15 part, sorbitan trioleate 3-8 part, ortho phosphorous acid
Sodium 10-15 part, Polyethylene Glycol 5-10 part, acylamidopropyldimethyl tertiary amine 15-30 part, N-cocoyl-Pidolidone
Triethanolamine 3-8 part, amino-modified silicone softening agent 10-20 part, fatty alcohol-polyoxyethylene ether 3-5 part, water 10-20 part, hydrogen
Sodium oxide 0.05-0.1 part.
It is further preferred that described a kind of real silk softness crease-shedding finishing agent, following component it is prepared from by weight:
Tartaric acid 12-18 part, citric acid 8-12 part, pungent capramidopropyl betaine 9-12 part, sorbitan trioleate 5-7
Part, sodium hypophosphite 11-14 part, Polyethylene Glycol 6-8 part, acylamidopropyldimethyl tertiary amine 18-25 part, N-cocos nucifera oil acyl
Base-Pidolidone triethanolamine 5-7 part, amino-modified silicone softening agent 14-18 part, fatty alcohol-polyoxyethylene ether 4-5 part, water
12-16 part, sodium hydroxide 0.05-0.08 part.
The preparation method of above-mentioned soft crease-shedding finishing agent comprises the following steps:
(1) tartaric acid, citric acid, pungent capramidopropyl betaine, sorbitan trioleate, sodium hypophosphite are protected
Protect agent, Polyethylene Glycol, water, stirring at normal temperature 30-60 minute；
(2) sodium hydroxide is added regulation pH in above-mentioned solution, stirs 10-20 minute；
(3) acylamidopropyldimethyl tertiary amine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether are added
State in solution, supersonic oscillations 20-40 minute at temperature is 20-60 DEG C, obtain finishing agent.
Further, the preparation method of described a kind of real silk softness crease-shedding finishing agent, in described step (1) during stirring
Between be 40-50 minute.
Further, the preparation method of described a kind of real silk softness crease-shedding finishing agent, in described step (2) during stirring
Between be 15-20 minute.
Further, the preparation method of described a kind of real silk softness crease-shedding finishing agent, ultrasound wave in described step (3)
The temperature of vibration is 30-40 DEG C, and the time is 30 minutes.
Beneficial effect: a kind of real silk softness crease-shedding finishing agent of the present invention has good wrinkle resistance, fabric washing 30 times
After, creasy recovery angle the most significantly reduces, and is 286 ° before washing, is 278 ° after washing；There is good feel simultaneously, and protect
Card has higher strength, wherein warp-wise strength 589N, broadwise strength 518N.
Detailed description of the invention
Embodiment 1
A kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: 10 parts of tartaric acid, citric acid 5 parts, pungent
Capramidopropyl betaine 15 parts, sorbitan trioleate 8 parts, sodium hypophosphite 15 parts, Polyethylene Glycol 10 parts, cocos nucifera oil
Amidopropyl dimethyl tertiary amine 15 parts, N-cocoyl-Pidolidone triethanolamine 3 parts, amino-modified silicone softening agent
10 parts, fatty alcohol-polyoxyethylene ether 5 parts, 10 parts of water, sodium hydroxide 0.1 part.
The preparation method of above-mentioned real silk softness crease-shedding finishing agent is: (1) is by tartaric acid, citric acid, pungent capramidopropyl
Glycine betaine, sorbitan trioleate sodium hypophosphite protective agent, Polyethylene Glycol, water, stirring at normal temperature 30 minutes；(2) by hydrogen
Sodium oxide adds regulation pH in above-mentioned solution, and mixing time is 10 minutes；(3) by acylamidopropyldimethyl tertiary amine, N-
Cocoyl-Pidolidone triethanolamine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether add above-mentioned solution
In, at temperature is 20 DEG C, supersonic oscillations 20 minutes, obtain finishing agent.
Embodiment 2
A kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: 20 parts of tartaric acid, citric acid 15 parts,
Pungent capramidopropyl betaine 7 parts, sorbitan trioleate 3 parts, sodium hypophosphite 10 parts, Polyethylene Glycol 5 parts, cocos nucifera oil
Amidopropyl dimethyl tertiary amine 30 parts, N-cocoyl-Pidolidone triethanolamine 8 parts, amino-modified silicone softening agent
20 parts, fatty alcohol-polyoxyethylene ether 3 parts, 20 parts of water, sodium hydroxide 0.05 part.
The preparation method of above-mentioned real silk softness crease-shedding finishing agent is: (1) is by tartaric acid, citric acid, pungent capramidopropyl
Glycine betaine, sorbitan trioleate, sodium hypophosphite protective agent, Polyethylene Glycol, water, stirring at normal temperature 60 minutes；(2) by hydrogen
Sodium oxide adds regulation pH in above-mentioned solution, and mixing time is 20 minutes；(3) by acylamidopropyldimethyl tertiary amine, N-
Cocoyl-Pidolidone triethanolamine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether add above-mentioned solution
In, at temperature is 60 DEG C, supersonic oscillations 40 minutes, obtain finishing agent.
