CN106190623A - A kind of abluent removing pesticide residues - Google Patents
A kind of abluent removing pesticide residues Download PDFInfo
- Publication number
- CN106190623A CN106190623A CN201610561658.9A CN201610561658A CN106190623A CN 106190623 A CN106190623 A CN 106190623A CN 201610561658 A CN201610561658 A CN 201610561658A CN 106190623 A CN106190623 A CN 106190623A
- Authority
- CN
- China
- Prior art keywords
- abluent
- oleic acid
- pesticide residues
- weight
- mannitol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
Abstract
The invention discloses a kind of natural, environmental protection, the abluent of the removing pesticide residues having no side effect, can effectively remove the pesticide residues in common vegetable melon and fruit, reducing the damage of poisonous chemical confrontation human body in pesticide, described abluent mainly includes following component: Fructus Luffae extract 3 8%, Flos Lonicerae extract 2 5%, brassinosteroid 0.5 0.8%, sodium alkyl benzene sulfonate 8 15%, aluminium polychlorid 2 4%, surfactant 6 10%, preservative 1 2%, Fructus Citri Limoniae essence 3 6%, surplus are pure water；Abluent prepared by the present invention, is particularly advantageous in that and can quickly decompose and dilute pesticide residues, dephosphorization scrubbing, and production technology is simple, with low cost, can the most extensively apply.
Description
Technical field
The invention belongs to remove pesticide residues technical field, be specifically a kind of abluent removing pesticide residues.
Background technology
Due to science and technology development, in agricultural production use pesticide variety also become increasingly abundant, use agriculture
Medicine rear portion pesticide directly or indirectly remains in corn, vegetable, fruit, livestock products, aquatic products and in soil and water body
Phenomenon, if can not well reclaim or remove pesticide residues, will be to human body or environmental danger.Pesticide residues are agricultures
Medicine is not decomposed in using later period and residues in the trace pesticide in organism, cutting, soil, water body, air
The general name of substance, toxic metabolite, degradation product and impurity.Residual pesticide is directly by fruit or water, air arrival people, animal
Internal, or it is ultimately transferred to people, animal etc. by environment, food chain.
Pesticide Residue is as pesticide and produces in a large number and be widely used and produce, and up to the present, changes in the world
Nearly 2,000,000 tons of medicine annual production of learning to farm, there are about more than 1000 kind of artificial-synthetic compound and is used as insecticide, antibacterial, algicide, removes
The class pesticide such as worm agent, defoliant.Pesticide especially organic agricultural chemicals is used in a large number, causes serious Pesticides Residues, becomes right
The serious threat of health.
Pesticide enters in grain, veterinary antibiotics, fish, shrimp, meat, egg, milk, causes food pollution, the health of harm people.Its
Middle significant portion chemical substance is very slow in human body metabolism's speed, and accumulated time is long, blood, brain, liver and the fat group to people
Knit and all can produce impact.Owing to pesticide residues are very big to people and biohazard, pesticide is used and is all carried out strict pipe by various countries
Reason, and Pesticide Residues allowance is dictated.While it is true, contact most melon and fruit vegetables in our daily life
The pesticide residues on dish surface or inevitably, the most efficiently, quickly, residual pesticide is chemical field in deep layer removing garden stuff
A great problem.
Summary of the invention
Present invention solves the technical problem that and be to provide a kind of natural, environmental protection, washing of the removing pesticide residues having no side effect
Clean dose.
Technical scheme is as follows:
A kind of abluent removing pesticide residues, mainly includes following component: Fructus Luffae extract 3-8%, Flos Lonicerae are extracted
Thing 2-5%, brassinosteroid 0.5-0.8%, sodium alkyl benzene sulfonate 2-5%, aluminium polychlorid 2-4%, surfactant 6-
10%, preservative 1-2%, Fructus Citri Limoniae essence 3-6%, surplus are pure water.
Further, described Fructus Luffae extract preparation method is: micronizing after being dried by Fructus Luffae, crosses 80-100 mesh
Sieve, gives the potassium hydroxide solution that mass concentration is 8-10% adding its 5-8 times amount in the Luffa powder obtained, mechanical agitation, turns
Speed is 1200-1800r/min, obtains suspension after stirring 5-10min, to the nothing adding suspension 1/5th amount in suspension
Water-ethanol is uniformly mixed, and uses microwave radiation exaraction 10-15min, is centrifuged 15-30min afterwards, after filtering precipitation, will obtain
Supernatant utilize equivalent chloroform extraction remove oil-soluble impurities, make spent ion exchange resin impurity screening, by filter after
Solution decompression reclaims ethanol, and the crystal powder being spray-dried the brown color obtained is Fructus Luffae extract, wherein contains soaping agents
The materials such as material, luffein, lymphatic temperament, wood glue, citrulline, xylan and interferon have antipyretic and antidote functions, permissible
Multiple chemical substance after absorption pesticide residue decomposition, departs from fruit and vegetable surfaces under flow action.
