CN106190559A - A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence - Google Patents
A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence Download PDFInfo
- Publication number
- CN106190559A CN106190559A CN201610626558.XA CN201610626558A CN106190559A CN 106190559 A CN106190559 A CN 106190559A CN 201610626558 A CN201610626558 A CN 201610626558A CN 106190559 A CN106190559 A CN 106190559A
- Authority
- CN
- China
- Prior art keywords
- essence
- liquid detergent
- bamboo vinegar
- camelliae sinensis
- flos camelliae
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/20—After-treatment of capsule walls, e.g. hardening
- B01J13/22—Coating
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0007—Aliphatic compounds
- C11B9/0015—Aliphatic compounds containing oxygen as the only heteroatom
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
Abstract
The invention discloses a kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence, be prepared by the raw materials in: Flos Camelliae sinensis dry flower 50 55, bamboo vinegar 0.1 0.15, tea tree oil 2.5 3, Fructus cari carvi quintessence oil 1 1.5, anisic aldehyde 0.5 0.6, ambrotone 3.5 4, petroleum ether 500 550, dehydrated alcohol 8 10, arabic gum 0.3 0.4, deionized water are appropriate, Ethylene glycol dimethacrylate 2.5 3, Ammonium persulfate. 0.1 0.11, sodium pyrosulfite 0.13 0.14, sodium carboxymethyl cellulose 1 1.2.Product of the present invention is microcapsule essence, and fragrance slowly discharges, heat-resist, and antioxidation is strong, is used in liquid detergent the fragrance that liquid detergent can not only be maintained permanent, and has certain bactericidal effect.
Description
Technical field
The present invention relates to essence technical field, particularly relate to a kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule fragrant
Essence.
Background technology
Daily chemical essence occupies the market share of about half as the pillar of fragrance industry, and along with economic development and society
Progressive, this ratio may proceed to rise, and along with the raising of living standards of the people, consumer is more and more higher to the requirement of detergent,
Not only want to the medicated clothing after washing and can leave lasting pure and fresh joyful fragrance, but also wish that the products such as liquid detergent have
Other additional benefit such as antibacterial, sterilization, skin protection.This is accomplished by the essence adding in detergent carrying out constantly modification and grinding
Send out.Typically essence high volatility, rate of release is too fast, easily occurs waste during storing, transporting and use,
Or the odor type caused that goes bad changes and becomes sour, it is impossible to meet the requirement of consumer, restrict its development.Microcapsule technology is can be effective
Improve these problems so that spice has longer fragrance remaining time, more preferable washing fastness and stability etc..But traditional conjunction
Become macromolecule wall material to have polyureas, polyester, melamine resin and polyacrylic etc., form microcapsule wall material utilizing synthesis macromolecule
During the monomer that often uses, cross-linking agent etc. such as toluene di-isocyanate(TDI), glutaraldehyde, formaldehyde etc., all there is certain toxicity, these
Poisonous reaction residue makes to synthesize the macromolecule microcapsule for wall material
Use be restricted.Therefore, take nontoxic and to have functional monomer synthetic environment-friendly wall material be microcapsule science
The target that worker pursues always.
" preparation of polymethyl methacrylate glycol ester wall material microcapsule and sign thereof " literary composition uses radical polymerization
Method high polymer polymethyl methacrylate that Ethylene glycol dimethacrylate monomer is formed by interface radical polymerization
Glycol ester is the microcapsule of wall material, has good heat stability, and wall material is nontoxic, is suitable for personal care articles and field of medicaments
It is with a wide range of applications.But the microcapsule essence liquid detergent to be added to made as the wall material of essence due to microcapsule
Preparation in, the density of microcapsule essence and liquid detergent matrix have difference, cause product to be layered, suspended uneven.This is accomplished by
Microcapsule wall material is modified, enables to meet the demand of liquid detergent flavouring.
Summary of the invention
The object of the invention is contemplated to make up the defect of prior art, it is provided that a kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent
Use microcapsule essence.
The present invention is achieved by the following technical solutions:
A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence, is prepared by the raw materials in: Flos Camelliae sinensis is done
Flower 50-55, bamboo vinegar 0.1-0.15, tea tree oil 2.5-3, Fructus cari carvi quintessence oil 1-1.5, anisic aldehyde 0.5-0.6, ambrotone 3.5-4,
Petroleum ether 500-550, dehydrated alcohol 8-10, arabic gum 0.3-0.4, deionized water are appropriate, Ethylene glycol dimethacrylate
2.5-3, Ammonium persulfate. 0.1-0.11, sodium pyrosulfite 0.13-0.14, sodium carboxymethyl cellulose 1-1.2.
