CN106318625A - Plant extract bacteriostatic and antiallergic faint-scent laundry detergent essence for infants - Google Patents

Abstract

The invention discloses plant extract bacteriostatic and antiallergic faint-scent laundry detergent essence for infants. The laundry detergent essence is prepared from, by weight, 50-55 parts of dry roman chamomile, 45-50 parts of dry indocalamus leaf, an appropriate amount of distilled water, 20-25 parts of radix saussureae lappae, 19-23 parts of marrubium vulgare, 0.8-1 part of cucumber essential oil, 40-50 parts of dichloromethane, 8-10 parts of anhydrous sodium sulfate, 3.5-4 parts of ambrotone, 0.3-0.4 part of Arabic gum, an appropriate amount of deionized water, 2.5-3 parts of ethylene glycol dimethacrylate, 0.1-0.11 part of ammonium persulfate, 0.13-0.14 part of sodium pyrosulfite and 1-1.2 parts of sodium carboxymethylcellulose. The essence is faint scent and mild, is added into laundry detergent special for the infants, acts on clothes texture through kneading, is high in fragrance depositing performance and high in practical value and has the bacteriostatic and antiallergic effects.

Description

Plant extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent essence for one kind

Technical field

The present invention relates to essence technical field, particularly relate to one kind and plant extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent perfume Essence.

Background technology

Daily chemical essence occupies the market share of about half as the pillar of fragrance industry, and along with economic development and society Progressive, this ratio may proceed to rise, and along with the raising of living standards of the people, consumer is more and more higher to the requirement of detergent, Not only want to the medicated clothing after washing and can leave lasting pure and fresh joyful fragrance, but also wish that the products such as liquid detergent have Other additional benefit such as antibacterial, sterilization, skin protection.This is accomplished by the essence adding in detergent carrying out constantly modification and grinding Send out.Typically essence high volatility, rate of release is too fast, easily occurs waste during storing, transporting and use, Or the odor type caused that goes bad changes and becomes sour, it is impossible to meet the requirement of consumer, restrict its development.Microcapsule technology is can be effective Improve these problems so that spice has longer fragrance remaining time, more preferable washing fastness and stability etc..But traditional conjunction Become macromolecule wall material to have polyureas, polyester, melamine resin and polyacrylic etc., form microcapsule wall material utilizing synthesis macromolecule During the monomer that often uses, cross-linking agent etc. such as toluene di-isocyanate(TDI), glutaraldehyde, formaldehyde etc., all there is certain toxicity, these Poisonous reaction residue makes to synthesize the macromolecule microcapsule for wall material

Use be restricted.Therefore, take nontoxic and to have functional monomer synthetic environment-friendly wall material be microcapsule science The target that worker pursues always.

" preparation of polymethyl methacrylate glycol ester wall material microcapsule and sign thereof " literary composition uses radical polymerization Method high polymer polymethyl methacrylate that Ethylene glycol dimethacrylate monomer is formed by interface radical polymerization Glycol ester is the microcapsule of wall material, has good heat stability, and wall material is nontoxic, is suitable for personal care articles and field of medicaments It is with a wide range of applications.But the microcapsule essence liquid detergent to be added to made as the wall material of essence due to microcapsule Preparation in, the density of microcapsule essence and liquid detergent matrix have difference, cause product to be layered, suspended uneven.This is accomplished by Microcapsule wall material is modified, enables to meet the demand of liquid detergent flavouring.

Summary of the invention

The object of the invention is contemplated to make up the defect of prior art, it is provided that plant extraction antibacterial antiallergic delicate fragrance for baby for one kind Type liquid detergent essence.

The present invention is achieved by the following technical solutions:

Plant an extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent essence, be prepared by the raw materials in: be dried Rome Flos Matricariae chamomillae 50-55, dry indicalamus leaf 45-50, distilled water are appropriate, Saussurea lappa Clarke 20-25, marrubium 19-23, cucumber essential oil 0.8- 1, dichloromethane 40-50, anhydrous sodium sulfate 8-10, ambrotone 3.5-4, arabic gum 0.3-0.4, deionized water be appropriate, diformazan Base acrylic acid glycol ester 2.5-3, Ammonium persulfate. 0.1-0.11, sodium pyrosulfite 0.13-0.14, sodium carboxymethyl cellulose 1- 1.2。

Plant extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent essence, be made up of step in detail below for described one kind:

