CN106219647A - A kind of efficient sea water desalting equipment - Google Patents
A kind of efficient sea water desalting equipment Download PDFInfo
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- CN106219647A CN106219647A CN201610845771.XA CN201610845771A CN106219647A CN 106219647 A CN106219647 A CN 106219647A CN 201610845771 A CN201610845771 A CN 201610845771A CN 106219647 A CN106219647 A CN 106219647A
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- sea water
- housing
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- 239000013535 sea water Substances 0.000 title claims abstract description 124
- 238000011033 desalting Methods 0.000 title claims abstract description 28
- 239000006200 vaporizer Substances 0.000 claims abstract description 57
- 238000009833 condensation Methods 0.000 claims abstract description 33
- 230000005494 condensation Effects 0.000 claims abstract description 33
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000013505 freshwater Substances 0.000 claims abstract description 26
- 230000008569 process Effects 0.000 claims abstract description 23
- 230000006835 compression Effects 0.000 claims abstract description 21
- 238000007906 compression Methods 0.000 claims abstract description 21
- 239000000203 mixture Substances 0.000 claims abstract description 6
- 208000002925 dental caries Diseases 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 137
- 150000003839 salts Chemical class 0.000 claims description 40
- 238000011049 filling Methods 0.000 claims description 27
- 239000007788 liquid Substances 0.000 claims description 24
- 230000008016 vaporization Effects 0.000 claims description 23
- 238000004140 cleaning Methods 0.000 claims description 21
- 238000009834 vaporization Methods 0.000 claims description 21
- 238000010438 heat treatment Methods 0.000 claims description 18
- 230000002194 synthesizing effect Effects 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 239000002356 single layer Substances 0.000 claims description 3
- 230000009466 transformation Effects 0.000 abstract description 11
- 230000007704 transition Effects 0.000 abstract description 6
- 238000010276 construction Methods 0.000 abstract description 2
- 230000035945 sensitivity Effects 0.000 abstract description 2
- 239000012071 phase Substances 0.000 description 43
- 235000002639 sodium chloride Nutrition 0.000 description 36
- 238000001704 evaporation Methods 0.000 description 27
- 238000010612 desalination reaction Methods 0.000 description 22
- 230000008020 evaporation Effects 0.000 description 22
- 230000000694 effects Effects 0.000 description 17
- 239000007789 gas Substances 0.000 description 13
- 238000005516 engineering process Methods 0.000 description 11
- 238000004821 distillation Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 239000012267 brine Substances 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 8
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 8
- 239000012141 concentrate Substances 0.000 description 6
- 230000008859 change Effects 0.000 description 5
- 238000005265 energy consumption Methods 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000003344 environmental pollutant Substances 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- 239000008236 heating water Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 231100000719 pollutant Toxicity 0.000 description 4
- 239000003507 refrigerant Substances 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 239000002826 coolant Substances 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000001223 reverse osmosis Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000009835 boiling Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000003651 drinking water Substances 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- 230000000737 periodic effect Effects 0.000 description 2
- 238000004886 process control Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 238000005057 refrigeration Methods 0.000 description 2
- 238000010025 steaming Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000007738 vacuum evaporation Methods 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000012206 bottled water Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 239000011552 falling film Substances 0.000 description 1
- 238000007701 flash-distillation Methods 0.000 description 1
- 230000002631 hypothermal effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000009288 screen filtration Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000004781 supercooling Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/02—Cleaning pipes or tubes or systems of pipes or tubes
- B08B9/023—Cleaning the external surface
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
- Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
Abstract
The invention discloses a kind of efficient sea water desalting equipment, including housing and vacuum extractor, described vacuum extractor is for carrying out evacuation process to described housing;Described housing is divided into upper and lower two cavitys communicated, it is provided with condenser in the upper cavity of described housing, vaporizer it is provided with in lower chamber, described vaporizer, described condenser and a heat compression unit one heat circulation system of composition, the condenser header of open top it is additionally provided with in the upper cavity of described housing, described condenser is arranged on the top of described condenser header, the fresh water that described condenser header produces after collecting condensation.Compact of the present invention, utilize sensitivity, high-termal conductivity and the isothermal of sea water moisture content phase transition temperature under high vacuum state, and condenser and the special construction of condenser header, realize moisture content in sea water to vaporize the phase transformation transfer of condensation and desalinate, improve speed and the efficiency of desalinization, there are the highest energy-conserving and environment-protective and be worth.
Description
Technical field
The present invention relates to desalinization process field, particularly relate to a kind of efficient sea water desalting equipment.
Background technology
Water resource is basic natural resources and strategic economic resources, and sustainable utilization of water resource is to be related to economic society
The Vital Strategic Problems that can develop, in tellurian gross amount of water resources, fresh water only accounts for 2.5%, and sea water accounts for 97.5%.Seawater utilization
It is human society one of the important measures that solve water resources crisis.
