CN106172414A - A kind of bactericidal composition containing benzo alkene fluorine bacterium azoles - Google Patents
A kind of bactericidal composition containing benzo alkene fluorine bacterium azoles Download PDFInfo
- Publication number
- CN106172414A CN106172414A CN201610577700.6A CN201610577700A CN106172414A CN 106172414 A CN106172414 A CN 106172414A CN 201610577700 A CN201610577700 A CN 201610577700A CN 106172414 A CN106172414 A CN 106172414A
- Authority
- CN
- China
- Prior art keywords
- fluorine bacterium
- bacterium azoles
- alkene fluorine
- benzo alkene
- pyrrole metsulfovax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 33
- 241000894006 Bacteria Species 0.000 title claims abstract description 31
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 29
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 29
- 239000011737 fluorine Substances 0.000 title claims abstract description 29
- 125000005605 benzo group Chemical group 0.000 title claims abstract description 28
- 150000003851 azoles Chemical class 0.000 title claims abstract description 27
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 13
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 claims abstract description 52
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 241000221785 Erysiphales Species 0.000 claims abstract description 14
- 239000000575 pesticide Substances 0.000 claims description 8
- 239000002552 dosage form Substances 0.000 claims description 2
- 239000003090 pesticide formulation Substances 0.000 claims description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract description 2
- 239000004615 ingredient Substances 0.000 abstract description 2
- 244000299906 Cucumis sativus var. sativus Species 0.000 abstract 1
- 201000010099 disease Diseases 0.000 description 7
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- -1 pyrazole amide Chemical class 0.000 description 7
- 240000008067 Cucumis sativus Species 0.000 description 6
- 239000003814 drug Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000007788 liquid Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000000375 suspending agent Substances 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- 239000004562 water dispersible granule Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 230000003449 preventive effect Effects 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 230000001988 toxicity Effects 0.000 description 3
- 231100000419 toxicity Toxicity 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 239000004563 wettable powder Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 244000052616 bacterial pathogen Species 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000012136 culture method Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 2
- 238000011081 inoculation Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 244000052769 pathogen Species 0.000 description 2
- 230000001717 pathogenic effect Effects 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- LYCAIKOWRPUZTN-NMQOAUCRSA-N 1,2-dideuteriooxyethane Chemical compound [2H]OCCO[2H] LYCAIKOWRPUZTN-NMQOAUCRSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 102000019259 Succinate Dehydrogenase Human genes 0.000 description 1
- 108010012901 Succinate Dehydrogenase Proteins 0.000 description 1
- 241000256618 Trichogramma Species 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- 229910000004 White lead Inorganic materials 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- WHDHEVMINMZADQ-UHFFFAOYSA-N [F].N1C=CC=C1 Chemical compound [F].N1C=CC=C1 WHDHEVMINMZADQ-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- WMGSQTMJHBYJMQ-UHFFFAOYSA-N aluminum;magnesium;silicate Chemical compound [Mg+2].[Al+3].[O-][Si]([O-])([O-])[O-] WMGSQTMJHBYJMQ-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000027721 electron transport chain Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 244000053095 fungal pathogen Species 0.000 description 1
- 239000000417 fungicide Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 239000002068 microbial inoculum Substances 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 230000002438 mitochondrial effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229940051841 polyoxyethylene ether Drugs 0.000 description 1
- 229920000056 polyoxyethylene ether Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of bactericidal composition containing benzo alkene fluorine bacterium azoles, its effective ingredient is benzo alkene fluorine bacterium azoles and pyrrole metsulfovax, both weight ratios are 1:50 50:1, after described compositions is compounding, powdery mildew of cucumber is had preferable potentiation in described ratio range, in addition, described compositions, to crop safety, is worth popularization and application on producing.
Description
Technical field
The present invention relates to a kind of bactericidal composition, time a kind of the killing containing benzo alkene fluorine bacterium azoles and pyrrole metsulfovax being specifically related to
Bacteria composition.