(1) join in vapor distillation device after dry Anthemis nobilis being mixed with dry indicalamus leaf, add total amount 5-6 times The distilled water of amount, is heated to 120-125 DEG C, carries out vapor distillation 5-6 hour, and fraction carries out oil-water separation, uses dichloro Methane aqueous phase extracted, after merging oil phase, adds anhydrous sodium sulfate in oil phase and is dried, obtain the liquid of clear.Make By rotary evaporator, dichloromethane is concentrated removing, obtain mixed essential oil；

(2) Saussurea lappa Clarke is mixed with marrubium, add the distilled water of total amount 6-8 times amount, boil 2-3 hour, cooled and filtered Slagging-off, is spray-dried filtrate, obtains mixed-powder；The mixed essential oil that the mixed-powder obtained and step (1) are obtained Mixing, adds cucumber essential oil, ambrotone, and the formation mixing essence that stirs is stand-by；Then arabic gum will add 100- The deionized water of 120 times amount, warming while stirring, to 50-60 DEG C until arabic gum is completely dissolved, forms solution；Will mixing perfume Smart and above-mentioned solution mixes, and puts into VELOCITY SHEAR 3-5 minute with 6000-7000 rev/min in effective dispersing machine, forms mixing perfume Essence emulsion；

(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10-12 times amount deionized water, and under room temperature, dropping is dissolved in 8-10 times amount The Ammonium persulfate. of ionized water, controlling time for adding is 30 minutes, is warming up to 50-60 DEG C, and insulation reaction 1.5-2 hour is cooled to Room temperature, obtains microcapsule essence；

(4) by the deionized water adding 3-5 times amount in sodium carboxymethyl cellulose, stir to being completely dissolved formation clear solution, By the surface of the microcapsule essence that spray solution obtains in step (3), finally it is dried at 50-60 DEG C in vacuum drying oven, Obtain the present invention.

The invention have the advantage that Ethylene glycol dimethacrylate self-crosslinking is formed the three of densification by the present invention by reaction Dimension net polymer is coated on mixing essence top layer and forms microcapsule essence, and the microcapsule essence size dimension made distribution is all Even, form is full, few gathering, has good heat stability and slow-releasing so that fragrance persistently discharges；By at microcapsule One layer of carboxymethylcellulose sodium solution of essence surface sprinkling, it is possible to the microcapsule essence made is suspended all in liquid detergent Even, moreover it is possible to act on fabric face be prevented from fabric repeat absorb dust.Product safety environment-protecting asepsis of the present invention, adds to and washes In clothing liquid, laundry processes enter fabric and remains, then slowly discharging fragrance by rubbing, make fabric have and hold Long fragrance.

The present invention utilizes the mode of vapor distillation to prepare Anthemis nobilis and indicalamus leaf mixed essential oil, has pure and fresh light Refined fragrance, has certain antiallergic, bacteriostasis efficacy, coordinates the interpolation of marrubium and Saussurea lappa Clarke extract, plays calmness Pacify, eliminate the effect of anaphylactogen；The pure and fresh gentleness of spice of the present invention, is added in the special liquid detergent of baby, is acted on by rubbing In medicated clothing texture, not only long lasting quality is good, and has antibacterial, effect of antiallergic, and practical value is high.

Detailed description of the invention

Plant an extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent essence, by the raw material system of following weight portion (kilogram) Become: be dried Anthemis nobilis 50, be dried that indicalamus leaf 45, distilled water be appropriate, Saussurea lappa Clarke 20, marrubium 19, cucumber essential oil 0.8, Dichloromethane 40, anhydrous sodium sulfate 8, ambrotone 3.5, arabic gum 0.3, deionized water are appropriate, ethylene glycol dimethacrylate Ester 2.5, Ammonium persulfate. 0.1, sodium pyrosulfite 0.13, sodium carboxymethyl cellulose 1.

