CN106221630B - A kind of adhesive and its application for sand ground antiseepage - Google Patents
A kind of adhesive and its application for sand ground antiseepage Download PDFInfo
- Publication number
- CN106221630B CN106221630B CN201610614419.5A CN201610614419A CN106221630B CN 106221630 B CN106221630 B CN 106221630B CN 201610614419 A CN201610614419 A CN 201610614419A CN 106221630 B CN106221630 B CN 106221630B
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- China
- Prior art keywords
- parts
- adhesive
- promotor
- antiager
- adhesive according
- Prior art date
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C09J161/28—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with melamine
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01B—SOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
- A01B79/00—Methods for working soil
- A01B79/02—Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Soil Sciences (AREA)
- Environmental Sciences (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Cultivation Of Plants (AREA)
Abstract
The present invention proposes a kind of adhesive for sand ground antiseepage, the following raw material including mass parts: 50-60 parts of melamine resin, 10-40 parts of water absorbing agent, 0.1-5 parts of promotor, 5-10 parts of gelling agent, 1-5 parts of antiager.Adhesive proposed by the present invention forms antiseepage water-retaining film in sandy land surface, has the function of desertification, sand prevention, and moisture can retain after raining or after watering.Sand prevention glue of the invention is applied to desert area, arid area, Protection Forest Region etc., substantially increases the survival rate of plant.
Description
Technical field
The invention belongs to soil conditioner fields, and in particular to a kind of soil conditioner for sand ground.
Background technique
Cultivated plant, greening environment are the effective means for improving living environment.Desertification and saline Land lead to environment
Deteriorate.The greatest difficulty of cultivated plant is that the earth's surface cannot conserve water and soil on desert or salt-soda soil, without nutrient, makes plantation
Plant cannot get moisture and nutrition, it is difficult to survive.Although will water after cultivated plant, the water behind desert region, watering
Branch seeps rapidly, and the root system of seedling is undeveloped, cannot penetrate in very deep soil and absorb moisture；And labor intensive of repeatedly watering
Material resources are huge.
In order to improve the efficiency of desert afforestation, water-storage material is prepared with hydrophilic compounds；Or exploitation seepage control technique prevents water
Divide and nutrient loss is a kind of effective means.It blocks water percolator for example, patent CN201957525U proposes a kind of water proof,
It is equipped with the impervious barrier that blocks water on original sand bed, sand bed is equipped with above the impervious barrier that blocks water, growing nutrient layer is equipped with above sand bed, it is raw
Straw plaited clathrum is set above long nutritive layer.But the device needs artificial setting, complicated for operation.
Summary of the invention
Place in view of the shortcomings of the prior art, the object of the present invention is to provide it is a kind of it is easy to operate, do not have to soil
The adhesive for sand ground antiseepage of pollution.
Another object of the present invention is to propose the application of the adhesive.
To achieve the above object, the specific technical proposal is:
A kind of adhesive for sand ground antiseepage, the following raw material including mass parts: melamine resin 50-60
Part, 10-40 parts of water absorbing agent, 0.1-5 parts of promotor, 5-10 parts of gelling agent, 1-5 parts of antiager,
Wherein, the water absorbing agent is Sodium Polyacrylate (SAP) or konjaku super strength water absorbent (KSAP)
Konjaku super strength water absorbent (KSAP) is the graft product of konjac polysaccharide and sodium acrylate, is the polymer of homogeneity,
It contains a large amount of hydroxyl and carboxylated hydrophilic group, and compared to SAP, konjaku super strength water absorbent (KSAP) overcomes common SAP institute
Have the defects that biological degradability is poor, be easy to cause environmental pollution, is preferred water absorbing agent.
Wherein, the promotor is polyethylene glycol, thiocarbamide, paracresol, N, one of mono- diethylaniline of N or a variety of
Preferably, the promotor is polyethylene glycol and paracresol, and the mass ratio of polyethylene glycol and paracresol is 3:1-
3, wherein the molecular weight of polyethylene glycol is 600~2000.
Paracresol has the function of disinfectant, has the irreplaceable advantage of other promotors, phase for sand ground cultivated plant
It is lower to the polyethylene glycol toxicity of molecular mass 600~2000, modest viscosity, suitable for making wetting agent and consistency modifiers；Poly- second
Two pure and mild paracresol synergistic effects, the coating for being coated with adhesive is fine and close soft, is conducive to plant growth.
Wherein, the gelling agent is kaolin and/or bentonite.
Wherein, the antiager is white carbon black or nano silica.
