CN109777470A - A kind of oil-sludge treatment demulsifier - Google Patents

A kind of oil-sludge treatment demulsifier Download PDF

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Publication number
CN109777470A
CN109777470A CN201711131384.0A CN201711131384A CN109777470A CN 109777470 A CN109777470 A CN 109777470A CN 201711131384 A CN201711131384 A CN 201711131384A CN 109777470 A CN109777470 A CN 109777470A
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CN
China
Prior art keywords
parts
oil
demulsifier
sludge treatment
sodium
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Pending
Application number
CN201711131384.0A
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Chinese (zh)
Inventor
黄新才
黄茜菲
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Liuzhou Huang Sheng Environmental Protection Technology Co Ltd
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Liuzhou Huang Sheng Environmental Protection Technology Co Ltd
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Publication date
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Priority to CN201711131384.0A priority Critical patent/CN109777470A/en
Publication of CN109777470A publication Critical patent/CN109777470A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a kind of oil-sludge treatment demulsifiers, it by weight part include following components: 10-20 parts of sodium hydroxide, 10-20 parts of propylene oxide, 1-10 parts of triethanolamine, 1-10 parts of sodium phosphate, 5-15 parts of magnesium sulfate, 1-5 parts of toluene diisocyanate, 5-15 parts of oleic acid, 1-10 parts of sodium nitrite, 10-20 parts of polyoxyethylene ether, 1-5 parts of organic inhibitor.The raw material of product of the present invention is commercial product, and demulsifier demulsification obtained is high-efficient, and adaptability is extensive, and usage amount is few, and the temperature that is demulsified is low, is not required to added electric field, has the characteristics that small dosage, high treating effect, reduces operating cost.

Description

A kind of oil-sludge treatment demulsifier
Technical field
The invention belongs to chemical fields, and in particular to be a kind of oil-sludge treatment demulsifier.
Background technique
It is an important link in oil and gas industry oilfield exploitation procedure that Oil/Gas Pipe trace gather is defeated, to solve oil gas The problem during collecting defeated, it is necessary to use a large amount of chemical agent, chemicals used in the process of oil-gas gathering and transportation is known as oil The defeated chemicals of gas collection, it is important one of oil field chemical, mainly there is demulsifier, organic inhibitor, drag reducer, emulsifier Etc..The chemical agent that emulsification crude oil demulsification can be made to be dehydrated is crude oil demulsifier, since emulsified crude oil has Water-In-Oil emulsified crude oil With oil-in-water emulsified crude oil two types, therefore crude oil demulsifier also divides two types, i.e., water-in-oil emulsion crude oil demulsifier and Oil-in-water type cream people's crude oil demulsifier.Water-in-oil emulsion crude oil demulsifier has low molecular weight demulsifier and high molecular weight demulsifier, low Molecule demulsifier mainly has fatty acid salt, alkyl sulfate salt, alkylbenzene sulfonate, OP type surfactant etc., macromolecule Demulsifier mainly has polyoxyethylene sodium hydroxide alkyl alcohol ether, polyoxyethylene sodium hydroxide phenol-amine resin etc..Oil-in-water type emulsion It is former
Oily demulsifier mainly has hydrochloric acid, sodium chloride, magnesium chloride, calcium chloride, methanol etc..Existing demulsifier on the market exists to original Oily bad adaptability, easily leads to the problems such as corrosion at the low efficiency that is demulsified.
Summary of the invention
It is an object of the invention to overcome problem above of the existing technology, a kind of demulsifier is provided, is possessed good Demulsification system.
To realize above-mentioned technical purpose and the technique effect, the invention is realized by the following technical scheme:
A kind of oil-sludge treatment demulsifier includes following components by weight part: 10-20 parts of sodium hydroxide, propylene oxide 10-20 Part, it is 1-10 parts of triethanolamine, 1-10 parts of sodium phosphate, 5-15 parts of magnesium sulfate, 1-5 parts of toluene diisocyanate, 5-15 parts of oleic acid, sub- 1-10 parts of sodium nitrate, 10-20 parts of polyoxyethylene ether, 1-5 parts of organic inhibitor.
Preferably, by weight part include following components: 15 parts of sodium hydroxide, 16 parts of propylene oxide, triethanolamine 8 Part, 3 parts of sodium phosphate, 12 parts of magnesium sulfate, 2 parts of toluene diisocyanate, 7 parts of oleic acid, 2 parts of sodium nitrite, 16 parts of polyoxyethylene ether, 2 parts of organic inhibitor.
Preferably, the organic inhibitor is the one of phosphine carboxylic acid, coloured glaze base benzothiazole, benzotriazole or lignosulfonate Kind.
The beneficial effects of the present invention are:
The raw material of product of the present invention is commercial product, and demulsifier demulsification obtained is high-efficient, and adaptability is extensive, and usage amount is few, And demulsification temperature is low, is not required to added electric field, has the characteristics that small dosage, high treating effect, reduces operating cost.
Specific embodiment
Below in conjunction with embodiment, next the present invention will be described in detail.
Embodiment 1
Take 15 parts of sodium hydroxide, 16 parts of propylene oxide, 8 parts of triethanolamine, 3 parts of sodium phosphate, 12 parts of magnesium sulfate, toluene diisocynate 2 parts of rouge, 7 parts of oleic acid, 2 parts of sodium nitrite, 16 parts of polyoxyethylene ether, 2 parts of phosphine carboxylic acid, it is prepared into oil-sludge treatment demulsifier.
Embodiment 2
Take 12 parts of sodium hydroxide, 17 parts of propylene oxide, 3 parts of triethanolamine, 9 parts of sodium phosphate, 7 parts of magnesium sulfate, toluene diisocynate 4 parts of rouge, 6 parts of oleic acid, 8 parts of sodium nitrite, 11 parts of polyoxyethylene ether, 5 parts of coloured glaze base benzothiazole is prepared into oil-sludge treatment demulsification Agent.
Embodiment 3
18 parts of sodium hydroxide, 11 parts of propylene oxide, 4 parts of triethanolamine, 2 parts of sodium phosphate, 11 parts of magnesium sulfate, toluene diisocyanate 3 parts, 12 parts of oleic acid, 4 parts of sodium nitrite, 18 parts of polyoxyethylene ether, 3 parts of lignosulfonate, it is prepared into oil-sludge treatment demulsifier.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, for the skill of this field For art personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, made any to repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (3)