Embodiment 3
A kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: 12 parts of tartaric acid, citric acid 12 parts,
Pungent capramidopropyl betaine 9 parts, sorbitan trioleate 5 parts, sodium hypophosphite 11 parts, Polyethylene Glycol 6 parts, cocos nucifera oil
Amidopropyl dimethyl tertiary amine 18 parts, N-cocoyl-Pidolidone triethanolamine 7 parts, amino-modified silicone softening agent
18 parts, fatty alcohol-polyoxyethylene ether 4 parts, 16 parts of water, sodium hydroxide 0.08 part.
The preparation method of above-mentioned real silk softness crease-shedding finishing agent is: (1) is by tartaric acid, citric acid, pungent capramidopropyl
Glycine betaine, sorbitan trioleate, sodium hypophosphite protective agent, Polyethylene Glycol, water, stirring at normal temperature 40 minutes；(2) by hydrogen
Sodium oxide adds regulation pH in above-mentioned solution, and mixing time is 15 minutes；(3) by acylamidopropyldimethyl tertiary amine, N-
Cocoyl-Pidolidone triethanolamine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether add above-mentioned solution
In, at temperature is 30 DEG C, supersonic oscillations 30 minutes, obtain finishing agent.
Embodiment 4
A kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: 18 parts of tartaric acid, citric acid 8 parts, pungent
Capramidopropyl betaine 12 parts, sorbitan trioleate 7 parts, sodium hypophosphite 14 parts, Polyethylene Glycol 8 parts, cocos nucifera oil
Amidopropyl dimethyl tertiary amine 25 parts, N-cocoyl-Pidolidone triethanolamine 5 parts, amino-modified silicone softening agent
14 parts, fatty alcohol-polyoxyethylene ether 5 parts, 12 parts of water, sodium hydroxide 0.05 part.
The preparation method of above-mentioned real silk softness crease-shedding finishing agent is: (1) is by tartaric acid, citric acid, pungent capramidopropyl
Glycine betaine, sorbitan trioleate, sodium hypophosphite protective agent, Polyethylene Glycol, water, stirring at normal temperature 40 minutes；(2) by hydrogen
Sodium oxide adds regulation pH in above-mentioned solution, and mixing time is 20 minutes；(3) by acylamidopropyldimethyl tertiary amine, N-
Cocoyl-Pidolidone triethanolamine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether add above-mentioned solution
In, at temperature is 40 DEG C, supersonic oscillations 30 minutes, obtain finishing agent.
Embodiment 5
A kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: 15 parts of tartaric acid, citric acid 10 parts,
Pungent capramidopropyl betaine 10 parts, sorbitan trioleate 6 parts, sodium hypophosphite 13 parts, Polyethylene Glycol 7 parts, coconut palm
Oleamidopropyl dimethyl tertiary amine 22 parts, N-cocoyl-Pidolidone triethanolamine 6 parts, amino-modified silicone are soft
Agent 16 parts, fatty alcohol-polyoxyethylene ether 4.5 parts, 14 parts of water, sodium hydroxide 0.06 part.
The preparation method of above-mentioned real silk softness crease-shedding finishing agent is: (1) is by tartaric acid, citric acid, pungent capramidopropyl
Glycine betaine, sorbitan trioleate, sodium hypophosphite protective agent, Polyethylene Glycol, water, stirring at normal temperature 40 minutes；(2) by hydrogen
Sodium oxide adds regulation pH in above-mentioned solution, and mixing time is 18 minutes；(3) by acylamidopropyldimethyl tertiary amine, N-
Cocoyl-Pidolidone triethanolamine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether add above-mentioned solution
In, at temperature is 40 DEG C, supersonic oscillations 30 minutes, obtain finishing agent.
Comparative example 1
A kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: 10 parts of tartaric acid, citric acid 5 parts, secondary
Sodium phosphite 15 parts, Polyethylene Glycol 10 parts, acylamidopropyldimethyl tertiary amine 15 parts, N-cocoyl-Pidolidone three
Ethanolamine 3 parts, amino-modified silicone softening agent 10 parts, fatty alcohol-polyoxyethylene ether 5 parts, 10 parts of water, sodium hydroxide 0.1 part.
The preparation method of above-mentioned real silk softness crease-shedding finishing agent is: (1) is by tartaric acid, citric acid, sodium hypophosphite protection
Agent, Polyethylene Glycol, water, stirring at normal temperature 30 minutes；(2) sodium hydroxide adds regulation pH in above-mentioned solution, and mixing time is 10
Minute；(3) acylamidopropyldimethyl tertiary amine, amino-modified silicone softening agent, fatty alcohol-polyoxyethylene ether are added
In above-mentioned solution, at temperature is 20 DEG C, supersonic oscillations 20 minutes, obtain finishing agent.
Comparative example 2
A kind of real silk softness crease-shedding finishing agent, is prepared from by weight by following component: 10 parts of tartaric acid, citric acid 5 parts, pungent
Capramidopropyl betaine 15 parts, sorbitan trioleate 8 parts, sodium hypophosphite 15 parts, Polyethylene Glycol 10 parts, amino
Modified organic silicon softening agent 10 parts, fatty alcohol-polyoxyethylene ether 5 parts, 10 parts of water, sodium hydroxide 0.1 part.
