CN106221194B - 一种夹层玻璃用装饰膜的制备方法 - Google Patents

一种夹层玻璃用装饰膜的制备方法 Download PDF

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CN106221194B
CN106221194B CN201610687965.1A CN201610687965A CN106221194B CN 106221194 B CN106221194 B CN 106221194B CN 201610687965 A CN201610687965 A CN 201610687965A CN 106221194 B CN106221194 B CN 106221194B
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付竹兰
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Abstract

本发明公开了一种夹层玻璃用装饰膜的制备方法，其采用改性的聚氨酯制备成为新型聚氨酯膜，新设计的聚氨酯具有良好的粘结性和透明度，将其使用在夹层玻璃的制备过程中可以保证夹层玻璃的安全性，稳定性和通透性。在该聚氨酯膜上采用纳米颜料油墨进行凹版印刷图案，图案清晰精致，印刷过程简单，可控制性强。

Description

一种夹层玻璃用装饰膜的制备方法
技术领域
本发明涉及装饰膜领域，特别是涉及一种夹层玻璃用装饰膜的制备方法。
背景技术
夹层玻璃是由两片或多片玻璃之间夹持一层或多层聚合物中间层制得的类似“三明治”结构的特殊玻璃。由于玻璃与中间层的贴合，夹层玻璃可以抵御外来物体的冲击和穿透，即使被破坏其碎片也会粘附在中间层中，从而可以减少玻璃破碎对人体的伤害。所以夹层玻璃具有优良的安全性，可以作为挡风玻璃、栏杆、幕墙或建筑物的光伏外墙。但是，这种夹层玻璃还存在着用途单一，装饰性差等问题，使其使用范围受到较大的限制。
中国专利CN00107125.4公开了一种双面透视的装饰夹层玻璃，其特征是：由上下两层玻璃和中间的聚醋酸乙烯-乙烯共聚物(EVA)薄膜构成，EVA薄膜的一个面上具有采用凹版印刷或丝网印刷技术处理而获得的高清晰度图案；其制造方法为：采用凹版印刷或丝网印刷技术在聚醋酸乙烯-乙烯共聚物(EVA)薄膜上形成高清晰度的画面，将经过处理的EVA薄膜置于两片玻璃之间，进行合片，合片后在真空条件下进行加热粘合，形成双面透视装饰夹层玻璃。该方法使用新型中间膜，制备夹层玻璃过程中无需上胶，简化了工艺步骤。
发明内容
本发明的目的是提供一种夹层玻璃用装饰膜的制备方法，该方法得到的装饰膜可以根据需要在其表面打印图案，图案效果清晰，精致。该装饰膜应用于夹层玻璃的生产中，粘合性好，透明度高，而且操作简单，可以提高夹层玻璃的生产效率。
为实现上述目的，本发明采用以下技术方案：
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷20-30份、聚内酯二醇40-60份、聚醚三元醇30-45份、二羟甲基丙酸20-35份和六亚甲基二异氰酸酯100份加入反应釜中，升温至70-90℃，加入3-6份催化剂搅拌均匀，反应4-6h后，加入40-50份有机溶剂稀释，搅拌均匀，加入15-30份三乙醇胺搅拌反应15min后，加入40-58份己二酸二己酯、24-43份羟甲基纤维素和10-18份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；
(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
优选的，所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。
优选的，所述聚醚三元醇的相对分子质量为750-1500。
优选的，所述催化剂为三甲基苄胺、十二叔铵或二甲基锡中的一种。
优选的，所述有机溶剂为甲苯和异丙醇的混合物，其中甲苯和异丙醇的体积比为3:1。
优选的，所述电晕处理中电晕值为36-44达因。
优选的，所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
本发明具有以下有益效果，采用改性的聚氨酯制备成为新型聚氨酯膜，新设计的聚氨酯具有良好的粘结性和透明度，将其使用在夹层玻璃的制备过程中可以保证夹层玻璃的安全性，稳定性和通透性。在该聚氨酯膜上采用纳米颜料油墨进行凹版印刷图案，图案清晰精致，印刷过程简单，可控制性强。
具体实施方式
为了更好的理解本发明，下面通过实施例对本发明进一步说明，实施例只用于解释本发明，不会对本发明构成任何的限定。
实施例1
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷20份、聚内酯二醇40份、聚醚三元醇30份、二羟甲基丙酸20份和六亚甲基二异氰酸酯100份加入反应釜中，升温至70℃，加入3份催化剂搅拌均匀，反应4h后，加入40份有机溶剂稀释，搅拌均匀，加入15份三乙醇胺搅拌反应15min后，加入40份己二酸二己酯、24份羟甲基纤维素和10份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。所述聚醚三元醇的相对分子质量为750。所述催化剂为三甲基苄胺。所述有机溶剂为甲苯和异丙醇的混合物，二者体积比为3:1。所述电晕处理中电晕值为36达因。所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
实施例2
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷30份、聚内酯二醇60份、聚醚三元醇45份、二羟甲基丙酸35份和六亚甲基二异氰酸酯100份加入反应釜中，升温至90℃，加入6份催化剂搅拌均匀，反应6h后，加入50份有机溶剂稀释，搅拌均匀，加入30份三乙醇胺搅拌反应15min后，加入58份己二酸二己酯、43份羟甲基纤维素和18份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。所述聚醚三元醇的相对分子质量为1500。所述催化剂为十二叔铵。所述有机溶剂为甲苯和异丙醇的混合物，二者体积比为3:1。所述电晕处理中电晕值为44达因。所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
实施例3
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷25份、聚内酯二醇50份、聚醚三元醇40份、二羟甲基丙酸30份和六亚甲基二异氰酸酯100份加入反应釜中，升温至80℃，加入5份催化剂搅拌均匀，反应5h后，加入45份有机溶剂稀释，搅拌均匀，加入20份三乙醇胺搅拌反应15min后，加入50份己二酸二己酯、30份羟甲基纤维素和15份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。所述聚醚三元醇的相对分子质量为1000。所述催化剂为二甲基锡。所述有机溶剂为甲苯和异丙醇的混合物，二者体积比为3:1。所述电晕处理中电晕值为40达因。所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
实施例4
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷20份、聚内酯二醇60份、聚醚三元醇30份、二羟甲基丙酸35份和六亚甲基二异氰酸酯100份加入反应釜中，升温至70℃，加入6份催化剂搅拌均匀，反应4h后，加入50份有机溶剂稀释，搅拌均匀，加入15份三乙醇胺搅拌反应15min后，加入58份己二酸二己酯、24份羟甲基纤维素和18份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。所述聚醚三元醇的相对分子质量为1500。所述催化剂为三甲基苄胺。所述有机溶剂为甲苯和异丙醇的混合物，二者的体积比为3:1。所述电晕处理中电晕值为36达因。所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
实施例5
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷30份、聚内酯二醇40份、聚醚三元醇45份、二羟甲基丙酸20份和六亚甲基二异氰酸酯100份加入反应釜中，升温至90℃，加入3份催化剂搅拌均匀，反应6h后，加入40份有机溶剂稀释，搅拌均匀，加入30份三乙醇胺搅拌反应15min后，加入40份己二酸二己酯、43份羟甲基纤维素和10份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。所述聚醚三元醇的相对分子质量为1500。所述催化剂为十二叔铵。所述有机溶剂为甲苯和异丙醇的混合物，二者的体积比为3:1。所述电晕处理中电晕值为44达因。所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
实施例6
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷28份、聚内酯二醇50份、聚醚三元醇36份、二羟甲基丙酸25份和六亚甲基二异氰酸酯100份加入反应釜中，升温至75℃，加入6份催化剂搅拌均匀，反应6h后，加入48份有机溶剂稀释，搅拌均匀，加入25份三乙醇胺搅拌反应15min后，加入55份己二酸二己酯、35份羟甲基纤维素和15份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。所述聚醚三元醇的相对分子质量为1200。所述催化剂为二甲基锡。所述有机溶剂为甲苯和异丙醇的混合物，二者的体积比为3:1。所述电晕处理中电晕值为42达因。所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
实施例7
一种夹层玻璃用装饰膜的制备方法，包括如下步骤：
(1)将端羟基聚甲基硅氧烷30份、聚内酯二醇45份、聚醚三元醇32份、二羟甲基丙酸25份和六亚甲基二异氰酸酯100份加入反应釜中，升温至78℃，加入6份催化剂搅拌均匀，反应4h后，加入40份有机溶剂稀释，搅拌均匀，加入25份三乙醇胺搅拌反应15min后，加入55份己二酸二己酯、40份羟甲基纤维素和16份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。所述聚醚三元醇的相对分子质量为800。所述催化剂为三甲基苄胺。所述有机溶剂为甲苯和异丙醇的混合物，二者的体积比为3:1。所述电晕处理中电晕值为42达因。所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。