Further, described Flos Lonicerae extract is mainly composed of chlorogenic acid, exists with white crystal state, chlorogenic acid
Having good antibacterial action, its aqueous solution is to be imbued with convergence, with dissolved organic matter, can promote the contraction of contact surface, dissolve
The toxicant of pesticide residues.
Further, described surfactant base proportioning is: the cocoanut oil alcohol sodium sulfate of 80-120 part, 160-240 part
The liquid oleic acid that acid number is 150-180, the mannitol of 60-120 part, the solid sodium hydroxide of 5-10 part purity more than 95%,
Its preparation method is as follows: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, sweet
Dew alcohol and oleic acid carry out esterification, time 20-30min, temperature 100-110 DEG C under the effect of catalyst sodium hydroxide, take off
Except the moisture in reaction mass molecule, obtain mannitol oleic acid monoester, then by mannitol oleic acid monoester and described part by weight
Cocoanut oil alcohol sodium sulfate mix homogeneously, adds the ethanol solution that mass concentration is 55-65% of its mixing quality 3-5 times amount, is placed in
Homogenizer homogenizing 15-30min, described homogenizer is high pressure homogenizer, and it uses plunger horizontal movement structures, vertebration,
Even if will not enter fuel tank after material from leakage, will not pollute external operating environment, speed is fast, and the time is short, and homogenizing effect is good, decompression
Concentration and recovery ethanol, the mixture obtained is described surfactant, and aqueous solution is semi-transparent clear state, has excellent
Good foaming, moistening, decontamination, emulsifiability.
Further, described preservative DL-malic acid diethylester, not only there is good antiseptic effect, or a kind of
Well emulsion stabilizer and liquid anticoagulant.
The preparation method of a kind of abluent removing pesticide residues is:
Step one: micronizing after being dried by Fructus Luffae, crosses 80-100 mesh sieve, gives in the Luffa powder obtained and adds its 5-8 times
The potassium hydroxide solution that mass concentration is 8-10% of amount, mechanical agitation, rotating speed is 1200-1800r/min, stirs 5-10min
After obtain suspension, in suspension add suspension 1/5th amount absolute ethyl alcohol and stirring mix homogeneously, use microwave auxiliary
Help extraction 10-15min, be centrifuged 15-30min afterwards, after filtering precipitation, the supernatant obtained utilizes the chloroform extraction of equivalent remove
Oil-soluble impurities, makes spent ion exchange resin impurity screening, and the solution decompression after filtering reclaims ethanol, and spray drying obtains
The crystal powder of brown color is Fructus Luffae extract；
Step 2: the sodium alkyl benzene sulfonate of described part by weight is mixed with the pure water of its weight 3-5 times, is slowly heated to
50 DEG C, being sufficiently stirred for dissolving, make aqueous phase substrate, sodium alkyl benzene sulfonate is the anionic surface of a kind of conventional synthetic
Activating agent, production cost is low, performance good, and to particulate fouling, albumen dirt and oily dirt have significant clean effect, standby；
Step 3: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, sweet
Dew alcohol and oleic acid carry out esterification, time 20-30min, temperature 100-110 DEG C under the effect of catalyst sodium hydroxide, take off
Except the moisture in reaction mass molecule, obtain mannitol oleic acid monoester, then by mannitol oleic acid monoester and described part by weight
Cocoanut oil alcohol sodium sulfate mix homogeneously, adds the ethanol solution that mass concentration is 55-65% of its mixing quality 3-5 times amount, is placed in
Homogenizer homogenizing 15-30min, concentrating under reduced pressure reclaims ethanol, and the mixture obtained is described surfactant；
Step 4: aqueous phase substrate step 2 prepared is poured in emulsifying pot, described emulsifying pot is vacuum emulsifying pot,
The oxidation being possible to prevent in preparation process, can well play emulsifying effectiveness, then be sequentially added into the Fructus Luffae of described part by weight
Stir after extract, Flos Lonicerae extract, brassinosteroid, aluminium polychlorid, add pure water to described part by weight,
After evacuation, stirring, homogenizing 3-5min, being incubated and within 15 minutes, start to cool to 40 DEG C, lives in the surface adding described part by weight
Property agent, preservative, Fructus Citri Limoniae essence, seal up for safekeeping after stirring, i.e. prepare the abluent of described removing pesticide residues.
The using method of the present invention: the abluent of the present invention is mixed homogeneously according to the volume ratio of 1:1000 with water, water temperature
Control at 25-35 DEG C, then fruit and vegerable are inserted immersion 5-10min in water, it is ensured that water, to fruit and vegetable surfaces all standing, then takes out fruit
Vegetables are rinsed, better after vibrations stirring in immersion process.