The preparation method of above-mentioned real silk softness crease-shedding finishing agent is: (1) is by tartaric acid, citric acid, pungent capramidopropyl
Glycine betaine, sorbitan trioleate, sodium hypophosphite protective agent, Polyethylene Glycol, water, stirring at normal temperature 30 minutes；(2) by hydrogen
Sodium oxide adds regulation pH in above-mentioned solution, and mixing time is 10 minutes；(3) by amino-modified silicone softening agent, fatty alcohol
Polyoxyethylene ether adds in above-mentioned solution, and at temperature is 20 DEG C, supersonic oscillations 20 minutes, obtain finishing agent.
The property indices of material of the present invention see table, it may be seen that process real silk with this softness crease-shedding finishing agent
Fabric has good wrinkle resistance, and after washing 30 times, creasy recovery angle the most significantly reduces, and is 286 °, after washing before washing
It it is 278 °；There is good feel simultaneously, and ensure to have higher strength, wherein warp-wise strength 589N, broadwise strength 518N.
The soft anti-wrinkle agent of table 1 processes the property indices after real silk fabric
Note: experiment real silk fabric is plain cloth.
Claims (6)
1. a real silk softness crease-shedding finishing agent, it is characterised in that be prepared from by weight by following component: tartaric acid 10-
20 parts, citric acid 5-15 part, pungent capramidopropyl betaine 7-15 part, sorbitan trioleate 3-8 part, ortho phosphorous acid
Sodium 10-15 part, Polyethylene Glycol 5-10 part, acylamidopropyldimethyl tertiary amine 15-30 part, N-cocoyl-Pidolidone
Triethanolamine 3-8 part, amino-modified silicone softening agent 10-20 part, fatty alcohol-polyoxyethylene ether 3-5 part, water 10-20 part, hydrogen
Sodium oxide 0.05-0.1 part.
A kind of real silk softness crease-shedding finishing agent the most according to claim 1, it is characterised in that by following component by weight
It is prepared from: tartaric acid 12-18 part, citric acid 8-12 part, pungent capramidopropyl betaine 9-12 part, anhydrous sorbitol three oil
Acid esters 5-7 part, sodium hypophosphite 11-14 part, Polyethylene Glycol 6-8 part, acylamidopropyldimethyl tertiary amine 18-25 part, N-
Cocoyl-Pidolidone triethanolamine 5-7 part, amino-modified silicone softening agent 14-18 part, fatty alcohol-polyoxyethylene ether 4-
5 parts, water 12-16 part, sodium hydroxide 0.05-0.08 part.
3. the preparation method of a real silk softness crease-shedding finishing agent is as follows, it is characterised in that comprise the following steps:
(1) by tartaric acid, citric acid, pungent capramidopropyl betaine, sorbitan trioleate, sodium hypophosphite, gather
Ethylene glycol, water, stirring at normal temperature 30-60 minute；
(2) sodium hydroxide is added regulation pH in above-mentioned solution, stirs 10-20 minute；
(3) by acylamidopropyldimethyl tertiary amine, N-cocoyl-Pidolidone triethanolamine, amino-modified silicone
Softening agent, fatty alcohol-polyoxyethylene ether add in above-mentioned solution, supersonic oscillations 20-40 minute at temperature is 20-60 DEG C,
To finishing agent.
The preparation method of a kind of real silk softness crease-shedding finishing agent the most according to claim 3, it is characterised in that: described step
(1) mixing time in is 40-50 minute.
The preparation method of a kind of real silk softness crease-shedding finishing agent the most according to claim 3, it is characterised in that: described step
(2) in, mixing time is 15-20 minute.
The preparation method of a kind of real silk softness crease-shedding finishing agent the most according to claim 3, it is characterised in that: described step
(3) in, the temperature of supersonic oscillations is 30-40 DEG C, and the time is 30 minutes.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107119454A (en) * | 2017-05-11 | 2017-09-01 | 江苏银桥纺织科技有限公司 | A kind of real silk fabric anti-crease finishing technique |
| CN107326673A (en) * | 2017-07-31 | 2017-11-07 | 苏州井村服饰有限公司 | A kind of garment material environmentally friendly crease-shedding finishing agent and preparation method thereof |
| CN107761373A (en) * | 2017-11-27 | 2018-03-06 | 无锡昊瑜节能环保设备有限公司 | A kind of real silk fabric soft finish technique |
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| CN107119454A (en) * | 2017-05-11 | 2017-09-01 | 江苏银桥纺织科技有限公司 | A kind of real silk fabric anti-crease finishing technique |
| CN107326673A (en) * | 2017-07-31 | 2017-11-07 | 苏州井村服饰有限公司 | A kind of garment material environmentally friendly crease-shedding finishing agent and preparation method thereof |
| CN107761373A (en) * | 2017-11-27 | 2018-03-06 | 无锡昊瑜节能环保设备有限公司 | A kind of real silk fabric soft finish technique |
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