CN106167868A - A kind of high strength and high hardness Cast aluminium alloy gold and preparation method thereof - Google Patents
A kind of high strength and high hardness Cast aluminium alloy gold and preparation method thereof Download PDFInfo
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- CN106167868A CN106167868A CN201610844399.0A CN201610844399A CN106167868A CN 106167868 A CN106167868 A CN 106167868A CN 201610844399 A CN201610844399 A CN 201610844399A CN 106167868 A CN106167868 A CN 106167868A
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C21/00—Alloys based on aluminium
- C22C21/10—Alloys based on aluminium with zinc as the next major constituent
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/026—Alloys based on aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/02—Making non-ferrous alloys by melting
- C22C1/03—Making non-ferrous alloys by melting using master alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/06—Making non-ferrous alloys with the use of special agents for refining or deoxidising
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Abstract
The present invention relates to aluminium alloy technology of preparing, be specially a kind of high strength and high hardness Cast aluminium alloy gold and preparation method thereof, solve the problem that existing aluminum alloy materials exists perishable deformation effect service life.A kind of high strength and high hardness Cast aluminium alloy gold, it is made up of the raw material of following mass percent: zinc 8.0 15.0wt.%, silicon 4.0 10.0wt.%, copper 1.5 4.5wt.%, ferrum 0.5 2.0 wt.%, manganese 0.03 0.5wt.%, magnesium 0.03 0.5wt.%, nickel 0.01 0.1wt.%, titanium 0.01 0.1wt.%, surplus is aluminum and inevitable impurity element.The present invention has stopped the generation of corrosion-deformation phenomenon effectively, extends and shortens service life, can be used for the high strength and high hardness structural member in the fields such as Aero-Space, telecommunications, automobile and weapons and exterior part.
Description
Technical field
The present invention relates to aluminium alloy technology of preparing, be specially a kind of high strength and high hardness Cast aluminium alloy gold and preparation side thereof
Method.
Background technology
Aluminum, as being only second to the practicality metal material of ferrum, obtains in the industry and is increasingly widely applied, particularly
As during structural material owing to having that density is little, specific strength and specific stiffness is higher, corrosion resistance is good and electrical and thermal conductivity is excellent, reclaim
Easily, the feature such as cryogenic property is good, be widely used in the technology necks such as transportation, Aero-Space, electronic apparatus, automobile making
Territory.
But, existing aluminum alloy materials there is also weak point, as manufacturing process is complicated, cost is high, Wear Resistance is poor,
Intensity is relatively low, uses the most in the presence of a harsh environment and corrosion-deformation easily occurs, and service life shortens.
Summary of the invention
The present invention is to solve the problem that existing aluminum alloy materials exists perishable deformation effect service life, it is provided that one
Plant high strength and high hardness Cast aluminium alloy gold and preparation method thereof.
The present invention adopts the following technical scheme that realization: a kind of high strength and high hardness Cast aluminium alloy gold, is by following matter
The raw material composition of amount percentage ratio: zinc 8.0-15.0wt.%, silicon 4.0-10.0wt.%, copper 1.5-4.5wt.%, ferrum 0.5-2.0
Wt.%, manganese 0.03-0.5wt.%, magnesium 0.03-0.5wt.%, nickel 0.01-0.1wt.%, titanium 0.01-0.1wt.%, surplus is aluminum
And inevitable impurity element.
The chemical property of zinc is active, in air at normal temperatures, and the basic zinc carbonate film that Surface Creation one layer is thin and compact,
Can stop oxidation further, during alumin(i)um zinc alloy system equilbrium phase diagram richness aluminum portions 275 DEG C, zinc dissolubility in aluminum is 31.6%, and
When 125 DEG C, its dissolubility then drops to 5.6%, is simultaneously introduced zinc and magnesium in aluminum, forms hardening constituent MgZn2, produces alloy
Significantly invigoration effect;MgZn2 content from 0.5% bring up to 12% time, can substantially increase tensile strength and yield strength, containing of magnesium
Amount exceedes in the required extra super duralumin alloy of formation MgZn2 phase, and the ratio of zinc and magnesium controls when about 2.7, and stress corrosion cracking resists
Power is maximum;As added copper on the basis of aluminum-zinc-manganese, forming aluminum-zinc-manganese-copper series alloy, its strengthening effect is at all aluminum
In alloy, maximum, is also the important aluminum alloy materials in space flight, aircraft industry, power industry.
