CN106221731A - A kind of demulsifier - Google Patents

A kind of demulsifier Download PDF

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Publication number
CN106221731A
CN106221731A CN201610765600.6A CN201610765600A CN106221731A CN 106221731 A CN106221731 A CN 106221731A CN 201610765600 A CN201610765600 A CN 201610765600A CN 106221731 A CN106221731 A CN 106221731A
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CN
China
Prior art keywords
parts
demulsifier
weight ratio
component
oxirane
Prior art date
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Granted
Application number
CN201610765600.6A
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Chinese (zh)
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CN106221731B (en
Inventor
吴朋至
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Three And Pro-Environment Group Co Ltd
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Jiangsu Three And Pro-Environment Group Co Ltd
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Priority to CN201610765600.6A priority Critical patent/CN106221731B/en
Publication of CN106221731A publication Critical patent/CN106221731A/en
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Publication of CN106221731B publication Critical patent/CN106221731B/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G33/00Dewatering or demulsification of hydrocarbon oils
    • C10G33/04Dewatering or demulsification of hydrocarbon oils with chemical means

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Epoxy Resins (AREA)

Abstract

The present invention relates to a kind of demulsifier, belong to sewage treatment drug field.Including triethanolamine 50 100 parts, polyoxypropylene 45 85 parts, sodium hydroxide 10 60 parts, sodium phosphate 50 75 parts, Oleum Ricini 100 120 parts, methanol 0 30 parts, expoxy propane 300 400 parts, 200 350 parts of oxirane, 300 400 parts of glacial acetic acid, 200 400 parts of water.Compared to existing technology, the present invention has strong adaptability, breakdown of emulsion efficiency feature high, uncorruptible.

Description

A kind of demulsifier
Technical field
The present invention relates to sewage treatment drug, particularly to a kind of demulsifier.
Background technology
Along with the development of World Oil Industry, oil extraction increases day by day so that crude oil emulsion liquid measure increases day by day, After water filling intensified oil reduction, water content in crude oil substantially increases, and major part crude oil is to exploit with water-oil emulsion form Out.Containing substantial amounts of water and inorganic salt in crude oil Produced Liquid, bring great difficulty to oil-gas gathering and transportation and crude refining, because of This must carry out being dehydrated, desalination.For produced problem during solution oil-gas gathering and transportation, it is necessary to use substantial amounts of chemical agent, at oil Chemicals used in the process of gas collection is defeated is referred to as oil-gas gathering and transportation chemicals, and it is one of important oil field chemical, and it mainly has Demulsifier, corrosion inhibiter, drag reducer, emulsifying agent etc..But, existing demulsifier on the market exists crude oil bad adaptability, breaks Efficiency is low, be easily caused the problems such as corrosion for breast.
Summary of the invention
The technical problem to be solved: for shortcomings and deficiencies of the prior art, the present invention provides a kind of adaptation Property strong, breakdown of emulsion efficiency demulsifier high, uncorruptible.
The present invention is designed such that a kind of demulsifier, it is characterised in that: the weight ratio of each component is: triethanolamine 50- 100 parts, polyoxypropylene 45-85 part, sodium hydroxide 10-60 part, sodium phosphate 50-75 part, Oleum Ricini 100-120 part, methanol 0-30 Part, expoxy propane 300-400 part, oxirane 200-350 part, glacial acetic acid 300-400 part, water 200-400 part.
Described triethanolamine weight ratio in each component is 95-98 part.
Described polyoxypropylene weight ratio in each component is 75-78 part.
Described sodium hydroxide weight ratio in each component is 22-25 part.
Described sodium phosphate weight ratio in each component is 60-63 part.
Described Oleum Ricini weight ratio in each component is 102 parts.
Described methanol weight ratio in each component is 12 parts.
Described expoxy propane, oxirane weight ratio in each component are 250-260 part.
By above-mentioned design, the present invention can bring following beneficial effect:
The demulsifier that the present invention provides includes triethanolamine, polyoxypropylene, sodium hydroxide, sodium phosphate, Oleum Ricini, first Alcohol, expoxy propane, oxirane, glacial acetic acid, water, can be rapidly dispersed in crude oil, has good breakdown of emulsion to crude oil emulsion Performance.Meanwhile, demulsifier dewatering speed is fast, dehydration rate is high for this, aqueous phase oil content is low, can tackle various crude oil, emulsion Process, applied range.
Detailed description of the invention
The invention will be further described below.
Embodiment 1:
A kind of demulsifier, the weight ratio of each component is: triethanolamine 75 parts, polyoxypropylene 65 parts, sodium hydroxide 45 parts, phosphorus Acid 60 parts of sodium, Oleum Ricini 110 parts, methanol 5 parts, expoxy propane 320 parts, 250 parts of oxirane, 315 parts of glacial acetic acid, 240 parts of water.
Embodiment 2:
A kind of demulsifier, the weight ratio of each component is: triethanolamine 82 parts, polyoxypropylene 68 parts, sodium hydroxide 43 parts, phosphorus Acid 65 parts of sodium, Oleum Ricini 117 parts, methanol 25 parts, expoxy propane 305 parts, 357 parts of oxirane, 245 parts of glacial acetic acid, water 358 Part.
Embodiment 3:
A kind of demulsifier, the weight ratio of each component is: triethanolamine 75 parts, polyoxypropylene 85 parts, sodium hydroxide 60 parts, phosphorus Acid 75 parts of sodium, Oleum Ricini 120 parts, methanol 30 parts, expoxy propane 400 parts, 350 parts of oxirane, 400 parts of glacial acetic acid, water 400 Part.
Embodiment 4:
A kind of demulsifier, the weight ratio of each component is: triethanolamine 96 parts, polyoxypropylene 78 parts, sodium hydroxide 25 parts, phosphorus Acid 63 parts of sodium, Oleum Ricini 102 parts, methanol 12 parts, expoxy propane 260 parts, 260 parts of oxirane, 400 parts of glacial acetic acid, water 300 Part.
Embodiment 5:
A kind of demulsifier, the weight ratio of each component is: triethanolamine 95 parts, polyoxypropylene 75 parts, sodium hydroxide 22 parts, phosphorus Acid 60 parts of sodium, Oleum Ricini 102 parts, methanol 12 parts, expoxy propane 250 parts, 250 parts of oxirane, 300 parts of glacial acetic acid, water 200 Part.

