CN106191964A - Oxidation rear substrate surface pore inlays packing material and technology - Google Patents

Oxidation rear substrate surface pore inlays packing material and technology Download PDF

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Publication number
CN106191964A
CN106191964A CN201610539519.6A CN201610539519A CN106191964A CN 106191964 A CN106191964 A CN 106191964A CN 201610539519 A CN201610539519 A CN 201610539519A CN 106191964 A CN106191964 A CN 106191964A
Authority
CN
China
Prior art keywords
workpiece
film
sealer
oxidation
hole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610539519.6A
Other languages
Chinese (zh)
Inventor
郭向阳
李力
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mei Yi Metallic Article Co Ltd Of Pingdingshan City
Original Assignee
Mei Yi Metallic Article Co Ltd Of Pingdingshan City
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mei Yi Metallic Article Co Ltd Of Pingdingshan City filed Critical Mei Yi Metallic Article Co Ltd Of Pingdingshan City
Priority to CN201610539519.6A priority Critical patent/CN106191964A/en
Publication of CN106191964A publication Critical patent/CN106191964A/en
Priority to CN201710491610.XA priority patent/CN107236978A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82After-treatment
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/80After-treatment
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D11/00Electrolytic coating by surface reaction, i.e. forming conversion layers
    • C25D11/02Anodisation
    • C25D11/34Anodisation of metals or alloys not provided for in groups C25D11/04 - C25D11/32

Abstract

The invention discloses oxidation rear substrate surface pore and inlay packing material and technology, comprise the following steps: step one, filling perforation, sealer is sprayed onto the base material surface of the work after oxidation and fills the hole on sealing substrate surface;Step 2, solid film, carry out high temperature curve sintering to the workpiece after filling perforation, and the material in sealer is inlayed be sealed in surface of the work and hole completely, forms a tunic;Step 3, polishing or sanding, mechanically polish the workpiece after solid film or after the loose of surface and unwanted layers removed by the method for sanding, and above-mentioned sealer combines together the most completely with oxide-film hole.Advantages of the present invention: embed hole sealing agent molecule in the surface pore of base material workpiece after oxidation, the finish surface obtained, make that workpiece has non-stick, coefficient of friction is low, antirust ability is strong, by the basal body structure that oxide-film is firm, in conjunction with described sealing material, make workpiece wear-resisting durable so that product can be widely used in industry and life.