Copper is important alloying element, has certain solid solution strengthening effect, and the CuAl2 of Precipitation has significantly in addition
Ageing strengthening effect.
Aluminium alloy adds silicon and can put forward heavy alloyed casting character and corrosion stability, if magnesium and silicon are simultaneously introduced in aluminum formation
Hardening constituent is MgSi, can increase substantially the intensity of alloy after adding copper.
Ferrum existing forms in alusil alloy common are α-AlFeSi and β-AlFeSi, the α-AlFeSi phase of Chinese character shape
The intensity of Alar, hardness can be improved, toughness is reduced seldom;As Fe > 0.5%, lamellar β-AlFeSi can improve mutually
The intensity of alloy also slightly reduces its elongation percentage.Additionally, for pack alloy, a certain amount of Fe content can prevent mucosa, also
The mobility of alloy can be increased.
A kind of high strength and high hardness Cast aluminium alloy gold and preparation method thereof, uses following steps: a, with metal aluminium ingot, aluminum zinc
Intermediate alloy or metal zinc ingot, nonmetal silicon, metallic copper, aluminum manganese intermediate alloy or manganese metal, manganese aluminium intermediate alloy or magnesium metal
Ingot, metallic iron, metallic nickel, Titanium, as the raw material of element each in aluminium alloy, weigh the most former by above-mentioned mass percent
Material;B, being put into by metal aluminium ingot and carry out melting in smelting furnace, smelting temperature is 650-680 DEG C, until being completely melt that making aluminum melts
Body;C, aluminum melt is progressively heated at 750-770 DEG C from 650-680 DEG C, be gradually added in heating process required zinc, copper,
Manganese, ferrum, magnesium and silicon, nickel, titanium, it is thus achieved that aluminium alloy melt;D, aluminium alloy melt is controlled at a temperature of 750-770 DEG C stir
10min, adds the special refining agent of aluminium alloy in whipping process and carries out refine and degasification, and refine is complete, removes melting on liquid level
Agent and scum silica frost, stand about 30min;E, the addition special refining agent of aluminium alloy carry out double refining, all at a temperature of 750-770 DEG C
Even stirring 20min, removes the scum silica frost on liquid level, stands about 30min the most again, cast after on-line filtration and degasification,
Get product.
There is advantages that the tensile strength of aluminum alloy materials casting stretching bar can reach 310Mpa,
Yield strength can reach 225Mpa, and elongation percentage can reach 8%, and Brinell hardness can reach 110HB, has effectively stopped corrosion-deformation
The generation of phenomenon, extends and shortens, and processing technique is rationally reliable, can be used for Aero-Space, telecommunications, vapour service life
High strength and high hardness structural member in the field such as car and weapons and exterior part.
Detailed description of the invention
Embodiment 1
A kind of high strength and high hardness Cast aluminium alloy gold, it is characterised in that: it is made up of the raw material of following mass percent: zinc
11wt.%, silicon 7wt.%, copper 3wt.%, ferrum 0.8 wt.%, manganese 0.35wt.%, magnesium 0.25wt.%, nickel 0.85wt.%, titanium
0.43wt.%, surplus is aluminum and inevitable impurity element.
