CN106187064B - A kind of method that reclaimed materials prepares interior wall dry powder and mortar - Google Patents

A kind of method that reclaimed materials prepares interior wall dry powder and mortar Download PDF

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Publication number
CN106187064B
CN106187064B CN201610539619.9A CN201610539619A CN106187064B CN 106187064 B CN106187064 B CN 106187064B CN 201610539619 A CN201610539619 A CN 201610539619A CN 106187064 B CN106187064 B CN 106187064B
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China
Prior art keywords
mortar
powder
dry powder
reclaimed materials
interior wall
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CN201610539619.9A
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Chinese (zh)
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CN106187064A (en
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张洲会
盛嘉禾
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DEQING YANGTAI BUILDING MATERIAL Co Ltd
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DEQING YANGTAI BUILDING MATERIAL Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B30/00Compositions for artificial stone, not containing binders
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • C04B2111/28Fire resistance, i.e. materials resistant to accidental fires or high temperatures
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Building Environments (AREA)

Abstract

A kind of method that reclaimed materials prepares interior wall dry powder and mortar, this method uses recycling refractory brick as main binder and aggregate, it is at low cost, good flame retardation effect, layered double hydroxide is added to match with redispersable latex powder, increase the cohesive force with basal plane, when fire occurs, there is preferably flame retardant effect;With absorption pernicious gas, bactericidal effect, there is extraordinary absorption fixed function to the micro heavy in former recycling refractory brick, be a kind of construction material of environmental protection.