Plant extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent essence, be made up of step in detail below for described one kind:

(1) join in vapor distillation device after dry Anthemis nobilis being mixed with dry indicalamus leaf, add total amount 5 times amount Distilled water, be heated to 120 DEG C, carry out vapor distillation 5 hours, fraction is carried out oil-water separation, use dichloromethane extraction Aqueous phase, after merging oil phase, adds anhydrous sodium sulfate in oil phase and is dried, obtain the liquid of clear.Use to rotate and steam Send out device and dichloromethane is concentrated removing, obtain mixed essential oil；

(2) being mixed with marrubium by Saussurea lappa Clarke, add the distilled water of total amount 6 times amount, boil 2 hours, cooled and filtered removes the gred, Filtrate is spray-dried, obtains mixed-powder；The mixed essential oil that the mixed-powder obtained obtains with step (1) is mixed, Adding cucumber essential oil, ambrotone, the formation mixing essence that stirs is stand-by；Then arabic gum will add 100 times amount Deionized water, warming while stirring to 50 DEG C, until arabic gum is completely dissolved, forms solution；Will mixing essence and above-mentioned solution Mixing, puts into the VELOCITY SHEAR 3 minutes with 6000 revs/min in effective dispersing machine, forms mixing essence emulsion；

(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10 times amount deionized waters, and under room temperature, dropping is dissolved in 8 times amount deionized waters Ammonium persulfate., control time for adding be 30 minutes, be warming up to 50 DEG C, insulation reaction 1.5 hours, be cooled to room temperature, obtain micro- Capsule essence；

(4) by the deionized water adding 3 times amount in sodium carboxymethyl cellulose, stirring, will to being completely dissolved formation clear solution The surface of the microcapsule essence that spray solution obtains in step (3), is finally dried in vacuum drying oven at 50 DEG C, obtains this Invention.

Adding in liquid detergent by product of the present invention, consumption is 0.5%, still has after test liquid detergent is placed 12 months Fragrance, and essence residual quantity is still greater than 10%.

Claims (2)

1. plant extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent essence for one kind, it is characterised in that by the raw material of following weight portion Make: dry Anthemis nobilis 50-55, dry indicalamus leaf 45-50, distilled water are appropriate, Saussurea lappa Clarke 20-25, marrubium 19- 23, cucumber essential oil 0.8-1, dichloromethane 40-50, anhydrous sodium sulfate 8-10, ambrotone 3.5-4, arabic gum 0.3-0.4, go Ionized water is appropriate, Ethylene glycol dimethacrylate 2.5-3, Ammonium persulfate. 0.1-0.11, sodium pyrosulfite 0.13-0.14, carboxylic Sodium carboxymethylcellulose pyce 1-1.2.

Plant extraction antibacterial antiallergic delicate fragrance type for baby liquid detergent essence for one kind the most according to claim 1, it is characterised in that by Step is made in detail below:

(1) join in vapor distillation device after dry Anthemis nobilis being mixed with dry indicalamus leaf, add total amount 5-6 times The distilled water of amount, is heated to 120-125 DEG C, carries out vapor distillation 5-6 hour, and fraction carries out oil-water separation, uses dichloro Methane aqueous phase extracted, after merging oil phase, adds anhydrous sodium sulfate in oil phase and is dried, obtain the liquid of clear.Make By rotary evaporator, dichloromethane is concentrated removing, obtain mixed essential oil；

(2) Saussurea lappa Clarke is mixed with marrubium, add the distilled water of total amount 6-8 times amount, boil 2-3 hour, cooled and filtered Slagging-off, is spray-dried filtrate, obtains mixed-powder；The mixed essential oil that the mixed-powder obtained and step (1) are obtained Mixing, adds cucumber essential oil, ambrotone, and the formation mixing essence that stirs is stand-by；Then arabic gum will add 100- The deionized water of 120 times amount, warming while stirring, to 50-60 DEG C until arabic gum is completely dissolved, forms solution；Will mixing perfume Smart and above-mentioned solution mixes, and puts into VELOCITY SHEAR 3-5 minute with 6000-7000 rev/min in effective dispersing machine, forms mixing perfume Essence emulsion；

(3) the mixing essence emulsion of step (2) put in reactor and be passed through nitrogen protection, adding dimethacrylate second two Alcohol ester, is stirring evenly and then adding into the sodium pyrosulfite being dissolved in 10-12 times amount deionized water, and under room temperature, dropping is dissolved in 8-10 times amount The Ammonium persulfate. of ionized water, controlling time for adding is 30 minutes, is warming up to 50-60 DEG C, and insulation reaction 1.5-2 hour is cooled to Room temperature, obtains microcapsule essence；

(4) by the deionized water adding 3-5 times amount in sodium carboxymethyl cellulose, stir to being completely dissolved formation clear solution, By the surface of the microcapsule essence that spray solution obtains in step (3), finally it is dried at 50-60 DEG C in vacuum drying oven, Obtain the present invention.