2, a kind of high strength and high hardness Cast aluminium alloy gold according to claim 1 and preparation method thereof, its feature exists
In: use following steps: a, with metal aluminium ingot, aluminum zinc intermediate alloy or metal zinc ingot, nonmetal silicon, metallic copper, aluminum manganese in the middle of
Alloy or manganese metal, manganese aluminium intermediate alloy or metal magnesium ingot, metallic iron, metallic nickel, Titanium are as element each in aluminium alloy
Raw material, weighs corresponding raw material by above-mentioned mass percent;B, metal aluminium ingot is put into smelting furnace carries out melting, smelting temperature
It it is 650 DEG C, until being completely melt to make aluminum melt;C, aluminum melt is progressively heated at 750 DEG C from 650 DEG C, in heating process
It is gradually added into required zinc, copper, manganese, ferrum, magnesium and silicon, nickel, titanium, it is thus achieved that aluminium alloy melt;D, aluminium alloy melt is controlled
Stirring 10min at a temperature of 750 DEG C, add the special refining agent of aluminium alloy and carry out refine and degasification in whipping process, refine is complete
Finish, remove the flux on liquid level and scum silica frost, stand about 30min;E, the addition special refining agent of aluminium alloy enter at a temperature of 750 DEG C
Row double refining, uniform stirring 20min, removes the scum silica frost on liquid level, stands about 30min the most again, through on-line filtration and remove
Cast after gas, get product.
The tensile strength of finished product is 310Mpa, and yield strength is 225Mpa, and elongation percentage is 8%, and hardness is 110HB.
Embodiment 2
A kind of high strength and high hardness Cast aluminium alloy gold, it is characterised in that: it is made up of the raw material of following mass percent: zinc
8.5wt.%, silicon 9.5wt.%, copper 3.8wt.%, ferrum 1.2 wt.%, manganese 0.45wt.%, magnesium 0.35wt.%, nickel
0.28wt.%, titanium 0.81wt.%, surplus is aluminum and inevitable impurity element.
2, a kind of high strength and high hardness Cast aluminium alloy gold according to claim 1 and preparation method thereof, its feature exists
In: use following steps: a, with metal aluminium ingot, aluminum zinc intermediate alloy or metal zinc ingot, nonmetal silicon, metallic copper, aluminum manganese in the middle of
Alloy or manganese metal, manganese aluminium intermediate alloy or metal magnesium ingot, metallic iron, metallic nickel, Titanium are as element each in aluminium alloy
Raw material, weighs corresponding raw material by above-mentioned mass percent;B, metal aluminium ingot is put into smelting furnace carries out melting, smelting temperature
It it is 660 DEG C, until being completely melt to make aluminum melt;C, aluminum melt is progressively heated at 760 DEG C from 660 DEG C, in heating process
It is gradually added into required zinc, copper, manganese, ferrum, magnesium and silicon, nickel, titanium, it is thus achieved that aluminium alloy melt;D, aluminium alloy melt is controlled
Stirring 10min at a temperature of 760 DEG C, add the special refining agent of aluminium alloy and carry out refine and degasification in whipping process, refine is complete
Finish, remove the flux on liquid level and scum silica frost, stand about 30min;E, the addition special refining agent of aluminium alloy enter at a temperature of 760 DEG C
Row double refining, uniform stirring 20min, removes the scum silica frost on liquid level, stands about 30min the most again, through on-line filtration and remove
Cast after gas, get product.
The tensile strength of finished product is 298 Mpa, and yield strength is 213Mpa, and elongation percentage is 8%, and hardness is 108HB.
Embodiment 3
A kind of high strength and high hardness Cast aluminium alloy gold, it is characterised in that: it is made up of the raw material of following mass percent: zinc
13wt.%, silicon 5.5wt.%, copper 2.5wt.%, ferrum 0.7 wt.%, manganese 0.25wt.%, magnesium 0.45wt.%, nickel 0.08wt.%,
Titanium 0.15wt.%, surplus is aluminum and inevitable impurity element.