Background technology
Powdery mildew is the worldwide disease of a kind of extensive generation, main employing chemical pesticide control powdery mildew, mesh in production
Before rely primarily on benzimidazole, triazole type, methoxy acrylic bactericide.But, killing of life-time service single kind
Microbial inoculum can make disease produce resistance in various degree, and prevention effect reduces.
Benzo alkene fluorine bacterium azoles is a kind of pyrazole amide series bactericidal agent, by electron transport chain on suppression mitochondrial inner membrane
Succinate dehydrogenase so that pathogenic fungi cannot produce energy via breathing, and then disintegrates the growth of pathogenic bacteria, and this compound is independent
Use cost is higher and easily sends out again the generation of resistance, thus reduces the service life of pesticide species.
Pyrrole metsulfovax is the novel acid amide fungicides of Mitsui chemical company research and development, not only has rust, sclerotiniose
Excellent activity, also shows that the Mars that preferably sterilizes, is now recommended for preventing and treating gray mold, powdery mildew and scab of apple
Other antibacterial are had gray mold and the powdery mildew of resistance, but pyrrole metsulfovax is used alone for a long time, can produce the biggest equally
Resistance risk, is unfavorable for effective control of disease.
The recipe determination of benzo alkene fluorine bacterium azoles and pyrrole metsulfovax is conducted in-depth research by present inventor, finds benzene
And alkene fluorine bacterium azoles and pyrrole metsulfovax carry out mixture, in certain scope, multiple fungus are had obvious synergistic function, warp
Research completes the present invention further.
There is no the relevant report of the complex composition of benzo alkene fluorine bacterium azoles and pyrrole metsulfovax at present.
Summary of the invention
It is an object of the invention to, it is provided that a kind of Synergistic bactericidal composition being suitable for agriculturally using, contribute to reducing and use
Dose, the generation delaying pathogen resistance and reduction use cost.
For solving above-mentioned technical problem, the present invention adopts the following technical scheme that a kind of Synergistic bactericidal composition, and its feature exists
In, active component contains benzo alkene fluorine bacterium azoles and pyrrole metsulfovax, and wherein, the weight ratio of benzo alkene fluorine bacterium azoles and pyrrole metsulfovax is 1:
50-50:1, preferably 1:10-10:1.
Further, in described bactericidal composition, the weight ratio of active component is 1-90%, preferably 10-70%.
Further, described bactericidal composition can be processed into agricultural by preparation method conventional in Pesticide formulation
Any dosage form of upper permission, such as, can be wettable powder, water dispersible granules, aqueous emulsion, microemulsion, water dispersible granules.
The compositions of the present invention can be the most blended with each material in the finished product preparation i.e. compositions of form offer, it is also possible to
Unit dose form provides, and is directly mixed in proportion in bucket or tank, is then diluted to required concentration before using.
Further, the compositions of the present invention can also add other agricultural active composition, such as antibacterial, insecticide,
The agricultural active composition such as herbicide, fertilizer.
The bactericidal composition of the present invention is applicable to prevent and kill off the multiple diseases such as powdery mildew of cucumber, Fructus Lycopersici esculenti powdery mildew, powdery mildew of strawberry
Evil.
Compared with prior art, the having the beneficial effect that of the composition pesticide of the present invention
(1), after the compositions of the present invention is compounding, there is in certain scope obvious synergistic function, preventive effect and single work
Property composition is compared and is significantly improved；
(2) in the compositions of the present invention, the active component mechanism of action is different, while effectively preventing and treating crop pest, permissible
Delay the drug-fast generation of pathogen, be conducive to delaying the service life of pesticide activity component；
(3) the compositions preparation technology of the present invention is simple, is suitable for popularization and application in actual production.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, present invention specific examples below
Illustrate, but the present invention is limited to absolutely not these examples.The following stated is only the preferable embodiment of the present invention, is used only for explaining
The present invention, but can not be therefore understands that be the restriction to the scope of the claims of the present invention.It should be pointed out that, all spirit in the present invention and
Any amendment, equivalent or the improvement etc. made within principle, should be included within the scope of the present invention, therefore,
The protection domain of patent of the present invention should be as the criterion with claims.
