CN106167983A - 一种抗菌防静电衣物柔软剂及其制备方法 - Google Patents
一种抗菌防静电衣物柔软剂及其制备方法 Download PDFInfo
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Abstract
本发明提供了一种抗菌防静电衣物柔软剂及其制备方法。制备方法如下：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至70‑90℃搅拌20‑30分钟；（2）加入氧化聚乙烯蜡搅拌；（3）加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌；（4）加入纳米二氧化钛、过氧化苯甲酰和去离子水搅拌；（5）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7‑氨基‑4‑甲基香豆素和环己醇，保温搅拌30‑50分钟；（6）出料即得。本发明的抗菌防静电衣物柔软剂，能提高纺织品的抗静电能力，明显消除衣物的静电粘连和减少对尘土污垢的吸附，使衣物不那么易脏，易清洗，同时具有一定的抗菌性，还具有舒适的香味。
Description
技术领域
本发明涉及纺织材料领域，具体涉及一种抗菌防静电衣物柔软剂及其制备方法。
背景技术
柔软剂是一类能改变纤维的静、动摩擦系数的化学物质，当改变静摩擦系数时，手感触摸有平滑感，易于在纤维或织物上移动；当改变动摩擦系数时，纤维与纤维之间的微细结构易于相互移动，也就是纤维或者织物易于变形，二者的综合感觉就是柔软。衣物在多次洗涤后手感会变得粗糙，易产生静电，同时也易吸附灰尘，一般合成纤维织物更差，尤其是超细纤维织物。为了使织物重新具有柔软、滑爽、舒适的手感，就需要使用抗菌防静电衣物柔软剂来对其进行改善，而抗菌防静电衣物柔软剂就是其中的关键。因此，研发具有性能优良的抗菌防静电衣物柔软剂对于衣物的使用寿命和资源的节约都具有重要的意义。
发明内容
要解决的技术问题：本发明的目的是提供一种抗菌防静电衣物柔软剂，能提高纺织品的抗静电能力，明显消除衣物的静电粘连和减少对尘土污垢的吸附，使衣物不那么易脏，易清洗，同时具有一定的抗菌性，还具有舒适的香味。
技术方案：一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵10-15份、茉莉油0.5-1份、依兰油0.4-0.7份、纳米二氧化钛0.2-0.5份、过氧化苯甲酰1-2份、抗坏血酸棕榈酸酯0.2-0.5份、硬脂酰乳酸钠1-3份、月桂醇聚氧乙烯醚1-2份、柠檬酸0.1-0.3份、氧化聚乙烯蜡2-5份、7-氨基-4-甲基香豆素0.3-0.5份、环己醇2-5份、去离子水80-100份。
进一步优选的，所述的一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵11-14份、茉莉油0.6-0.9份、依兰油0.5-0.6份、纳米二氧化钛0.3-0.4份、过氧化苯甲酰1.2-1.8份、抗坏血酸棕榈酸酯0.3-0.4份、硬脂酰乳酸钠1.5-2.5份、月桂醇聚氧乙烯醚1.2-1.7份、柠檬酸0.15-0.25份、氧化聚乙烯蜡3-4份、7-氨基-4-甲基香豆素0.35-0.45份、环己醇3-4份、去离子水85-95份。
上述抗菌防静电衣物柔软剂的制备方法包括以下步骤：
（1） 将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至70-90℃搅拌20-30分钟；
（2） 加入氧化聚乙烯蜡搅拌60-90分钟；
（3） 加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌1-2小时；
（4） 加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌30-60分钟；
（5） 加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌30-50分钟；
（6） 出料即得。
进一步的，所述的一种抗菌防静电衣物柔软剂的制备方法，所述的步骤（1）中温度为75-85℃，搅拌时间为25分钟。
进一步的，所述的一种抗菌防静电衣物柔软剂的制备方法，所述的步骤（2）中搅拌时间为70-80分钟。
进一步的，所述的一种抗菌防静电衣物柔软剂的制备方法，所述的步骤（3）中搅拌时间为1.5小时。
进一步的，所述的一种抗菌防静电衣物柔软剂的制备方法，所述的步骤（4）中搅拌时间为40-50分钟。
进一步的，所述的一种抗菌防静电衣物柔软剂的制备方法，所述的步骤（5）中搅拌时间为35-45分钟。
有益效果：本发明的抗菌防静电衣物柔软剂能提高纺织品的抗静电能力，明显消除衣物的静电粘连和减少对尘土污垢的吸附，使衣物不那么易脏，易清洗，同时具有一定的抗菌性，还具有舒适的香味，气味宜人。
具体实施方式
实施例1
一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵10份、茉莉油0.5份、依兰油0.4份、纳米二氧化钛0.2份、过氧化苯甲酰1份、抗坏血酸棕榈酸酯0.2份、硬脂酰乳酸钠1份、月桂醇聚氧乙烯醚1份、柠檬酸0.1份、氧化聚乙烯蜡2份、7-氨基-4-甲基香豆素0.3份、环己醇2份、去离子水80份。