Description

Oxidation rear substrate surface pore inlays packing material and technology
Technical field
The present invention relates to aoxidize rear substrate surface pore and inlay packing material and technology.
Background technology
Metal works easily gets rusty, and for preventing from getting rusty, the most typically can use and metal works is carried out oxidation processes, present stage Seem the most smooth, smooth through the peroxidating surface of workpiece that particularly high accuracy aoxidizes, but aobvious workpiece is placed on Under micro mirror, still it can be seen that there is the hole that some are loose on the surface of these workpiece, due to depositing of this some holes when carrying out microscopic observation Have some limitations in the use making workpiece, as the casting iron pan of cooker be difficult in use to have good viscous and Antirust anti-wear performance, and service life be there is also certain impact.
Summary of the invention
The invention aims to solve problems of the prior art, and the oxidation rear substrate surface pore proposed Inlay packing material and technology.
To achieve these goals, present invention employs following technical scheme:
Oxidation rear substrate surface pore inlays packing material and technology, it is characterised in that comprise the following steps:
Step one, filling perforation, be sprayed onto the base material surface of the work after oxidation sealer and fill the hole of substrate surface, this Some holes gap seals, and sealer is uniformly mixed by any one the corresponding retarder thinner in following four material, institute Stating four kinds of materials is: a, fluorine carbon material, b, organosilicon and inorganic silicon material, c, inorganic molybdenum bisuphide material, d, unsaturated hydrocarbons, Unsaturated fatty acid, palmitic acid, stearic acid, the monoglyceride compounds of unsaturated fatty acid or the glycerol of palmitic, stearic Three acid compound materials;
Step 2, solid film, carry out high temperature curve sintering so that the material in sealer is inlayed completely to the workpiece after filling perforation It is sealed in the hole of surface of the work, forms a tunic;
Step 3, polishing or sanding, the workpiece after solid film is mechanically polished or the method for sanding by the loose of surface and After unwanted layers is removed, above-mentioned sealer combines together the most completely with oxide-film hole.
Preferably, in described step 2, the thickness of solid film rear oxidation film is more than or equal to 15um, the material in described sealer At the film layer of 2/3 thickness that absorption is sealed in oxide-film ecto-entad.
It is an advantage of the current invention that: oxidation rear substrate surface provided by the present invention pore inlays packing material and technology, In the surface pore of base material workpiece after oxidation embed hole sealing agent molecule, the finish surface obtained, make workpiece have non-stick, The advantage that coefficient of friction is low, antirust ability is strong, by the basal body structure that oxide-film is firm, in conjunction with described sealing material so that work Part is the most wear-resisting durable so that product can be widely used in various industry and life.
Accompanying drawing explanation
Fig. 1 is that the sealer material of the present invention is embedded in the micro state schematic diagram aoxidizing rear substrate surface.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, right The present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, not For limiting the present invention.
The oxidation rear substrate surface pore that the present invention provides inlays packing material and technology, comprises the following steps:
Step one, filling perforation, be sprayed onto the base material surface of the work after oxidation sealer and fill the hole of substrate surface, described Workpiece refers to the steel substrate that surface is the most loose porous, the most coarse, and these holes are sealed, and sealer is by following four Any one the corresponding retarder thinner planted in material is uniformly mixed, and described four kinds of materials are: a, fluorine carbon material, b, Organosilicon and inorganic silicon material, c, inorganic molybdenum bisuphide material, d, unsaturated hydrocarbons, unsaturated fatty acid, palmitic acid, tristearin Acid, the monoglyceride compounds of unsaturated fatty acid or the triglycerides compound material of palmitic, stearic.
Step 2, solid film, carry out high temperature curve sintering so that the material in sealer is inlayed completely to the workpiece after filling perforation It is sealed in the hole of surface of the work, forms a tunic.
Step 3, polishing or sanding, the workpiece after solid film is mechanically polished or the method for sanding by the loose of surface and After unwanted layers is removed, above-mentioned sealer combines together the most completely with oxide-film and hole.Owing in described sealer, material is not Viscosity can make workpiece the most outstanding and relatively more resistant to abrasive wear durable with low coefficient of friction by the basal body structure that oxide-film is firm, Use the finish surface that this kind of closing mode obtains, be based on oxide-film structure, embed above-mentioned in substrate work-piece hole The uncoated body surface of hole sealing agent molecule, has fabulous functional, it is possible to adapt to various different industry and life Application.
Gu membrane process is prior art, Gu film refers to: after above-mentioned material and diluent are uniformly mixed into liquid solvent, spray The surface of the workpiece substrate after oxidation, because firming agent is liquid, in therefore it can flow into the hole of surface of the work, then at height Breed during temperature curve sintering so that the substrate surface after firming agent liquid and oxidation and hole strong bonded, form one Layer protecting film, then uses method the loosening surface and after unwanted layers removal of mechanical polishing, sanding, sealer and oxide-film And hole combines together the most completely, being allowed to be formed the oxide-film of many premium properties, its performance includes non-adhesion behavior, low rubbing Wipe coefficient.Being allowed to the most outstanding and relatively more resistant to abrasive wear durable of embodiment by the basal body structure that oxide-film is firm, this kind closes mode The finish surface finally making us obtain is to embed above-mentioned hole sealing agent in substrate work-piece hole based on oxide-film structure The uncoated body surface of molecule so that product can be widely used in industry and life.
Material described in this programme itself has good non-stick, but is difficult to fix with substrate work-piece, and this programme leads to Crossing and these materials are uniformly mixed with diluent respectively, described diluent is prior art, and every kind of material all has corresponding thereto Diluent, after mixing formed firming agent be liquid, then firming agent is sprayed on porose base material surface of the work, firming agent handle The hole of surface of the work is filled up completely with inlays, and state diagram after filling is as it is shown in figure 1,1 be the hole of surface of the work in figure, and 2 is above-mentioned Any of which material molecule in " a ", " b ", " c " or " d " four kinds of materials.

