CN106207104A - Storage battery coating plate method - Google Patents

Storage battery coating plate method Download PDF

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Publication number
CN106207104A
CN106207104A CN201610603313.5A CN201610603313A CN106207104A CN 106207104 A CN106207104 A CN 106207104A CN 201610603313 A CN201610603313 A CN 201610603313A CN 106207104 A CN106207104 A CN 106207104A
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CN
China
Prior art keywords
full
filling
plate
pole plate
filling machine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201610603313.5A
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Chinese (zh)
Other versions
CN106207104B (en
Inventor
孙尉轩
孙修平
刘建中
唐进兴
徐腾
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JIANGSU KENENG POWER Co Ltd
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JIANGSU KENENG POWER Co Ltd
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Priority to CN201610603313.5A priority Critical patent/CN106207104B/en
Publication of CN106207104A publication Critical patent/CN106207104A/en
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Publication of CN106207104B publication Critical patent/CN106207104B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/14Electrodes for lead-acid accumulators
    • H01M4/16Processes of manufacture
    • H01M4/20Processes of manufacture of pasted electrodes
    • H01M4/21Drying of pasted electrodes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/02Electrodes composed of, or comprising, active material
    • H01M4/14Electrodes for lead-acid accumulators
    • H01M4/16Processes of manufacture
    • H01M4/20Processes of manufacture of pasted electrodes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

The invention discloses a kind of storage battery coating plate method, including: treat that the pole plate of coated plate is placed in pole plate dryer, be dried to pole plate water content≤5%;Adjust a pair set screw of the plate outlet of full-filling machine so that it is distance ground level is identical;Pole plate is placed in grid supply machine, opens grid supply machine, full-filling machine, drenches acid device and dry tack free stove, and full-filling machine by grid supply machine conveying to pole plate full-filling anode diachylon or cathode lead plaster, pole plate, passes sequentially through full-filling machine, drenches acid device and dry tack free stove;Inspect by random samples once every 2min, the weight of pole plate after detection full-filling, if the weight of the coated plate after full-filling exceed preset value weight ± 3g, adjust full-filling machine goes out cream speed, make the weight of pole plate after coated plate preset value weight ± 3g within.By coated plate method disclosed by the invention, not only coated plate concise in technology, it is easy to operation, and by the pole plate after coated plate method coated plate disclosed by the invention, service life is long.