Description

A kind of method that reclaimed materials prepares interior wall dry powder and mortar
Technical field
The invention belongs to building material fields, and in particular to a kind of method that reclaimed materials prepares interior wall dry powder and mortar.
Background technology
With the fast development of construction industry, the requirement to construction industry quality is higher and higher.Due to the skill by construction personnel The influence of the various raw material such as art qualification and cement, sand, the mortar of construction site configuration, either masonry mortar, Usually there is building plastering mortar cracking phenomena (even most traditional clay wall in decorative mortar or floor leveling mortar Brick also will appear Large Area Cracking using cement mortar plastering), to cause construction quality is unstable, intensity beat less than require, Situation even with low quality happens occasionally, it has also become construction quality common fault.In addition, with the improvement of living standards, people couple The requirement of itself living environment also increasingly increases severely, and in the construction process in house, takes heat preservation, heat-insulated and mute measure, The surface of major project increases one layer of thermal insulation layer.The material most started is styrofoam thermal insulation layer, after have it is heat-insulation mortar bed, it is former Reason is all that several small bubbles of vacuum form thin films and achieve the effect that heat preservation, heat-insulated and mute.But wherein polyphenyl The high-temperature resistant result of plate is very poor, and flameproof effect is also undesirable, and the fire on the ground such as Shanghai, Shenyang, state compulsion was once caused to prohibit The use of styrofoam is stopped.And comparatively inorganic kervit microbead insulated sand slurry compares due to being formed with incombustible inorganic material It is safer, but its cost is high, and engineering overall cost can be caused to rise.Find that a kind of brittleness is low, tensile strength is big, heat preservation energy-saving And mortar at low cost is always the research hotspot in building material industry.
After being used for multiple times, various performances are greatly reduced the refractory material of field of steel-making, cannot be satisfied the needs of steel-making, And these refractory materials contain the ingredients such as a large amount of corundum, cement, these ingredients can be applied to dry powder and mortar.
Invention content
It is an object of the invention in view of the problems of the existing technology, provide a kind of reclaimed materials to prepare interior wall dry powder sand The method of slurry.
A kind of method that reclaimed materials prepares interior wall dry powder and mortar, comprises the steps of:
Step 1:Refractory brick grinding particulate will be recycled, after crossing 80 mesh sieve, redispersable latex powder and the double gold of stratiform is added Belong to hydroxide, continue to grind after stirring evenly, crosses 325 mesh sieve, obtain fine powder;
Step 2:Above-mentioned fine powder is poured into blender, bentonite, calcined shell powder, activated carbon, citric acid and silicon is added Diatomaceous earth is uniformly mixed;
Step 3:The recycling firebrick particle after 80 mesh of the mistake sieve in step 1 is added in blender again and continues stirring It is even.
Preferably, the main component of the recycling refractory brick is:Corundum, pure calcium aluminate cement, clay, aluminium oxide, magnesium Sand, zirconium dioxide.
Preferably, the layered double hydroxide is ferrous aluminium class layered hydroxide.
Layered double hydroxide (layered double hydroxides, LDHs, also known as hydrotalcite stratiform material Material) it is a kind of anion type laminated compound with broad prospect of application, structure is similar to shepardite, and chemical general formula is [M2+ (1-x)M3+ x(OH)2]x+(An-)x/n·yH2O.Wherein M2+、M3+It respectively represents and occupies octahedra hydroxide centre bit on laminate The divalent and trivalent metal ion set, An-For interlayer exchangeable anions.With the similar divalent of radius, trivalent metal cation portion Divide or all replace M2+And M3+A variety of binary, ternary even four-component hydrotalcite compound can be synthesized.LDHs is by positively charged Main layer board and interlayer anion be mutually assembled by non-covalent bond, have special interlayer anion interchangeability, Aperture can the shape-selective adsorptivity of modulation, cation assortable property, surface Acid and basic sites compossibility etc. on layer, make it have unique Function, not only there is the ion exchanging function of similar ion exchange resin, also special absorption and a catalysis, and it is general have compared with The ability of high thermal stability and acid and alkali-resistance, so becoming one kind in catalysis, absorption, ion exchange, photoelectromagnetic, medicine and work( Can the fields such as high molecular material there is the new materials of potentiality and foreground, be widely used as catalyst, adsorbent, ion-exchanger, Electrode material, medicinal slow release agent and fire proofing material etc..
The purpose that layered double hydroxide is added in the present invention is to recycle the superfine powder after refractory brick grinding It is distributed to the inside and surface of layered double hydroxide, there is better caking property under the cooperation of redispersable latex powder Can, and when encountering fire, due to being uniformly dispersed, flame retardant effect is more preferable.
And the purpose of preferably ferrous aluminium class layered hydroxide is, is conducive to form hercynite knot after fire Structure, rather than magnesia-alumina spinel structure.The caking property of magnesia-alumina spinel structure and concrete substrates is poor, is easy to fall off, significantly Influence fire retardation of the dry powder and mortar to building.
Preferably, reclaimed materials of the present invention prepares interior wall dry powder and mortar, by group following weight percentage components At:
Calcined shell powder is added and activated carbon has following functions:When can effectively remove the free formaldehyde in air, Harmful substances such as benzene, ammonia and because of peculiar smell caused by pet, smoking, rubbish, purify the air of a room;Second is that having pole to Escherichia coli In addition strong antibacterial and bactericidal effect also has notable effect to salmonella, yellow glucose fungus;Third, being recycled in refractory brick to original Micro heavy there is extraordinary absorption fixed function, heavy metal to can be ignored the harm of human body.
The beneficial of the present invention is effectively:There is very good adhesion with basal plane, material is economical and practical, has used a large amount of return Receive refractory brick, at low cost, good flame retardation effect;Layered double hydroxide is added to match with redispersable latex powder, increases There is preferably flame retardant effect when fire occurs with the cohesive force of basal plane, calcined shell powder and activated carbon, more ring is added It protects, is non-hazardous to human body.
Specific implementation mode
Embodiment 1
A kind of method that reclaimed materials prepares interior wall dry powder and mortar, which is characterized in that comprise the steps of:
Step 1:Refractory brick grinding particulate will be recycled, after crossing 80 mesh sieve, redispersable latex powder and the double gold of stratiform is added Belong to hydroxide, continue to grind after stirring evenly, crosses 325 mesh sieve, obtain fine powder;
Step 2:Above-mentioned fine powder is poured into blender, bentonite, calcined shell powder, activated carbon, citric acid and silicon is added Diatomaceous earth is uniformly mixed;
Step 3:The recycling firebrick particle after 80 mesh of the mistake sieve in step 1 is added in blender again and continues stirring It is even;
The main component of the recycling refractory brick is:Corundum, pure calcium aluminate cement, clay, aluminium oxide, magnesia, dioxy Change zirconium;
The layered double hydroxide is ferrous aluminium class layered hydroxide;
Dry powder and mortar prepared by the reclaimed materials, by forming following weight percentage components:
Embodiment 2
A kind of method that reclaimed materials prepares interior wall dry powder and mortar, which is characterized in that comprise the steps of:
Step 1:Refractory brick grinding particulate will be recycled, after crossing 80 mesh sieve, redispersable latex powder and the double gold of stratiform is added Belong to hydroxide, continue to grind after stirring evenly, crosses 325 mesh sieve, obtain fine powder;
Step 2:Above-mentioned fine powder is poured into blender, bentonite, calcined shell powder, activated carbon, citric acid and silicon is added Diatomaceous earth is uniformly mixed;
Step 3:The recycling firebrick particle after 80 mesh of the mistake sieve in step 1 is added in blender again and continues stirring It is even;
The main component of the recycling refractory brick is:Corundum, pure calcium aluminate cement, clay, aluminium oxide, magnesia, dioxy Change zirconium;
The layered double hydroxide is ferrous aluminium class layered hydroxide;
Dry powder and mortar prepared by the reclaimed materials, by forming following weight percentage components:
Embodiment 3
A kind of method that reclaimed materials prepares interior wall dry powder and mortar, which is characterized in that comprise the steps of:
Step 1:Refractory brick grinding particulate will be recycled, after crossing 80 mesh sieve, redispersable latex powder and the double gold of stratiform is added Belong to hydroxide, continue to grind after stirring evenly, crosses 325 mesh sieve, obtain fine powder;
Step 2:Above-mentioned fine powder is poured into blender, bentonite, calcined shell powder, activated carbon, citric acid and silicon is added Diatomaceous earth is uniformly mixed;
Step 3:The recycling firebrick particle after 80 mesh of the mistake sieve in step 1 is added in blender again and continues stirring It is even;
The main component of the recycling refractory brick is:Corundum, pure calcium aluminate cement, clay, aluminium oxide, magnesia, dioxy Change zirconium;
The layered double hydroxide is ferrous aluminium class layered hydroxide;
Dry powder and mortar prepared by the reclaimed materials, by forming following weight percentage components:
Comparative example 1
By the layered double hydroxide removal in embodiment 1, remaining condition is constant.
Comparative example 2
Ferrous aluminium class layered hydroxide in embodiment 1 is replaced with into magnesia-alumina layered hydroxide, remaining condition is not Become.
Fire prevention detection carried out to embodiment 1-3 and comparative example 1-2, detection mortar from the dropping situations on wall, Testing result is as follows:
Serial number Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1 Comparative example 2
1 Nothing Nothing Nothing Slightly Nothing
2 Nothing Nothing Nothing Nothing Nothing
3 Nothing Nothing Nothing Seriously Slightly
4 Nothing Nothing Nothing Seriously Seriously
As a result:Nothing:Nothing falls off;Slightly:Slightly fall off;Seriously:Severe detachment
Group 1:With alcohol blast burner flame away from coating 5cm, toast, dry powder and mortar is applied to concrete wall surface, coating layer thickness 5mm, fire duration 5min.
Group 2:With alcohol blast burner flame away from coating 5cm, toast, dry powder and mortar is applied to concrete wall surface, coating layer thickness: 1cm, fire duration 5min.
Group 3:With alcohol blast burner flame away from coating 5cm, toast, dry powder and mortar is applied to concrete wall surface, coating layer thickness: 5mm, fire duration 10min.
Group 4:With alcohol blast burner flame away from coating 5cm, toast, dry powder and mortar is applied to concrete wall surface, coating layer thickness: 5mm, fire duration 30min.
By the above testing result it is recognised that ferrous aluminium class layered hydroxide ratio is added in the dry powder and mortar of the present invention not Layered hydroxide is added or the layered hydroxide of other elements is added, dry powder and mortar is applied to concrete wall surface, in fire When have many adhesive properties, flame retardant effect is well very much.
This detection data is just for above-mentioned detection sample.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, according to the technique and scheme of the present invention and its Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.

