CN106206257A - The method preparing low-temperature polysilicon film and transistor - Google Patents

The method preparing low-temperature polysilicon film and transistor Download PDF

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Publication number
CN106206257A
CN106206257A CN201610661993.6A CN201610661993A CN106206257A CN 106206257 A CN106206257 A CN 106206257A CN 201610661993 A CN201610661993 A CN 201610661993A CN 106206257 A CN106206257 A CN 106206257A
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area
polysilicon film
substrate
temperature
layer
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CN201610661993.6A
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Chinese (zh)
Inventor
王鹏飞
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Kunshan Govisionox Optoelectronics Co Ltd
Kunshan Guoxian Photoelectric Co Ltd
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Kunshan Guoxian Photoelectric Co Ltd
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Priority to CN201610661993.6A priority Critical patent/CN106206257A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02518Deposited layers
    • H01L21/02521Materials
    • H01L21/02524Group 14 semiconducting materials
    • H01L21/02532Silicon, silicon germanium, germanium
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02518Deposited layers
    • H01L21/02587Structure
    • H01L21/0259Microstructure
    • H01L21/02592Microstructure amorphous
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02365Forming inorganic semiconducting materials on a substrate
    • H01L21/02656Special treatments
    • H01L21/02664Aftertreatments
    • H01L21/02667Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth
    • H01L21/02675Crystallisation or recrystallisation of non-monocrystalline semiconductor materials, e.g. regrowth using laser beams
    • H01L21/02683Continuous wave laser beam
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/0684Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions characterised by the shape, relative sizes or dispositions of the semiconductor regions or junctions between the regions
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/02Semiconductor bodies ; Multistep manufacturing processes therefor
    • H01L29/06Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions
    • H01L29/10Semiconductor bodies ; Multistep manufacturing processes therefor characterised by their shape; characterised by the shapes, relative sizes, or dispositions of the semiconductor regions ; characterised by the concentration or distribution of impurities within semiconductor regions with semiconductor regions connected to an electrode not carrying current to be rectified, amplified or switched and such electrode being part of a semiconductor device which comprises three or more electrodes
    • H01L29/1025Channel region of field-effect devices
    • H01L29/1029Channel region of field-effect devices of field-effect transistors
    • H01L29/1033Channel region of field-effect devices of field-effect transistors with insulated gate, e.g. characterised by the length, the width, the geometric contour or the doping structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices adapted for rectifying, amplifying, oscillating or switching, or capacitors or resistors with at least one potential-jump barrier or surface barrier, e.g. PN junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof  ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66742Thin film unipolar transistors
    • H01L29/6675Amorphous silicon or polysilicon transistors

Abstract

The present invention relates to a kind of method preparing low-temperature polysilicon film, comprise the steps: to provide substrate;Form temperature difference cambium layer on the substrate;Described temperature difference cambium layer includes that multiple first area and second area, described first area and second area, when carrying out laser annealing, form temperature difference;Accumulation amorphous silicon layer on described temperature difference cambium layer;Carry out laser annealing to form polysilicon layer.The invention still further relates to a kind of method preparing low-temperature polysilicon film transistor.Said method makes amorphous silicon layer difference corresponding region when laser annealing also form temperature difference; so; crystal grain in the low-temperature space of amorphous silicon layer can spread in high-temperature region, finally realizes the super transverse crystallization of silicon crystal grain, obtains the polysilicon layer that crystallite dimension is big and is evenly distributed.Owing to the formation of temperature difference obtains not by laser scanning line, but being obtained by laser once irradiating, therefore production efficiency is higher.