In 16 end of the centurys, the mankind start to carry out preparing fresh with distillator direct evaporation sea water aboard ship, and 19 end of the centurys, along with steaming
The appearance of steamer ship, vaporizer producing distilled water is born the most therewith, to meet the supply of steamer boiler and drinking water.50 years 20th century
Occur for multi-stage flash evaporation technology.The sixties U.S. successfully prepared in the world first equipment with high desalinization, high pass penetration, can be used for sea
The asymmetric cellulose acetate reverse osmosis film of water desalination, and produced First reverse osmosis unit in the world in the seventies, with
The development of the technology such as the raising reverse osmosis membrane performance raising, prices, energy recovery efficiency, hyperfiltration becomes investment
Province, the desalinization potable water mode of low cost.The eighties in 20th century, low-temperature multiple-effect distillation emerged, light with embrane method sea water
Change technology is compared, and it is big etc. that the way of distillation has available low grade heat energy, production capacity low to raw material seawater water quality requirement, device
Advantage, low-temperature multiple-effect seawater desalination technology refers to the highest evaporating temperature of the saline desalination technology less than 70 degree, it is characterized in that by
A series of horizontal tube sprinkling falling-film evaporator is together in series, and enters through evaporation repeatedly and condensation with a certain amount of steam,
The evaporating temperature of an effect next is below an above effect, thus obtains being multiple times than the desalination process of the distilled water of quantity of steam, its stream
Cheng Wei: charging sea water is preheated in heat extraction condenser and deaerates, and is divided into two streams afterwards.One logistics is as condensed fluid
Dumping and flow back to sea, additionally one logistics becomes the feeding liquid of still-process.Feed liquid is drawn after adding dirt dispersion agent
Enter in heat-recovery section respectively imitate that temperature is minimum a group.Spray system sprays feed liquid the overhead coil being distributed in each vaporizer
On, during flowing freely the most in the form of a film along overhead coil, a part of sea water is cold owing to absorbing in vaporizer
Coagulate the latent heat of steam and vaporize.The residue feed liquid pump slightly concentrated is driven in next group of vaporizer, the operation of this group
Temperature than upper one group higher, in new group again be repeated evaporation and spray process.Remaining feed liquid is beaten the most forward, directly
To finally leaving this effect group with the form of concentrated solution in the effect group that temperature is the highest.Raw steam is input to the steaming of the highest effect of temperature
Sending out inside pipe, while condensing in pipe, pipe is outer also creates the evaporation essentially identical with condensation number.The secondary produced steams
Vapour through strong brine liquid drop separator with ensure distilled water purity after, be incorporated into again next effect heat-transfer pipe in, second
The operation temperature and pressure outline of effect is less than the first effect.This evaporation and condensation process weigh along each effect of a string vaporizer always
Multiple, often to imitate and all create a considerable amount of distilled water, the steam imitated to last is condensed by sea water coolant in heat extraction section.First
The condensed fluid of effect is collected, and a part for this distilled water returns to again steam generator, exceedes the raw quantity of steam of input
Part is flowed in the first container of a series of special container, and each container is all connected to the condensation side of next low temperature effect.This
Sample makes a part of distilled water produce flash distillation and make remaining product water cool down, and imparts heat to the main body of recuperation of heat effect simultaneously
In.So stepped flowing of product water by flash cooled step by step.Liberated heat improves the aggregate efficiency of system, cold
But distilled water is finally extracted out with water pump and is input in fluid reservoir.The product water so produced is pure water completely, and it is not
Containing any pollutant, mean salt amount is less than 20ppm.If installing two-stage mist eliminating net, product water salt content is smaller than 5ppm.Picture
Distilled water is the same, and concentrated seawater is from the first effect stepped inflow a series of strong brine flash tank, and flash cooled is to reclaim
Its heat.After supercooling, strong brine squeezes into sea through strong brine pump.Incoagulable gas is extracted out from each condensing tube,
And flow to another effect from an effect.These incoagulable gas are finally enriched with at the coldest end of heat extraction condenser, and use steam jet ejector
Or mechanical vacuum pumped.
Different from multistage flash evaporation and traditional multiple-effect evaporation, low-temperature multi-effect technology has following pluses and minuses:
(1) low due to operation temperature, it is to avoid or slow down corrosion and the fouling of equipment;
(2) pretreatment of charging sea water is the simplest.System hypothermia operation can simplify the preprocessing process of sea water.Sea water enters
Only need to be through screen filtration and the antisludging agent adding about 5ppm before entering low-temperature multi-effect device, being also not required to multistage flash evaporation must
Acid adding degassing process must be carried out;
(3) power consumption of system is little.Low-temperature multi-effect system is the lowest for the power consumption carrying liquid, it is possible to decrease desalination
The water producing cost of water;
(4) system operation is safe and reliable.In low-temperature multi-effect system, in happens is that pipe, steam condenses and manages outer liquid film and steam
Sending out, even if heat-transfer pipe there occurs that corrosion failure leaks, owing to vapour lateral pressure is more than side of liquid film pressure, strong brine can never flow
In product water.
The condensation of low-temperature multiple-effect distillation and the heat transfer coefficient of evaporation process improve with its operation temperature and improve, simultaneously by
When low-temperature operation, the specific volume of steam is bigger so that the volume tool of equipment is big, virtually adds the input cost of equipment, because of
This, technically need to improve as much as possible the operation temperature of low-temperature multi-effect process, make up to higher water generation ratio, and improve behaviour
Make temperature and add energy resource consumption the most to a certain extent.
To sum up, how to reduce the volume of sea water desalinating unit, reduce energy resource consumption, raising desalinization speed and efficiency,
Seem increasingly important.
Summary of the invention
The volume that it is an object of the invention to overcome the low-temperature multi-effect seawater desalination device of prior art is relatively big, energy resource consumption
More and desalinization speed and inefficient defect.
In order to solve above-mentioned technical problem, originally provide a kind of efficient sea water desalting equipment, including housing and vacuum means
Putting, described vacuum extractor is for carrying out evacuation process to described housing;Described housing is divided into upper and lower two chambeies communicated
Body, is provided with condenser in the upper cavity of described housing, be provided with vaporizer in the lower chamber of described housing, described vaporizer,
Described condenser and a heat compression unit one heat circulation system of composition, be additionally provided with top in the upper cavity of described housing
Uncovered condenser header, described condenser is arranged on the top of described condenser header, and described condenser header is used for collecting
The fresh water produced in condensation process.
Preferably, described condenser is V-arrangement or circular arc, and described condenser header is arranged under the bottom of described condenser
Side.
Further, the top surrounding of described condenser header is additionally provided with steam channel, and described steam channel is used for making
The water vapour produced after sea water vaporization enters in described condenser header.