One, example of formulations
1, embodiment 1:21% benzo alkene fluorine bacterium azoles pyrrole metsulfovax wettable powder (20:1)
Benzo alkene fluorine bacterium azoles 20%
Pyrrole metsulfovax 1%
Naphthalene sulfonic acid-formaldehyde condensation product 5%
Sodium lignin sulfonate 3%
White carbon 3%
Kieselguhr surplus
2, embodiment 2:12% benzo alkene fluorine bacterium azoles pyrrole metsulfovax aqueous emulsion (5:1)
Benzo alkene fluorine bacterium azoles 10%
Pyrrole metsulfovax 2%
N-Methyl pyrrolidone 15%
Polyoxyethylene sorbitol acid anhydride ester 3%
Alkyl polyglycol ether 5%
Polyoxyethylene fatty alcohol 3%
Deionized water surplus
3, embodiment 3:33% benzo alkene fluorine bacterium azoles pyrrole metsulfovax water dispersible granules (1:10)
Benzo alkene fluorine bacterium azoles 3%
Pyrrole metsulfovax 30%
Alkylphenol polyoxyethylene sulfate 4%
Calcium lignosulfonate 5%
Carbamide 3%
Arabic gum 2%
Kieselguhr surplus
4, embodiment 4:30% benzo alkene fluorine bacterium azoles pyrrole metsulfovax suspending agent (1:1)
Benzo alkene fluorine bacterium azoles 15%
Pyrrole metsulfovax 15%
Sodium lignin sulfonate 5%
Fatty alcohol-polyoxyethylene ether 6%
Aluminium-magnesium silicate 1%
Organic silicone 0.5%
Ethylene glycol 2%
Deionized water surplus
Two, Toxicity Determination
Subjects: Fructus Cucumidis sativi percentage pathogenic bacteria
Test method: test is with reference to People's Republic of China's industry standard NY/T 1156.11-2008 " farm-chemical indoor determination
Test rule antibacterial the 11st part: preventing and treating cucurbits powdery mildew test pot-culture method ", use pot-culture method to measure.
Sowing susceptible cucumber variety, potted plant to grow to 2 leaf periods standby.Benzo alkene fluorine bacterium azoles and the former medicine of pyrrole metsulfovax
Dissolve with dimethylformamide respectively, then dissolve with 0.1% tween 80 aqueous surfactant solution.Often process 3 basins, repeat for 4 times,
10 mL medicinal liquids are uniformly sprayed on blade face to whole moistenings, treat that medicinal liquid dries naturally standby.And set containing only solvent and surface activity
Agent and make blank without the process of effective ingredient.24 h after chemicals treatment, spray inoculation cucumber powdery mildew's pathogen spore suspension
Liquid.The process for preparation of spore suspension is as follows: takes and covers with Powdery Mildew blade, with refueling a small amount of tween 80 surfactant
Spore is washed down by sterilized water, and double gauze filters, and is modulated into 1X10 after microscopy5The suspension of individual/mL.Inoculation is placed on thermostatic chamber
In, cultivate 7 days under the conditions of temperature 24 DEG C.When blank disease liquid rate reaches more than 80%, the state of an illness of getting a haircut everywhere is investigated in classification
Condition, calculates disease index and the prevention effect of each process.
Prevention effect is converted into probit value (y), and liquor strength (ug/mL) is converted into logarithm value (x), by minimum in terms of multiplication
Calculate concentration EC in virulence equation and suppression50, toxicity index and the co-toxicity coefficient (CTC) of medicament is calculated according to the abundant method of Sun Yun.Test knot
Fruit is shown in Table 1.
Toxicity Determination result shows, benzo alkene fluorine bacterium azoles and pyrrole metsulfovax when weight ratio is between 1:50-50:1,
The co-toxicity coefficient preventing and treating powdery mildew of cucumber is all higher than 120, shows preferable potentiation, time especially when 1:10-10:1, altogether
Poison coefficient is all higher than 150, and potentiation becomes apparent from.
Three, field control effectiveness test
In order to verify the practical application effect of the present invention further, the medicament of the embodiment of the present invention is used to carry out preventing and treating Fructus Cucumidis sativi white lead
Sick field control effectiveness test.