Description

The method preparing low-temperature polysilicon film and transistor
Technical field
The present invention relates to Display Technique field, particularly relate to a kind of side preparing low-temperature polysilicon film and transistor Method.
Background technology
Compared with amorphous silicon film transistor (a-Si TFT), low-temperature polysilicon film transistor (LTPS TFT) technology has Standby plurality of advantages, as mobility is the highest, up to 10-100cm2About/Vs, can prepare (less than 600 simultaneously under cryogenic DEG C), choice of the substrates is flexible, is currently the only and flexible display technologies compatible active layers technology of preparing.
Traditional low-temperature polysilicon film preparation uses linear laser beam scanning, utilizes adjacent scanning in scanning process Temperature difference on line produces polysilicon.Although this method can produce more uniform polysilicon membrane, but scanning speed Slowly, limiting the preparation of large area display, production efficiency is relatively low simultaneously, adds production cost.
Summary of the invention
Based on this, it is necessary to provide a kind of method preparing low-temperature polysilicon film that production efficiency is high.
Additionally, also provide for a kind of method preparing low-temperature polysilicon film transistor.
A kind of method preparing low-temperature polysilicon film, comprises the steps:
Substrate is provided;
Form temperature difference cambium layer on the substrate;Described temperature difference cambium layer includes multiple first area and second area, Described first area and second area, when carrying out laser annealing, form temperature difference;
Accumulation amorphous silicon layer on described temperature difference cambium layer;
Carry out laser annealing to form polysilicon layer.
Wherein in an embodiment, the described cambial step of the temperature difference that formed on the substrate includes:
Form reservoir;
Described reservoir is patterned technique, forms the region having beyond reeded region and groove;Described groove Region is first area, and the region beyond described groove is second area.
Wherein in an embodiment, described reservoir is formed on cushion, and described cushion is formed in substrate.
Wherein in an embodiment, described cushion is the silicon nitride layer and silicon oxide layer being sequentially laminated on substrate, Described reservoir is heat insulation layer, water proof and heat insulation insulation material are formed.
Wherein in an embodiment, the described cambial step of the temperature difference that formed on the substrate includes:
Substrate is formed cushion;
Described cushion is carried out selective doping, obtains doped region and undoped region;Described doped region is One region, described undoped region is second area.
Wherein in an embodiment, described cushion is the silicon nitride layer and silicon oxide layer being sequentially laminated on substrate.
Wherein in an embodiment, the material of doping is boron or phosphate material, doped region and the insulation in undoped region Performance is inconsistent.
A kind of method preparing low-temperature polysilicon film transistor, including the preparation process of low-temperature polysilicon film;Described The preparation process of low-temperature polysilicon film uses above-mentioned preparation method;
Wherein, described first area is the non-channel region of transistor, and described second area is the channel region of transistor.
Wherein in an embodiment, described substrate is glass substrate.
Said method, owing to defining one layer of temperature difference cambium layer, when carrying out laser annealing, temperature difference cambium layer in substrate First area and second area can be respectively provided with different temperature, so that be covered in the non-crystalline silicon on temperature difference cambium layer The different corresponding regions of layer also form temperature difference, and so, the crystal grain in the low-temperature space of amorphous silicon layer can spread in high-temperature region, Finally realize the super transverse crystallization of silicon crystal grain, obtain the polysilicon layer that crystallite dimension is big and is evenly distributed.Due to temperature difference Being formed and obtain not by laser scanning line, but obtained by laser once irradiating, therefore production efficiency is higher.
Accompanying drawing explanation
Fig. 1 is the method flow diagram preparing low-temperature polysilicon film of an embodiment;
Fig. 2 a~2d is the profile of the structure of each step gained of flow process shown in Fig. 1;
Fig. 3 a~3e is the profile of the structure of each step gained forming cambial first embodiment of the temperature difference;
Fig. 4 a~4d is the profile of the structure of each step gained forming cambial second embodiment of the temperature difference.
Detailed description of the invention
It is further described below in conjunction with drawings and Examples.
Fig. 1 is the method flow diagram preparing low-temperature polysilicon film of an embodiment.Fig. 2 a~2d is cutting of each stage Face figure.In conjunction with Fig. 1 and Fig. 2 a~2d, following description prepares the method for low-temperature polysilicon film.
As it is shown in figure 1, this method preparing low-temperature polysilicon film comprises the steps.
Step S110: substrate 100 is provided.With reference to Fig. 2 a, substrate 100 ultimately forms polysilicon membrane.Substrate 100 can Think substrate of glass.
Step S120: form temperature difference cambium layer 200 in described substrate 100.Temperature difference cambium layer 200 includes multiple firstth district Territory 201 and second area 202.First area 201 and second area 202, when carrying out laser annealing, form temperature difference.Based on One region 201 and the different materials of second area 202, characteristic etc., when carrying out laser annealing, the two absorbs and stores energy Ability is different, thus causes the temperature difference of the two, and then forms temperature difference.
Step S130: accumulation amorphous silicon layer 300 on described temperature difference cambium layer 200.The annealed process of non-crystalline silicon is permissible Form polysilicon.Polysilicon to be formed, needs first to deposit one layer of amorphous silicon layer, and non-crystalline silicon can shape at a lower temperature Become, be then passed through annealing and form polysilicon.
