CN106167294A - A kind of sewage auxiliary dephosphorization device - Google Patents

A kind of sewage auxiliary dephosphorization device Download PDF

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Publication number
CN106167294A
CN106167294A CN201610780286.9A CN201610780286A CN106167294A CN 106167294 A CN106167294 A CN 106167294A CN 201610780286 A CN201610780286 A CN 201610780286A CN 106167294 A CN106167294 A CN 106167294A
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CN
China
Prior art keywords
sludge
tank
dephosphorization
coagulative precipitation
sewage
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610780286.9A
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Chinese (zh)
Inventor
胡家富
杨勇
蒋红
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Nanjing Hehai Environmental Research Institute Co Ltd
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Nanjing Hehai Environmental Research Institute Co Ltd
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Priority to CN201610780286.9A priority Critical patent/CN106167294A/en
Publication of CN106167294A publication Critical patent/CN106167294A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5209Regulation methods for flocculation or precipitation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/105Phosphorus compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Activated Sludge Processes (AREA)

Abstract

The present invention relates to a kind of sewage auxiliary dephosphorization device with method, described dephosphorization apparatus includes sludge filter press, sludge concentration tank, sludge-tank, storage pool and coagulative precipitation tank, described sludge filter press connects storage pool by pipeline, described storage pool connects coagulative precipitation tank by pipeline, and described coagulative precipitation tank connects sludge-tank by sludge pipe.The method has a good removal effect to TP, COD in sewage, especially can stably reaching standard to the removal of total phosphorus, it is not necessary to carry out water outlet chemical dephosphorization.Meet stable effluent quality and reach " urban wastewater treatment firm pollutant emission standard " (GB18918 2002), and lay a good foundation for advanced treating.

Description

A kind of sewage auxiliary dephosphorization device
Technical field
The present invention relates to a kind of dephosphorization apparatus, be specifically related to a kind of sewage auxiliary dephosphorization device and phosphorus removing method, belong to dirty Water treatment field.
Background technology
Phosphorus is a kind of non-renewable resources, is again the essential element causing body eutrophication.The excess that farmland applies Phosphate fertilizer, city domestic sewage contains more phosphorus, and some trade effluent also contains abundant phosphorus, and they are all water eutrophications The major incentive changed.For prevention body eutrophication, " urban wastewater treatment firm pollutant emission standard " (GB18918-2002) Middle by one-level A water outlet phosphorus standard by phosphate meter carry mark rise to by total phosphorus (0.50 mg/L) count.Therefore, research and development sewage dephosphorization The situation of technique is the most urgent.
The most conventional dephosphorization process mainly has bioanalysis, chemical method.Bioanalysis be utilize polyP bacteria anoxia, anaerobism and Aerobic alternately in the case of complete the removal to phosphor in sewage.But operative practice shows, simple biological phosphate-eliminating processes and is difficult to Improve, be difficult to make water outlet qualified discharge.In recent years, chemical dephosphorization assists Biological Phosphorus Removal Processes because of its treatment effeciency together with chemistry Height, processing speed is fast and enjoys favor.After auxiliary dephosphorization technique is typically located at biological respinse dispensing point, most common it is arranged on In second pond, in second pond water inlet pipe, add Dephosphorization reagent, so can avoid the Dephosphorization reagent impact on activated sludge.But Himself there is also following defect: sludge settling as huge in added amount of chemical, that produce is back to again biochemistry bottom second pond Chi Zhong, will produce certain impact to activated sludge in biochemistry pool.
In Sewage Plant, rich phosphorus liquid is typically made up of sludge concentration tank supernatant and sludge press filtration liquid, and these two strands rich phosphorus liquid can not Directly discharge, it is necessary to reentering sewage disposal system, thus constantly form rich phosphorus liquid, in the most constantly entrance system, formation follows Ring.And the total phosphorus content that these two strands of sewage are formed often accounts in water about the 10% of total phosphorus content, add subsequent bio dephosphorization Load, too increase the difficulty of dephosphorization.Therefore, a kind of new scheme of exigence solves this technical problem.
Summary of the invention
In order to solve the problem of above-mentioned existence, the invention discloses a kind of sewage auxiliary dephosphorization device, this apparatus structure is tight Gathering, design ingenious, this technical scheme provides the sewage auxiliary dephosphorization technique of a kind of strengthening, this technique is simple, efficiently, run steady Fixed, investment operating cost is low, this invention ensures that effluent quality total phosphorus content qualified discharge.
To achieve these goals, technical scheme is as follows, and a kind of sewage auxiliary dephosphorization device, its feature exists In, described dephosphorization apparatus includes sludge filter press, sludge concentration tank, sludge-tank, storage pool and coagulative precipitation tank, described mud Pressure filter connects storage pool by pipeline, and described storage pool connects coagulative precipitation tank by pipeline, and described coagulative precipitation tank passes through Sludge pipe connects sludge-tank.
As a modification of the present invention, being provided with agitator in described coagulative precipitation tank, described agitator is set to two Layer propeller mixer.Quickly stirring promotes the abundant reaction of Dephosphorization reagent.
Sewage auxiliary dephosphorization method, described step is as follows, and 1) collection of richness phosphorus liquid is entered rich phosphorus liquid storage pool 4,2) then Entering coagulative precipitation tank 6, in coagulative precipitation tank 6, accurate automatic feeding chemical dephosphorization medicament carries out chemical dephosphorization, 3) after precipitating Supernatant reenter system, the lower mud entrance sludge concentration tank of precipitation carries out sludge condensation.
As a modification of the present invention, specific as follows in described step 1), described rich phosphorus liquid is by sludge concentration tank Above two strands of rich phosphorus liquid are accessed rich phosphorus liquid storage pool by clear liquid and sludge press filtration liquid two parts composition.
As a modification of the present invention, described step 2) in coagulative precipitation tank through coagulation section and precipitating phase two Process, wherein coagulation section uses mechanical agitation, and precipitating phase uses rectangular sedimentation tank, and mixing time is 1 ~ 2h, and the sedimentation time is 5 ~6h。
As a modification of the present invention, described step 2) in chemical dephosphorization medicament be poly-ferric chloride, valid density is i.e. With Fe3+Meter is at least more than 10%.Described accurate automatic feeding chemical dephosphorization medicament, coagulative precipitation tank water side is provided with total phosphorus On-Line Monitor Device, have input the matched curve of influent concentration and dosage in throwing device, can be according to water inlet total phosphorus concentration Real-time and Dynamic automatization accurately adds poly-ferric chloride, it is ensured that water outlet total phosphorus concentration is less than 10mg/L.
Relative to prior art, advantages of the present invention is as follows, 1) whole Technical Design is ingenious, compact conformation, and 2) this technology Scheme is improved and optimizes existing technology of phosphorus removal from wastewater, it is possible to the total phosphorus content of circulation in minimizing system, reduces in water total Phosphorus load and intractability;There is high treating effect, floor space is little, effect stability, operation cost are low remarkable advantage, have Promotional value;3) this technical scheme only carries out chemical dephosphorization to sludge concentration tank supernatant and sludge press filtration liquid, only processes the water yield For less than the 10% of total Water, greatly reduce adding of chemical dephosphorization medicament, reduce operation cost;4) by arranging automatically Accurately dosing system and total phosphorus on-line monitoring equipment, be provided with the plan into water total phosphorus concentration Yu added amount of chemical in dosing system Close curve, it is possible to the most accurately adding of agent, thus decrease the waste of medicament, reduce operation cost;5) use Valid density is (with Fe3+Meter) more than 10% poly-ferric chloride carry out chemical dephosphorization, have that hydrolysis rate is fast, hydration is weak, The alumen ustum formed is closely knit, sedimentation velocity fast, affected the features such as little, dosage is few, high treating effect by water temperature change, mixes than other 10 ~ 20% expenses are saved in solidifying agent.This technique has good removal effect, the especially removal to total phosphorus to TP, COD in sewage Can stably reaching standard, it is not necessary to carry out water outlet chemical dephosphorization.
Accompanying drawing explanation
Fig. 1 is sewage treatment technology process plane graph of the present invention;
Wherein: 1 is sludge filter press, 2 is sludge concentration tank, and 3 is sludge-tank, and 4 is rich phosphorus liquid storage pool, and 5 is sludge pipe, and 6 are Coagulative precipitation tank, 7 is sludge press filtration liquid, and 8 is sludge concentration tank supernatant, and 9 is supernatants after precipitation.
Detailed description of the invention
In order to deepen that the present invention is appreciated and understood by, below in conjunction with the accompanying drawings and detailed description of the invention, this it is further elucidated with Invention.
Embodiment 1: seeing Fig. 1, a kind of sewage auxiliary dephosphorization device, described dephosphorization apparatus includes sludge filter press 1, mud Concentration basin 2, sludge-tank 3, storage pool 4 and coagulative precipitation tank 6, described sludge filter press connects storage pool 4 by pipeline, described Storage pool 4 connects coagulative precipitation tank 6 by pipeline, and described coagulative precipitation tank 6 connects sludge-tank 3, described coagulation by sludge pipe Being provided with agitator in sedimentation tank, described agitator is set to two-layer propeller mixer.Quickly stirring promotes Dephosphorization reagent Fully reaction.
Embodiment 2: seeing Fig. 1, sewage auxiliary dephosphorization method, described step is as follows, 1) collection of richness phosphorus liquid is entered rich phosphorus Liquid storage pool 4,2) subsequently into coagulative precipitation tank 6, accurate automatic feeding chemical dephosphorization medicament in coagulative precipitation tank 6 Learn dephosphorization, 3) supernatant after precipitation reenters system, and the lower mud entrance sludge concentration tank of precipitation carries out sludge condensation.
In described step 1) specific as follows, described rich phosphorus liquid is by sludge concentration tank supernatant and sludge press filtration liquid two parts Above two strands of rich phosphorus liquid are accessed rich phosphorus liquid storage pool by composition;
Described step 2) in coagulative precipitation tank through coagulation section and two processes of precipitating phase, wherein coagulation section use machinery stir Mixing, precipitating phase uses rectangular sedimentation tank, and mixing time is 1 ~ 2h, and the sedimentation time is 5 ~ 6h;
Described step 2) in chemical dephosphorization medicament be poly-ferric chloride, valid density is i.e. with Fe3+Meter is at least more than 10%.Institute Stating accurate automatic feeding chemical dephosphorization medicament, coagulative precipitation tank water side is provided with total phosphorus on-Line Monitor Device, at throwing device In have input the matched curve of influent concentration and dosage, can accurately adding according to water inlet total phosphorus concentration Real-time and Dynamic automatization Poly-ferric chloride, it is ensured that water outlet total phosphorus concentration is less than 10mg/L, reduces water inlet end total phosphorus load, total phosphorus circulation in minimizing system Amount.
The method is applicable not only to urban wastewater treatment firm and high phosphorus trade effluent, to meet urban wastewater treatment firm pollution Thing discharge standard " one-level A standard or corresponding industrial wastewater discharge standard in (GB18918-2002).
Application Example: the present invention proposes the sewage auxiliary dephosphorization technique of a kind of strengthening, is first collected into by richness phosphorus liquid Entering rich phosphorus liquid storage pool, subsequently into coagulative precipitation tank, in coagulative precipitation tank, accurate automatic feeding chemical dephosphorization medicament is carried out Chemical dephosphorization, the supernatant after precipitation reenters system, and the mud under precipitation enters sludge concentration tank and carries out sludge condensation.With Under further illustrate the present invention by specific embodiment.
The present invention has been used for the upgrading technical research of certain winery sewage treatment process, pending waste water mainly by The brewing wastewater of brew house, flushing place waste water and sanitary sewage, waste water is black, opaque shape, greasy sweet, the colourity of abnormal smells from the patient High, turbidity big, pH is acidity, its water quality totally in high COD, high NH4 +, high TP but good biodegradability feature.The rich phosphorus produced The concrete water quality of liquid is as shown in table 1.
Table 1 brewing wastewater water quality index
Wherein, rich phosphorus liquid enters rich phosphorus liquid storage pool through gravity flow, is then pumped into coagulative precipitation tank, and coagulation district a size of 4500 × 2000 × 2500mm(L × B × H), available depth 2.2m, totally three, hydraulic detention time 1.5h, rotating speed is 100r/min, fills Divide and promote medicament mixing, accelerate response speed and ensure reaction effect;Settling zone a size of 13000 × 4500 × 3800mm(L × B × H), available depth 3.5m, totally three, hydraulic detention time 5.6h, form is rectangular sedimentation tank;Every coagulative precipitation tank sets 3 sludge buckets, sludge bucket upper dimension is 4500 × 4000(L × B), lower dimension is 600 × 600(L × B), sludge bucket is high 1800mm;Agitator is chosen as two-layer propeller mixer, and Dephosphorization reagent is chosen as poly-ferric chloride, and valid density is (with Fe3+ Meter) 20%, dosage is 100mg/L.
Supernatant after precipitation is back to front end, reenters system, and the mud under precipitation enters in sludge concentration tank.Two Level water outlet can also carry out low side reuse by further coagulating sedimentation, sand filtration, nanofiltration, it might even be possible to is carried out by reverse osmosis again High-end reuse.
After using this kind of technique, before and after Sewage Plant, water quality contrasts as shown in table 2.
Effluent quality index before and after the use of certain brewing wastewater group technology of table 2
The present invention at the treatment effect of this wastewater factory is: the rich total tp removal rate of phosphorus liquid about 90%, water outlet total phosphorus Clearance is about about 35%.In sum, the auxiliary dephosphorization technique using strengthening of novelty of the present invention, decrease into water total Phosphorus load, alleviates biological phosphate-eliminating difficulty, makes total phosphorus aqueous concentration be greatly lowered.
It should be noted that above-described embodiment is only presently preferred embodiments of the present invention, it is not used for limiting the present invention Protection domain, the equivalent made on the basis of technique scheme or replacement, belong to the protection model of the present invention Enclose.

Claims (6)

1. a sewage auxiliary dephosphorization device, it is characterised in that described dephosphorization apparatus include sludge filter press, sludge concentration tank, Sludge-tank, storage pool and coagulative precipitation tank, described sludge filter press connects storage pool by pipeline, and described storage pool is by pipe Road connects coagulative precipitation tank, and described coagulative precipitation tank connects sludge-tank by sludge pipe.
Sewage auxiliary dephosphorization device the most according to claim 1, it is characterised in that be provided with in described coagulative precipitation tank and stir Mixing device, described agitator is set to two-layer propeller mixer.
3. sewage auxiliary dephosphorization method, it is characterised in that described step is as follows: 1) richness phosphorus liquid is collected entrance rich phosphorus liquid storage Pond, 2) subsequently into coagulative precipitation tank, in coagulative precipitation tank, accurate automatic feeding chemical dephosphorization medicament carries out chemical dephosphorization, and 3) Supernatant after precipitation reenters system, and the mud under precipitation enters sludge concentration tank and carries out sludge condensation.
Sewage auxiliary dephosphorization method the most according to claim 3, it is characterised in that specific as follows in described step 1), institute The rich phosphorus liquid stated is made up of sludge concentration tank supernatant and sludge press filtration liquid two parts, and above two strands of rich phosphorus liquid are accessed rich phosphorus liquid Storage pool.
Sewage auxiliary dephosphorization method the most according to claim 3, it is characterised in that described step 2) at coagulative precipitation tank Interior through coagulation section with two processes of precipitating phase, wherein coagulation section uses mechanical agitation, and precipitating phase uses rectangular sedimentation tank, stirs The time of mixing is 1 ~ 2h, and the sedimentation time is 5 ~ 6h.
Sewage auxiliary dephosphorization method the most according to claim 3, it is characterised in that described step 2) in chemical dephosphorization medicament For poly-ferric chloride, valid density is i.e. with Fe3+Meter is at least more than 10%.
CN201610780286.9A 2016-08-31 2016-08-31 A kind of sewage auxiliary dephosphorization device Pending CN106167294A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112079424A (en) * 2020-09-08 2020-12-15 天津壹新环保工程有限公司 Cyclic utilization system and process of phosphorus removal agent
CN113735299A (en) * 2020-05-14 2021-12-03 领跃电子科技(珠海)有限公司 Wastewater dephosphorization device and dephosphorization method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102358674A (en) * 2011-09-23 2012-02-22 南京中世环境科技股份有限公司 Sewage treatment method capable of sludge quantitative reduction
CN202988773U (en) * 2012-12-29 2013-06-12 重庆市渝西水务有限公司 Phosphorous-removal reflux tank structure for excess sludge refluxing and utilizing system
CN203256016U (en) * 2013-04-16 2013-10-30 上海市城市建设设计研究总院 Rapid phosphorous removal pool for liquid supernatant
CN105541008A (en) * 2015-12-22 2016-05-04 浙江大学 An efficient denitrifying and carbon-removing device for culture wastewater anaerobic biogas slurry with a low C/N ratio and a process thereof
CN105693042A (en) * 2015-05-20 2016-06-22 余素萍 Method for treating phosphorus-containing sewage
CN205999098U (en) * 2016-08-31 2017-03-08 南京河海环境研究院有限公司 A kind of sewage auxiliary dephosphorization device

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102358674A (en) * 2011-09-23 2012-02-22 南京中世环境科技股份有限公司 Sewage treatment method capable of sludge quantitative reduction
CN202988773U (en) * 2012-12-29 2013-06-12 重庆市渝西水务有限公司 Phosphorous-removal reflux tank structure for excess sludge refluxing and utilizing system
CN203256016U (en) * 2013-04-16 2013-10-30 上海市城市建设设计研究总院 Rapid phosphorous removal pool for liquid supernatant
CN105693042A (en) * 2015-05-20 2016-06-22 余素萍 Method for treating phosphorus-containing sewage
CN105541008A (en) * 2015-12-22 2016-05-04 浙江大学 An efficient denitrifying and carbon-removing device for culture wastewater anaerobic biogas slurry with a low C/N ratio and a process thereof
CN205999098U (en) * 2016-08-31 2017-03-08 南京河海环境研究院有限公司 A kind of sewage auxiliary dephosphorization device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113735299A (en) * 2020-05-14 2021-12-03 领跃电子科技(珠海)有限公司 Wastewater dephosphorization device and dephosphorization method thereof
CN112079424A (en) * 2020-09-08 2020-12-15 天津壹新环保工程有限公司 Cyclic utilization system and process of phosphorus removal agent

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