Further, described heat compression unit is by the compression of heat transfer medium and suction group synthesis heat power supply device and cold
Source apparatus;Described heat power supply device, for providing the heat source recycled for described vaporizer, vaporizes the cavity of resorption of described housing
Internal sea water;Described cold source device for providing the low temperature cold source recycled for described condenser, by produce after vaporization
Water vapour is condensed into fresh water.
Further, being additionally provided with captation outside described housing, described captation is cold with described by the pipeline that catchments
The bottom connection of condenser header, described captation is also associated with the water purification for being extracted out by the fresh water in described captation
Pump.
Further, described vacuum extractor is connected with the upper cavity of described housing by the first vacuum line, and passes through
Second vacuum line connects with described captation, and it is true that described vacuum means is set to water jet air ejector, stream-jet ejector, vane type
One in empty pump or Roots vaccum pump.
Further, it is additionally provided with brokenly, between upper cavity and the lower chamber of described housing of described housing, plate of indulging in serfing the Net, described
The big steam vapour phase stream that broken plate of indulging in serfing the Net produces in by described lower chamber is broken into fine vapor vapour phase stream, described broken plate of indulging in serfing the Net
For holey plate, it is arranged for monolayer or multilamellar is arranged.
Further, outside described housing, be additionally provided with water filling device, described water filling device include water-filled pool, water injecting pipeline and
Water filling adjusting means, described water-filled pool is connected with the lower chamber of described housing by described water injecting pipeline, described water filling regulation dress
Putting and be arranged on described water injecting pipeline, described water filling adjusting means sea level fluctuations in the lower chamber regulating described housing is also
Sea level fluctuations is controlled the lower section at described broken plate of indulging in serfing the Net.
Further, described vaporizer being additionally provided with salt crust cleaning plant, described salt crust cleaning plant and drives dress
Putting connected, described salt crust cleaning plant is push-and-pull tube-in-tube structure or revolution blade structure, and described salt crust cleaning plant drives described
Continue push-and-pull or revolution under the drive of dynamic device, the salt crust on described vaporizer is cleared up.
Further, the bottom of described housing is additionally provided with for clearing up the salt crust got off and sea water concentration on vaporizer
The concentrating pump that liquid is discharged, described salt crust and concentrated solution are for heating the sea water in described water-filled pool by heat-exchangers of the plate type.
The efficient sea water desalting equipment of the present invention, has the advantages that
1, the present invention utilizes vacuum state low temperature phase change and the principle realization sea evaporation of water that thermal resistance is little, isothermal is good light
Change, can be under the bigger temperature and pressure of suitable heating-up temperature and cold-producing medium cryogenic liquid condensation temperature, with relatively low phase transition temperature
Realizing the phase transformation transfer desalination of moisture content in sea water, its desalination speed and efficiency are far above existing evaporation of seawater desalinating process technology,
The energy consumption of desalinization and auxiliary material consuming cost can be reduced, under vacuum environment, at the heating high-efficiency evaporating temperature of sea water and low temperature
Vapour phase rapid condensation, can greatly reduce the heat exchange area of sea water desalinating unit, and make desalinating process control simple, performance is steady
Fixed, its surface structure is smaller and more exquisite.
2, vaporizer and the condenser of the present invention is arranged in a housing, and its structure is compacter, and volume is smaller and more exquisite,
Be provided with condenser header in the upper cavity of housing, described condenser be shaped as V-arrangement or circular arc, described condenser header sets
Putting the bottom part down at described condenser, on the one hand the condenser of V-arrangement or circular arc setting increases water vapour and condenser
Contact area, improves and changes heat exchange efficiency and speed, is on the other hand easy to condensed water droplet and flows into smoothly in condenser header.
3, the present invention is fine vacuum sea water by distillation mode, can obtain the fresh water of high-purity, vacuum evaporation after sea water vaporization
And condensation at low temperature, little low-grade energy can be utilized to consume quickly from sea water, obtain desalination water, vaccum cryogenic distillation dense
Contracting sea water salt crust uses mechanical chipping, and desalting process does not has consumable goods and pollutant to produce, and desalination process does not has waste gas to arrange
Putting and harmful substance produces, the height that desalting process concentrates can directly drain back into sea containing sea brine or refine sea salt, simultaneously
Salt crust and the concentrated pump of sea water concentrated solution can also be by the sea water in heat-exchangers of the plate type heating water-filled pool after discharging, it is achieved sea
The efficient desalination process of circulation of water.
4, the integrated hermetically sealed vacuum structure of the housing of the present invention, maintains the height needed for the distillation desalination of sea water low-temperature vaporization
Vacuum easily realizes, and utilizes the heating as desalinization of refrigerant heat and low-temperature refrigeration technology and the circulation compression of condensation
Hot low-temperature receiver, will reduce heating source thermal energy consumption and condensation energy loss, it is possible to decrease the supporting cost of manufacture of equipment and system and sea
Water desalinating cost, improves efficiency of energy utilization, and energy-conserving and environment-protective are significant.
Accompanying drawing explanation
In order to be illustrated more clearly that technical scheme, below will be to required in embodiment or description of the prior art
The accompanying drawing used is briefly described, it should be apparent that, the accompanying drawing in describing below is only some embodiments of the present invention, right
From the point of view of those of ordinary skill in the art, on the premise of not paying creative work, it is also possible to obtain it according to these accompanying drawings
Its accompanying drawing.
Fig. 1 is the inventive principle structural representation of the present invention;
Fig. 2 is condenser header the first structural representation with condenser of the present invention;
Fig. 3 is condenser header the second structural representation with condenser of the present invention.