Claims (2)

1. oxidation rear substrate surface pore inlays packing material and technology, it is characterised in that comprise the following steps:
Step one, filling perforation, be sprayed onto the base material surface of the work after oxidation sealer and fill the hole of substrate surface, this some holes Gap seals, and sealer is uniformly mixed by any one the corresponding retarder thinner in following four material, and described four Planting material is: a, fluorine carbon material, b, organosilicon and inorganic silicon material, c, inorganic molybdenum bisuphide material, d, unsaturated hydrocarbons, insatiable hunger Glycerol three acid with fatty acid, palmitic acid, stearic acid, the monoglyceride compounds of unsaturated fatty acid or palmitic, stearic Compound material;
Step 2, solid film, carry out high temperature curve sintering so that sealing inlayed completely by the material in sealer to the workpiece after filling perforation On hole and the surface of workpiece, form a tunic;
Step 3, polishing or sanding, mechanically polish the workpiece after solid film or method the loosening surface and unnecessary of sanding After layer is removed, above-mentioned sealer combines together the most completely with oxide-film hole.
Oxidation rear substrate surface the most according to claim 1 pore inlays packing material and technology, it is characterised in that: described In step 2, the thickness of solid film rear oxidation film is sealed in oxide-film by outward more than or equal to 15um, the material absorption in described sealer At the film layer of 2/3 inside thickness.
CN201610539519.6A 2016-07-09 2016-07-09 Oxidation rear substrate surface pore inlays packing material and technology Pending CN106191964A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201610539519.6A CN106191964A (en) 2016-07-09 2016-07-09 Oxidation rear substrate surface pore inlays packing material and technology
CN201710491610.XA CN107236978A (en) 2016-07-09 2017-06-26 The enclosure method of the packing material and pore of closing oxidation rear substrate surface pore

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610539519.6A CN106191964A (en) 2016-07-09 2016-07-09 Oxidation rear substrate surface pore inlays packing material and technology

Publications (1)

Publication Number Publication Date
CN106191964A true CN106191964A (en) 2016-12-07

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CN201710491610.XA Pending CN107236978A (en) 2016-07-09 2017-06-26 The enclosure method of the packing material and pore of closing oxidation rear substrate surface pore

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Publication number Priority date Publication date Assignee Title
CN111809214B (en) * 2019-04-12 2022-03-22 平顶山市美伊金属制品有限公司 Method for sealing pores on surface of oxidized substrate

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CN101045996A (en) * 2006-03-28 2007-10-03 北京化工大学 Process of clossing anode coating of aluminium or aluminium alloy with Ce-Mo salt
DE102007052575A1 (en) * 2007-11-03 2009-05-07 Märzhäuser Wetzlar GmbH & Co. KG Protective layer of hard-anodized microscopic aluminum workpieces, comprises a composite-lacquer reinforced with a filler, and a hard-anodized layer that is colored black
CN101240440B (en) * 2007-11-16 2011-02-16 苏州有色金属研究院有限公司 Technique for preparing high-hardness large-aperture thick film by mixed acid anode oxidation
CN101314865B (en) * 2007-12-28 2010-06-09 中国兵器工业第五二研究所 Production method for hard lubricant film layer of aluminum alloy
CN101338446B (en) * 2008-08-14 2011-03-30 苏州有色金属研究院有限公司 Heat treatment process for aluminum alloy self-lubricating surface composite material
CN101665970B (en) * 2008-09-03 2011-03-30 中国科学院宁波材料技术与工程研究所 Normal-temperature sealer for anodic oxide film of aluminum and aluminum alloy and sealing method thereof
CN101736385A (en) * 2008-11-19 2010-06-16 苏州有色金属研究院有限公司 Treatment process of self-lubricating surface of aluminium alloy
CN101481814A (en) * 2008-12-09 2009-07-15 陈世楠 Surface treating method for aluminum product
JP5491758B2 (en) * 2009-03-31 2014-05-14 日本バルカー工業株式会社 Filled fluororesin sheet, method for producing the same, and gasket
CN102011166B (en) * 2010-10-20 2014-10-15 安泰科技股份有限公司 Aluminum-based composite material with ultra-low friction coefficient and preparation method thereof
CN102021632A (en) * 2010-12-15 2011-04-20 中国铝业股份有限公司 Method for preparing protective film on copper alloy surface
CN102021629A (en) * 2010-12-30 2011-04-20 南昌航空大学 Method for preparing titanium-alloy surface micro-arc oxidation antifriction compound film layer
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Application publication date: 20161207