The invention has the beneficial effects as follows: in water, dissolve rapidly diffusion, penetrate into fruit and vegetable surfaces, quickly decompose top layer
Pesticide residues, have good elimination effect to organic agricultural chemicals and phosphorous toxicant, add multiple natural materials, suppress toxic substance
To human non-toxic's side effect while matter, quickly removing the pesticide residues of foodstuff surface, the structure destroying residual pesticide makes agriculture
The medicine factor comes off, degrades, and reaches efficient, quick, deep layer and removes the purpose of residual pesticide in fruit and vegerable.Abluent prepared by the present invention
Can quickly decompose and dilute pesticide residues, dephosphorization scrubbing, production technology is simple, with low cost, can be the most extensive
Application.
Detailed description of the invention
Embodiment 1:
A kind of abluent removing pesticide residues, mainly includes following component: Fructus Luffae extract 3%, Flos Lonicerae extract
2%, brassinosteroid 0.5%, sodium alkyl benzene sulfonate 2%, aluminium polychlorid 2%, surfactant 6%, preservative 1%, lemon
Lemon essence 3%, surplus are pure water.
Wherein, described Fructus Luffae extract preparation method is: micronizing after being dried by Fructus Luffae, crosses 80 mesh sieves, is obtained
Luffa powder in add the potassium hydroxide solution that mass concentration is 8% of its 5 times amount, mechanical agitation, rotating speed is 1200r/min,
Obtain suspension after stirring 5min, to the absolute ethyl alcohol and stirring mix homogeneously of addition suspension 1/5th amount in suspension, make
Use microwave radiation exaraction 10min, be centrifuged 15min afterwards, after filtering precipitation, the supernatant obtained utilizes the chloroform extraction of equivalent remove
Removing oil-soluble impurities, make spent ion exchange resin impurity screening, the solution decompression after filtering reclaims ethanol, and spray drying obtains
The crystal powder of brown color be Fructus Luffae extract, wherein contain saponins, luffein, lymphatic temperament, wood glue, melon
The materials such as propylhomoserin, xylan and interferon have antipyretic and antidote functions, can adsorb the multiple chemistry after pesticide residue decomposes
Material, departs from fruit and vegetable surfaces under flow action.Described Flos Lonicerae extract is mainly composed of chlorogenic acid, with white crystal
State exists, and chlorogenic acid has good antibacterial action, and its aqueous solution is to be imbued with convergence, can promote to connect with dissolved organic matter
The contraction of contacting surface, dissolves the toxicant of pesticide residues.Described surfactant base proportioning is: the cocoanut oil alcohol sulfur of 80 parts
Acid sodium, the liquid oleic acid that acid number is 150 of 160 parts, the mannitol of 60 parts, the solid sodium hydroxide of 5 parts of purity more than 95%, its
Preparation method is as follows: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, manna
Alcohol and oleic acid carry out esterification, time 20min, temperature 100 DEG C, elimination reaction material under the effect of catalyst sodium hydroxide
Moisture in molecule, obtains mannitol oleic acid monoester, then the cocoanut oil alcohol sulphuric acid by mannitol oleic acid monoester Yu described part by weight
Sodium mix homogeneously, adds the ethanol solution that mass concentration is 55% of its mixing quality 3 times amount, is placed in homogenizer homogenizing 15min,
Described homogenizer is high pressure homogenizer, and it uses plunger horizontal movement structures, vertebration, even if will not enter after material from leakage
Entering fuel tank, will not pollute external operating environment, speed is fast, and the time is short, and homogenizing effect is good, and concentrating under reduced pressure reclaims ethanol, obtains
Mixture is described surfactant, and aqueous solution is semi-transparent clear state, has excellent foaming, moistening, decontamination, breast
Change performance.Described preservative DL-malic acid diethylester, not only has good antiseptic effect, or a kind of well emulsifying
Stabilizer and liquid anticoagulant.
The preparation method of a kind of abluent removing pesticide residues is:
Step one: micronizing after being dried by Fructus Luffae, crosses 80 mesh sieves, gives the matter adding its 5 times amount in the Luffa powder obtained
Amount concentration is the potassium hydroxide solution of 8%, mechanical agitation, and rotating speed is 1200r/min, obtains suspension after stirring 5min, gives outstanding
Turbid liquid adds the absolute ethyl alcohol and stirring mix homogeneously of suspension 1/5th amount, uses microwave radiation exaraction 10min, be centrifuged afterwards
15min, after filtering precipitation, utilizes the supernatant obtained the chloroform extraction of equivalent to remove oil-soluble impurities, uses ion exchange
Resin filter impurity, the solution decompression after filtering reclaims ethanol, and the crystal powder being spray-dried the brown color obtained is silk
Melon extract；
Step 2: the pure water of the sodium alkyl benzene sulfonate of described part by weight with its weight 3 times is mixed, is slowly heated to 50
DEG C, it being sufficiently stirred for dissolving, make aqueous phase substrate, sodium alkyl benzene sulfonate is to live in the anionic surface of a kind of conventional synthetic
Property agent, production cost is low, performance good, and to particulate fouling, albumen dirt and oily dirt have significant clean effect, standby；
Step 3: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, sweet
Dew alcohol and oleic acid carry out esterification, time 20min, temperature 100 DEG C, elimination reaction thing under the effect of catalyst sodium hydroxide
Moisture in material molecule, obtains mannitol oleic acid monoester, then the cocoanut oil alcohol sulfur by mannitol oleic acid monoester Yu described part by weight
Acid sodium mix homogeneously, adds the ethanol solution that mass concentration is 55% of its mixing quality 3 times amount, is placed in homogenizer homogenizing
15min, concentrating under reduced pressure reclaims ethanol, and the mixture obtained is described surfactant；
Step 4: aqueous phase substrate step 2 prepared is poured in emulsifying pot, described emulsifying pot is vacuum emulsifying pot,
The oxidation being possible to prevent in preparation process, can well play emulsifying effectiveness, then be sequentially added into the Fructus Luffae of described part by weight
Stir after extract, Flos Lonicerae extract, brassinosteroid, aluminium polychlorid, add pure water to described part by weight,
After evacuation, stirring, homogenizing 3min, it is incubated and within 15 minutes, starts to cool to 40 DEG C, add the surface activity of described part by weight
Agent, preservative, Fructus Citri Limoniae essence, seal up for safekeeping after stirring, and i.e. prepares the abluent of described removing pesticide residues.