Wherein, in figure, reference corresponds to: 1-housing, 2-water filling device, 201-water-filled pool, 202-water injecting pipeline,
203-water filling adjusting means, 3-vaporizer, 4-condenser, 5-vacuum extractor, 6-captation, 7-condenser header, 8-steams
Vapour passage, 9-heat compression unit, 10-heat power supply device, 11-cold source device, 12-salt crust cleaning plant, 13-driving means, 14-
First vacuum line, 15-the second vacuum line, 16-catchments pipeline, 17-clarified water pump, the broken plate of indulging in serfing the Net of 18-, 19-concentrating pump, 20-
Heat-exchangers of the plate type.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, the technical scheme in inventive embodiments is carried out clear, complete
Ground describes, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on this
Inventive embodiment, the every other reality that those of ordinary skill in the art are obtained on the premise of not making creative work
Execute example, broadly fall into the scope of protection of the invention.
The present invention utilizes condenser, the special construction of condenser header, and under vacuum state, liquid rapid phase transition and height
Sensitive heat conductivility, after making heating of seawater, under relatively low vapourizing temperature, explosive evaporation is vapour phase rapidly, and the least at resistance
Vaccum case in quickly transfer to the low-temperature end of condenser with the temperature difference, after heat is rapidly conducted to cool down water, rapid condensation becomes
Pure water, makes to realize liquid phase containing the moisture content in sea brine and arrives the rapid phase transition of liquid phase to vapour phase again, available little under vaccum working condition
Energy expenditure quickly realize sea water purification.Under vacuum state, sea water realizes the principle of efficient fast purification and is: standard atmosphere
During pressure (absolute pressure about 0.1Mpa), the vaporization boiling temperature of water is 100 degree, and in the case of absolute pressure is the lowest, such as
Water is under the vacuum state of absolute pressure 0.02Mpa, and water saturation temperature only has 60 degree, during absolute pressure 0.01Mpa vacuum,
Water can realize vaporizing phase transformation at about 46 degree.Therefore, by the phase transformation space sealing of desalting process, tieed up by air extractor
After holding vacuum state, can be achieved with seething with excitement the moisture content in sea water under relatively low heating-up temperature vaporizes and evaporates.Vacuum environment
Under, liquid phase-change process has the advantages that thermal resistance is little, heat conductivity is high, isothermal is good, can obtain several times, tens times of even hundred times
In the vaporization phase velocity of normality operating mode, heating source adds heat pipe by thermal energy conduction to sea water by heat exchanger, makes the water in sea water
Part sensitive rapid evaporation at a lower temperature, and the vapour phase evaporating generation quickly moves to low-temperature end under the small temperature difference,
Vapour phase is condensed into water purification at the low-temperature receiver end Fast exothermic of condenser cooling water pipe, and condensation water purification flows in sump, then passes through
Clarified water pump is extracted out.Efficient sea water desalting equipment and technique are compared with other sea water desalting equipments, and it utilizes high vacuum state to plunge into the commercial sea
Water low boiling and low condensation temperature produce phase transformation under the action of thermal difference of heating medium temperature and coolant, utilize sensitivity, height
Heat conductivity and the phase transition process of isothermal, by the moisture content fast vaporizing in sea water and condensation, therefore can the most quickly obtain pure
Clean water.The vacuum desalinating process of sea water, in addition to less heating source power and equipment for liquid transportation power, is not lost material
Material and pollutant produce, and the lowest available energy consumption cost obtains the desalinization pure water of high-quality.
Embodiment 1
As depicted in figs. 1 and 2, the invention discloses a kind of efficient sea water desalting equipment, including housing 1, water filling device 2,
Vaporizer 3, condenser 4, vacuum extractor 5 and captation 6, described vacuum extractor 5 is by the first vacuum line 14 and institute
Stating housing 1 to connect, and connected with described captation 6 by the second vacuum line 15, described vacuum extractor 5 is bled for jetting
One in device, stream-jet ejector, vane-type vacuum pump or Roots vaccum pump, described vacuum extractor 5 is by housing 1 and the dress that catchments
Put the portion's noncondensing gas in 6 and constantly discharge and maintain the high vacuum state of the two.
Described housing 1 is divided into upper and lower two cavitys communicated, and described condenser 4 and described vaporizer 3 are separately positioned on institute
Stating in the upper and lower cavity of housing 1, described vaporizer 3, described condenser 4 and a heat compression unit 9 form a recycle heat
System, described vaporizer 3 is used for making sea water be vaporizated into water vapour, and described condenser 4 is for being condensed into fresh water by water vapour;Described
Being provided with the condenser header 7 of open top in the upper cavity of housing 1, described condenser 4 is arranged on described condenser header 7
Top, the fresh water that described condenser header 7 produces after collecting water vapour condensation.
Described heat compression unit 9 is by synthesizing heat power supply device 10 to the compression of heat transfer medium (such as cold-producing medium) with suction group
With cold source device 11, described heat power supply device 10 provides the heat source indirect heat transfer recycled to the evaporation arranged in housing 1
Sea water outside device 3, sea water is heated and makes moisture content therein vaporization phase transformation produce water vapour, and described vaporizer 3 is pipe type heat transfer
Pipe, the heat transfer medium in described vaporizer 3 is cold-producing medium, it is also possible to for low-pressure steam, heat carrier conduction oil or hot blast (except pipe
Outside formula heat exchanger tube, described vaporizer 3 can also be electrically heated rod);Described cold source device 11 provides the low temperature cold recycled
Source absorbs the gas heat outside described condenser 4, is fresh water by vapour phase water vapour rapid condensation, and described condenser 4 is light pipe
Or finned tube composition, its structure is box type or coil arrangement, and described low temperature cold source includes low-temperature refrigerant closed cycle profit
With or open sea water direct-cooled in line, in order to increase the contact area of vapour phase water vapour and condenser 4, improve heat exchanger effectiveness,
Condenser 4 is designed as V-arrangement (as shown in Figure 2) by the present invention, and described condenser header 7 is arranged on the condenser 4 that described V-arrangement is arranged
Bottom part down, when the volume of described condenser header 7 is much larger than the volume of condenser 4, at the top four of condenser header 7
Week can also arrange steam channel 8, and the water vapour that this steam channel 8 produces after making sea water vaporization enters described condenser collection
In case 7.