1. a kind of oil-sludge treatment demulsifier, which is characterized in that by weight part include following components: 10-20 parts of sodium hydroxide, 10-20 parts of propylene oxide, 1-10 parts of triethanolamine, 1-10 parts of sodium phosphate, 5-15 parts of magnesium sulfate, 1-5 parts of toluene diisocyanate, 5-15 parts of oleic acid, 1-10 parts of sodium nitrite, 10-20 parts of polyoxyethylene ether, 1-5 parts of organic inhibitor.
2. oil-sludge treatment demulsifier according to claim 1, which is characterized in that by weight part include following components: 15 parts of sodium hydroxide, 16 parts of propylene oxide, 8 parts of triethanolamine, 3 parts of sodium phosphate, 12 parts of magnesium sulfate, 2 parts of toluene diisocyanate, 7 parts of oleic acid, 2 parts of sodium nitrite, 16 parts of polyoxyethylene ether, 2 parts of organic inhibitor.
3. oil-sludge treatment demulsifier according to claim 1, it is characterised in that: the organic inhibitor is phosphine carboxylic acid, coloured glaze One kind of base benzothiazole, benzotriazole or lignosulfonate.
CN201711131384.0A 2017-11-15 2017-11-15 A kind of oil-sludge treatment demulsifier Pending CN109777470A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201711131384.0A CN109777470A (en) 2017-11-15 2017-11-15 A kind of oil-sludge treatment demulsifier

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711131384.0A CN109777470A (en) 2017-11-15 2017-11-15 A kind of oil-sludge treatment demulsifier

Publications (1)

Publication Number Publication Date
CN109777470A true CN109777470A (en) 2019-05-21

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111039629A (en) * 2019-10-08 2020-04-21 水利部交通运输部国家能源局南京水利科学研究院 Method for preparing artificial stone by using dredged sludge and rotary furnace bottom ash of iron and steel plant
CN115584278A (en) * 2021-07-06 2023-01-10 北京中科润金环保工程股份有限公司 Special low-temperature environment-friendly anti-corrosive demulsifier for aging oil

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851528A (en) * 2009-03-31 2010-10-06 中国石油化工股份有限公司 Method for deeply desalting hydrocarbon oil
CN104556297A (en) * 2015-01-28 2015-04-29 桑达化工(南通)有限公司 High-efficiency demulsifier
CN104593120A (en) * 2015-01-22 2015-05-06 南通恒隆化工有限公司 Demulsifier
CN105540933A (en) * 2016-01-27 2016-05-04 北京中石大能源技术服务有限公司 Method and system for rapid treatment of oil-water well return acidizing fluid
CN106221731A (en) * 2016-08-30 2016-12-14 江苏三和环保集团有限公司 A kind of demulsifier

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851528A (en) * 2009-03-31 2010-10-06 中国石油化工股份有限公司 Method for deeply desalting hydrocarbon oil
CN104593120A (en) * 2015-01-22 2015-05-06 南通恒隆化工有限公司 Demulsifier
CN104556297A (en) * 2015-01-28 2015-04-29 桑达化工(南通)有限公司 High-efficiency demulsifier
CN105540933A (en) * 2016-01-27 2016-05-04 北京中石大能源技术服务有限公司 Method and system for rapid treatment of oil-water well return acidizing fluid
CN106221731A (en) * 2016-08-30 2016-12-14 江苏三和环保集团有限公司 A kind of demulsifier

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111039629A (en) * 2019-10-08 2020-04-21 水利部交通运输部国家能源局南京水利科学研究院 Method for preparing artificial stone by using dredged sludge and rotary furnace bottom ash of iron and steel plant
CN111039629B (en) * 2019-10-08 2021-08-17 水利部交通运输部国家能源局南京水利科学研究院 Method for preparing artificial stone by using dredged sludge and rotary furnace bottom ash of iron and steel plant
CN115584278A (en) * 2021-07-06 2023-01-10 北京中科润金环保工程股份有限公司 Special low-temperature environment-friendly anti-corrosive demulsifier for aging oil

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Application publication date: 20190521