CN106221731B - A kind of demulsifier - Google Patents

A kind of demulsifier Download PDF

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Publication number
CN106221731B
CN106221731B CN201610765600.6A CN201610765600A CN106221731B CN 106221731 B CN106221731 B CN 106221731B CN 201610765600 A CN201610765600 A CN 201610765600A CN 106221731 B CN106221731 B CN 106221731B
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Prior art keywords
parts
weight ratio
component
demulsifier
oil
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CN201610765600.6A
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CN106221731A (en
Inventor
吴朋至
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Jiangsu Three And Pro-Environment Group Co Ltd
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Jiangsu Three And Pro-Environment Group Co Ltd
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Priority to CN201610765600.6A priority Critical patent/CN106221731B/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00Dewatering or demulsification of hydrocarbon oils
    • C10G33/04Dewatering or demulsification of hydrocarbon oils with chemical means

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Epoxy Resins (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

The present invention relates to a kind of demulsifiers, belong to sewage treatment drug field.Including 50 100 parts of triethanolamine, 45 85 parts of polyoxypropylene, 10 60 parts of sodium hydroxide, 50 75 parts of sodium phosphate, 100 120 parts of castor oil, 0 30 parts of methanol, 300 400 parts of propylene oxide, 200 350 parts of ethylene oxide, 300 400 parts of glacial acetic acid, 200 400 parts of water.Compared with prior art, adaptable strong, efficient, the uncorruptible feature of demulsification of the present invention.

Description

A kind of demulsifier
Technical field
The present invention relates to sewage treatment drug, more particularly to a kind of demulsifier.
Background technology
With the development of World Oil Industry, oil extraction increasingly increases so that and crude oil emulsion liquid measure increasingly increases, After water filling intensified oil reduction, water content in crude oil obviously increases, and most of crude oil is exploited in the form of water-oil emulsion Out.Contain a large amount of water and inorganic salts in crude oil Produced Liquid, great difficulty is brought to oil-gas gathering and transportation and crude refining, because This must be dehydrated, desalination.To solve the problem during oil-gas gathering and transportation, it is necessary to a large amount of chemical agent is used, in oil Chemicals used in the process of gas collection is defeated is known as oil-gas gathering and transportation chemicals, it is important one of oil field chemical, mainly has Demulsifier, corrosion inhibiter, drag reducer, emulsifier etc..But existing demulsifier on the market exists to crude oil bad adaptability, breaks Newborn efficiency is low, easily leads to the problems such as corrosion.
Invention content
The technical problems to be solved by the invention:In view of the deficiencies of the prior art and defect, the present invention provide a kind of adaptation Property strong, efficient, the uncorruptible demulsifier of demulsification.
What the present invention was designed so as to:A kind of demulsifier, it is characterised in that:The weight ratio of each component is:Triethanolamine 50- 100 parts, 45-85 parts of polyoxypropylene, 10-60 parts of sodium hydroxide, 50-75 parts of sodium phosphate, 100-120 parts of castor oil, methanol 0-30 Part, 300-400 parts of propylene oxide, 200-350 parts of ethylene oxide, 300-400 parts of glacial acetic acid, 200-400 parts of water.
Weight ratio of the triethanolamine in each component is 95-98 parts.
Weight ratio of the polyoxypropylene in each component is 75-78 parts.
Weight ratio of the sodium hydroxide in each component is 22-25 parts.
Weight ratio of the sodium phosphate in each component is 60-63 parts.
Weight ratio of the castor oil in each component is 102 parts.
Weight ratio of the methanol in each component is 12 parts.
The propylene oxide, weight ratio of the ethylene oxide in each component are 250-260 parts.
By above-mentioned design scheme, the present invention can bring following advantageous effect:
Demulsifier provided by the invention includes triethanolamine, polyoxypropylene, sodium hydroxide, sodium phosphate, castor oil, first Alcohol, propylene oxide, ethylene oxide, glacial acetic acid, water can be rapidly dispersed into crude oil, have good demulsification to crude oil emulsion Performance.Meanwhile the demulsifier dewatering speed is fast, dehydration rate is high, water phase oil content is low, can cope with various crude oil, emulsion Processing, has a wide range of application.
Specific implementation mode
The invention will be further described below.
Embodiment 1:
The weight ratio of a kind of demulsifier, each component is:75 parts of triethanolamine, 65 parts of polyoxypropylene, 45 parts of sodium hydroxide, phosphorus 60 parts of sour sodium, 110 parts of castor oil, 5 parts of methanol, 320 parts of propylene oxide, 250 parts of ethylene oxide, 315 parts of glacial acetic acid, 240 parts of water.
Embodiment 2:
The weight ratio of a kind of demulsifier, each component is:82 parts of triethanolamine, 68 parts of polyoxypropylene, 43 parts of sodium hydroxide, phosphorus 65 parts of sour sodium, 117 parts of castor oil, 25 parts of methanol, 305 parts of propylene oxide, 357 parts of ethylene oxide, 245 parts of glacial acetic acid, water 358 Part.
Embodiment 3:
The weight ratio of a kind of demulsifier, each component is:75 parts of triethanolamine, 85 parts of polyoxypropylene, 60 parts of sodium hydroxide, phosphorus 75 parts of sour sodium, 120 parts of castor oil, 30 parts of methanol, 400 parts of propylene oxide, 350 parts of ethylene oxide, 400 parts of glacial acetic acid, water 400 Part.
Embodiment 4:
The weight ratio of a kind of demulsifier, each component is:96 parts of triethanolamine, 78 parts of polyoxypropylene, 25 parts of sodium hydroxide, phosphorus 63 parts of sour sodium, 102 parts of castor oil, 12 parts of methanol, 260 parts of propylene oxide, 260 parts of ethylene oxide, 400 parts of glacial acetic acid, water 300 Part.
Embodiment 5:
The weight ratio of a kind of demulsifier, each component is:95 parts of triethanolamine, 75 parts of polyoxypropylene, 22 parts of sodium hydroxide, phosphorus 60 parts of sour sodium, 102 parts of castor oil, 12 parts of methanol, 250 parts of propylene oxide, 250 parts of ethylene oxide, 300 parts of glacial acetic acid, water 200 Part.