It is additionally provided with periodic cleaning sea water on described vaporizer 3 to concentrate and be bonded at the salt crust cleaning plant of vaporizer 3 outer wall
12, described salt crust cleaning plant 12 is push-and-pull tube-in-tube structure, and described salt crust cleaning plant 12 is connected with a driving means 13, described
Salt crust cleaning plant 12 continues push-and-pull under the drive of described driving means 13, is removed by the salt crust on described vaporizer 3,
Described driving means 13 part is arranged in housing 1, and another part is arranged on the outside of housing 1.
The broken plate 18 of indulging in serfing the Net that monolayer is arranged, institute it is provided with between upper cavity and the lower chamber of described housing 1 of described housing 1
State brokenly in plate 18 of indulging in serfing the Net makes described lower chamber the steam vapour phase stream produced to pass through mesh when moving and going to upper cavity and be broken into
Fine vapor vapour phase stream, the described broken holey plate that plate 18 is metal material of indulging in serfing the Net, this reticulated cell generally circular in shape or square
Shape.
Described captation 6 is connected with the bottom of described condenser header 7 by the pipeline 16 that catchments, described captation 6
Being also associated with the clarified water pump 17 for being extracted out by the fresh water in captation 6, the fresh water that described condenser header 7 condenses leads to
Crossing the pipeline 16 that catchments persistently to import in captation 6, the fresh water in captation 6 is sent endlessly by clarified water pump 17
Go out.
Described water filling device 2 includes water-filled pool 201, water injecting pipeline 202 and water filling adjusting means 203, described water-filled pool 201
Being connected by the lower chamber of described water injecting pipeline 202 with described housing 1, described water filling adjusting means 203 is arranged on described water filling
On pipeline 202, the sea water in described water-filled pool 201 enters described shell by the evacuation self-priming mode of described vacuum extractor 5
In the lower chamber of body 1, described water filling adjusting means 203 is used for regulating the sea level fluctuations in described housing 1, and by sea level fluctuations control
Making the lower section at described broken plate 18 of indulging in serfing the Net, sea water liquid level specifically can maintain vaporizer 3, and to go up most the pipe of a row immersed
Do not have but the most broken plate 18 of indulging in serfing the Net.
Sea water after the cleaned salt crust got off and continued vaporization concentrate on described vaporizer 3 sinks, and is arranged on shell
Concentrating pump 19 bottom body 1 is discharged, the salt crust discharged and concentrated solution sea in heat-exchangers of the plate type 20 heats water-filled pool 201
Water, the sea water in i.e. housing 1 is injected in heating, the most constantly can complete the most quickly desalination process of sea water.
The technique that the sea water desalinating unit of the present embodiment desalinizes seawater is as follows:
S1, described vacuum extractor 5 (are taken out respectively by the first vacuum line 14 and the second vacuum line 15 in housing 1
Vacuum equipment 5 connects with the upper cavity of housing 1) and captation 6 in incondensable gas constantly discharge and maintain high vacuum
State;
S2, sea water enter in housing 1 by the way of water filling adjusting means 203 is with evacuation self-priming, and described water filling regulates
Device 203 makes the sea water liquid level in housing 1 maintain vaporizer 3 most to go up an array of pipes and be submerged but the most broken plate 18 of indulging in serfing the Net;
S3, heat compression unit 9 are by synthesizing heat power supply device 10 to the compression of heat transfer medium (such as cold-producing medium) with suction group
With cold source device 11, the compressor/heat source of heat power supply device 10 is for vaporizer 3, and the diffusion cryogenic liquid of cold source device 11 is for condenser
4, heat energy is passed to the sea water outside vaporizer by indirect heating manner by vaporizer 3 by heat source, sea water be heated and
Making moisture content therein vaporize phase transformation, the gas phase stream of vaporization is the most mobile toward low-temperature end, the most quickly under the effect of temperature differential pressure
The big steam vapour phase stream that evaporation produces is broken into tiny gas steam vapour phase stream, this fine vapor gas phase when passing through brokenly and indulging in serfing the Net plate 18
Be condensed into fresh water after flowing condenser 4 heat release arranged by V-arrangement, the heat that condensation is discharged the most constantly by condenser 4 to effluent
The cryogenic liquid crossed is taken away in the way of indirect heat transfer, and the condenser 4 that the fresh water condensed out is arranged along V-arrangement flows into condensation
In device header 7, and flowed in captation 6 by the pipeline 16 that catchments, and constantly extract out through clarified water pump 17;
Outside S4, vaporizer 3 sea water produced salt crust after evaporation then under the constantly cleaning that salt crust removes device with
Sea water after continued vaporization concentration sinks to the bottom of lower chamber, and the concentrating pump 19 being arranged on housing bottom is discharged, and discharges
Salt crust and concentrated solution for injecting the sea water in housing 1, i.e. sea in water-filled pool 201 by heat-exchangers of the plate type 20 heating
Water, the most constantly can complete the most quickly desalination of sea water.
Embodiment 2
As shown in figures 1 and 3, the invention discloses a kind of efficient sea water desalting equipment, including housing 1, water filling device 2,
Vaporizer 3, condenser 4, vacuum extractor 5 and captation 6, described vacuum extractor 5 is by the first vacuum line 14 and institute
Stating housing 1 to connect, and connected with described captation 6 by the second vacuum line 15, described vacuum extractor 5 is bled for jetting
One in device, stream-jet ejector, vane-type vacuum pump or Roots vaccum pump, described vacuum extractor 5 is by housing 1 and the dress that catchments
Put the portion's noncondensing gas in 6 and constantly discharge and maintain the high vacuum state of the two.