Description

Storage battery coating plate method
Technical field
The present invention relates to a kind of storage battery coating plate method.
Background technology
Lead-acid accumulator is a kind of gradual failure product, anti-along with accumulator due to pole plate during normal use Answering charge and discharge and constantly expand and shrink, the active substance meeting self falling on pole plate, when active substance comes off, it can be formed Become fault and make accumulator, cause earlier period damage, so that battery is scrapped;Simultaneously because accumulator charge and discharge repeatedly and not Expand disconnectedly and shrink, easily causing battery pole plates hydraulic performance decline or inefficacy, affecting charge and discharge point effect.
Summary of the invention
It is an object of the invention to solve at least the above, and the advantage that at least will be described later is provided.
It is a still further object of the present invention to provide a kind of storage battery coating plate method, its not only technique simple, and can effectively subtract The coming off of full-filling thing on few pole plate, extends pole plate service life.
In order to realize according to object of the present invention and further advantage, it is provided that a kind of storage battery coating plate method, including:
Step one, the pole plate treating coated plate is placed in pole plate dryer, at temperature is 50 DEG C, is dried to pole plate water content ≤ 5%;
Step 2, adjust a pair set screw of plate outlet of full-filling machine so that it is distance ground level is identical;
Step 3, will through the dried pole plate of step one be placed in grid supply machine, open grid supply machine, full-filling machine, pouring Acid device and dry tack free stove, full-filling machine, is depended on by grid supply machine conveying to pole plate full-filling anode diachylon or cathode lead plaster, pole plate Secondary by full-filling machine, pouring acid device and dry tack free stove, wherein,
Anode diachylon includes the material of following mass fraction: antimony oxide 1 part, stannous sulfate 1 part, 2 parts of graphite, terylene Chopped fiber 0.7 part, concentration are 20 parts of sulphuric acid, deionized water 30 parts, 80 parts of Hydrocerussitum (Ceruse) and the nano-carbon powder 0.1 part of 90%;
Cathode lead plaster includes the material of following mass fraction: β-PbO 80 parts, 7 parts of barium sulfate, 2 parts of graphite, terylene short fiber Tie up 1 part, concentration be 90% 10 parts of sulphuric acid, lignocellulose 1 part and nano-carbon powder 0.1 part;
Step 4, inspect by random samples once every 2min, the weight of pole plate after detection full-filling, if the weight of the coated plate after full-filling surpasses Cross preset value weight ± 3g, adjust full-filling machine goes out cream speed, make the weight of pole plate after coated plate preset value weight ± 3g Within.
Preferably, in described storage battery coating plate method, in described step 2, the speed controlling of full-filling machine 120/ min。
Preferably, in described storage battery coating plate method, when full-filling machine full-filling for anode diachylon time, adjust full-filling machine A pair roller space be 2.4 ± 0.05mm;
When full-filling machine full-filling for cathode lead plaster time, adjust full-filling machine a pair roller space be 1.45 ± 0.05mm.
Preferably, in described storage battery coating plate method, when full-filling machine full-filling for anode diachylon time, select grid weight Amount is 171 ± 2g, and slab lattice thickness is that the positive plate of 2.1 ± 0.05mm is as treating full-filling pole plate;
When full-filling machine full-filling for anode diachylon time, selecting grid weight is 126 ± 2g, slab lattice thickness is 1.3 ± The negative plate of 0.05mm is as treating full-filling pole plate.
Preferably, in described storage battery coating plate method, when full-filling machine full-filling for anode diachylon time, preset value weight 437g;
When full-filling machine full-filling for cathode lead plaster time, preset value weight 308g adjust full-filling machine a pair roller space be 2.4±0.05mm。
Preferably, in described storage battery coating plate method, in described step 3, when full-filling machine full-filling for anode diachylon Time, 30min before full-filling pole plate, open dry tack free stove, arranging furnace temperature is: 100 DEG C≤furnace temperature≤150 DEG C;
When full-filling machine full-filling for cathode lead plaster time, 30min before full-filling pole plate, open dry tack free stove, furnace temperature is set For: 70 DEG C≤furnace temperature≤100 DEG C.