Step S140: carry out laser annealing to form polysilicon.Specifically, be on amorphous silicon layer 300 with the secondth district The position of territory 202 correspondence forms polysilicon region.Generally, non-crystalline silicon uses high annealing to form polysilicon.But it is high Temperature annealing forms the method for polysilicon and is not suitable for certain situation, such as, need to be formed on a glass substrate polysilicon.It addition, it is logical Cross laser scanning side crystallization method, it is also possible to form polysilicon at a lower temperature, but treatment effeciency is the lowest.This step Laser anneal method is Dispensable continuous irradiation, when carrying out laser and irradiating, and the first area 201 of temperature difference cambium layer 200 and the Two regions 202 are different due to the ability absorbing energy, can have different temperature.
Owing to defining one layer of temperature difference cambium layer 200, when carrying out laser annealing, temperature difference cambium layer 200 in substrate 100 First area 201 and second area 202 can be respectively provided with different temperature so that be covered in temperature difference cambium layer 200 it On the different corresponding regions of amorphous silicon layer 300 also form temperature difference, so, the crystal grain in the low-temperature space of amorphous silicon layer 300 Can spread in high-temperature region, finally realize the super transverse crystallization of silicon crystal grain, obtain the polycrystalline that crystallite dimension is big and is evenly distributed Silicon layer.Owing to the formation of temperature difference obtains not by laser scanning line, but obtained by laser once irradiating, therefore produce In hgher efficiency.
In above-described embodiment, it is important to the formation of temperature difference cambium layer 200, specifically can use various ways.As long as Same annealing laser irradiates the method for generation different temperatures can.Below with two specific embodiments to forming the temperature difference The method of cambium layer 200 illustrates.
In the first embodiment, in conjunction with Fig. 3 a~3e, the described cambial step of the temperature difference that formed on the substrate, i.e. Above-mentioned steps S120 includes:
Step S121: form cushion 210.As shown in Figure 3 a, cushion 210 is formed in above-mentioned substrate 100.Described Cushion is the silicon nitride layer and silicon oxide layer being sequentially laminated on substrate.For exclusion of water oxygen and stop from glass substrate Pollutant.
Step S122: form reservoir 220 at described cushion 210.Reservoir 220 can store heat when laser annealing Amount, thus elevate the temperature.As shown in Figure 3 b.
Step S123: described reservoir 220 is patterned technique, forms the district having beyond reeded region and groove Territory.Described grooved area is corresponding to above-mentioned first area 201, and the region beyond described groove is second area 202.Such as Fig. 3 c Shown in.
After above-mentioned steps, the amorphous silicon layer 300 such as figure formed on the reservoir 220 being patterned after technique Shown in 3d.After laser annealing processes, the crystal grain of low-temperature space spreads to high-temperature region, forms state as shown in Figure 3 e.
In this second embodiment, in conjunction with Fig. 4 a~4d, the described cambial step of the temperature difference that formed on the substrate, i.e. Above-mentioned steps S120 includes:
Step S121 ': form cushion 210.As shown in fig. 4 a, cushion 210 is formed in above-mentioned substrate 100.Institute Stating cushion is the silicon nitride layer and silicon oxide layer being sequentially laminated on substrate.For exclusion of water oxygen and stop from glass base The pollutant of plate.
Step S122 ': cushion 210 is carried out selective doping, obtains doped region and undoped region.Described doping Region is corresponding to above-mentioned first area 201, and described undoped region should be in above-mentioned second area 202.Chosen property is adulterated After, doped region and undoped region, when carrying out laser annealing and processing, can produce temperature contrast.As shown in Figure 4 b.To buffering The material that layer 210 is doped is boron or phosphate material, and the heat-insulating property in doped region and undoped region is inconsistent.Doping method Including ion implanting etc..
After above-mentioned steps, the amorphous silicon layer 300 such as Fig. 4 c formed on the cushion 210 carry out selective doping Shown in.After laser annealing processes, the crystal grain of low-temperature space spreads to high-temperature region, forms state as shown in figure 4d.
The method preparing low-temperature polysilicon film of above-described embodiment can apply to low-temperature polysilicon film transistor In manufacture process.Forming polysilicon membrane is the previous step manufacturing transistor.
When the concrete method using above-described embodiment, first form polysilicon membrane according to the method for above-described embodiment. Wherein, the described second area 202 of the polysilicon membrane of formation can be as the channel region of transistor.First area 201 is then Can be as isolation area.Afterwards can according to formed transistor technique formed thin film transistor (TFT), these techniques include isolation, doping, Deposit, etching etc., for forming the source electrode of transistor, drain electrode, grid structure.This is for manufacturing the normal process steps of transistor, at this Do not repeat.
When needs carry out multilamellar transistor technology, the preparation process of above-mentioned low-temperature polysilicon film can be repeated, with And utilize the polysilicon membrane formed to manufacture transistor.
Owing to being low-temperature polysilicon film manufacturing technology, polysilicon can be formed at relatively low temperature (less than 600 DEG C), The most described substrate can be glass substrate.
Each technical characteristic of embodiment described above can combine arbitrarily, for making description succinct, not to above-mentioned reality The all possible combination of each technical characteristic executed in example is all described, but, as long as the combination of these technical characteristics is not deposited In contradiction, all it is considered to be the scope that this specification is recorded.
Embodiment described above only have expressed the several embodiments of the present invention, and it describes more concrete and detailed, but also Can not therefore be construed as limiting the scope of the patent.It should be pointed out that, come for those of ordinary skill in the art Saying, without departing from the inventive concept of the premise, it is also possible to make some deformation and improvement, these broadly fall into the protection of the present invention Scope.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.