上述抗菌防静电衣物柔软剂的制备方法为：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至70℃搅拌20分钟；（2）加入氧化聚乙烯蜡搅拌60分钟；（3）加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌1小时；（4）加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌30分钟；（5）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌30分钟；（6）出料即得。
实施例2
一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵11份、茉莉油0.6份、依兰油0.5份、纳米二氧化钛0.3份、过氧化苯甲酰1.2份、抗坏血酸棕榈酸酯0.3份、硬脂酰乳酸钠1.5份、月桂醇聚氧乙烯醚1.2份、柠檬酸0.15份、氧化聚乙烯蜡3份、7-氨基-4-甲基香豆素0.35份、环己醇3份、去离子水85份。
上述抗菌防静电衣物柔软剂的制备方法为：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至75℃搅拌25分钟；（2）加入氧化聚乙烯蜡搅拌70分钟；（3）加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌1.5小时；（4）加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌40分钟；（5）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌35分钟；（6）出料即得。
实施例3
一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵12.5份、茉莉油0.75份、依兰油0.55份、纳米二氧化钛0.35份、过氧化苯甲酰1.5份、抗坏血酸棕榈酸酯0.35份、硬脂酰乳酸钠2份、月桂醇聚氧乙烯醚1.5份、柠檬酸0.2份、氧化聚乙烯蜡3.5份、7-氨基-4-甲基香豆素0.4份、环己醇3.5份、去离子水90份。
上述抗菌防静电衣物柔软剂的制备方法为：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至80℃搅拌25分钟；（2）加入氧化聚乙烯蜡搅拌75分钟；（3）加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌1.5小时；（4）加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌45分钟；（5）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌40分钟；（6）出料即得。
实施例4
一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵14份、茉莉油0.9份、依兰油0.6份、纳米二氧化钛0.4份、过氧化苯甲酰1.8份、抗坏血酸棕榈酸酯0.4份、硬脂酰乳酸钠2.5份、月桂醇聚氧乙烯醚1.7份、柠檬酸0.25份、氧化聚乙烯蜡4份、7-氨基-4-甲基香豆素0.45份、环己醇4份、去离子水95份。
上述抗菌防静电衣物柔软剂的制备方法为：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至85℃搅拌25分钟；（2）加入氧化聚乙烯蜡搅拌80分钟；（3）加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌1.5小时；（4）加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌50分钟；（5）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌45分钟；（6）出料即得。
实施例5
一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵15份、茉莉油1份、依兰油0.7份、纳米二氧化钛0.5份、过氧化苯甲酰2份、抗坏血酸棕榈酸酯0.5份、硬脂酰乳酸钠3份、月桂醇聚氧乙烯醚2份、柠檬酸0.3份、氧化聚乙烯蜡5份、7-氨基-4-甲基香豆素0.5份、环己醇5份、去离子水100份。
上述抗菌防静电衣物柔软剂的制备方法为：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至90℃搅拌30分钟；（2）加入氧化聚乙烯蜡搅拌90分钟；（3）加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌2小时；（4）加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌60分钟；（5）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌50分钟；（6）出料即得。
对比例1
本实施例与实施例5的区别在于不含有硬脂酰乳酸钠和月桂醇聚氧乙烯醚。具体地说是：