The present invention at least includes following beneficial effect: be first dried pole plate, and controls its water content, effectively enhances lead Cream and the combination of pole plate, prevent from coming off;Adjustment with full-filling machine, it is ensured that the flatness of pole plate, is effectively guaranteed simultaneously and fills out Pole plate weight after painting consistent in density;The lead plaster of design in the present invention, its activity is strong, and after being assembled into battery, battery is initial Capacity is big, and circulation is awaited your instructions long.By coated plate method disclosed by the invention, not only coated plate concise in technology, it is easy to operation, and by this Pole plate after bright disclosed coated plate method coated plate, service life is long.
Part is embodied by the further advantage of the present invention, target and feature by description below, and part also will be by this Invention research and practice and be understood by the person skilled in the art.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, to make those skilled in the art with reference to description Word can be implemented according to this.
Should be appreciated that used herein such as " have ", " comprising " and " including " term do not allot one or many Other element individual or the existence of a combination thereof or interpolation.
The full-filling machine selected in the present embodiment is sunlight YG-STA360 type, and dry tack free stove is that Wuhan is dark blue.
1, equipment, instrument inspection
1.1 artificial front security protections
Operator should finish changing working clothing before entering operation scene, puts on Labor protection shoes, always wears your gloves, the labor protection such as mask is used Tool.
Equipment, place and Work tool inspection before 1.2 starts:
(1) start dry tack free stove: within the most about 30 minutes, allow dry tack free stove heat, set furnace temperature, when full-filling machine full-filling During for anode diachylon: 100 DEG C≤furnace temperature≤150 DEG C;When full-filling machine full-filling for cathode lead plaster time: 70 DEG C≤furnace temperature≤100 DEG C. And starting dry tack free stove chain, (initial stage is also dependent on practical situation to Process Planning definite value for the kiln speed of adjustment dry tack free stove Slow down kiln speed, to increase rate of rise in temperature), (during as found that drying oven pole plate conveyer chain belt surface has green corrosion, Ying Kai With wire brush, green corrosion is brushed off and washes down with pure water before beginning coated plate);
(2) adjust plate receiving device: sky walks several overtime works, adjust plate receiving device so that it is width adequate pole plate model.
(3) the cleaning of full-filling machine and rust cleaning: use hands rotating rocker, slowly digs hopper, first with tap water, then rushes with pure water Wash hopper, head, pressure roller, roller-way, cleaning, wiped clean rust and remaining cream.
(4) check full-filling machine tensioning coated belt regulating wheel, coated belt pure water moistening started full-filling machine, dallies 10 minutes, Check whether normal.
(5) check that electric wiring is the most intact, reports immediately if any breakage and repaiies, it is ensured that safety utilization of electric power
(6) check that compressed air line is the most intact, should report for repairment immediately if any breakage.
Check equipment and whether environmental health cleans, totally, do not clean place such as dust, stain, rust etc., should enter immediately Row is removed.
1.3 raw material inspection
(1) pouring acid quality examination:
Acid density should be drenched by operative employee's self-inspection before every every class, be rechecked by Quality Inspector's density sour to pouring and sampled and send chemical examination Could use after room analysis is qualified;
(2) pure water quality examination
An electrical conductivity of water is checked by Quality Inspector at coated plate pure water outlet when per tour starts, after meeting technological requirement, Can use.
Pole plate inspection the most to be coated:
