CN106186545A - A kind of new membrane bioreactor sewage water processing means - Google Patents

A kind of new membrane bioreactor sewage water processing means Download PDF

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Publication number
CN106186545A
CN106186545A CN201610701292.0A CN201610701292A CN106186545A CN 106186545 A CN106186545 A CN 106186545A CN 201610701292 A CN201610701292 A CN 201610701292A CN 106186545 A CN106186545 A CN 106186545A
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water
membrane
water level
level controller
processing means
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CN201610701292.0A
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CN106186545B (en
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董金萍
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D67/00Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002Organic membrane manufacture
    • B01D67/0006Organic membrane manufacture by chemical reactions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D71/00Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06Organic material
    • B01D71/76Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/78Graft polymers
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/286Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/10Packings; Fillings; Grids
    • C02F3/102Permeable membranes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2323/00Details relating to membrane preparation
    • B01D2323/38Graft polymerization
    • B01D2323/385Graft polymerization involving radiation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/442Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by nanofiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2209/00Controlling or monitoring parameters in water treatment
    • C02F2209/42Liquid level
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1205Particular type of activated sludge processes
    • C02F3/1226Particular type of activated sludge processes comprising an absorbent material suspended in the mixed liquor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1268Membrane bioreactor systems
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

The invention discloses a kind of new membrane bioreactor sewage water processing means, including following assembly: suction water pump, water inlet pipe, bioreactor, gas explosion device, aeration control system, sewage backflow pipeline, membrane reactor, ultrasonic vibration box, supersonic generator, membrane module, outlet pipe one, advanced treatment apparatus, outlet pipe two;Also include three water level controllers: water level controller one, water level controller two, water level controller three.Described bioreactor top is connected with suction water pump, described water level controller one controls the inflow of water inlet pipe, described gas explosion device is arranged on bioreactor bottom, it is provided with water level controller two in described gas explosion device, described ultrasonic vibration box is arranged between the inwall of membrane reactor and membrane module, ultrasonic vibration box is connected with the supersonic generator signal outside membrane reactor by holding wire, and described membrane reactor bottom is provided with outlet pipe one, and described outlet pipe one is connected with advanced treatment apparatus.

