CN106167593A - A kind of flame-proof PVC floor and preparation method thereof - Google Patents
A kind of flame-proof PVC floor and preparation method thereof Download PDFInfo
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- CN106167593A CN106167593A CN201610681915.2A CN201610681915A CN106167593A CN 106167593 A CN106167593 A CN 106167593A CN 201610681915 A CN201610681915 A CN 201610681915A CN 106167593 A CN106167593 A CN 106167593A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B7/00—Mixing; Kneading
- B29B7/74—Mixing; Kneading using other mixers or combinations of mixers, e.g. of dissimilar mixers ; Plant
- B29B7/7461—Combinations of dissimilar mixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
- B29C2043/5808—Measuring, controlling or regulating pressure or compressing force
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/32—Component parts, details or accessories; Auxiliary operations
- B29C43/58—Measuring, controlling or regulating
- B29C2043/5816—Measuring, controlling or regulating temperature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The present invention relates to a kind of flame-proof PVC floor and preparation method thereof, relate to technical field of floor, be made up of the raw material of following weight portion: polyvinyl chloride resin 90 110 parts, o-phthalic acid dibutyl ester 35 55 parts, aluminium hydroxide 45 60 parts, 30 50 parts of magnesium hydroxide, stabilizer 47 parts, filler 20 35 parts, lubricant 26 parts, epoxy soybean oil 39 parts, coloring agent 0.5 2.5 parts, surface conditioning agent 27 parts.The PVC floor of the present invention, uses aluminium hydroxide and magnesium hydroxide inorganic combustion inhibitor nontoxic, environmentally friendly, cheap, has function fire-retardant, that eliminate smoke, can strengthen intensity and the anti-wear performance on floor simultaneously, can be substantially reduced thickness and the weight on floor；Add filler and further enhance intensity and the anti-wear performance on floor, extend the service life on floor；The simple science of preparation technology of the present invention, production efficiency is high.
Description
Technical field
The present invention relates to technical field of floor, be specifically related to a kind of flame-proof PVC floor and preparation method thereof.
Background technology
Along with the progress of society, the development of science and technology, building that living environment especially residential location is used by people and dress
Exterior material requires more and more higher.Having the most novel energy-conserving and environment-protective construction material on the market now, wherein polrvinyl chloride (PVC) is moulded
Material floor is high-tech pavement the most novel in current world building material industry, initially enters China from early 1980s
Market, big and medium-sized cities the most at home have obtained universal accreditation, use widely, such as indoor family, hospital,
The various places such as school, office building, factory, public place, supermarket, stadiums.Therefore the PVC ground of excellent performance environment-friendly type is developed
Plate glue becomes important topic.
PVC plastic floor refers to by macromolecule resin and auxiliary agent thereof by the ground decoration material made by suitable technique
Material.Comparing wood floors, from product itself, it is mothproof, fire-retardant that PVC plastic floor has uvioresistant, acid-alkali-corrosive-resisting, anti-olive
Property good advantage, and non-skid property is good, safety and comfort of walking；From the point of view of environmental protection, environmental protection, nontoxic, to human body
And environment is free from side effects, easy maintenance, clean with clear water at ordinary times, just can wiping well with erasing rubber if having spot
Totally.The wearability of traditional PVC plastic adhesive floor is poor, and non-skid property is poor, there is potential safety hazard.Plastic floor generally makes
Being used in the place that the crowd is dense, it is desirable to wearability is good, service life could be grown, very to the flame-retardancy requirements of plastic floor simultaneously
Height, the most once breaking out of fire consequence is hardly imaginable, but the abrasion-resistant flame-retardant performance of the plastic floor of prior art does not also reach
Requirement.
Summary of the invention
For above-mentioned deficiency, in order to overcome the defect of prior art, the present invention provides a kind of wear-resisting, fire-retardant PVC floor
And preparation method thereof.
In order to realize the purpose of the present invention, adopt the following technical scheme that
A kind of flame-proof PVC floor, is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, stabilizer is rare-earth stabilizer.
Preferably, the one during filler is flyash or wollastonite.