(placing 7 days) grid to be coated is checked, first checks grid with or without cold cracking, detection side by Quality Inspector Method: in units of pallet, every layer of every pallet takes 1 from corner, top and corner, bottom, 8 altogether, checks pole plate volume piecewise On the reel of diameter 50mm, rolling up once with diagonal way forward, once, each position of pole plate should be adjacent to reel to backward-coiled, as Occurring without crackle, it is determined that qualified, reply plate ear position especially checks, method: become 80~90 degree of angles with finger top, visually Check for fracture.Confirm that positive plate can throw in use without cold cracking phenomenon.Positive/negative plate to be checked is with or without outside other Sight problem, if any other appearance qualities, should report in time, can not throw in use without authorization.10 poles are also weighed before using The average weight of plate, and record.
(4) lead plaster inspection: checking that the lead plaster outward appearance put down has free from admixture, stain, color has without exception, and additive is with or without stirring Mix uniformly, chopped fiber with or without phenomenon of uniting, confirm qualified after can use.
2, coated plate
Step one, the pole plate treating coated plate is placed in pole plate dryer, at temperature is 50 DEG C, is dried to pole plate water content ≤ 5%, wherein, when full-filling machine full-filling for anode diachylon time, selecting grid weight is 171 ± 2g, slab lattice thickness is 2.1 ± The positive plate of 0.05mm is as treating full-filling pole plate;
When full-filling machine full-filling for anode diachylon time, selecting grid weight is 126 ± 2g, slab lattice thickness is 1.3 ± The negative plate of 0.05mm is as treating full-filling pole plate;
Step 2, adjust a pair set screw of plate outlet of full-filling machine so that it is distance ground level is identical;Adjust full-filling Machine pressure roller distance, when full-filling machine full-filling for anode diachylon time, adjust full-filling machine a pair roller space be 2.4 ± 0.05mm; When full-filling machine full-filling for cathode lead plaster time, adjust full-filling machine a pair roller space be 1.45 ± 0.05mm
Step 3, will through the dried pole plate of step one be placed in grid supply machine, open grid supply machine, full-filling machine, pouring Acid device and dry tack free stove, full-filling machine, is depended on by grid supply machine conveying to pole plate full-filling anode diachylon or cathode lead plaster, pole plate Secondary by full-filling machine, pouring acid device and dry tack free stove, wherein, the speed controlling of full-filling machine is at 140/min, and it is close that pole plate drenches acid Degree parameter is shown in Table one;
Anode diachylon includes: antimony oxide 1Kg, stannous sulfate 1Kg, graphite 2Kg, polyester staple fiber 0.7Kg, concentration are Sulphuric acid 20Kg, deionized water 30Kg, Hydrocerussitum (Ceruse) 80Kg and the nano-carbon powder 0.1Kg of 90%;
Cathode lead plaster includes: β-PbO 80Kg, barium sulfate 7Kg, graphite 2Kg, polyester staple fiber 1Kg, concentration are 90% Sulphuric acid 10Kg, lignocellulose 1Kg and nano-carbon powder 0.1Kg;
Step 4, inspect by random samples once every 2min, the weight of pole plate after detection full-filling, if the weight of the coated plate after full-filling surpasses Cross preset value weight ± 3g, adjust full-filling machine goes out cream speed, make the weight of pole plate after coated plate preset value weight ± 3g Within;
Wherein, when full-filling machine full-filling for anode diachylon time, preset value weight 437g;When full-filling machine full-filling for negative electrode lead During cream, it is 2.4 ± 0.05mm that preset value weight 308g adjusts a pair roller space of full-filling machine.
3, detection
Outward appearance:
The polar board surface prepared through the embodiment of the present invention is smooth, woven design is clear, full-filling is full, drench acid uniformly, and pole plate is without becoming Shape, lug surface are concavo-convex without tile, without serious without groove mark, intact cream, unbiased cream, surface without lead plaster, four frame nothing left cream, surface Leakage muscle, subside without one side, surface without glue.
Weight detecting:
With the pole plate after the balance measurement full-filling that scale division value is 1g, the most qualified.
Table one, pole plate drench acid density parameter
Although embodiment of the present invention are disclosed as above, but it is not restricted in description and embodiment listed Using, it can be applied to various applicable the field of the invention completely, for those skilled in the art, and can be easily Realizing other amendment, therefore under the general concept limited without departing substantially from claim and equivalency range, the present invention does not limit In specific details.