Description

A kind of new membrane bioreactor sewage water processing means
Technical field
The invention belongs to sewage treatment area, be specifically related to a kind of new membrane bioreactor sewage water processing means.
Background technology
China is as populous nation and industrial power, along with economic fast development, for water resource demand increasingly Greatly, water, as valuable natural resources, is all life and human lives produces indispensable base substance of depending on for existence, but China's water resource is not enriched, and on the one hand the scarcity of water resource is faced with the short water supply even problem of some areas shipwreck, On the other hand along with the fast development of modern industry, the water resource pollution brought therewith is day by day serious, urban domestic wastewater and each The handling rate of industrial wastewater is low, and the orthobiosis not only affecting the people also results in river, the pollution of soil etc., water resource supply and demand The intensification of contradiction makes country increasingly pay attention to sewage disposal recycling.Existing sewage treatment process is various, and traditional process It is big mostly to there is processing means floor space in technique, and solid-liquid separation efficiency is low, and mud surplus is big, and efficiency is low, power consumption height, goes out The problems such as water water quality is unstable, complex management, such process technique can not meet the demand of existing sewage disposal, therefore, Novel sewage processes the research just tool of technique and is of great significance.
Membrane bioreactor is the Novel state Waste Water Treatment of membrane separation technique and biologic treating technique combination.With Membrane module replaces traditional biological treatment technology end second pond, keeps high activity sludge concentration in bioreactor, improves raw Thing processes organic loading, thus reduces sewage treatment facility floor space, and by keeping low sludge loading to reduce excess sludge Amount.For improving further the recovery utilization rate to water resource, the research of new membrane bioreactor include its with other at science and engineering Skill with the use of become sewage disposal research new direction, how to develop more stable, efficient water outlet technique, improve and Water quality is exactly the problem that the present invention is to be studied.
Summary of the invention
It is an object of the invention to provide a kind of new membrane bioreactor sewage water processing means.
For achieving the above object, a kind of new membrane bioreactor sewage water processing means, including following assembly: pump up water Pump, water inlet pipe, bioreactor, gas explosion device, aeration control system, sewage backflow pipeline, membrane reactor, ultrasonic vibration box, Supersonic generator, membrane module, outlet pipe one, advanced treatment apparatus, outlet pipe two;Also include three water level controllers: water level Controller one, water level controller two, water level controller three.Described bioreactor top is connected with suction water pump, described water level Controller one controls the inflow of water inlet pipe, and described gas explosion device is arranged on bioreactor bottom, sets in described gas explosion device Being equipped with water level controller two, described ultrasonic vibration box is arranged between the inwall of membrane reactor and membrane module, and ultrasonic vibration box leads to Crossing holding wire to be connected with the supersonic generator signal outside membrane reactor, described membrane reactor bottom is provided with outlet pipe one, Described outlet pipe one is connected with advanced treatment apparatus.
Further, described membrane bioreactor is separate film biological reactor, has simple to operate, and film easy cleaning is more The advantage changed, the regulation of described water level controller one controls to enter the sewage quantity of membrane bioreactor, thus overcomes separate film raw The shortcoming that power consumption that thing reactor causes owing to water pump flow velocity is big is big.
Further, adding Powdered Activated Carbon in membrane reactor, its addition can make mud flco in the formation on film surface Thing is looser, and water permeability improves, and slow down the formation of sludge filtering cake layer.
Further, described gas explosion device is to regulate aeration rate by aeration control system and water level controller two, described Water level controller two is the height being regulated water level by the size measuring dissolved oxygen amount, is regulated by instant mensuration of dissolved oxygen amount Water level just thus regulates aeration rate, has instant, accurate, the advantage of full-automatic regulation.
Further, in described membrane module, film is modified poly (ether-sulfone) NF membrane, and its method of modifying is: by polyether sulfone filtering film Cleaning up, be placed in drying baker that 40 DEG C of freeze-day with constant temperature are to constant weight, recording its weight is G1, put in vessel, with metering system Acid methyl ester is grafted monomers, to it through decompression distilation before using, is made into the monomer solution that mass concentration is 7%, pours into State in vessel so that it is do not had the surface of film, graft reaction occurs under the conditions of ultraviolet radiation, produces graft polymers, take out Afterwards with the surface that ethyl acetate is solvent monomer flushing membrane, then rinse with experimental water, be placed in 55 DEG C of freeze-day with constant temperature in drying baker To constant weight, recording its weight is G2, it is described modified poly (ether-sulfone) NF membrane, hydrophobicity and the antimicrobial degraded of film can be improved Ability and expand its pH range.
Further, the photo-grafting rate of described modified poly (ether-sulfone) NF membrane can characterize by below equation:
Further, described advanced treatment apparatus is built with filler, and described filler is divided into two-layer, and upper strata is activated carbon, under Layer is modified high-molecular chelating agent, and activated carbon and high-molecular chelating agent are respectively provided with the strongest adsorption activity, in waste water The materials such as heavy metal have the advantages that adsorbance is big, speed is fast, adsorption efficiency is high, and the sewage crossed through its advanced treating can directly be used In life closet flushing, greening treegarden irrigation etc..
Further, described modified high-molecular chelating agen is modified animal feather, and its method of modifying is: collect animal feather Clean up, with being dipped in after deionized water rinsing in sig water, CS2 solution, soak 15h at 50-60 DEG C, then use deionization Water washes except surface residue, obtains modified animal feather, modified animal feather abundance, it is easy to degraded, preparation technology Simply, the heavy metal to variable concentrations has good adsorption.