Embodiment 2:
A kind of abluent removing pesticide residues, mainly includes following component: Fructus Luffae extract 5.5%, Flos Lonicerae are extracted
Thing 3.5%, brassinosteroid 0.65%, sodium alkyl benzene sulfonate 3.5%, aluminium polychlorid 3%, surfactant 8%, preservative
1.5%, Fructus Citri Limoniae essence 4.5%, surplus are pure water.
Wherein, described Fructus Luffae extract preparation method is: micronizing after being dried by Fructus Luffae, crosses 90 mesh sieves, is obtained
Luffa powder in add the potassium hydroxide solution that mass concentration is 9% of its 6.5 times amount, mechanical agitation, rotating speed is 1500r/
Min, obtains suspension after stirring 7.5min, to adding the absolute ethyl alcohol and stirring mixing of suspension 1/5th amount in suspension all
Even, use microwave radiation exaraction 12.5min, be centrifuged 22.5min afterwards, after filtering precipitation, the supernatant obtained is utilized equivalent
Chloroform extraction removes oil-soluble impurities, makes spent ion exchange resin impurity screening, and the solution decompression after filtering reclaims ethanol, spray
The crystal powder of the brown color that mist is dried to obtain is Fructus Luffae extract, wherein contains saponins, luffein, mucus
The materials such as matter, wood glue, citrulline, xylan and interferon have antipyretic and antidote functions, after can adsorbing pesticide residue decomposition
Multiple chemical substance, under flow action with fruit and vegetable surfaces depart from.Described Flos Lonicerae extract is mainly composed of chlorogenic acid,
Existing with white crystal state, chlorogenic acid has good antibacterial action, and its aqueous solution is to be imbued with convergence, can dissolve organic
Thing, promotes the contraction of contact surface, dissolves the toxicant of pesticide residues.Described surfactant base proportioning is: 100 parts
Cocoanut oil alcohol sodium sulfate, the liquid oleic acid that acid number is 165 of 200 parts, the mannitol of 90 parts, the solid of 7.5 parts of purity more than 95%
Sodium hydroxide, its preparation method is as follows: the vacuum that the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in sealing is anti-
Answering in still, mannitol and oleic acid carry out esterification under the effect of catalyst sodium hydroxide, time 25min, temperature 105 DEG C,
Moisture in elimination reaction material molecule, obtains mannitol oleic acid monoester, then by mannitol oleic acid monoester and described part by weight
Cocoanut oil alcohol sodium sulfate mix homogeneously, add the ethanol solution that mass concentration is 60% of its mixing quality 4 times amount, be placed in homogenizing
Machine homogenizing 22.5min, described homogenizer is high pressure homogenizer, and it uses plunger horizontal movement structures, vertebration, even if thing
Will not enter fuel tank after material leakage, will not pollute external operating environment, speed is fast, and the time is short, and homogenizing effect is good, and concentrating under reduced pressure returns
Receiving ethanol, the mixture obtained is described surfactant, and aqueous solution is semi-transparent clear state, has excellent sending out
Bubble, moistening, decontamination, emulsifiability.Described preservative DL-malic acid diethylester, not only has good antiseptic effect, or
A kind of well emulsion stabilizer and liquid anticoagulant.