Preferably, lubricant is stearic acid.
Further, the preparation method on a kind of flame-proof PVC floor, specifically include following steps:
(1) each raw material of corresponding weight portion is weighed, by polyvinyl chloride resin, o-phthalic acid dibutyl ester, aluminium hydroxide, hydroxide
Magnesium, stabilizer, lubricant and epoxy soybean oil add in high speed mixer, rise high-temperature to after 180-230 DEG C, and rotating speed is
200-320r/min, mixing and stirring；
(2) adding filler, coloring agent and surface conditioning agent in compound prepared by step (1), regulation temperature is 80-
120 DEG C, keep rotating speed constant, mix and blend 10-15min；
(3) closing high-speed batch mixer, the compound of cooling step (2) is to 35-45 DEG C；
(4) by material mill mill 15-25min of step (3) mix homogeneously, front roll temperature 165 DEG C, back roller 160
℃；Reduce roll spacing compacting material, and during mill, play triangle bag, traction, last thin pass-out sheet；Sheet material is cut into little
Sheet, puts in the mould of preheating；
(5) 170 DEG C, under 6MPa pressure, use pressure forming machine tabletting, pressurize 40-50min, be cooled to 70 DEG C, be transferred to
Coldplate is also forced into 10MPa, and cold pressing 8-15min, cuts sample preparation and get final product.
Beneficial effects of the present invention:
The PVC floor of the present invention, uses aluminium hydroxide and magnesium hydroxide inorganic combustion inhibitor nontoxic, environmentally friendly, price
Cheap, there is function fire-retardant, that eliminate smoke, intensity and the anti-wear performance on floor can be strengthened simultaneously, floor can be substantially reduced
Thickness and weight；Add filler and further enhance intensity and the anti-wear performance on floor, extend the service life on floor；The present invention's
The simple science of preparation technology, production efficiency is high.
Detailed description of the invention
Elaborating embodiments of the invention below, the present embodiment is carried out under premised on technical solution of the present invention
Implement, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following enforcement
Example.
Embodiment 1
A kind of flame-proof PVC floor, is made up of the raw material of following weight portion: polyvinyl chloride resin 90 parts, o-phthalic acid dibutyl ester 35
Part, aluminium hydroxide 45 parts, 30 parts of magnesium hydroxide, stabilizer 4 parts, filler 20 parts, lubricant 2 parts, epoxy soybean oil 3 parts, coloring
Agent 0.5 part, surface conditioning agent 2 parts.Wherein stabilizer is rare-earth stabilizer, and filler is the one in flyash or wollastonite, profit
Lubrication prescription is stearic acid.
The preparation method on a kind of flame-proof PVC floor, specifically includes following steps:
(1) each raw material of corresponding weight portion is weighed, by polyvinyl chloride resin, o-phthalic acid dibutyl ester, aluminium hydroxide, hydroxide
Magnesium, stabilizer, lubricant and epoxy soybean oil add in high speed mixer, rise high-temperature to after 180 DEG C, and rotating speed is 200r/
Min, mixing and stirring；
(2) adding filler, coloring agent and surface conditioning agent in compound prepared by step (1), regulation temperature is 80 DEG C,
Keep rotating speed constant, mix and blend 10min；
(3) closing high-speed batch mixer, the compound of cooling step (2) is to 35 DEG C；
(4) by material mill mill 15min of step (3) mix homogeneously, front roll temperature 165 DEG C, back roller 160 DEG C；
Reduce roll spacing compacting material, and during mill, play triangle bag, traction, last thin pass-out sheet；Sheet material is cut into small pieces, puts
Enter in the mould of preheating；
(5) 170 DEG C, under 6MPa pressure, use pressure forming machine tabletting, pressurize 40min, be cooled to 70 DEG C, be transferred to cold
But plate be forced into 10MPa, cold pressing 8min, cutting sample preparation and get final product.