2, a kind of high strength and high hardness Cast aluminium alloy gold according to claim 1 and preparation method thereof, its feature exists
In: use following steps: a, with metal aluminium ingot, aluminum zinc intermediate alloy or metal zinc ingot, nonmetal silicon, metallic copper, aluminum manganese in the middle of
Alloy or manganese metal, manganese aluminium intermediate alloy or metal magnesium ingot, metallic iron, metallic nickel, Titanium are as element each in aluminium alloy
Raw material, weighs corresponding raw material by above-mentioned mass percent;B, metal aluminium ingot is put into smelting furnace carries out melting, smelting temperature
It it is 680 DEG C, until being completely melt to make aluminum melt;C, aluminum melt is progressively heated at 770 DEG C from 680 DEG C, in heating process
It is gradually added into required zinc, copper, manganese, ferrum, magnesium and silicon, nickel, titanium, it is thus achieved that aluminium alloy melt;D, aluminium alloy melt is controlled
Stirring 10min at a temperature of 770 DEG C, add the special refining agent of aluminium alloy and carry out refine and degasification in whipping process, refine is complete
Finish, remove the flux on liquid level and scum silica frost, stand about 30min;E, the addition special refining agent of aluminium alloy enter at a temperature of 770 DEG C
Row double refining, uniform stirring 20min, removes the scum silica frost on liquid level, stands about 30min the most again, through on-line filtration and remove
Cast after gas, get product.
The tensile strength of finished product is 289Mpa, and yield strength is 206Mpa, and elongation percentage is 7%, and hardness is 107HB.
In specific implementation process, the special refining agent of aluminium alloy can use the North Star casting of Hulan District, Harbin City to assist material factory
The LHJ---500 type aluminum refining agent produced.
Claims (2)
1. a high strength and high hardness Cast aluminium alloy gold, it is characterised in that: it is made up of the raw material of following mass percent: zinc
8.0-15.0wt.%, silicon 4.0-10.0wt.%, copper 1.5-4.5wt.%, ferrum 0.5-2.0 wt.%, manganese 0.03-0.5wt.%,
Magnesium 0.03-0.5wt.%, nickel 0.01-0.1wt.%, titanium 0.01-0.1wt.%, surplus is aluminum and inevitable impurity element.
A kind of high strength and high hardness Cast aluminium alloy gold the most according to claim 1 and preparation method thereof, it is characterised in that: adopt
With following steps: a, with metal aluminium ingot, aluminum zinc intermediate alloy or metal zinc ingot, nonmetal silicon, metallic copper, aluminum manganese intermediate alloy or
Manganese metal, manganese aluminium intermediate alloy or metal magnesium ingot, metallic iron, metallic nickel, Titanium, as the raw material of element each in aluminium alloy, are pressed
Above-mentioned mass percent weighs corresponding raw material;B, being put into by metal aluminium ingot and carry out melting in smelting furnace, smelting temperature is 650-
680 DEG C, until being completely melt to make aluminum melt;C, aluminum melt is progressively heated at 750-770 DEG C from 650-680 DEG C, in heating
During be gradually added into required zinc, copper, manganese, ferrum, magnesium and silicon, nickel, titanium, it is thus achieved that aluminium alloy melt;D, by aluminium alloy melt
Control to stir 10min at a temperature of 750-770 DEG C, whipping process adds the special refining agent of aluminium alloy and carries out refine and remove
Gas, refine is complete, removes the flux on liquid level and scum silica frost, stands about 30min;E, the addition special refining agent of aluminium alloy are at 750-
Carry out double refining, uniform stirring 20min at a temperature of 770 DEG C, remove the scum silica frost on liquid level, stand about 30min, warp the most again
Cast after crossing on-line filtration and degasification, get product.