The adhesive, is prepared using following methods: water absorbing agent being added when MF resin is heated up to 40-50 DEG C, promotes
After agent, gelling agent, antiager, stirred 10-50 minutes with 1000-1500 revs/min of speed.Dilution can be used according to construction requirement
Agent adjusts viscosity.
Wherein, the diluent is ethyl alcohol.
Application of the adhesive of the present invention in plant on sand land.
A method of sand ground is administered, comprising steps of
Hole or ditch are excavated in the earth's surface of sand ground, in the inner surface of the hole or ditch spraying adhesive, then in hole or ditch
The interior seed for placing plant or seedling, place into soil.
The beneficial effects of the present invention are:
Since desert area geology desertifies, water suction is fast, is not able to maintain moisture, soil nutrient loss.Adhesive proposed by the present invention,
Antiseepage water-retaining film is formed in sandy land surface, has the function of desertification, sand prevention, moisture can retain after raining or after watering.It incite somebody to action this
The sand prevention glue of invention is applied to desert area, arid area, Protection Forest Region etc., substantially increases the survival rate of plant.
Sand prevention glue high temperature resistant of the present invention, low-temperature resistance do not freeze, and moisture can be made to retain for a long time after rain, prevent wind sand,
Moisture plants grass, kind tree, administers prone soil on the basis of retaining.
Specific embodiment
The following examples are used to illustrate the present invention, but are not intended to limit the scope of the present invention..In the present invention, the quality
Part it is the common mass unit of those skilled in the art, such as can be gram, kilogram, ton, or for the easy to operate matter made by oneself
Measure unit.In the same formula, " part " indicates identical in quality.
Embodiment 1
A kind of adhesive for sand ground antiseepage, the following raw material including mass parts: melamino-formaldehyde (MF) resin 55
Part, 30 parts of water absorbing agent, 5 parts of promotor, 7 parts of gelling agent, 3 parts of antiager,
Wherein, water absorbing agent is konjaku super strength water absorbent (KSAP), and promotor is 3 parts and 2 parts of paracresol of polyethylene glycol, gel
Agent is kaolin.Antiager is white carbon black.
Water absorbing agent, promotor, gelling agent, antiager is added when MF resin is heated up to 45 DEG C to stir with 1500 revs/min
30 minutes.According to construction requirement viscosity can be adjusted with diluent.
In the present embodiment, diluent is ethyl alcohol, and the viscosity of addition ethyl alcohol to mixture is 1000-2000mPas.
Adhesive described in the present embodiment carries out plant on sand land, and experiment place is prince wife Cao pasture salt-soda soil.
The uniform trench in plot, furrow width 50cm, ditch depth 40cm, ditch spacing 6m.By adhesive spraying in bottom of trench and ditch
Then side wall places vegetable seeds in ditch, including shrub lespedeza 30g, Festuca Arundinacea 20g, twigs of the chaste tree 30g, (amount of vegetable seeds is by every
Square meter sand ground meter).It is put into soil, is sprinkled water.
After implementing 3 months, the comprehensive emergence rate of vegetable seeds reaches 85% or more.By annual growth, the ground vegetative coverage
Degree reaches 75% or more.
Embodiment 2
A kind of adhesive for sand ground antiseepage, the following raw material including mass parts: melamino-formaldehyde (MF) resin 55
Part, 30 parts of water absorbing agent, 4 parts of promotor, 7 parts of gelling agent, 3 parts of antiager,
Wherein, water absorbing agent is konjaku super strength water absorbent (KSAP), and promotor is thiocarbamide, and gelling agent is kaolin.Antiager
For white carbon black.
Water absorbing agent, promotor, gelling agent, antiager is added when MF resin is heated up to 45 DEG C to stir with 1500 revs/min
30 minutes.According to construction requirement viscosity can be adjusted with diluent.
Embodiment 3
A kind of adhesive for sand ground antiseepage, the following raw material including mass parts: melamino-formaldehyde (MF) resin 55
Part, 30 parts of water absorbing agent, 5 parts of promotor, 7 parts of gelling agent, 3 parts of antiager,
Wherein, water absorbing agent is konjaku super strength water absorbent (KSAP), and promotor is 3 parts and 2 parts of paracresol of polyethylene glycol, gel
Agent is kaolin.Antiager is nano silica.
Water absorbing agent, promotor, gelling agent, antiager is added when MF resin is heated up to 45 DEG C to stir with 1500 revs/min
30 minutes.According to construction requirement viscosity can be adjusted with diluent.