Claims (6)

1. a storage battery coating plate method, it is characterised in that including:
Step one, the pole plate treating coated plate is placed in pole plate dryer, at temperature is 50 DEG C, be dried to pole plate water content≤ 5%;
Step 2, adjust a pair set screw of plate outlet of full-filling machine so that it is distance ground level is identical;
Step 3, will through the dried pole plate of step one be placed in grid supply machine, open grid supply machine, full-filling machine, drench acid dress Putting and dry tack free stove, full-filling machine, is led to by grid supply machine conveying successively to pole plate full-filling anode diachylon or cathode lead plaster, pole plate Cross full-filling machine, drench acid device and dry tack free stove, wherein,
Anode diachylon includes the material of following mass fraction: antimony oxide 1 part, stannous sulfate 1 part, 2 parts of graphite, terylene short fiber Tie up 0.7 part, concentration be 90% 20 parts of sulphuric acid, deionized water 30 parts, 80 parts of Hydrocerussitum (Ceruse) and nano-carbon powder 0.1 part;
Cathode lead plaster includes the material of following mass fraction: β-PbO 80 parts, 7 parts of barium sulfate, 2 parts of graphite, polyester staple fiber 1 Part, concentration are 10 parts of sulphuric acid, lignocellulose 1 part and the nano-carbon powder 0.1 part of 90%;
Step 4, inspecting by random samples once every 2min, the weight of pole plate after detection full-filling, if the weight of the coated plate after full-filling exceedes pre- If value weight ± 3g, adjust full-filling machine goes out cream speed, make the weight of pole plate after coated plate preset value weight ± 3g within.
2. storage battery coating plate method as claimed in claim 1, it is characterised in that in described step 2, the speed control of full-filling machine System is at 120/min.
3. storage battery coating plate method as claimed in claim 1, it is characterised in that in described step 2, when full-filling machine full-filling During for anode diachylon, a pair roller space adjusting full-filling machine is 2.4 ± 0.05mm;
When full-filling machine full-filling for cathode lead plaster time, adjust full-filling machine a pair roller space be 1.45 ± 0.05mm.
4. storage battery coating plate method as claimed in claim 1, it is characterised in that when full-filling machine full-filling for anode diachylon time, Selecting grid weight is 171 ± 2g, and slab lattice thickness is that the positive plate of 2.1 ± 0.05mm is as treating full-filling pole plate;
When full-filling machine full-filling for anode diachylon time, select grid weight be 126 ± 2g, slab lattice thickness is 1.3 ± 0.05mm's Negative plate is as treating full-filling pole plate.
5. storage battery coating plate method as claimed in claim 4, it is characterised in that described step 4, when full-filling machine full-filling be During anode diachylon, preset value weight 437g;
When full-filling machine full-filling for cathode lead plaster time, preset value weight 308g adjust a pair roller space of full-filling machine be 2.4 ± 0.05mm。
6. storage battery coating plate method as claimed in claim 1, it is characterised in that in described step 3, when full-filling machine full-filling During for anode diachylon, 30min before full-filling pole plate, open dry tack free stove, arranging furnace temperature is: 100 DEG C≤furnace temperature≤150 DEG C;
When full-filling machine full-filling for cathode lead plaster time, 30min before full-filling pole plate, open dry tack free stove, arranging furnace temperature is: 70 DEG C≤furnace temperature≤100 DEG C.
CN201610603313.5A 2016-07-28 2016-07-28 Storage battery coating plate method Expired - Fee Related CN106207104B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201610603313.5A CN106207104B (en) 2016-07-28 2016-07-28 Storage battery coating plate method

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CN106207104B CN106207104B (en) 2019-03-12

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108365180A (en) * 2017-12-29 2018-08-03 广州倬粤动力新能源有限公司 Pole plate drenches tin method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201270270Y (en) * 2008-06-05 2009-07-08 哈尔滨润邦科技发展有限公司 Production apparatus for non-maintaining enclosed battery double-face coating plate
CN102306799A (en) * 2010-03-24 2012-01-04 衡阳瑞达电源有限公司 Deep cycle-resistant lead-acid storage battery plate and manufacturing method
CN102842721A (en) * 2012-08-01 2012-12-26 浙江众益电源有限公司 Method for prolonging cycle life of lead-acid storage battery
CN103531750A (en) * 2013-09-18 2014-01-22 超威电源有限公司 Method for ensuring coating weight uniformity of lead-acid storage battery machine
CN104466266A (en) * 2014-12-25 2015-03-25 萍乡市天东电器科技有限公司 Lead-acid storage battery and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN201270270Y (en) * 2008-06-05 2009-07-08 哈尔滨润邦科技发展有限公司 Production apparatus for non-maintaining enclosed battery double-face coating plate
CN102306799A (en) * 2010-03-24 2012-01-04 衡阳瑞达电源有限公司 Deep cycle-resistant lead-acid storage battery plate and manufacturing method
CN102842721A (en) * 2012-08-01 2012-12-26 浙江众益电源有限公司 Method for prolonging cycle life of lead-acid storage battery
CN103531750A (en) * 2013-09-18 2014-01-22 超威电源有限公司 Method for ensuring coating weight uniformity of lead-acid storage battery machine
CN104466266A (en) * 2014-12-25 2015-03-25 萍乡市天东电器科技有限公司 Lead-acid storage battery and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108365180A (en) * 2017-12-29 2018-08-03 广州倬粤动力新能源有限公司 Pole plate drenches tin method

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