Claims (7)

1.一种夹层玻璃用装饰膜的制备方法，其特征在于，包括如下步骤：
(1)将端羟基聚甲基硅氧烷20-30份、聚内酯二醇40-60份、聚醚三元醇30-45份、二羟甲基丙酸20-35份和六亚甲基二异氰酸酯100份加入反应釜中，升温至70-90℃，加入3-6份催化剂搅拌均匀，反应4-6h后，加入40-50份有机溶剂稀释，搅拌均匀，加入15-30份三乙醇胺搅拌反应15min后，加入40-58份己二酸二己酯、24-43份羟甲基纤维素和10-18份乙酸丁酯混合均匀，经涂布干燥制备透明聚氨酯膜；
(2)使用电晕处理透明聚氨酯膜的表面，利用凹版印刷技术，使用纳米颜料油墨印刷所需图案，即制得所述夹层玻璃用装饰膜。
2.根据权利要求1所述的夹层玻璃用装饰膜的制备方法，其特征在于：所述聚醚三元醇为由环氧丙烷和甘油加成聚合制得的聚醚三元醇。
3.根据权利要求1所述的夹层玻璃用装饰膜的制备方法，其特征在于：所述聚醚三元醇的相对分子质量为750-1500。
4.根据权利要求1所述的夹层玻璃用装饰膜的制备方法，其特征在于：所述催化剂为三甲基苄胺、十二叔铵或二甲基锡中的一种。
5.根据权利要求1所述的夹层玻璃用装饰膜的制备方法，其特征在于：所述有机溶剂为甲苯和异丙醇的混合物，其中甲苯和异丙醇的体积比为3:1。
6.根据权利要求1所述的夹层玻璃用装饰膜的制备方法，其特征在于：所述电晕处理中电晕值为36-44达因。
7.根据权利要求1所述的夹层玻璃用装饰膜的制备方法，其特征在于：所述装饰膜采用热熔贴合的方式将其贴合在玻璃上。
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