Described housing 1 is divided into upper and lower two cavitys communicated, and described condenser 4 and described vaporizer 3 are separately positioned on institute
State in the upper and lower cavity of housing 1, described vaporizer 3, described condenser 4 and a heat compression unit one recycle heat of composition
System, described vaporizer 3 is used for making sea water be vaporizated into water vapour, and described condenser 4 is for being condensed into fresh water by water vapour;Described
Being provided with the condenser header 7 of open top in the upper cavity of housing 1, described condenser 4 is arranged on described condenser header 7
Top, the fresh water that described condenser header 7 produces after collecting water vapour condensation.
Described heat compression unit 9 is by synthesizing heat power supply device 10 to the compression of heat transfer medium (such as cold-producing medium) with suction group
With cold source device 11, described heat power supply device 10 provides the heat source indirect heat transfer recycled to the evaporation arranged in housing 1
Sea water outside device 3, sea water is heated and makes moisture content therein vaporization phase transformation produce water vapour, and described vaporizer 3 changes for tubular type
Heat pipe, the heat transfer medium in described vaporizer 3 is cold-producing medium, it is also possible to for low-pressure steam, heat carrier conduction oil or hot blast (except
Outside pipe type heat transfer pipe, described vaporizer 3 can also be electrically heated rod);Described cold source device 11 provides the low temperature recycled
Low-temperature receiver absorbs the gas heat outside described condenser 4, is fresh water by vapour phase water vapour rapid condensation, and described condenser 4 is
Light pipe or finned tube composition, its structure is box type or coil arrangement, and described low temperature cold source includes that low-temperature refrigerant enclosed is followed
Ring utilizes or open sea water is direct-cooled in line, in order to increase the contact area of vapour phase water vapour and condenser 4, improves heat exchange effect
Rate, condenser 4 is designed as circular arc by the present invention, and described condenser header 7 is arranged on the bottom part down of circular arc condenser 4
(as shown in Figure 3), when the volume of described condenser header 7 is much larger than the volume of condenser 4, at the top of condenser header 7
Surrounding can also arrange steam channel 8, and the water vapour that this steam channel 8 produces after making sea water vaporization enters described condenser
In header 7.
It is additionally provided with periodic cleaning sea water on described vaporizer 3 to concentrate and be bonded at the salt crust cleaning plant of vaporizer 3 outer wall
12, described salt crust cleaning plant 12 is revolution blade structure, and described salt crust cleaning plant 12 is connected with a driving means 13, described
Salt crust cleaning plant 12 persistently turns round under the drive of described driving means 13, is removed by the salt crust on described vaporizer 3,
Described driving means 13 part is arranged in housing 1, and another part is arranged on the outside of housing 1.
The broken plate 18 of indulging in serfing the Net that multilamellar is arranged, institute it is provided with between upper cavity and the lower chamber of described housing 1 of described housing 1
State brokenly in plate 18 of indulging in serfing the Net makes described lower chamber the big steam vapour phase stream produced to pass through mesh when moving and going to upper cavity and rupture
Become fine vapor vapour phase stream, the described broken holey plate that plate 18 is non-metallic material of indulging in serfing the Net, this reticulated cell be shaped as rhombus
Or other polygons.
Described captation 6 is connected with the bottom of described condenser header 7 by the pipeline 16 that catchments, described captation 6
Being also associated with the clarified water pump 17 for being extracted out by the fresh water in captation 6, the fresh water that described condenser header 7 condenses leads to
Crossing the pipeline 16 that catchments persistently to import in captation 6, the fresh water in captation 6 is sent endlessly by clarified water pump 17
Go out.
Described water filling device 2 includes water-filled pool 201, water injecting pipeline 202 and water filling adjusting means 203, described water-filled pool 201
Being connected by the lower chamber of described water injecting pipeline 202 with described housing 1, described water filling adjusting means 203 is arranged on described water filling
On pipeline 202, the sea water in described water-filled pool 201 enters the lower chamber of described housing 1 by the pressure mode of movement of suction pump
In, described water filling adjusting means 203 is for regulating the sea level fluctuations in described housing 1, and is controlled by sea level fluctuations described broken
Indulge in serfing the Net the lower section of plate 18, specifically sea water liquid level can be maintained vaporizer 3 go up most the pipe of a row be submerged but not higher than
Broken plate 18 of indulging in serfing the Net.
Sea water after the cleaned salt crust got off and continued vaporization concentrate on described vaporizer 3 sinks, and is arranged on shell
Concentrating pump 19 bottom body 1 is discharged, the salt crust discharged and concentrated solution sea in heat-exchangers of the plate type 20 heats water-filled pool 201
Water, the sea water in i.e. housing 1 is injected in heating, the most constantly can complete the most quickly desalination process of sea water.