Claims (8)

1. a demulsifier, it is characterised in that: the weight ratio of each component is: triethanolamine 50-100 part, polyoxypropylene 45-85 Part, sodium hydroxide 10-60 part, sodium phosphate 50-75 part, Oleum Ricini 100-120 part, methanol 0-30 part, expoxy propane 300-400 Part, oxirane 200-350 part, glacial acetic acid 300-400 part, water 200-400 part.
Demulsifier the most according to claim 1, it is characterised in that: described triethanolamine weight ratio in each component is 95-98 part.
Demulsifier the most according to claim 1, it is characterised in that: described polyoxypropylene weight ratio in each component is 75-78 part.
Demulsifier the most according to claim 1, it is characterised in that: described sodium hydroxide weight ratio in each component is 22-25 part.
Demulsifier the most according to claim 1, it is characterised in that: described sodium phosphate weight ratio in each component is 60-63 part.
Demulsifier the most according to claim 1, it is characterised in that: described Oleum Ricini weight ratio in each component is 102 parts.
Demulsifier the most according to claim 1, it is characterised in that: described methanol weight ratio in each component is 12 Part.
Demulsifier the most according to claim 1, it is characterised in that: described expoxy propane, oxirane are in each component Weight ratio be 250-260 part.
CN201610765600.6A 2016-08-30 2016-08-30 A kind of demulsifier Active CN106221731B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610765600.6A CN106221731B (en) 2016-08-30 2016-08-30 A kind of demulsifier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610765600.6A CN106221731B (en) 2016-08-30 2016-08-30 A kind of demulsifier

Publications (2)

Publication Number Publication Date
CN106221731A true CN106221731A (en) 2016-12-14
CN106221731B CN106221731B (en) 2018-08-21

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Country Status (1)

Country Link
CN (1) CN106221731B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777470A (en) * 2017-11-15 2019-05-21 柳州市皇盛环保科技有限公司 A kind of oil-sludge treatment demulsifier
CN115584278A (en) * 2021-07-06 2023-01-10 北京中科润金环保工程股份有限公司 Special low-temperature environment-friendly anti-corrosive demulsifier for aging oil
CN115838606A (en) * 2022-12-23 2023-03-24 天津市正方科技发展有限公司 Treatment method of viscous aging oil

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2154090C1 (en) * 1999-07-08 2000-08-10 Открытое акционерное общество "Научно-исследовательский институт по нефтепромысловой химии" Method of preparing demulsifier for dehydration and desalting of crude oil
CN101100615A (en) * 2007-07-31 2008-01-09 中国石油天然气股份有限公司 Low-temperature demulsifying agent and preparation method thereof
CN102807890A (en) * 2012-08-31 2012-12-05 句容宁武高新技术发展有限公司 Method for preparing demulsifier

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2154090C1 (en) * 1999-07-08 2000-08-10 Открытое акционерное общество "Научно-исследовательский институт по нефтепромысловой химии" Method of preparing demulsifier for dehydration and desalting of crude oil
CN101100615A (en) * 2007-07-31 2008-01-09 中国石油天然气股份有限公司 Low-temperature demulsifying agent and preparation method thereof
CN102807890A (en) * 2012-08-31 2012-12-05 句容宁武高新技术发展有限公司 Method for preparing demulsifier

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109777470A (en) * 2017-11-15 2019-05-21 柳州市皇盛环保科技有限公司 A kind of oil-sludge treatment demulsifier
CN115584278A (en) * 2021-07-06 2023-01-10 北京中科润金环保工程股份有限公司 Special low-temperature environment-friendly anti-corrosive demulsifier for aging oil
CN115838606A (en) * 2022-12-23 2023-03-24 天津市正方科技发展有限公司 Treatment method of viscous aging oil

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Publication number Publication date
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Denomination of invention: A demulsifier

Effective date of registration: 20221130

Granted publication date: 20180821

Pledgee: Bank of China Limited Yixing branch

Pledgor: JIANGSU SANHE E.P. GROUP CO.,LTD.

Registration number: Y2022980024126