A kind of new membrane bioreactor sewage water processing means
Technical field
The invention belongs to sewage treatment area, be specifically related to a kind of new membrane bioreactor sewage water processing means.
Background technology
China is as populous nation and industrial power, along with economic fast development, for water resource demand increasingly
Greatly, water, as valuable natural resources, is all life and human lives produces indispensable base substance of depending on for existence, but
China's water resource is not enriched, and on the one hand the scarcity of water resource is faced with the short water supply even problem of some areas shipwreck,
On the other hand along with the fast development of modern industry, the water resource pollution brought therewith is day by day serious, urban domestic wastewater and each
The handling rate of industrial wastewater is low, and the orthobiosis not only affecting the people also results in river, the pollution of soil etc., water resource supply and demand
The intensification of contradiction makes country increasingly pay attention to sewage disposal recycling.Existing sewage treatment process is various, and traditional process
It is big mostly to there is processing means floor space in technique, and solid-liquid separation efficiency is low, and mud surplus is big, and efficiency is low, power consumption height, goes out
The problems such as water water quality is unstable, complex management, such process technique can not meet the demand of existing sewage disposal, therefore,
Novel sewage processes the research just tool of technique and is of great significance.
Membrane bioreactor is the Novel state Waste Water Treatment of membrane separation technique and biologic treating technique combination.With
Membrane module replaces traditional biological treatment technology end second pond, keeps high activity sludge concentration in bioreactor, improves raw
Thing processes organic loading, thus reduces sewage treatment facility floor space, and by keeping low sludge loading to reduce excess sludge
Amount.For improving further the recovery utilization rate to water resource, the research of new membrane bioreactor include its with other at science and engineering
Skill with the use of become sewage disposal research new direction, how to develop more stable, efficient water outlet technique, improve and
Water quality is exactly the problem that the present invention is to be studied.
Summary of the invention
It is an object of the invention to provide a kind of new membrane bioreactor sewage water processing means.
For achieving the above object, a kind of new membrane bioreactor sewage water processing means, including following assembly: pump up water
Pump, water inlet pipe, bioreactor, gas explosion device, aeration control system, sewage backflow pipeline, membrane reactor, ultrasonic vibration box,
Supersonic generator, membrane module, outlet pipe one, advanced treatment apparatus, outlet pipe two;Also include three water level controllers: water level
Controller one, water level controller two, water level controller three.Described bioreactor top is connected with suction water pump, described water level
Controller one controls the inflow of water inlet pipe, and described gas explosion device is arranged on bioreactor bottom, sets in described gas explosion device
Being equipped with water level controller two, described ultrasonic vibration box is arranged between the inwall of membrane reactor and membrane module, and ultrasonic vibration box leads to
Crossing holding wire to be connected with the supersonic generator signal outside membrane reactor, described membrane reactor bottom is provided with outlet pipe one,
Described outlet pipe one is connected with advanced treatment apparatus.
Further, described membrane bioreactor is separate film biological reactor, has simple to operate, and film easy cleaning is more
The advantage changed, the regulation of described water level controller one controls to enter the sewage quantity of membrane bioreactor, thus overcomes separate film raw
The shortcoming that power consumption that thing reactor causes owing to water pump flow velocity is big is big.
Further, adding Powdered Activated Carbon in membrane reactor, its addition can make mud flco in the formation on film surface
Thing is looser, and water permeability improves, and slow down the formation of sludge filtering cake layer.
Further, described gas explosion device is to regulate aeration rate by aeration control system and water level controller two, described
Water level controller two is the height being regulated water level by the size measuring dissolved oxygen amount, is regulated by instant mensuration of dissolved oxygen amount
Water level just thus regulates aeration rate, has instant, accurate, the advantage of full-automatic regulation.
Further, in described membrane module, film is modified poly (ether-sulfone) NF membrane, and its method of modifying is: by polyether sulfone filtering film
Cleaning up, be placed in drying baker that 40 DEG C of freeze-day with constant temperature are to constant weight, recording its weight is G1, put in vessel, with metering system
Acid methyl ester is grafted monomers, to it through decompression distilation before using, is made into the monomer solution that mass concentration is 7%, pours into
State in vessel so that it is do not had the surface of film, graft reaction occurs under the conditions of ultraviolet radiation, produces graft polymers, take out
Afterwards with the surface that ethyl acetate is solvent monomer flushing membrane, then rinse with experimental water, be placed in 55 DEG C of freeze-day with constant temperature in drying baker
To constant weight, recording its weight is G2, it is described modified poly (ether-sulfone) NF membrane, hydrophobicity and the antimicrobial degraded of film can be improved
Ability and expand its pH range.
Further, the photo-grafting rate of described modified poly (ether-sulfone) NF membrane can characterize by below equation:
Further, described advanced treatment apparatus is built with filler, and described filler is divided into two-layer, and upper strata is activated carbon, under
Layer is modified high-molecular chelating agent, and activated carbon and high-molecular chelating agent are respectively provided with the strongest adsorption activity, in waste water
The materials such as heavy metal have the advantages that adsorbance is big, speed is fast, adsorption efficiency is high, and the sewage crossed through its advanced treating can directly be used
In life closet flushing, greening treegarden irrigation etc..
Further, described modified high-molecular chelating agen is modified animal feather, and its method of modifying is: collect animal feather
Clean up, with being dipped in after deionized water rinsing in sig water, CS2 solution, soak 15h at 50-60 DEG C, then use deionization
Water washes except surface residue, obtains modified animal feather, modified animal feather abundance, it is easy to degraded, preparation technology
Simply, the heavy metal to variable concentrations has good adsorption.