一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵15份、茉莉油1份、依兰油0.7份、纳米二氧化钛0.5份、过氧化苯甲酰2份、抗坏血酸棕榈酸酯0.5份、柠檬酸0.3份、氧化聚乙烯蜡5份、7-氨基-4-甲基香豆素0.5份、环己醇5份、去离子水100份。
上述抗菌防静电衣物柔软剂的制备方法为：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至90℃搅拌30分钟；（2）加入氧化聚乙烯蜡搅拌90分钟；（3）加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌60分钟；（4）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌50分钟；（5）出料即得。
对比例2
本实施例与实施例5的区别在于不含有纳米二氧化钛和7-氨基-4-甲基香豆素。具体地说是：
一种抗菌防静电衣物柔软剂，由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵15份、茉莉油1份、依兰油0.7份、过氧化苯甲酰2份、抗坏血酸棕榈酸酯0.5份、硬脂酰乳酸钠3份、月桂醇聚氧乙烯醚2份、柠檬酸0.3份、氧化聚乙烯蜡5份、环己醇5份、去离子水100份。
上述抗菌防静电衣物柔软剂的制备方法为：（1）将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至90℃搅拌30分钟；（2）加入氧化聚乙烯蜡搅拌90分钟；（3）加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌2小时；（4）加入过氧化苯甲酰和去离子水，搅拌60分钟；（5）加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸和环己醇，保温搅拌50分钟；（6）出料即得。
本发明的抗菌防静电衣物柔软剂能提高纺织品的抗静电能力，明显消除衣物的静电粘连和减少对尘土污垢的吸附，使衣物不那么易脏，易清洗，同时具有一定的抗菌性，还具有舒适的香味，气味宜人。
表1 抗菌防静电衣物柔软剂的部分性能指标
| 产品名称 | 峰值电压（V） | 大肠杆菌抑制率（%） |
| 实施例1 | 3.2 | 100 |
| 实施例2 | 3.1 | 100 |
| 实施例3 | 3.0 | 100 |
| 实施例4 | 2.8 | 100 |
| 实施例5 | 3.0 | 100 |
| 对比例1 | 17.3 | 99.4 |
| 对比例2 | 9.3 | 92.9 |
注：上述指标为织物浸渍本发明1小时后晾干测得。
Claims (8)
1.一种抗菌防静电衣物柔软剂，其特征在于：由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵10-15份、茉莉油0.5-1份、依兰油0.4-0.7份、纳米二氧化钛0.2-0.5份、过氧化苯甲酰1-2份、抗坏血酸棕榈酸酯0.2-0.5份、硬脂酰乳酸钠1-3份、月桂醇聚氧乙烯醚1-2份、柠檬酸0.1-0.3份、氧化聚乙烯蜡2-5份、7-氨基-4-甲基香豆素0.3-0.5份、环己醇2-5份、去离子水80-100份。
2.根据权利要求1所述的一种抗菌防静电衣物柔软剂，其特征在于：由以下成分以重量份制备而成：双氢化牛油基二甲基氯化铵11-14份、茉莉油0.6-0.9份、依兰油0.5-0.6份、纳米二氧化钛0.3-0.4份、过氧化苯甲酰1.2-1.8份、抗坏血酸棕榈酸酯0.3-0.4份、硬脂酰乳酸钠1.5-2.5份、月桂醇聚氧乙烯醚1.2-1.7份、柠檬酸0.15-0.25份、氧化聚乙烯蜡3-4份、7-氨基-4-甲基香豆素0.35-0.45份、环己醇3-4份、去离子水85-95份。
3.权利要求1至2任一项所述的一种抗菌防静电衣物柔软剂的制备方法，其特征在于：包括以下步骤：
（1） 将双氢化牛油基二甲基氯化铵放入反应釜中，将温度升至70-90℃搅拌20-30分钟；
（2） 加入氧化聚乙烯蜡搅拌60-90分钟；
（3） 加入硬脂酰乳酸钠和月桂醇聚氧乙烯醚，继续保温搅拌1-2小时；
（4） 加入纳米二氧化钛、过氧化苯甲酰和去离子水，搅拌30-60分钟；
（5） 加入茉莉油、依兰油、抗坏血酸棕榈酸酯、柠檬酸、7-氨基-4-甲基香豆素和环己醇，保温搅拌30-50分钟；
（6） 出料即得。
4.根据权利要求3所述的一种抗菌防静电衣物柔软剂的制备方法，其特征在于：所述步骤（1）中温度为75-85℃，搅拌时间为25分钟。
5.根据权利要求3所述的一种抗菌防静电衣物柔软剂的制备方法，其特征在于：所述步骤（2）中搅拌时间为70-80分钟。
6.根据权利要求3所述的一种抗菌防静电衣物柔软剂的制备方法，其特征在于：所述步骤（3）中搅拌时间为1.5小时。
7.根据权利要求3所述的一种抗菌防静电衣物柔软剂的制备方法，其特征在于：所述步骤（4）中搅拌时间为40-50分钟。
8.根据权利要求3所述的一种抗菌防静电衣物柔软剂的制备方法，其特征在于：所述步骤（5）中搅拌时间为35-45分钟。
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Application publication date: 20161130 |