Claims (7)

1. a kind of demulsifier, it is characterised in that:The weight ratio of each component is:50-100 parts of triethanolamine, polyoxypropylene 45-85 Part, 10-60 parts of sodium hydroxide, 50-75 parts of sodium phosphate, 100-120 parts of castor oil, 0-30 parts of methanol, propylene oxide 300-400 Part, 200-350 parts of ethylene oxide, 300-400 parts of glacial acetic acid, 200-400 parts of water.
2. demulsifier according to claim 1, it is characterised in that:Weight ratio of the triethanolamine in each component be 95-98 parts.
3. demulsifier according to claim 1, it is characterised in that:Weight ratio of the polyoxypropylene in each component be 75-78 parts.
4. demulsifier according to claim 1, it is characterised in that:Weight ratio of the sodium hydroxide in each component be 22-25 parts.
5. demulsifier according to claim 1, it is characterised in that:Weight ratio of the sodium phosphate in each component be 60-63 parts.
6. demulsifier according to claim 1, it is characterised in that:Weight ratio of the castor oil in each component be 102 parts.
7. demulsifier according to claim 1, it is characterised in that:Weight ratio of the methanol in each component is 12 Part.
CN201610765600.6A 2016-08-30 2016-08-30 A kind of demulsifier Active CN106221731B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610765600.6A CN106221731B (en) 2016-08-30 2016-08-30 A kind of demulsifier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610765600.6A CN106221731B (en) 2016-08-30 2016-08-30 A kind of demulsifier

Publications (2)

Publication Number Publication Date
CN106221731A CN106221731A (en) 2016-12-14
CN106221731B true CN106221731B (en) 2018-08-21

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777470A (en) * 2017-11-15 2019-05-21 柳州市皇盛环保科技有限公司 A kind of oil-sludge treatment demulsifier
CN115584278A (en) * 2021-07-06 2023-01-10 北京中科润金环保工程股份有限公司 Special low-temperature environment-friendly anti-corrosive demulsifier for aging oil
CN115838606A (en) * 2022-12-23 2023-03-24 天津市正方科技发展有限公司 Treatment method of viscous aging oil

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2154090C1 (en) * 1999-07-08 2000-08-10 Открытое акционерное общество "Научно-исследовательский институт по нефтепромысловой химии" Method of preparing demulsifier for dehydration and desalting of crude oil
CN101100615B (en) * 2007-07-31 2010-06-30 中国石油天然气股份有限公司 Low-temperature demulsifying agent and preparation method thereof
CN102807890A (en) * 2012-08-31 2012-12-05 句容宁武高新技术发展有限公司 Method for preparing demulsifier

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PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: A demulsifier

Effective date of registration: 20221130

Granted publication date: 20180821

Pledgee: Bank of China Limited Yixing branch

Pledgor: JIANGSU SANHE E.P. GROUP CO.,LTD.

Registration number: Y2022980024126

PE01 Entry into force of the registration of the contract for pledge of patent right