It is an advantage of the current invention that: inventive film bioreactor selects separate film biological reactor, it is simple to film clear Wash and change, by Modified Membrane and membrane reactor are added Powdered Activated Carbon and ultrasonic vibration box with the use of, can effectively subtract The pollution of slow film, improves hydrophobicity and the antimicrobial degradation capability of film, extends the service life of film.The present invention passes through three water The setting of level controller and with the use of, regulated the inflow of control and suck water pump by water level controller one, thus reduce point Put the shortcoming that the power consumption of formula membrane bioreactor existence is high;Water level controller two is to be adjusted by automatic measurement dissolved oxygen amount The size of joint aeration rate;The water yield of water level controller three scalable entrance advanced treatment apparatus, thus advanced treatment apparatus of fitting Processing speed;Residual heavy metal in advanced treatment apparatus removable membrane bioreactor water outlet, treated water can be straight Connect for life closet flushing, greening treegarden irrigation etc., more meet environmental requirement.
Accompanying drawing explanation
Fig. 1 is the structural representation of new membrane bioreactor sewage water processing means;
Wherein, 1-aspirates water pump;2-water level controller one;3-water inlet pipe;4-bioreactor;5-gas explosion device; 6-water level controller two;7-aeration control system;8-sewage backflow pipeline;9-membrane reactor;10-ultrasonic vibration box;11-is ultrasonic Wave producer;12-membrane module;13-outlet pipe one;14-water level controller three;15-advanced treatment apparatus;16-outlet pipe two.
Detailed description of the invention
Hereinafter, in conjunction with accompanying drawing 1 and embodiment, the detailed description of the invention of the present invention is described in detail:
As Fig. 1 illustrates a kind of new membrane bioreactor sewage water processing means of the present invention, including following assembly: pump up water Pump 1, water inlet pipe 3, bioreactor 4, gas explosion device 5, aeration control system 7, sewage backflow pipeline 8, membrane reactor 9, ultrasonic Ripple Vibration Box 10, supersonic generator 11, membrane module 12, outlet pipe 1, advanced treatment apparatus 15, outlet pipe 2 16;Also include Three water level controllers: water level controller 1, water level controller 26, water level controller 3 14.Described bioreactor 4 top Being connected with suction water pump 1, described water level controller 1 controls the inflow of water inlet pipe 3, and described gas explosion device 5 is arranged on biology Reactor 4 bottom, is provided with water level controller 26 in described gas explosion device 5, described ultrasonic vibration box 10 is arranged on membrane reactor Between inwall and the membrane module 12 of 9, ultrasonic vibration box 10 is believed with the supersonic generator 11 outside membrane reactor 9 by holding wire Number connect, described membrane reactor 9 bottom is provided with outlet pipe 1, and described outlet pipe 1 is connected with advanced treatment apparatus 15. Described membrane bioreactor is separate film biological reactor, has simple to operate, the advantage that film easy cleaning is changed, described water level Controller 1 regulation controls to enter the sewage quantity of membrane bioreactor, thus overcomes separate film biological reactor due to water pump The shortcoming that flow velocity is big and causes power consumption is big;Adding Powdered Activated Carbon in membrane reactor 9, its addition can make mud flco Formation on film surface is looser, and water permeability improves, and slow down the formation of sludge filtering cake layer;Described gas explosion device 5 is logical Crossing aeration control system 7 and water level controller 26 regulates aeration rate, described water level controller 26 is by measuring dissolved oxygen amount Size regulates the height of water level, regulates water level height by the instant mensuration of dissolved oxygen amount thus regulates aeration rate, has i.e. Time, accurately, the advantage of full-automatic regulation;In described membrane module 12, film is modified poly (ether-sulfone) NF membrane, and its method of modifying is: will be poly- Ether sulfone NF membrane cleans up, and is placed in drying baker that 40 DEG C of freeze-day with constant temperature are to constant weight, and recording its weight is G1, put in vessel, With methyl methacrylate as grafted monomers, to it through decompression distilation before using, it is made into the monomer that mass concentration is 7% molten Liquid, pours in above-mentioned vessel so that it is do not had the surface of film, graft reaction occurs under the conditions of ultraviolet radiation, produces grafting poly- Compound, with the surface that ethyl acetate is solvent monomer flushing membrane after taking-up, then rinses with experimental water, is placed in drying baker 55 DEG C Freeze-day with constant temperature is to constant weight, and recording its weight is G2, it is described modified poly (ether-sulfone) NF membrane, the hydrophobicity of film can be improved and resist micro- Biodegradability and expand its pH range;The photo-grafting rate of described modified poly (ether-sulfone) NF membrane can be come by below equation Characterize:Described advanced treatment apparatus 15 is built with filler, and described filler is divided into two-layer, upper strata For activated carbon, lower floor is modified high-molecular chelating agent, and activated carbon and high-molecular chelating agent are respectively provided with the strongest adsorption activity, right The materials such as the heavy metal in waste water have the advantages that adsorbance is big, speed is fast, adsorption efficiency is high, through the dirt that its advanced treating is crossed Water can be directly used for life closet flushing, greening treegarden irrigation etc.;Described modified high-molecular chelating agen is modified animal feather, its Method of modifying is: collects animal feather and cleans up, with being dipped in after deionized water rinsing in sig water, CS2 solution, and 50- Soaking 15h at 60 DEG C, then wash except surface residue with deionized water, obtain modified animal feather, modified animal feather comes Source is enriched, it is easy to degraded, and preparation technology is simple, and the heavy metal of variable concentrations is had good adsorption.
The present invention is not limited to above-mentioned embodiment, in the case of without departing substantially from the flesh and blood of the present invention, and this area skill Art personnel it is conceivable that any deformation, improve, replace and each fall within the scope of the present invention.