The technique that the sea water desalinating unit of the present embodiment desalinizes seawater is as follows:
S1, described vacuum extractor 5 (are taken out respectively by the first vacuum line 14 and the second vacuum line 15 in housing 1
Vacuum equipment connects with the upper cavity of housing 1) and captation 6 in incondensable gas constantly discharge and maintain high vacuum shape
State;
S2, sea water enter in housing 1 by water filling adjusting means 203 with the pressure mode of movement of suction pump, described water filling
Adjusting means 203 makes the sea water liquid level in housing 1 maintain vaporizer 3 most to go up an array of pipes and be submerged but the most broken plate of indulging in serfing the Net
18;
S3, heat compression unit 9 are by synthesizing heat power supply device 10 to the compression of heat transfer medium (such as cold-producing medium) with suction group
With cold source device 11, the compressor/heat source of heat power supply device 10 is for vaporizer 3, and the diffusion cryogenic liquid of cold source device 11 is for condenser
4, heat energy is passed to the sea water outside vaporizer by indirect heating manner by vaporizer 3 by heat source, sea water be heated and
Making moisture content therein vaporize phase transformation, the gas phase stream of vaporization is the most mobile toward low-temperature end, the most quickly under the effect of temperature differential pressure
The big steam vapour phase stream that evaporation produces is broken into fine vapor vapour phase stream when passing through brokenly and indulging in serfing the Net plate 18, this fine vapor vapour phase stream
By being condensed into fresh water after condenser 4 heat release that circular arc is arranged, the heat that discharged of condensation the most constantly by condenser 4 to effluent
The cryogenic liquid crossed is taken away in the way of indirect heat transfer, and the condenser 4 that the fresh water condensed out is arranged along circular arc flows into
In condenser header 7, and flowed in captation 6 by the pipeline 16 that catchments, and constantly extract out through clarified water pump 17;
Outside S4, vaporizer 3 sea water produced salt crust after evaporation then under the constantly cleaning that salt crust removes device with
Sea water after continued vaporization concentration sinks to the bottom of lower chamber, and the concentrating pump 19 being arranged on housing bottom is discharged, and discharges
Salt crust and concentrated solution for injecting the sea water in housing 1, i.e. sea in water-filled pool 201 by heat-exchangers of the plate type 20 heating
Water, the most constantly can complete the most quickly desalination of sea water.
From above-described embodiment it can be seen that present invention solution is desalting process, sea water desalinating unit volume is relatively
Greatly, the problem that speed is relatively low and energy resource consumption is bigger is desalinated.The integrated full-closed structure of housing 1 of the present invention, with extraneous phase
Logical heavy liquor pump 19, catchment pipeline 16 and captation 6 and the clarified water pump 17 that is attached thereto all is tightly connected, do not allow outside air
Leak in housing 1.The trace incondensable gas carried in sea water is timely by vacuum extractor 5 and the vacuum line being tightly connected
Discharge, to maintain the vacuum required by efficient sea water desalting process phase transformation vaporization and condensation adiabatic condensation temperature.When using cold-producing medium
During as the coolant of condenser 4, its low-temperature receiver minimum temperature will be less than-45 degree, the heat source temperature after compression at about 65 degree, because of
This can by the vaporizer 3 and the heating surface area size of condenser 4 that adjust in housing 1 or by the way of taking auxiliary heating the most permissible
Meeting controlling the water circulation load and the requirement of load variations scope, condenser is shaped to V-arrangement or circular arc by the present invention, and cold
The bottom part down of condenser arranges a condenser header 7, and the present invention by above-mentioned improvement, adds being heated during condenser
Area, is effectively increased desalinization efficiency and speed.
The efficient sea water desalting equipment of the present invention, has the advantages that
1, the present invention utilizes vacuum state low temperature phase change and the principle realization sea evaporation of water that thermal resistance is little, isothermal is good light
Change, can be under the bigger temperature and pressure of suitable heating-up temperature and cold-producing medium cryogenic liquid condensation temperature, with relatively low phase transition temperature
Realizing the phase transformation transfer desalination of moisture content in sea water, its desalination speed and efficiency are far above existing evaporation of seawater desalinating process technology,
The energy consumption of desalinization and auxiliary material consuming cost can be reduced, under vacuum environment, at the heating high-efficiency evaporating temperature of sea water and low temperature
Vapour phase rapid condensation, can greatly reduce the heat exchange area of sea water desalinating unit, and make desalinating process control simple, performance is steady
Fixed, its surface structure is smaller and more exquisite.
2, vaporizer and the condenser of the present invention is arranged in a housing, and its structure is compacter, and volume is smaller and more exquisite,
Be provided with condenser header in the upper cavity of housing, described condenser be shaped as V-arrangement or circular arc, described condenser header sets
Putting the bottom part down at described condenser, on the one hand the condenser of V-arrangement or circular arc setting increases water vapour and condenser
Contact area, improves and changes heat exchange efficiency and speed, is on the other hand easy to condensed water droplet and flows into smoothly in condenser header.
3, the present invention is fine vacuum sea water by distillation mode, can obtain the fresh water of high-purity, vacuum evaporation after sea water vaporization
And condensation at low temperature, little low-grade energy can be utilized to consume quickly from sea water, obtain desalination water, vaccum cryogenic distillation dense
Contracting sea water salt crust uses mechanical chipping, and desalting process does not has consumable goods and pollutant to produce, and desalination process does not has waste gas to arrange
Putting and harmful substance produces, the height that desalting process concentrates can directly drain back into sea containing sea brine or refine sea salt, simultaneously
Salt crust and the concentrated pump of sea water concentrated solution can also be by the sea water in heat-exchangers of the plate type heating water-filled pool after discharging, it is achieved sea
The efficient desalination process of circulation of water.
4, the integrated hermetically sealed vacuum structure of the housing of the present invention, maintains the height needed for the distillation desalination of sea water low-temperature vaporization
Vacuum easily realizes, and utilizes the heating as desalinization of refrigerant heat and low-temperature refrigeration technology and the circulation compression of condensation
Hot low-temperature receiver, will reduce heating source thermal energy consumption and condensation energy loss, it is possible to decrease the supporting cost of manufacture of equipment and system and sea
Water desalinating cost, improves efficiency of energy utilization, and energy-conserving and environment-protective are significant.
Above disclosed be only the present invention several preferred embodiments, certainly can not with this limit the present invention it
Interest field, the equivalent variations therefore made according to the claims in the present invention, still belong to the scope that the present invention is contained.