Described a kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence, is made up of step in detail below:
(1) Flos Camelliae sinensis dry flower is put in reflux, extract, device, add petroleum ether, be stirred at reflux extraction 60-90 at 60-65 DEG C and divide
Clock, pours out petroleum ether, repeats under identical condition to extract 2-3 time, is merged by petroleum ether lixiviating solution, dense in 40-50 DEG C of vacuum
Being reduced in the vacuum drying oven of the most dry 40-50 of being placed on DEG C dries to constant weight, and to obtain extractum stand-by；Dehydrated alcohol is joined above-mentioned leaching
In cream, it is heated to 35-40 DEG C while stirring and extremely dissolves, filtered at room temperature, discard residue, by upper strata material vacuum filtration final vacuum
It is concentrated to closely do, then be placed in baking oven be dried to constant weight with the temperature of 40-50 DEG C, obtains essential oil of the flower of Camellia sinensis；
(2) essential oil of the flower of Camellia sinensis that step (1) prepares is mixed with bamboo vinegar, tea tree oil, Fructus cari carvi quintessence oil, anisic aldehyde, ambrotone
Form mixing essence stand-by；Then arabic gum will add the deionized water of 100-120 times amount, warming while stirring to 50-
60 DEG C, until arabic gum is completely dissolved, form solution；Will mixing essence mix with above-mentioned solution, put in effective dispersing machine with
VELOCITY SHEAR 3-5 minute of 6000-7000 rev/min, forms mixing essence emulsion；
(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two
Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10-12 times amount deionized water, and under room temperature, dropping is dissolved in 8-10 times amount
The Ammonium persulfate. of ionized water, controlling time for adding is 30 minutes, is warming up to 50-60 DEG C, and insulation reaction 1.5-2 hour is cooled to
Room temperature, obtains microcapsule essence；
(4) by the deionized water adding 3-5 times amount in sodium carboxymethyl cellulose, stir to being completely dissolved formation clear solution,
By the surface of the microcapsule essence that spray solution obtains in step (3), finally it is dried at 50-60 DEG C in vacuum drying oven,
Obtain the present invention.
The invention have the advantage that Ethylene glycol dimethacrylate self-crosslinking is formed the three of densification by the present invention by reaction
Dimension net polymer is coated on mixing essence top layer and forms microcapsule essence, and the microcapsule essence size dimension made distribution is all
Even, form is full, few gathering, has good heat stability and slow-releasing so that fragrance persistently discharges；By at microcapsule
One layer of carboxymethylcellulose sodium solution of essence surface sprinkling, it is possible to the microcapsule essence made is suspended all in liquid detergent
Even, moreover it is possible to act on fabric face be prevented from fabric repeat absorb dust.Product safety environment-protecting asepsis of the present invention, adds to and washes
In clothing liquid, laundry processes enter fabric and remains, then slowly discharging fragrance by rubbing, make fabric have and hold
Long fragrance.
The present invention extracts essential oil of the flower of Camellia sinensis by a series of technique, has Mel fragrance, coordinates bamboo vinegar, tea tree oil, Tibetan
The interpolation of fennel essential oil, improves the bactericidal property of mixing essence further, then compounds with ambrotone, and fragrance vividly harmony is held
For a long time；Product of the present invention is microcapsule essence, and fragrance slowly discharges, heat-resist, and antioxidation is strong, and being used in liquid detergent can not only
Maintain the fragrance that liquid detergent is permanent, and there is certain bactericidal effect.
Detailed description of the invention
A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence, by the raw material system of following weight portion (kilogram)
Become: Flos Camelliae sinensis dry flower 50, bamboo vinegar 0.1, tea tree oil 2.5, Fructus cari carvi quintessence oil 1, anisic aldehyde 0.5, ambrotone 3.5, petroleum ether
500, dehydrated alcohol 8, arabic gum 0.3, deionized water be appropriate, Ethylene glycol dimethacrylate 2.5, Ammonium persulfate. 0.1, burnt
Sodium sulfite 0.13, sodium carboxymethyl cellulose 1.
Described a kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence, is made up of step in detail below:
(1) Flos Camelliae sinensis dry flower is put in reflux, extract, device, add petroleum ether, be stirred at reflux extraction 60 minutes at 60 DEG C, pour out
Petroleum ether, repeats to extract 2 times under identical condition, is merged by petroleum ether lixiviating solution, is concentrated in vacuo near dry rearmounted at 40 DEG C
Drying to constant weight in the vacuum drying oven of 40 DEG C, it is stand-by to obtain extractum；Dehydrated alcohol is joined in above-mentioned extractum, adds while stirring
Heat, to 35 DEG C to dissolving, filtered at room temperature, discards residue, is concentrated to by upper strata material vacuum filtration final vacuum near dry, then is placed in
Baking oven is dried to constant weight with the temperature of 40 DEG C, obtains essential oil of the flower of Camellia sinensis；
(2) essential oil of the flower of Camellia sinensis that step (1) prepares is mixed with bamboo vinegar, tea tree oil, Fructus cari carvi quintessence oil, anisic aldehyde, ambrotone
Form mixing essence stand-by；Then arabic gum will add the deionized water of 100 times amount, warming while stirring to 50 DEG C until
Arabic gum is completely dissolved, and forms solution；Will mixing essence mix with above-mentioned solution, put in effective dispersing machine with 6000 turns/
The VELOCITY SHEAR divided 3 minutes, forms mixing essence emulsion；
(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two
Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10 times amount deionized waters, and under room temperature, dropping is dissolved in 8 times amount deionized waters
Ammonium persulfate., control time for adding be 30 minutes, be warming up to 50 DEG C, insulation reaction 1.5 hours, be cooled to room temperature, obtain micro-
Capsule essence；
(4) by the deionized water adding 3 times amount in sodium carboxymethyl cellulose, stirring, will to being completely dissolved formation clear solution
The surface of the microcapsule essence that spray solution obtains in step (3), is finally dried in vacuum drying oven at 50 DEG C, obtains this
Invention.