The preparation method of a kind of abluent removing pesticide residues is:
Step one: micronizing after being dried by Fructus Luffae, crosses 90 mesh sieves, gives in the Luffa powder obtained and adds its 6.5 times amount
Mass concentration is the potassium hydroxide solution of 9%, mechanical agitation, and rotating speed is 1500r/min, obtains suspension after stirring 7.5min,
To the absolute ethyl alcohol and stirring mix homogeneously of addition suspension 1/5th amount in suspension, use microwave radiation exaraction 12.5min,
Rear centrifugal 22.5min, after filtering precipitation, utilizes the supernatant obtained the chloroform extraction of equivalent to remove oil-soluble impurities, uses
Ion exchange resin impurity screening, the solution decompression after filtering reclaims ethanol, is spray-dried the crystal powder of the brown color obtained
End is Fructus Luffae extract；
Step 2: the pure water of the sodium alkyl benzene sulfonate of described part by weight with its weight 4 times is mixed, is slowly heated to 50
DEG C, it being sufficiently stirred for dissolving, make aqueous phase substrate, sodium alkyl benzene sulfonate is to live in the anionic surface of a kind of conventional synthetic
Property agent, production cost is low, performance good, and to particulate fouling, albumen dirt and oily dirt have significant clean effect, standby；
Step 3: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, sweet
Dew alcohol and oleic acid carry out esterification, time 25min, temperature 105 DEG C, elimination reaction thing under the effect of catalyst sodium hydroxide
Moisture in material molecule, obtains mannitol oleic acid monoester, then the cocoanut oil alcohol sulfur by mannitol oleic acid monoester Yu described part by weight
Acid sodium mix homogeneously, adds the ethanol solution that mass concentration is 60% of its mixing quality 4 times amount, is placed in homogenizer homogenizing
22.5min, concentrating under reduced pressure reclaims ethanol, and the mixture obtained is described surfactant；
Step 4: aqueous phase substrate step 2 prepared is poured in emulsifying pot, described emulsifying pot is vacuum emulsifying pot,
The oxidation being possible to prevent in preparation process, can well play emulsifying effectiveness, then be sequentially added into the Fructus Luffae of described part by weight
Stir after extract, Flos Lonicerae extract, brassinosteroid, aluminium polychlorid, add pure water to described part by weight,
After evacuation, stirring, homogenizing 4min, it is incubated and within 15 minutes, starts to cool to 40 DEG C, add the surface activity of described part by weight
Agent, preservative, Fructus Citri Limoniae essence, seal up for safekeeping after stirring, and i.e. prepares the abluent of described removing pesticide residues.
Embodiment 3:
A kind of abluent removing pesticide residues, mainly includes following component: Fructus Luffae extract 8%, Flos Lonicerae extract
5%, brassinosteroid 0.8%, sodium alkyl benzene sulfonate 5%, aluminium polychlorid 4%, surfactant 10%, preservative 2%, lemon
Lemon essence 6%, surplus are pure water.
Wherein, described Fructus Luffae extract preparation method is: micronizing after being dried by Fructus Luffae, crosses 100 mesh sieves, is obtained
Luffa powder in add the potassium hydroxide solution that mass concentration is 10% of its 8 times amount, mechanical agitation, rotating speed is 1800r/min,
Obtain suspension after stirring 10min, to the absolute ethyl alcohol and stirring mix homogeneously of addition suspension 1/5th amount in suspension, make
Use microwave radiation exaraction 15min, be centrifuged 30min afterwards, after filtering precipitation, the supernatant obtained utilizes the chloroform extraction of equivalent remove
Removing oil-soluble impurities, make spent ion exchange resin impurity screening, the solution decompression after filtering reclaims ethanol, and spray drying obtains
The crystal powder of brown color be Fructus Luffae extract, wherein contain saponins, luffein, lymphatic temperament, wood glue, melon
The materials such as propylhomoserin, xylan and interferon have antipyretic and antidote functions, can adsorb the multiple chemistry after pesticide residue decomposes
Material, departs from fruit and vegetable surfaces under flow action.Described Flos Lonicerae extract is mainly composed of chlorogenic acid, with white crystal
State exists, and chlorogenic acid has good antibacterial action, and its aqueous solution is to be imbued with convergence, can promote to connect with dissolved organic matter
The contraction of contacting surface, dissolves the toxicant of pesticide residues.Described surfactant base proportioning is: the cocoanut oil alcohol sulfur of 120 parts
Acid sodium, the liquid oleic acid that acid number is 180 of 240 parts, the mannitol of 120 parts, the solid sodium hydroxide of 10 parts of purity more than 95%,
Its preparation method is as follows: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, sweet
Dew alcohol and oleic acid carry out esterification, time 30min, temperature 110 DEG C, elimination reaction thing under the effect of catalyst sodium hydroxide
Moisture in material molecule, obtains mannitol oleic acid monoester, then the cocoanut oil alcohol sulfur by mannitol oleic acid monoester Yu described part by weight
Acid sodium mix homogeneously, adds the ethanol solution that mass concentration is 65% of its mixing quality 5 times amount, is placed in homogenizer homogenizing
30min, described homogenizer is high pressure homogenizer, and it uses plunger horizontal movement structures, vertebration, even if after material from leakage
Will not enter fuel tank, will not pollute external operating environment, speed is fast, and the time is short, and homogenizing effect is good, and concentrating under reduced pressure reclaims ethanol,
The mixture obtained is described surfactant, and aqueous solution is semi-transparent clear state, have excellent foaming, moistening,
Decontamination, emulsifiability.Described preservative DL-malic acid diethylester, not only has good antiseptic effect, or a kind of fine
Emulsion stabilizer and liquid anticoagulant.