Claims (3)

1. a kind of method that reclaimed materials prepares interior wall dry powder and mortar, which is characterized in that comprise the steps of:
Step 1:Refractory brick grinding particulate will be recycled, after crossing 80 mesh sieve, redispersable latex powder and layered bi-metal hydrogen is added Oxide continues to grind after stirring evenly, and crosses 325 mesh sieve, obtains fine powder;
Step 2:Above-mentioned fine powder is poured into blender, bentonite, calcined shell powder, activated carbon, citric acid and diatom is added Soil is uniformly mixed;
Step 3:The recycling firebrick particle after 80 mesh of the mistake sieve in step 1 is added in blender again and continues to stir evenly i.e. It can;
Dry powder and mortar prepared by the reclaimed materials, by forming following weight percentage components:
Recycle refractory brick 70-80%
Redispersable latex powder 2-5%
Layered double hydroxide 0.5-1%
Bentonite 3-5%
Citric acid 0.2-0.5%
Calcined shell powder 1-3%
Activated carbon 0.5-0.8%
Diatomite surplus.
2. the method that reclaimed materials according to claim 1 prepares interior wall dry powder and mortar, which is characterized in that the recycling The main component of refractory brick is:Corundum, pure calcium aluminate cement, clay, aluminium oxide, magnesia, zirconium dioxide.
3. the method that reclaimed materials according to claim 1 prepares interior wall dry powder and mortar, which is characterized in that the stratiform Double-metal hydroxide is ferrous aluminium class layered hydroxide.
CN201610539619.9A 2016-07-06 2016-07-06 A kind of method that reclaimed materials prepares interior wall dry powder and mortar Active CN106187064B (en)

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Application Number Priority Date Filing Date Title
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Publication number Priority date Publication date Assignee Title
CN106747034A (en) * 2017-01-18 2017-05-31 丽水市知科科技有限公司 A kind of inexpensive external wall dry powder and mortar and preparation method thereof

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CN102775106B (en) * 2012-06-11 2016-05-18 深圳市华威环保建材有限公司 A kind of regeneration common brick sand dry powder mortar and manufacture method thereof
CN105254261A (en) * 2014-07-17 2016-01-20 北京化工大学 Lightweight high-strength nature hydraulicity me mortar for masonry building repair, and preparation method thereof
CN104591562A (en) * 2014-08-04 2015-05-06 湖北文理学院 Method for using solid waste to prepare regenerated building mortar

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Denomination of invention: A method for preparing dry powder mortar for interior walls using recycled materials

Granted publication date: 20180904

Pledgee: Qianyuan sub branch of Zhejiang Deqing Rural Commercial Bank Co.,Ltd.

Pledgor: DEQING YANGTAI BUILDING MATERIAL Co.,Ltd.

Registration number: Y2024980017709