Adding in liquid detergent by product of the present invention, consumption is 0.5%, still has after test liquid detergent is placed 12 months
Fragrance, and essence residual quantity is still greater than 10%.
Claims (2)
1. a Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence, it is characterised in that by the raw material of following weight portion
Make: Flos Camelliae sinensis dry flower 50-55, bamboo vinegar 0.1-0.15, tea tree oil 2.5-3, Fructus cari carvi quintessence oil 1-1.5, anisic aldehyde 0.5-
0.6, ambrotone 3.5-4, petroleum ether 500-550, dehydrated alcohol 8-10, arabic gum 0.3-0.4, deionized water be appropriate, diformazan
Base acrylic acid glycol ester 2.5-3, Ammonium persulfate. 0.1-0.11, sodium pyrosulfite 0.13-0.14, sodium carboxymethyl cellulose 1-
1.2。
A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence, it is characterised in that by
Step is made in detail below:
(1) Flos Camelliae sinensis dry flower is put in reflux, extract, device, add petroleum ether, be stirred at reflux extraction 60-90 at 60-65 DEG C and divide
Clock, pours out petroleum ether, repeats under identical condition to extract 2-3 time, is merged by petroleum ether lixiviating solution, dense in 40-50 DEG C of vacuum
Being reduced in the vacuum drying oven of the most dry 40-50 of being placed on DEG C dries to constant weight, and to obtain extractum stand-by；Dehydrated alcohol is joined above-mentioned leaching
In cream, it is heated to 35-40 DEG C while stirring and extremely dissolves, filtered at room temperature, discard residue, by upper strata material vacuum filtration final vacuum
It is concentrated to closely do, then be placed in baking oven be dried to constant weight with the temperature of 40-50 DEG C, obtains essential oil of the flower of Camellia sinensis；
(2) essential oil of the flower of Camellia sinensis that step (1) prepares is mixed with bamboo vinegar, tea tree oil, Fructus cari carvi quintessence oil, anisic aldehyde, ambrotone
Form mixing essence stand-by；Then arabic gum will add the deionized water of 100-120 times amount, warming while stirring to 50-
60 DEG C, until arabic gum is completely dissolved, form solution；Will mixing essence mix with above-mentioned solution, put in effective dispersing machine with
VELOCITY SHEAR 3-5 minute of 6000-7000 rev/min, forms mixing essence emulsion；
(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two
Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10-12 times amount deionized water, and under room temperature, dropping is dissolved in 8-10 times amount
The Ammonium persulfate. of ionized water, controlling time for adding is 30 minutes, is warming up to 50-60 DEG C, and insulation reaction 1.5-2 hour is cooled to
Room temperature, obtains microcapsule essence；
(4) by the deionized water adding 3-5 times amount in sodium carboxymethyl cellulose, stir to being completely dissolved formation clear solution,
By the surface of the microcapsule essence that spray solution obtains in step (3), finally it is dried at 50-60 DEG C in vacuum drying oven,
Obtain the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610626558.XA CN106190559A (en) | 2016-08-03 | 2016-08-03 | A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610626558.XA CN106190559A (en) | 2016-08-03 | 2016-08-03 | A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106190559A true CN106190559A (en) | 2016-12-07 |
Family
ID=57497057
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610626558.XA Pending CN106190559A (en) | 2016-08-03 | 2016-08-03 | A kind of Flos Camelliae sinensis bamboo vinegar antibacterial enhancing liquid detergent microcapsule essence |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107774205A (en) * | 2017-11-10 | 2018-03-09 | 昆明理工大学 | A kind of fragrant plant dries the apparatus and method of coproduction microcapsule essence |
| CN108264972A (en) * | 2016-12-30 | 2018-07-10 | 北京绿伞化学股份有限公司 | A kind of tea tree ethereal oil concentrated detergent China liquid and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108264972A (en) * | 2016-12-30 | 2018-07-10 | 北京绿伞化学股份有限公司 | A kind of tea tree ethereal oil concentrated detergent China liquid and preparation method thereof |
| CN107774205A (en) * | 2017-11-10 | 2018-03-09 | 昆明理工大学 | A kind of fragrant plant dries the apparatus and method of coproduction microcapsule essence |
| CN107774205B (en) * | 2017-11-10 | 2024-02-02 | 昆明理工大学 | Device and method for drying aromatic plants and co-producing microcapsule essence |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161207 |
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