Claims (9)

1. the method preparing low-temperature polysilicon film, comprises the steps:
Substrate is provided;
Form temperature difference cambium layer on the substrate;Described temperature difference cambium layer includes multiple first area and second area, described First area and second area, when carrying out laser annealing, form temperature difference;
Accumulation amorphous silicon layer on described temperature difference cambium layer;
Carry out laser annealing to form polysilicon layer.
The method preparing low-temperature polysilicon film the most according to claim 1, it is characterised in that described on the substrate Form the cambial step of the temperature difference to include:
Form reservoir;
Described reservoir is patterned technique, forms the region having beyond reeded region and groove;Described grooved area For first area, the region beyond described groove is second area.
The method preparing low-temperature polysilicon film the most according to claim 2, it is characterised in that described reservoir is formed at On cushion, described cushion is formed in substrate.
The method preparing low-temperature polysilicon film the most according to claim 3, it is characterised in that described cushion is successively The silicon nitride layer being layered on substrate and silicon oxide layer, described reservoir is heat insulation layer, by water proof and heat insulation thermal insulating material Material is formed.
The method preparing low-temperature polysilicon film the most according to claim 1, it is characterised in that described on the substrate Form the cambial step of the temperature difference to include:
Substrate is formed cushion;
Described cushion is carried out selective doping, obtains doped region and undoped region;Described doped region is the firstth district Territory, described undoped region is second area.
The method preparing low-temperature polysilicon film the most according to claim 5, it is characterised in that described cushion is successively The silicon nitride layer being layered on substrate and silicon oxide layer.
The method preparing low-temperature polysilicon film the most according to claim 5, it is characterised in that the material of doping be boron or Phosphate material, the heat-insulating property in doped region and undoped region is inconsistent.
8. the method preparing low-temperature polysilicon film transistor, including the preparation process of low-temperature polysilicon film;Described low The preparation process of temperature polysilicon membrane uses the preparation method described in any one of claim 1~7;
Wherein, described first area is the non-channel region of transistor, and described second area is the channel region of transistor.
The method preparing low-temperature polysilicon film transistor the most according to claim 8, it is characterised in that described substrate is Glass substrate.
CN201610661993.6A 2016-08-12 2016-08-12 The method preparing low-temperature polysilicon film and transistor Pending CN106206257A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2018145515A1 (en) * 2017-02-09 2018-08-16 京东方科技集团股份有限公司 Thin film transistor and fabrication method therefor, display substrate and display device

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CN102945789A (en) * 2012-11-22 2013-02-27 京东方科技集团股份有限公司 Preparation method of low-temperature polycrystalline silicon film, thin-film transistor and preparation method of thin-film transistor
US20130183875A1 (en) * 2012-01-17 2013-07-18 Chang Fu Tsai Socket having symmetrically arranged first and second casings with interlocking arrangements to define a led seat
CN104064451A (en) * 2014-07-10 2014-09-24 深圳市华星光电技术有限公司 Low-temperature poly-silicon manufacturing method, method for manufacturing TFT substrate by utilization of low-temperature poly-silicon manufacturing method, and TFT substrate structure
CN104505340A (en) * 2014-11-28 2015-04-08 信利(惠州)智能显示有限公司 Preparation method for low-temperature polycrystalline silicon film
CN104966663A (en) * 2015-05-22 2015-10-07 信利(惠州)智能显示有限公司 LTPS film, preparation method thereof, and TFT

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JPH0319210A (en) * 1989-06-15 1991-01-28 Matsushita Electron Corp Manufacture of semiconductor device
US20060043367A1 (en) * 2004-09-01 2006-03-02 Mao-Yi Chang Semiconductor device and method of fabricating a low temperature poly-silicon layer
US20130183875A1 (en) * 2012-01-17 2013-07-18 Chang Fu Tsai Socket having symmetrically arranged first and second casings with interlocking arrangements to define a led seat
CN102945789A (en) * 2012-11-22 2013-02-27 京东方科技集团股份有限公司 Preparation method of low-temperature polycrystalline silicon film, thin-film transistor and preparation method of thin-film transistor
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WO2018145515A1 (en) * 2017-02-09 2018-08-16 京东方科技集团股份有限公司 Thin film transistor and fabrication method therefor, display substrate and display device

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