Above embodiment be only preferred embodiments of the present invention will be described, not to the scope of the present invention into
Row limits, and without departing from the spirit of the design of the present invention, this field ordinary engineering and technical personnel is to technical side of the invention
The all variations and modifications that case is made, should fall within the scope of protection determined by the claims of the present invention.
Claims (9)
1. a kind of adhesive for sand ground antiseepage, which is characterized in that the following raw material including mass parts: melamino-formaldehyde tree
50-60 parts of rouge, 10-40 parts of water absorbing agent, 0.1-5 parts of promotor, 5-10 parts of gelling agent, 1-5 parts of antiager.
2. adhesive according to claim 1, which is characterized in that the water absorbing agent is Sodium Polyacrylate (SAP) or konjaku
Super strength water absorbent (KSAP).
3. adhesive according to claim 1, which is characterized in that the promotor be polyethylene glycol, thiocarbamide, paracresol,
One of mono- diethylaniline of N, N is a variety of.
4. adhesive according to claim 3, which is characterized in that the promotor is polyethylene glycol and paracresol, poly- second
The mass ratio of two pure and mild paracresol is 3:1-3, and wherein the molecular weight of polyethylene glycol is 600~2000.
5. adhesive according to claim 3, which is characterized in that the gelling agent is kaolin and/or bentonite.
6. adhesive according to claim 3, which is characterized in that the antiager is white carbon black or nano silica.
7. any adhesive according to claim 1~6, which is characterized in that prepared using following methods: MF resin is added
After water absorbing agent, promotor, gelling agent, antiager is added when temperature is to 40-50 DEG C, stirred with 1000-1500 revs/min of speed
10-50 minutes.
8. application of the adhesive as claimed in claim 1 to 7 in plant on sand land.
9. a kind of method for administering sand ground, which is characterized in that comprising steps of
Hole or ditch are excavated in the earth's surface of sand ground, sprays any adhesive of claim 1~7 in the inner surface of hole or ditch,
Then seed or the seedling that plant is placed in hole or ditch, place into soil.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614419.5A CN106221630B (en) | 2016-07-29 | 2016-07-29 | A kind of adhesive and its application for sand ground antiseepage |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610614419.5A CN106221630B (en) | 2016-07-29 | 2016-07-29 | A kind of adhesive and its application for sand ground antiseepage |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106221630A CN106221630A (en) | 2016-12-14 |
| CN106221630B true CN106221630B (en) | 2019-06-25 |
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ID=57535479
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610614419.5A Expired - Fee Related CN106221630B (en) | 2016-07-29 | 2016-07-29 | A kind of adhesive and its application for sand ground antiseepage |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106221630B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110178557B (en) * | 2019-03-19 | 2021-02-19 | 福州市长乐区巧通工业设计有限公司 | Intermediate zone forest layer of three-layer ecological sand prevention and soil stabilization forest zone and forest establishment method thereof |
| CN110663463A (en) * | 2019-11-06 | 2020-01-10 | 许名香 | Desert greening method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5137931A (en) * | 1974-07-30 | 1976-03-30 | Ici Ltd | |
| CN101333431A (en) * | 2007-06-28 | 2008-12-31 | 北京化工大学 | Water-solubility sand-fixing and dust suppression agent grafted by oxidized starch |
| CN103740052A (en) * | 2013-12-09 | 2014-04-23 | 辽宁盖亚科技开发有限责任公司 | Water-absorbent gel, and preparation method and application thereof |
| CN106009506A (en) * | 2016-07-29 | 2016-10-12 | 神盾防火科技有限公司 | Clear water anti-seepage adhesive, and preparation method and application thereof |
-
2016
- 2016-07-29 CN CN201610614419.5A patent/CN106221630B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5137931A (en) * | 1974-07-30 | 1976-03-30 | Ici Ltd | |
| CN101333431A (en) * | 2007-06-28 | 2008-12-31 | 北京化工大学 | Water-solubility sand-fixing and dust suppression agent grafted by oxidized starch |
| CN103740052A (en) * | 2013-12-09 | 2014-04-23 | 辽宁盖亚科技开发有限责任公司 | Water-absorbent gel, and preparation method and application thereof |
| CN106009506A (en) * | 2016-07-29 | 2016-10-12 | 神盾防火科技有限公司 | Clear water anti-seepage adhesive, and preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 化学固沙材料的研究现状及进展;来晓燕等;《化工文摘》;20071001(第05期);第46-48页 |
| 高分子材料在化学固沙中的应用;王丹等;《生物质化学工程》;20060630(第03期);第44-47页 |
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| Publication number | Publication date |
|---|---|
| CN106221630A (en) | 2016-12-14 |
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