The preparation method of a kind of abluent removing pesticide residues is:
Step one: micronizing after being dried by Fructus Luffae, crosses 100 mesh sieves, gives the matter adding its 8 times amount in the Luffa powder obtained
Amount concentration is the potassium hydroxide solution of 10%, mechanical agitation, and rotating speed is 1800r/min, obtains suspension, give after stirring 10min
In suspension add suspension 1/5th amount absolute ethyl alcohol and stirring mix homogeneously, use microwave radiation exaraction 15min, after from
Heart 30min, after filtering precipitation, utilizes the supernatant obtained the chloroform extraction of equivalent to remove oil-soluble impurities, uses ion to hand over
Changing resin filter impurity, the solution decompression after filtering reclaims ethanol, and the crystal powder being spray-dried the brown color obtained is
Fructus Luffae extract；
Step 2: the pure water of the sodium alkyl benzene sulfonate of described part by weight with its weight 5 times is mixed, is slowly heated to 50
DEG C, it being sufficiently stirred for dissolving, make aqueous phase substrate, sodium alkyl benzene sulfonate is to live in the anionic surface of a kind of conventional synthetic
Property agent, production cost is low, performance good, and to particulate fouling, albumen dirt and oily dirt have significant clean effect, standby；
Step 3: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, sweet
Dew alcohol and oleic acid carry out esterification, time 30min, temperature 110 DEG C, elimination reaction thing under the effect of catalyst sodium hydroxide
Moisture in material molecule, obtains mannitol oleic acid monoester, then the cocoanut oil alcohol sulfur by mannitol oleic acid monoester Yu described part by weight
Acid sodium mix homogeneously, adds the ethanol solution that mass concentration is 65% of its mixing quality 5 times amount, is placed in homogenizer homogenizing
30min, concentrating under reduced pressure reclaims ethanol, and the mixture obtained is described surfactant；
Step 4: aqueous phase substrate step 2 prepared is poured in emulsifying pot, described emulsifying pot is vacuum emulsifying pot,
The oxidation being possible to prevent in preparation process, can well play emulsifying effectiveness, then be sequentially added into the Fructus Luffae of described part by weight
Stir after extract, Flos Lonicerae extract, brassinosteroid, aluminium polychlorid, add pure water to described part by weight,
After evacuation, stirring, homogenizing 5min, it is incubated and within 15 minutes, starts to cool to 40 DEG C, add the surface activity of described part by weight
Agent, preservative, Fructus Citri Limoniae essence, seal up for safekeeping after stirring, and i.e. prepares the abluent of described removing pesticide residues.
Concrete verification experimental verification:
1. subjects: the period of maturation grass in the period of maturation Fructus Cucumidis sativi planted with certain Vegetable Base respectively and certain strawberry cultivating base
Certain kind of berries test reason object, normally uses pesticide at trophophase, mainly has antibacterial, insecticide, synergist etc..
2. experimental technique: take each 4 parts of above-mentioned pending test specimen, be divided into four groups, three groups of test group, one group blank
Group, often group comprises a Fructus Cucumidis sativi and a Fructus Fragariae Ananssae, every part of 250g, uses spectrophotometer and corresponding instrument detection before record test
The Organophosphorus and carbamate pesticides class content often organized, then uses the embodiment of the present invention 1, embodiment 2 respectively, implements to test group
The abluent of example 3 preparation processes according to using method, and matched group uses clean water, the detection data after record process.
3. detection result, and record process data, as shown in the table:
From above-mentioned detection data, the abluent technique prepared by the present invention is to there being the work well removing pesticide residues
With, can significantly remove the noxious substance of fruit and vegerable Pesticide Residues, effect is notable.
Last it is noted that above example is only in order to illustrate technical scheme, it is not intended to limit；Although
With reference to previous embodiment, the present invention is described in detail, it will be understood by those within the art that: it still may be used
So that the technical scheme described in previous embodiment to be modified, or wherein portion of techniques feature is carried out equivalent；And
These amendments or replacement, do not make the essence of appropriate technical solution depart from spirit and the model of embodiment of the present invention technical scheme
Enclose.
Claims (6)
1. the abluent removing pesticide residues, it is characterised in that described abluent mainly includes following component: Fructus Luffae carries
Take thing 3-8%, Flos Lonicerae extract 2-5%, brassinosteroid 0.5-0.8%, sodium alkyl benzene sulfonate 2-5%, aluminium polychlorid
2-4%, surfactant 6-10%, preservative 1-2%, Fructus Citri Limoniae essence 3-6%, surplus are pure water.