Claims (8)

1. a new membrane bioreactor sewage water processing means, it is characterised in that include following assembly: aspirate water pump (1), enter Water pipe (3), bioreactor (4), gas explosion device (5), aeration control system (7), sewage backflow pipeline (8), membrane reactor (9), ultrasonic vibration box (10), supersonic generator (11), membrane module (12), outlet pipe one (13), advanced treatment apparatus (15), Outlet pipe two (16);Also include three water level controllers: water level controller one (2), water level controller two (6), water level controller Three (14).Described bioreactor (4) top is connected with suction water pump (1), and described water level controller one (2) controls water inlet pipe (3) inflow, described gas explosion device (5) is arranged on bioreactor (4) bottom, and described gas explosion device (5) is inner is provided with water Level controller two (6), described ultrasonic vibration box (10) is arranged between the inwall of membrane reactor (9) and membrane module (12), ultrasonic Ripple Vibration Box (10) is connected by supersonic generator (11) signal that holding wire is outside with membrane reactor (9), described membrane reactor (9) bottom is provided with outlet pipe one (13), and described outlet pipe one (13) is connected with advanced treatment apparatus (15).
2. a kind of new membrane bioreactor sewage water processing means as claimed in claim 1, it is characterised in that the described film of institute is raw Thing reactor is separate film biological reactor, and the regulation of described water level controller one (2) controls to enter the dirt of membrane bioreactor The water yield.
3. a kind of new membrane bioreactor sewage water processing means as claimed in claim 1, it is characterised in that at membrane reactor (9) added with Powdered Activated Carbon in.
4. a kind of new membrane bioreactor sewage water processing means as claimed in claim 1, it is characterised in that described gas explosion fills Putting (5) is to regulate aeration rate by aeration control system (7) and water level controller two (6), and described water level controller two (6) is logical Cross and measure the size of dissolved oxygen amount to regulate the height of water level.
5. a kind of new membrane bioreactor sewage water processing means described in claim 1, it is characterised in that described membrane module (12) in, film is modified poly (ether-sulfone) NF membrane, and its method of modifying is: cleaned up by polyether sulfone filtering film, is placed in drying baker 40 DEG C freeze-day with constant temperature is to constant weight, and recording its weight is G1, put in vessel, with methyl methacrylate as grafted monomers, before using To it through decompression distilation, it is made into the monomer solution that mass concentration is 7%, pours in above-mentioned vessel so that it is do not had the table of film Face, under the conditions of ultraviolet radiation occur graft reaction, produce graft polymers, after taking-up with ethyl acetate be solvent monomer punching Washing the surface of film, then rinse with experimental water, be placed in drying baker that 55 DEG C of freeze-day with constant temperature are to constant weight, recording its weight is G2, i.e. For described modified poly (ether-sulfone) NF membrane.
6. a kind of new membrane bioreactor sewage water processing means as claimed in claim 5, it is characterised in that described modification gathers The photo-grafting rate of ether sulfone NF membrane can characterize by below equation:
7. a kind of new membrane bioreactor sewage water processing means as claimed in claim 1, it is characterised in that described depth Reason device (15) is built with filler, and described filler is divided into two-layer, and upper strata is activated carbon, and lower floor is modified high-molecular chelating agent.
8. a kind of new membrane bioreactor sewage water processing means as claimed in claim 1, it is characterised in that described modified high Molecule chelating agen is modified animal feather, and its method of modifying is: collects animal feather and cleans up, incites somebody to action with after deionized water rinsing It immerses sig water, CS2In solution, soak 15h at 50-60 DEG C, then wash except surface residue with deionized water, changed Property animal feather.
CN201610701292.0A 2016-08-19 2016-08-19 A kind of new membrane bioreactor sewage water processing unit Expired - Fee Related CN106186545B (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
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CN101376538A (en) * 2007-08-29 2009-03-04 亚蕾 Powdered activated charcoal strengthened built-in beam type membrane bioreactor
CN104556364A (en) * 2014-12-24 2015-04-29 辽宁北方环境保护有限公司 Membrane bioreactor device for retarding membrane pollution and sewage treatment method
CN204509048U (en) * 2015-02-15 2015-07-29 新疆思凯压力容器制造有限公司 A kind of waste disposal plant adopting membrane bioreactor
CN104903257A (en) * 2012-12-07 2015-09-09 通用电气公司 Use of activated carbon in membrane bioreactor

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1586702A (en) * 2004-07-29 2005-03-02 复旦大学 Method for preparing nano filter membrane using surface crafting technology
CN101376538A (en) * 2007-08-29 2009-03-04 亚蕾 Powdered activated charcoal strengthened built-in beam type membrane bioreactor
CN104903257A (en) * 2012-12-07 2015-09-09 通用电气公司 Use of activated carbon in membrane bioreactor
CN104556364A (en) * 2014-12-24 2015-04-29 辽宁北方环境保护有限公司 Membrane bioreactor device for retarding membrane pollution and sewage treatment method
CN204509048U (en) * 2015-02-15 2015-07-29 新疆思凯压力容器制造有限公司 A kind of waste disposal plant adopting membrane bioreactor

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