Claims (10)
1. an efficient sea water desalting equipment, including housing (1) and vacuum extractor (5), described vacuum extractor (5) is for right
Described housing (1) carries out evacuation process;Described housing (1) is divided into upper and lower two cavitys communicated, described housing (1) upper
It is provided with condenser (4) in cavity, in the lower chamber of described housing (1), is provided with vaporizer (3), described vaporizer (3), described
Condenser (4) and heat compression unit (9) one heat circulation system of composition, it is characterised in that the epicoele of described housing (1)
The internal condenser header (7) being additionally provided with open top, described condenser (4) is arranged on the upper of described condenser header (7)
Side, described condenser header (7) is for collecting the fresh water produced in condensation process.
Efficient sea water desalting equipment the most according to claim 1, it is characterised in that described condenser (4) is V-arrangement or circular arc
Shape, described condenser header (7) is arranged on the bottom part down of described condenser (4).
3. according to the efficient sea water desalting equipment described in claim 2, it is characterised in that the top four of described condenser header (7)
Being additionally provided with steam channel (8) week, the water vapour that described steam channel (8) produces after making sea water vaporization enters described condensation
In device header (7).
4. according to the efficient sea water desalting equipment described in any one right in claim 1-3, it is characterised in that described heat
Compression unit (9) is by synthesizing heat power supply device (10) and cold source device (11) to the compression of heat transfer medium with suction group;
Described heat power supply device (10), for providing the heat source recycled for described vaporizer (3), vaporizes described housing (1)
Lower chamber in sea water;
Described cold source device (11) for providing the low temperature cold source recycled for described condenser (4), by produce after vaporization
Water vapour is condensed into fresh water.
Efficient sea water desalting equipment the most according to claim 4, it is characterised in that described housing is additionally provided with collection outside (1)
Water device (6), described captation (6) is connected by the bottom of the pipeline that catchments (16) with described condenser header (7), described collection
Water device (6) is also associated with the clarified water pump (17) for being extracted out by the fresh water in described captation (6).
Efficient sea water desalting equipment the most according to claim 5, it is characterised in that described vacuum extractor (5) is by the
One vacuum line (14) connects with the upper cavity of described housing (1), and by the second vacuum line (15) and described captation
(6) connection, described vacuum extractor (5) is in water jet air ejector, stream-jet ejector, vane-type vacuum pump or Roots vaccum pump
A kind of.
7. according to the efficient sea water desalting equipment described in claim 5 or 6, it is characterised in that the upper cavity of described housing (1) with
Being additionally provided with brokenly plate of indulging in serfing the Net (18) between the lower chamber of described housing (1), described broken plate (18) of indulging in serfing the Net is for by described lower chamber
The big steam vapour phase stream of interior generation is broken into fine vapor vapour phase stream, and described broken plate (18) of indulging in serfing the Net is holey plate, and it is single
Layer is arranged or multilamellar is arranged.
Efficient sea water desalting equipment the most according to claim 7, it is characterised in that described housing is additionally provided with note outside (1)
Water device (2), described water filling device (2) includes water-filled pool (201), water injecting pipeline (202) and water filling adjusting means (203), institute
State water-filled pool (201) to be connected with the lower chamber of described housing (1) by described water injecting pipeline (202), described water filling adjusting means
(203) being arranged on described water injecting pipeline (202), described water filling adjusting means (203) is used for regulating the cavity of resorption of described housing (1)
Sea level fluctuations is also controlled the lower section in described broken plate (18) of indulging in serfing the Net by internal sea level fluctuations.
Efficient sea water desalting equipment the most according to claim 8, it is characterised in that described vaporizer is additionally provided with on (3)
Salt crust cleaning plant (12), described salt crust cleaning plant (12) is connected with a driving means (13), described salt crust cleaning plant
(12) it is push-and-pull tube-in-tube structure or revolution blade structure, the drive in described driving means (13) of the described salt crust cleaning plant (12)
Continue down push-and-pull or revolution, the salt crust on described vaporizer (3) is cleared up.
Efficient sea water desalting equipment the most according to claim 8 or claim 9, it is characterised in that the bottom of described housing (1) is also
It is provided with for the salt crust got off and the concentrating pump (19) of sea water concentrated solution discharge, described salt crust and concentration will be cleared up on vaporizer
Liquid is for heating the sea water in described water-filled pool (201) by heat-exchangers of the plate type (20).
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CN109824105A (en) * | 2019-03-28 | 2019-05-31 | 上海济俭工业设备有限公司 | A kind of vacuum heat pump distillation and concentration system |
EP3543320A1 (en) * | 2018-03-23 | 2019-09-25 | Vilniaus Gedimino technikos universitetas | Device and method for enhancing biochar hydrophilicity |
CN110563234A (en) * | 2019-09-02 | 2019-12-13 | 龚建国 | low-energy-consumption seawater desalination system and method |
WO2022243727A1 (en) * | 2021-05-19 | 2022-11-24 | Shabanpour Haghighi Sajad | Methods and apparatus for treatment, desalination and sterilization of water by boiling at ambient temperature with reduced pressure |
CN116199292A (en) * | 2023-04-20 | 2023-06-02 | 桂林理工大学 | Surface super-hydrophilic modified sea water desalinator |
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EP3543320A1 (en) * | 2018-03-23 | 2019-09-25 | Vilniaus Gedimino technikos universitetas | Device and method for enhancing biochar hydrophilicity |
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CN116199292A (en) * | 2023-04-20 | 2023-06-02 | 桂林理工大学 | Surface super-hydrophilic modified sea water desalinator |
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CN117023683A (en) * | 2023-09-11 | 2023-11-10 | 山东水文水环境科技有限公司 | Multipolar flash evaporation sea water desalination system by utilizing geothermal energy |
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