A kind of abluent removing pesticide residues the most as claimed in claim 1, it is characterised in that described Fructus Luffae extract system
Preparation Method is: micronizing after being dried by Fructus Luffae, crosses 80-100 mesh sieve, gives the matter adding its 5-8 times amount in the Luffa powder obtained
Amount concentration is the potassium hydroxide solution of 8-10%, mechanical agitation, and rotating speed is 1200-1800r/min, obtains after stirring 5-10min
Suspension, to the absolute ethyl alcohol and stirring mix homogeneously of addition suspension 1/5th amount in suspension, uses microwave radiation exaraction
10-15min, is centrifuged 15-30min afterwards, after filtering precipitation, the supernatant obtained utilizes the chloroform extraction of equivalent remove fat-soluble
Impurity, makes spent ion exchange resin impurity screening, and the solution decompression after filtering reclaims ethanol, is spray-dried the brown color obtained
Crystal powder be Fructus Luffae extract.
A kind of abluent removing pesticide residues the most as claimed in claim 1, it is characterised in that described Flos Lonicerae extract
It is mainly composed of chlorogenic acid, exists with white crystal state.
A kind of abluent removing pesticide residues the most as claimed in claim 1, it is characterised in that described surfactant is former
Material proportioning is: the cocoanut oil alcohol sodium sulfate of 80-120 part, the liquid oleic acid that acid number is 150-180 of 160-240 part, 60-120 part
Mannitol, the solid sodium hydroxide of 5-10 part purity more than 95%, its preparation method is as follows: by the manna of described part by weight
Alcohol, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, and mannitol and oleic acid enter under the effect of catalyst sodium hydroxide
Row esterification, time 20-30min, temperature 100-110 DEG C, the moisture in elimination reaction material molecule, obtain mannitol oleic acid
Monoesters, then mannitol oleic acid monoester is mixed homogeneously with the cocoanut oil alcohol sodium sulfate of described part by weight, add its mixing quality 3-5
The mass concentration of times amount is the ethanol solution of 55-65%, is placed in homogenizer homogenizing 15-30min, and concentrating under reduced pressure reclaims ethanol,
To mixture be described surfactant.
A kind of abluent removing pesticide residues the most as claimed in claim 1, it is characterised in that described preservative DL-Herba Marsileae Quadrifoliae
Fruit acid diethylester.
6. the abluent removing pesticide residues, it is characterised in that preparation method is:
Step one: micronizing after being dried by Fructus Luffae, crosses 80-100 mesh sieve, gives in the Luffa powder obtained and adds its 5-8 times amount
Mass concentration is the potassium hydroxide solution of 8-10%, mechanical agitation, and rotating speed is 1200-1800r/min, after stirring 5-10min
To suspension, to the absolute ethyl alcohol and stirring mix homogeneously of addition suspension 1/5th amount in suspension, use Microwave-assisted Extraction
Take 10-15min, be centrifuged 15-30min afterwards, after filtering precipitation, the supernatant obtained utilizes the chloroform extraction of equivalent remove liposoluble
Property impurity, make spent ion exchange resin impurity screening, will filter after solution decompression reclaim ethanol, be spray-dried obtain pale brown
The crystal powder of color is Fructus Luffae extract；
Step 2: the sodium alkyl benzene sulfonate of described part by weight is mixed with the pure water of its weight 3-5 times, is slowly heated to 50
DEG C, it is sufficiently stirred for dissolving, makes aqueous phase substrate, standby；
Step 3: the mannitol of described part by weight, oleic acid, sodium hydroxide are placed in the vacuum response still of sealing, mannitol
Carrying out esterification, time 20-30min, temperature 100-110 DEG C under the effect of catalyst sodium hydroxide with oleic acid, removing is anti-
Answer the moisture in material molecule, obtain mannitol oleic acid monoester, then the cocos nucifera oil by mannitol oleic acid monoester Yu described part by weight
Alcohol sodium sulfate mix homogeneously, adds the ethanol solution that mass concentration is 55-65% of its mixing quality 3-5 times amount, is placed in homogenizing
Machine homogenizing 15-30min, concentrating under reduced pressure reclaims ethanol, and the mixture obtained is described surfactant；
Step 4: aqueous phase substrate step 2 prepared is poured in emulsifying pot, is then sequentially added into the Fructus Luffae of described part by weight
Stir after extract, Flos Lonicerae extract, brassinosteroid, aluminium polychlorid, add pure water to described part by weight,
After evacuation, stirring, homogenizing 3-5min, being incubated and within 15 minutes, start to cool to 40 DEG C, lives in the surface adding described part by weight