It is an advantage of the current invention that: inventive film bioreactor selects separate film biological reactor, it is simple to film clear
Wash and change, by Modified Membrane and membrane reactor are added Powdered Activated Carbon and ultrasonic vibration box with the use of, can effectively subtract
The pollution of slow film, improves hydrophobicity and the antimicrobial degradation capability of film, extends the service life of film.The present invention passes through three water
The setting of level controller and with the use of, regulated the inflow of control and suck water pump by water level controller one, thus reduce point
Put the shortcoming that the power consumption of formula membrane bioreactor existence is high;Water level controller two is to be adjusted by automatic measurement dissolved oxygen amount
The size of joint aeration rate;The water yield of water level controller three scalable entrance advanced treatment apparatus, thus advanced treatment apparatus of fitting
Processing speed;Residual heavy metal in advanced treatment apparatus removable membrane bioreactor water outlet, treated water can be straight
Connect for life closet flushing, greening treegarden irrigation etc., more meet environmental requirement.
Accompanying drawing explanation
Fig. 1 is the structural representation of new membrane bioreactor sewage water processing means;
Wherein, 1-aspirates water pump;2-water level controller one;3-water inlet pipe;4-bioreactor;5-gas explosion device;
6-water level controller two;7-aeration control system;8-sewage backflow pipeline;9-membrane reactor;10-ultrasonic vibration box;11-is ultrasonic
Wave producer;12-membrane module;13-outlet pipe one;14-water level controller three;15-advanced treatment apparatus;16-outlet pipe two.
Detailed description of the invention
Hereinafter, in conjunction with accompanying drawing 1 and embodiment, the detailed description of the invention of the present invention is described in detail:
As Fig. 1 illustrates a kind of new membrane bioreactor sewage water processing means of the present invention, including following assembly: pump up water
Pump 1, water inlet pipe 3, bioreactor 4, gas explosion device 5, aeration control system 7, sewage backflow pipeline 8, membrane reactor 9, ultrasonic
Ripple Vibration Box 10, supersonic generator 11, membrane module 12, outlet pipe 1, advanced treatment apparatus 15, outlet pipe 2 16;Also include
Three water level controllers: water level controller 1, water level controller 26, water level controller 3 14.Described bioreactor 4 top
Being connected with suction water pump 1, described water level controller 1 controls the inflow of water inlet pipe 3, and described gas explosion device 5 is arranged on biology
Reactor 4 bottom, is provided with water level controller 26 in described gas explosion device 5, described ultrasonic vibration box 10 is arranged on membrane reactor
Between inwall and the membrane module 12 of 9, ultrasonic vibration box 10 is believed with the supersonic generator 11 outside membrane reactor 9 by holding wire
Number connect, described membrane reactor 9 bottom is provided with outlet pipe 1, and described outlet pipe 1 is connected with advanced treatment apparatus 15.
Described membrane bioreactor is separate film biological reactor, has simple to operate, the advantage that film easy cleaning is changed, described water level
Controller 1 regulation controls to enter the sewage quantity of membrane bioreactor, thus overcomes separate film biological reactor due to water pump
The shortcoming that flow velocity is big and causes power consumption is big;Adding Powdered Activated Carbon in membrane reactor 9, its addition can make mud flco
Formation on film surface is looser, and water permeability improves, and slow down the formation of sludge filtering cake layer;Described gas explosion device 5 is logical
Crossing aeration control system 7 and water level controller 26 regulates aeration rate, described water level controller 26 is by measuring dissolved oxygen amount
Size regulates the height of water level, regulates water level height by the instant mensuration of dissolved oxygen amount thus regulates aeration rate, has i.e.
Time, accurately, the advantage of full-automatic regulation;In described membrane module 12, film is modified poly (ether-sulfone) NF membrane, and its method of modifying is: will be poly-
Ether sulfone NF membrane cleans up, and is placed in drying baker that 40 DEG C of freeze-day with constant temperature are to constant weight, and recording its weight is G1, put in vessel,
With methyl methacrylate as grafted monomers, to it through decompression distilation before using, it is made into the monomer that mass concentration is 7% molten
Liquid, pours in above-mentioned vessel so that it is do not had the surface of film, graft reaction occurs under the conditions of ultraviolet radiation, produces grafting poly-
Compound, with the surface that ethyl acetate is solvent monomer flushing membrane after taking-up, then rinses with experimental water, is placed in drying baker 55 DEG C
Freeze-day with constant temperature is to constant weight, and recording its weight is G2, it is described modified poly (ether-sulfone) NF membrane, the hydrophobicity of film can be improved and resist micro-
Biodegradability and expand its pH range;The photo-grafting rate of described modified poly (ether-sulfone) NF membrane can be come by below equation
Characterize:Described advanced treatment apparatus 15 is built with filler, and described filler is divided into two-layer, upper strata
For activated carbon, lower floor is modified high-molecular chelating agent, and activated carbon and high-molecular chelating agent are respectively provided with the strongest adsorption activity, right
The materials such as the heavy metal in waste water have the advantages that adsorbance is big, speed is fast, adsorption efficiency is high, through the dirt that its advanced treating is crossed
Water can be directly used for life closet flushing, greening treegarden irrigation etc.;Described modified high-molecular chelating agen is modified animal feather, its
Method of modifying is: collects animal feather and cleans up, with being dipped in after deionized water rinsing in sig water, CS2 solution, and 50-
Soaking 15h at 60 DEG C, then wash except surface residue with deionized water, obtain modified animal feather, modified animal feather comes
Source is enriched, it is easy to degraded, and preparation technology is simple, and the heavy metal of variable concentrations is had good adsorption.
The present invention is not limited to above-mentioned embodiment, in the case of without departing substantially from the flesh and blood of the present invention, and this area skill
Art personnel it is conceivable that any deformation, improve, replace and each fall within the scope of the present invention.