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106636813A (en) * | 2016-12-12 | 2017-05-10 | 余姚市庆达机械有限公司 | Corrosion-resistant aluminum alloy and preparation method thereof |
CN107739913A (en) * | 2017-10-23 | 2018-02-27 | 北京泰科先锋科技有限公司 | Make alloy material of anti-take-off button and preparation method thereof |
CN108220718A (en) * | 2017-12-29 | 2018-06-29 | 潘换珍 | A kind of high intensity high-yield-ratio cast aluminium alloy material and preparation method thereof |
CN109136697A (en) * | 2018-08-28 | 2019-01-04 | 兰州飞行控制有限责任公司 | A kind of high intensity aluminum bronze line aluminium alloy |
CN109252077A (en) * | 2018-11-26 | 2019-01-22 | 山西瑞格金属新材料有限公司 | A kind of high-intensitive high yield low melting point aluminium alloy of die casting |
CN109280825A (en) * | 2018-11-26 | 2019-01-29 | 山西瑞格金属新材料有限公司 | A kind of high bending resistance thin wall component aluminium alloy of high intensity |
CN110684914A (en) * | 2019-10-25 | 2020-01-14 | 佛山市三水瑞晟通金属制品有限公司 | High-strength high-hardness aluminum alloy and preparation method thereof |
CN110691859A (en) * | 2017-05-30 | 2020-01-14 | 俄铝工程技术中心有限责任公司 | High strength aluminum-based alloy |
CN110938767A (en) * | 2018-09-25 | 2020-03-31 | 比亚迪股份有限公司 | Die-casting aluminum alloy and preparation method thereof |
WO2021003939A1 (en) * | 2019-07-05 | 2021-01-14 | 比亚迪股份有限公司 | Aluminum alloy, preparation method therefor and aluminum alloy structural member |
WO2021128619A1 (en) * | 2019-12-26 | 2021-07-01 | 比亚迪股份有限公司 | Aluminum alloy and preparation method thereof, and aluminum alloy structural member |
CN115896566A (en) * | 2022-12-29 | 2023-04-04 | 蔚来汽车科技(安徽)有限公司 | Aluminum alloy, part prepared from aluminum alloy and vehicle comprising part |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106636813A (en) * | 2016-12-12 | 2017-05-10 | 余姚市庆达机械有限公司 | Corrosion-resistant aluminum alloy and preparation method thereof |
CN110691859B (en) * | 2017-05-30 | 2021-08-03 | 俄铝工程技术中心有限责任公司 | High strength aluminum-based alloy |
CN110691859A (en) * | 2017-05-30 | 2020-01-14 | 俄铝工程技术中心有限责任公司 | High strength aluminum-based alloy |
CN107739913A (en) * | 2017-10-23 | 2018-02-27 | 北京泰科先锋科技有限公司 | Make alloy material of anti-take-off button and preparation method thereof |
CN108220718A (en) * | 2017-12-29 | 2018-06-29 | 潘换珍 | A kind of high intensity high-yield-ratio cast aluminium alloy material and preparation method thereof |
CN109136697A (en) * | 2018-08-28 | 2019-01-04 | 兰州飞行控制有限责任公司 | A kind of high intensity aluminum bronze line aluminium alloy |
CN110938767A (en) * | 2018-09-25 | 2020-03-31 | 比亚迪股份有限公司 | Die-casting aluminum alloy and preparation method thereof |
CN109252077A (en) * | 2018-11-26 | 2019-01-22 | 山西瑞格金属新材料有限公司 | A kind of high-intensitive high yield low melting point aluminium alloy of die casting |
CN109280825A (en) * | 2018-11-26 | 2019-01-29 | 山西瑞格金属新材料有限公司 | A kind of high bending resistance thin wall component aluminium alloy of high intensity |
WO2021003939A1 (en) * | 2019-07-05 | 2021-01-14 | 比亚迪股份有限公司 | Aluminum alloy, preparation method therefor and aluminum alloy structural member |
CN110684914A (en) * | 2019-10-25 | 2020-01-14 | 佛山市三水瑞晟通金属制品有限公司 | High-strength high-hardness aluminum alloy and preparation method thereof |
WO2021128619A1 (en) * | 2019-12-26 | 2021-07-01 | 比亚迪股份有限公司 | Aluminum alloy and preparation method thereof, and aluminum alloy structural member |
EP4083248A4 (en) * | 2019-12-26 | 2023-05-24 | BYD Company Limited | Aluminum alloy and preparation method thereof, and aluminum alloy structural member |
CN115896566A (en) * | 2022-12-29 | 2023-04-04 | 蔚来汽车科技(安徽)有限公司 | Aluminum alloy, part prepared from aluminum alloy and vehicle comprising part |
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Address after: 043800 Shanxi city of Yuncheng Province Wang Pei township of Wenxi county. Applicant after: Shanxi Reggae Metal New Material Co Ltd Address before: 043800 Shanxi city of Yuncheng Province Wang Pei township of Wenxi county. Applicant before: Wenxi County Regal Magnesium Co., Ltd. |
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