Property agent, preservative, Fructus Citri Limoniae essence, seal up for safekeeping after stirring, i.e. prepare the abluent of described removing pesticide residues.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610561658.9A CN106190623A (en) | 2016-07-14 | 2016-07-14 | A kind of abluent removing pesticide residues |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610561658.9A CN106190623A (en) | 2016-07-14 | 2016-07-14 | A kind of abluent removing pesticide residues |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106190623A true CN106190623A (en) | 2016-12-07 |
Family
ID=57475261
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610561658.9A Pending CN106190623A (en) | 2016-07-14 | 2016-07-14 | A kind of abluent removing pesticide residues |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106190623A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110055143A (en) * | 2019-05-31 | 2019-07-26 | 西安优露清科技股份有限公司 | A kind of composition of the component containing natural activity and its preparation method and application |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065486A (en) * | 1991-04-02 | 1992-10-21 | 泸州精细化工研究所 | The manufacture method of compound activated aids for synthetic detergent |
| CN102746949A (en) * | 2012-07-03 | 2012-10-24 | 曾彧婕 | Novel liquid laundry detergent and preparation method thereof |
| CN104818130A (en) * | 2015-04-30 | 2015-08-05 | 青岛东昌瑞纺织品有限公司 | Non-toxic fruit and vegetable detergent |
| CN105062728A (en) * | 2015-07-19 | 2015-11-18 | 中盐榆林盐化有限公司 | Preparation method of plant washing salt |
| CN105106283A (en) * | 2015-09-11 | 2015-12-02 | 无锡市长安曙光手套厂 | Application of towel gourd extract in preparation of medicine for treating obesity or dietary supplement |
| CN105255600A (en) * | 2015-11-16 | 2016-01-20 | 王金胜 | Plant-sourced vegetable and fruit pesticide detergent |
-
2016
- 2016-07-14 CN CN201610561658.9A patent/CN106190623A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1065486A (en) * | 1991-04-02 | 1992-10-21 | 泸州精细化工研究所 | The manufacture method of compound activated aids for synthetic detergent |
| CN102746949A (en) * | 2012-07-03 | 2012-10-24 | 曾彧婕 | Novel liquid laundry detergent and preparation method thereof |
| CN104818130A (en) * | 2015-04-30 | 2015-08-05 | 青岛东昌瑞纺织品有限公司 | Non-toxic fruit and vegetable detergent |
| CN105062728A (en) * | 2015-07-19 | 2015-11-18 | 中盐榆林盐化有限公司 | Preparation method of plant washing salt |
| CN105106283A (en) * | 2015-09-11 | 2015-12-02 | 无锡市长安曙光手套厂 | Application of towel gourd extract in preparation of medicine for treating obesity or dietary supplement |
| CN105255600A (en) * | 2015-11-16 | 2016-01-20 | 王金胜 | Plant-sourced vegetable and fruit pesticide detergent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110055143A (en) * | 2019-05-31 | 2019-07-26 | 西安优露清科技股份有限公司 | A kind of composition of the component containing natural activity and its preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106577862A (en) | Sugar orange insecticide and preparation method of same | |
| CN108935456A (en) | A kind of pesticide synergistic agent and its application in Herbicidal combinations, Pesticidal combination and bactericidal composition | |
| CN102010798A (en) | Detergent for washing tableware or vegetables and fruits by hands | |
| CN102283216A (en) | Acaricidal composition containing abamectin and etoxazole | |
| CN106386886A (en) | Environment-friendly pesticide for vegetables, melons and fruits and preparation method thereof | |
| CN101070513A (en) | Farm-chemical biological decomposing composition and preparing method | |
| CN106689238A (en) | Botanical pesticide as well as preparation method and application thereof | |
| CN106332921B (en) | A kind of plant insecticide and its preparation method and application | |
| CN102845420B (en) | Bird repelling agent and preparation method thereof | |
| CN103262847A (en) | Biogenic pesticide containing xanthoxylin and abamectin and preparation method thereof | |
| CN104872216A (en) | Plant-source synergist and insect aerosol prepared by same | |
| CN106190623A (en) | A kind of abluent removing pesticide residues | |
| CN113519544A (en) | Plant source acaricide and preparation method and application thereof | |
| CN106577806B (en) | A kind of vegetable insecticide and preparation method thereof | |
| CN105379966B (en) | A kind of water-soluble allicin mixture and preparation method thereof | |
| CN100430460C (en) | Natural scavenging agent for removing residual pesticide on vegetable and fruitage | |
| CN103374818A (en) | Biological source insect-preventing fabric and preparation method thereof | |
| CN109833296A (en) | Can the new merit chigger disease of prevention and control plants essential oil microemulsion formulation and preparation method thereof | |
| CN1153599A (en) | Plant pesticide | |
| CN106281775A (en) | The preparation method of fruit and vegetable cleanout fluid | |
| CN108184833A (en) | Pyrethrins microcapsule formulations with beta-cyclodextrin or derivatives thereof for wall material and its preparation method and application | |
| CN107858212A (en) | A kind of fruit thimerosal and preparation method thereof | |
| CN105963160A (en) | Pure natural plant essential oil mosquito repellent ointment and preparation method thereof | |
| KR102228911B1 (en) | Natural fertilizer and manufacturing method thereof | |
| CN107821413A (en) | A kind of cockroach bait formulation and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |