CN106178375A - High-molecular gel extinguishing chemical - Google Patents

High-molecular gel extinguishing chemical Download PDF

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Publication number
CN106178375A
CN106178375A CN201610208917.XA CN201610208917A CN106178375A CN 106178375 A CN106178375 A CN 106178375A CN 201610208917 A CN201610208917 A CN 201610208917A CN 106178375 A CN106178375 A CN 106178375A
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CN
China
Prior art keywords
powder body
extinguishing chemical
water
cellulose
macromolecular material
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610208917.XA
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Chinese (zh)
Inventor
晋宝生
罗加勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING DONGLIN FIRE SCIENCE AND TECHNOLOGY Co Ltd
Original Assignee
BEIJING DONGLIN FIRE SCIENCE AND TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BEIJING DONGLIN FIRE SCIENCE AND TECHNOLOGY Co Ltd filed Critical BEIJING DONGLIN FIRE SCIENCE AND TECHNOLOGY Co Ltd
Priority to CN201610208917.XA priority Critical patent/CN106178375A/en
Publication of CN106178375A publication Critical patent/CN106178375A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62DCHEMICAL MEANS FOR EXTINGUISHING FIRES OR FOR COMBATING OR PROTECTING AGAINST HARMFUL CHEMICAL AGENTS; CHEMICAL MATERIALS FOR USE IN BREATHING APPARATUS
    • A62D1/00Fire-extinguishing compositions; Use of chemical substances in extinguishing fires
    • A62D1/0064Gels; Film-forming compositions

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The invention discloses high-molecular gel extinguishing chemical, it relates to a kind of extinguishing chemical.It is made up of the component of following weight proportion: macromolecular material powder body 1 part, water 600 1200, and described macromolecular material powder body includes Konjac glucomannan powder body 30%, bentonite 20%, corn starch 25%, cellulose 25%.Described gel extinguishant technological process is: takes pure water and contains average rate in dispersion machine a mixing bowl and add slurry product to be filled in powder product stirring terminates slurry is drawn into fill tower.Energy-saving and environmental protection of the present invention, low cost, effective, safety is high.

Description

High-molecular gel extinguishing chemical
Technical field
The present invention relates to a kind of extinguishing chemical, be specifically related to a kind of high-molecular gel extinguishing chemical.
Background technology
Extinguishing chemical kind is a lot, and general employing light water fire extinguishing, light water sprays burning things which may cause a fire disaster, can flow away at once, can continue Attack time was less than one minute, and inefficient, blow-off velocity is also slow, has revivable phenomenon to occur time after fire extinguishing also;Also have one The extinguishing effect of a little powder extinguishing agents etc is the most bad, it is therefore desirable to invention one can carry out high-effect fire-extinguishing, it is to avoid revivable Extinguishing chemical.
Summary of the invention
For not enough present on prior art, the present invention seeks to be to provide a kind of high-molecular gel extinguishing chemical, joint Energy, environmental protection, low cost, effective, it is possible to ensure the safety of fire extinguishing personnel.
To achieve these goals, the present invention is to realize by the following technical solutions: high-molecular gel extinguishing chemical, its It is made up of the component of following weight proportion: macromolecular material powder body 1 part, water 600-1200, described macromolecular material powder body bag Include Konjac glucomannan powder body 30%, bentonite 20%, corn starch 25%, cellulose 25%.
Described macromolecular material raw powder's production technology is: 1, by Konjac glucomannan powder body and bentonite freezing a few hours Being ground to 120 mesh-1400 mesh (completing in full closeding equipment during grinding, leak) without micropowder uses negative pressure-pumping machine to seal In hull closure, raw material is stand-by in extracting out and being transferred to storage window.2, cellulose is put into low speed ball mill grinding a few hours [mesh Be cellulose is milled to super-refinement, it two produces heat temperature (higher than environment 10 DEG C-15 when ball of milling mutually collides DEG C)] corn starch in freezing is rapidly added hot warming middle-JIAO cellulose (formation altitude temperature difference effect) stand a few hours After mill again (making mutual temperature equalization) transfer to Konjac glucomannan and bentonite window with negative pressure-pumping machine in machinery stir Mix powder product to be filled.
Without chemical reaction in technical process, without high temperature, simply grind, utilize the physics mistakes such as altitude temperature difference effect absorption migration Journey.The preparation method of described gel extinguishant is: in pre-designed ratio by powder on the Process ba-sis of macromolecular material powder body Agent product and water proportioning.Its technological process is: the pure water taking this Workshop Production is contained in dispersion machine a mixing bowl Average rate adds powder product (general water and powder product ratio are 1:600~1200) and stirs and terminate that (sampling Detection meets Technical standard is appropriate) slurry is drawn into fill tower in slurry product to be filled.Technique terminates, whole mistake Without chemical reaction in journey, free from extraneous odour, without dust, any to bad environmental situation without other.Organic solution in the slurry of the present invention Ratio could form organic solvent on the surface of object with the ratio of colloid solution through scientific formula and cover, and mobility is good Good.This agent is to canister non-corrosiveness, and to human non-toxic, free from environmental pollution, extinguishing effect is very good.
Beneficial effects of the present invention: energy-saving and environmental protection, low cost, effective, safety is high.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with Detailed description of the invention, is expanded on further the present invention.
This detailed description of the invention is by the following technical solutions: high-molecular gel extinguishing chemical, and it is made up of following components: high score Sub-gel extinguishant, it is made up of the component of following weight proportion: macromolecular material powder body 1 part, water 600-1200, described height Molecular material powder body includes Konjac glucomannan powder body 30%, bentonite 20%, corn starch 25%, cellulose 25%.
Described macromolecular material raw powder's production technology is: 1, by Konjac glucomannan powder body and bentonite freezing a few hours Being ground to 120 mesh-1400 mesh (completing in full closeding equipment during grinding, leak) without micropowder uses negative pressure-pumping machine to seal In hull closure, raw material is stand-by in extracting out and being transferred to storage window.2, cellulose is put into low speed ball mill grinding a few hours [mesh Be cellulose is milled to super-refinement, it two produces heat temperature (higher than environment 10 DEG C-15 when ball of milling mutually collides DEG C)] corn starch in freezing is rapidly added hot warming middle-JIAO cellulose (formation altitude temperature difference effect) stand a few hours After mill again (making mutual temperature equalization) transfer to Konjac glucomannan and bentonite window with negative pressure-pumping machine in machinery stir Mix powder product to be filled.
Without chemical reaction in technical process, without high temperature, simply grind, utilize the physics mistakes such as altitude temperature difference effect absorption migration Journey.The preparation method of described gel extinguishant is: in pre-designed ratio by powder on the Process ba-sis of macromolecular material powder body Agent product and water proportioning.Its technological process is: the pure water taking this Workshop Production is contained in dispersion machine a mixing bowl Average rate adds powder product (general water and powder product ratio are 1:600~1200) and stirs and terminate that (sampling Detection meets Technical standard is appropriate) slurry is drawn into fill tower in slurry product to be filled.Technique terminates, whole During without chemical reaction, free from extraneous odour, without dust, any to bad environmental situation without other.Evil spirit in this detailed description of the invention Taro glue (powder body): white powder, granularity is at 80 mesh-140 mesh, and nontoxic, tasteless, colourless, pH value is that 6.8-7.2(is neutral), water Dissolubility is good, rate of water absorption is high, and viscosity is good, transparent shape after water suction, its powder body model such as KP30, KJ22, KS28 etc., this raw material profit Obtain with konjaku powder deep processing.Its content of beary metal of this raw material is minimum, exports the most in a large number, pharmaceutically obtain extensively should With (auxiliary diabetics controls blood glucose, blood fat reducing;Treatment constipation, fat-reducing etc.), apply the widest in luxury food.This is former Material acts primarily as the effect such as water conservation, delay in this formula, under External Force Acting extrudes, will not be dehydrated, in whole technical process Do not produce any chemical reaction, accounting 30% in this formula for a product.
Bentonite: buy finished product raw material from market, this raw material system mineral (is commonly called as differentiation soil, GUANYINTU), edible, micro-Huang Color, mildly bitter flavor, pH value is that 7(is neutral), this raw material plays water-absorbing-retaining effect in this formula, and balance between each raw material is closely sealed Property, accounting 20% in this formula for a product.Corn starch: food stage, slightly yellow powder body, granularity 100 mesh-150 mesh, at this formula In play thickness effect, water suction while occluded water, at high temperature can with other raw materials play high temperature resistance and strengthen water tension force, Strengthening the polymerization between each formula, pH value is 6.9-7.3, accounting 25% in formula.Cellulose: by glucose form big Molecular polysaccharide, water insoluble, it is the Main Ingredients and Appearance of plant cell wall, the widest in distributed in nature, also it is the most one of polysaccharide, Account for plant kingdom's carbon content more than 50%, if Cotton Gossypii short flannel, cotton stalk, Fructus Citri tangerinae bar are as the primary raw material in this cellulose, formula material from Finished fiber element is bought in market, occupies dietary cellulose and is used as thickening agent in food, and pH value is that 7(is neutral), account in this formula Ratio 25%.Water: producing the water used by slurry is the pure water that the pure water generator that this workshop is provided for oneself produces, and former water is taken at municipal administration Supply water, through quartz and activated carbon secondary filter, then the pure water obtained through reverse osmosis (RO) membrane filtration, PH is 7, the ratio of water in slurry Example be 1:600 1200(powder be 1, water purification is 600 1200).The high molecular fire-extinguishing agent of this detailed description of the invention is by seldom The water gel that the macromolecular material of amount is formed with substantial amounts of water.Owing to the water absorption of height water suction colloid is big, water holding capacity is strong, causes Close property is fine, even if water-retaining property, film property, attached wall are all fine under conditions of being heated, it is sprayed in fire, can be because of dehydration Consume substantial amounts of heat, make fire scene temperature drastically decline.Gelinite can completely cut off air in body surface NATURAL DISTRIBUTION simultaneously, even if High temperature also will not dehydration or dehydration renewable, prevent flare from spreading, reach put out a fire purpose.Particularly forest, building construction, plastics The fire such as factories, by gelinite aircraft and other sprinkler, are sprinkled upon in the most unburned combustible object, such as forest, tree Wood, on leaves, grass source can use the surfaces such as airplane spray, building roof, room wall window, can spray with ejector, at this Formed on a little objects containing moisture film, effectively stop flare to spread.Macromolecule colloid is strong because of water holding capacity, extinguishing ability Greatly, bigger fire prevention and extinguishing ability are played than conventional water.
It is known that owing to evaporation of water ratio of specific heat thermal capacitance is the biggest, be the most cheap fire extinguishing material, when adding height in water During the colloid of molecular material, owing to polymer particles is splashed swollen, make containing substantial amounts of hydrogel particle in water, when it is sprayed on building During thing surface, air, flare can be completely cut off, more much larger than the extinguishing ability being not added with high absorbency material water.
After this extinguishing chemical sprays, fire scene temperature declines rapidly, and does not has cigarette to only have a small amount of gas, is safe from harm people, its PH value is neutral, easily degrades, and cost is the lowest, gelinite only eight points to a jiao a kilogram.
The extinguishing chemical of this detailed description of the invention is in process of production:
1, any cigarette, dirt are not produced;
2, the most outwards drain any liquid and include sewage;
3, any abnormal smells from the patient and any radioactive substance are not produced;
4, not producing noise, high efficiency goes to the workshop interior mechanic sound only 45-50 decibel (discontinuity);
5, raw material and include the finished product in production process, semi-finished product the most do not exist waste product and waste material (even if the most defective Leading portion can be returned reactivate).
Whenever this detailed description of the invention raw material, semi-finished product, finished product are all without Biodeterioration;Such as variable color, foul, store Time is long, manageability (main anti glare anti static coatings, protection against the tide).
Transport can be powder body, liquid, condensation product, transportation the most easily, not burn into tasteless nontoxic, pollution-free, i.e. Just imprudence is splashed on object or ground, can finally disappear by natural degradation carbonific.
The ultimate principle of the present invention and principal character and advantages of the present invention have more than been shown and described.The technology of the industry Personnel, it should be appreciated that the present invention is not restricted to the described embodiments, simply illustrating this described in above-described embodiment and description The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, and these become Change and improvement both falls within scope of the claimed invention.Claimed scope by appending claims and Equivalent defines.

Claims (3)

1. high-molecular gel extinguishing chemical, it is characterised in that high-molecular gel extinguishing chemical, it is by the component group of following weight proportion Become: macromolecular material powder body 1 part, water 600-1200, described macromolecular material powder body includes Konjac glucomannan powder body 30%, bentonite 20%, corn starch 25%, cellulose 25%.
High-molecular gel extinguishing chemical the most according to claim 1, it is characterised in that the system of described macromolecular material powder body Preparation Method is: (1), to 120 mesh-1400 mesh, Konjac glucomannan powder body and bentonite freeze grinding are used negative pressure-pumping machines Raw material in provision for sealing is extracted out in being transferred to storage window stand-by;(2), cellulose is put into low speed ball mill grinding Mill again after the cellulose standing a few hours that corn starch in freezing is rapidly added hot warming middle-JIAO and use negative pressure-pumping Machine transfer to mechanical agitation in Konjac glucomannan and bentonite window to be filled powder product.
High-molecular gel extinguishing chemical the most according to claim 1, it is characterised in that described gel extinguishant technological process For: take average rate addition powder product stirring in pure water contains dispersion machine a mixing bowl and terminate slurry Slurry product to be filled in being drawn into fill tower.
CN201610208917.XA 2016-04-06 2016-04-06 High-molecular gel extinguishing chemical Pending CN106178375A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201610208917.XA CN106178375A (en) 2016-04-06 2016-04-06 High-molecular gel extinguishing chemical

Publications (1)

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CN106178375A true CN106178375A (en) 2016-12-07

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106377861A (en) * 2016-08-19 2017-02-08 北京东霖消防科技有限公司 High-molecular hydro-gel fire extinguishing agent
CN106390349A (en) * 2016-08-19 2017-02-15 北京东霖消防科技有限公司 Macromolecule fire extinguishment additive powder
CN107789785A (en) * 2017-12-06 2018-03-13 成都新纶峰科技有限公司 A kind of novel environment friendly high-molecular gel water-based extinguishing agent
CN108042964A (en) * 2017-12-08 2018-05-18 厦门泰消防科技开发有限公司 A kind of starch type fire retardant extinguisher
CN110898371A (en) * 2019-12-09 2020-03-24 应急管理部天津消防研究所 Green and environment-friendly hydrogel fire extinguishing agent for forest fire extinguishing and preparation method thereof
CN113279805A (en) * 2021-03-22 2021-08-20 重庆大学 Temperature-sensitive hydrogel for biomass efficient environment-friendly coal mine

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1557516A (en) * 2004-01-14 2004-12-29 浙江大学 High water absorption resin water suction gel fire extinguisher and its application
CN1718260A (en) * 2005-07-29 2006-01-11 许庆华 Concave-convex bar gel extinguishant
CN103263747A (en) * 2013-06-06 2013-08-28 东靖飞 Starch-base fire extinguishing agent
US9289636B2 (en) * 2010-11-17 2016-03-22 James A. Mathis Fire extinguishing agent and method of use

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1557516A (en) * 2004-01-14 2004-12-29 浙江大学 High water absorption resin water suction gel fire extinguisher and its application
CN1718260A (en) * 2005-07-29 2006-01-11 许庆华 Concave-convex bar gel extinguishant
US9289636B2 (en) * 2010-11-17 2016-03-22 James A. Mathis Fire extinguishing agent and method of use
CN103263747A (en) * 2013-06-06 2013-08-28 东靖飞 Starch-base fire extinguishing agent

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106377861A (en) * 2016-08-19 2017-02-08 北京东霖消防科技有限公司 High-molecular hydro-gel fire extinguishing agent
CN106390349A (en) * 2016-08-19 2017-02-15 北京东霖消防科技有限公司 Macromolecule fire extinguishment additive powder
CN107789785A (en) * 2017-12-06 2018-03-13 成都新纶峰科技有限公司 A kind of novel environment friendly high-molecular gel water-based extinguishing agent
CN113144495A (en) * 2017-12-06 2021-07-23 成都新纶峰科技有限公司 Novel environment-friendly polymer gel water-based extinguishing agent
CN108042964A (en) * 2017-12-08 2018-05-18 厦门泰消防科技开发有限公司 A kind of starch type fire retardant extinguisher
CN110898371A (en) * 2019-12-09 2020-03-24 应急管理部天津消防研究所 Green and environment-friendly hydrogel fire extinguishing agent for forest fire extinguishing and preparation method thereof
CN113279805A (en) * 2021-03-22 2021-08-20 重庆大学 Temperature-sensitive hydrogel for biomass efficient environment-friendly coal mine

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Application publication date: 20161207