Reagent agent: (1) 21% benzo alkene fluorine bacterium azoles pyrrole metsulfovax wettable powder；(2) 12% benzo alkene fluorine bacterium azoles
Pyrrole metsulfovax aqueous emulsion；(3) 33% benzo alkene fluorine bacterium azoles pyrrole metsulfovax water dispersible granules；(4) 30% benzo alkene fluorine bacterium azoles pyrroles
Metsulfovax suspending agent；(5) comparative example 1:10% benzo alkene fluorine bacterium azole suspending agent；(6) comparative example 6:15% pyrrole fluorine bacterium ester suspending agent.
Within 5 days, 10 days after medicine, investigating disease indexs and calculate preventive effect, result of the test is shown in Table 2.
Field control effectiveness test result shows, powdery mildew of cucumber is respectively provided with and preferably prevents and treats effect by the compositions of embodiments of the invention
Really, preferable lasting effect and quick-acting are shown.Described compositions in the case of dosage reduces, after medicine 5 days, 10 days
Preventive effect is all significantly better than single active component.Meanwhile, during test, reagent agent, to cucumber crop safety, occurs without poisoning, right
The beneficial organism safety such as Apis and world trichogramma, are worth popularization and application on producing.
Claims (5)
1. a composition pesticide, it is characterised in that active component comprises benzo alkene fluorine bacterium azoles and pyrrole metsulfovax.
Composition pesticide the most according to claim 1, it is characterised in that described benzo alkene fluorine bacterium azoles and the weight of pyrrole metsulfovax
Amount ratio is 1:50-50:1.
3. according to the composition pesticide of claim 1 or 2, it is characterised in that described benzo alkene fluorine bacterium azoles and the weight of pyrrole metsulfovax
Amount ratio is 1:10-10:1.
4. according to the composition pesticide described in claim any one of claim 1-3, it is characterised in that described compositions is auxiliary
It is processed into any one dosage form with the auxiliary element in Pesticide formulation.
5. according to the composition pesticide described in claim any one of claim 1-4 for preventing and treating the use of crop powdery mildew
On the way.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610577700.6A CN106172414B (en) | 2016-07-21 | 2016-07-21 | A kind of bactericidal composition of the fluorine bacterium azoles of alkene containing benzo |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610577700.6A CN106172414B (en) | 2016-07-21 | 2016-07-21 | A kind of bactericidal composition of the fluorine bacterium azoles of alkene containing benzo |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106172414A true CN106172414A (en) | 2016-12-07 |
| CN106172414B CN106172414B (en) | 2018-12-14 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610577700.6A Active CN106172414B (en) | 2016-07-21 | 2016-07-21 | A kind of bactericidal composition of the fluorine bacterium azoles of alkene containing benzo |
Country Status (1)
| Country | Link |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103228140A (en) * | 2010-08-05 | 2013-07-31 | 拜耳知识产权有限责任公司 | Active compound combinations comprising prothioconazole and fluxapyroxad |
| CN105409965A (en) * | 2014-09-12 | 2016-03-23 | 陕西美邦农药有限公司 | Sterilization composition containing benzovindiflupyr |
-
2016
- 2016-07-21 CN CN201610577700.6A patent/CN106172414B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103228140A (en) * | 2010-08-05 | 2013-07-31 | 拜耳知识产权有限责任公司 | Active compound combinations comprising prothioconazole and fluxapyroxad |
| CN105409965A (en) * | 2014-09-12 | 2016-03-23 | 陕西美邦农药有限公司 | Sterilization composition containing benzovindiflupyr |
Non-Patent Citations (3)
| Title |
|---|
| 张庆宽: ""新颖杀菌剂-吡噻菌胺"", 《世界农药》 * |
| 张翼翾: ""广谱、持效期长的杀菌剂——苯并烯氟菌唑"", 《世界农药》 * |
| 陈倩等: ""1-甲基-3-三氟甲基-1H-吡唑-4-甲酰氯的合成"", 《农药》 * |
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| Publication number | Publication date |
|---|---|
| CN106172414B (en) | 2018-12-14 |
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