Embodiment 2
A kind of flame-proof PVC floor, is made up of the raw material of following weight portion: polyvinyl chloride resin 110 parts, o-phthalic acid dibutyl ester
55 parts, aluminium hydroxide 60 parts, 50 parts of magnesium hydroxide, stabilizer 7 parts, filler 35 parts, lubricant 6 parts, epoxy soybean oil 9 parts,
Toner 2.5 parts, surface conditioning agent 7 parts.Wherein stabilizer is rare-earth stabilizer, and filler is the one in flyash or wollastonite,
Lubricant is stearic acid.
The preparation method on a kind of flame-proof PVC floor, specifically includes following steps:
(1) each raw material of corresponding weight portion is weighed, by polyvinyl chloride resin, o-phthalic acid dibutyl ester, aluminium hydroxide, hydroxide
Magnesium, stabilizer, lubricant and epoxy soybean oil add in high speed mixer, rise high-temperature to after 200 DEG C, and rotating speed is 220r/
Min, mixing and stirring；
(2) adding filler, coloring agent and surface conditioning agent in compound prepared by step (1), regulation temperature is 100
DEG C, keep rotating speed constant, mix and blend 12min；
(3) closing high-speed batch mixer, the compound of cooling step (2) is to 40 DEG C；
(4) by material mill mill 20min of step (3) mix homogeneously, front roll temperature 165 DEG C, back roller 160 DEG C；
Reduce roll spacing compacting material, and during mill, play triangle bag, traction, last thin pass-out sheet；Sheet material is cut into small pieces, puts
Enter in the mould of preheating；
(5) 170 DEG C, under 6MPa pressure, use pressure forming machine tabletting, pressurize 50min, be cooled to 70 DEG C, be transferred to cold
But plate be forced into 10MPa, cold pressing 15min, cutting sample preparation and get final product.
Embodiment 3
A kind of flame-proof PVC floor, is made up of the raw material of following weight portion: polyvinyl chloride resin 94 parts, o-phthalic acid dibutyl ester 40
Part, aluminium hydroxide 48 parts, 35 parts of magnesium hydroxide, stabilizer 5 parts, filler 26 parts, lubricant 4 parts, epoxy soybean oil 5 parts, coloring
Agent 1 part, surface conditioning agent 4 parts.Wherein stabilizer is rare-earth stabilizer, and filler is the one in flyash or wollastonite, lubrication
Agent is stearic acid.
The preparation method on a kind of flame-proof PVC floor, specifically includes following steps:
(1) each raw material of corresponding weight portion is weighed, by polyvinyl chloride resin, o-phthalic acid dibutyl ester, aluminium hydroxide, hydroxide
Magnesium, stabilizer, lubricant and epoxy soybean oil add in high speed mixer, rise high-temperature to after 190 DEG C, and rotating speed is 250r/
Min, mixing and stirring；
(2) adding filler, coloring agent and surface conditioning agent in compound prepared by step (1), regulation temperature is 90 DEG C,
Keep rotating speed constant, mix and blend 15min；
(3) closing high-speed batch mixer, the compound of cooling step (2) is to 45 DEG C；
(4) by material mill mill 20min of step (3) mix homogeneously, front roll temperature 165 DEG C, back roller 160 DEG C；
Reduce roll spacing compacting material, and during mill, play triangle bag, traction, last thin pass-out sheet；Sheet material is cut into small pieces, puts
Enter in the mould of preheating；
(5) 170 DEG C, under 6MPa pressure, use pressure forming machine tabletting, pressurize 45min, be cooled to 70 DEG C, be transferred to cold
But plate be forced into 10MPa, cold pressing 10min, cutting sample preparation and get final product.
Embodiment 4
A kind of flame-proof PVC floor, is made up of the raw material of following weight portion: polyvinyl chloride resin 105 parts, o-phthalic acid dibutyl ester
45 parts, aluminium hydroxide 50 parts, 35 parts of magnesium hydroxide, stabilizer 5 parts, filler 22 parts, lubricant 4 parts, epoxy soybean oil 6 parts,
Toner 2 parts, surface conditioning agent 5 parts.Wherein stabilizer is rare-earth stabilizer, and filler is the one in flyash or wollastonite, profit
Lubrication prescription is stearic acid.
The preparation method on a kind of flame-proof PVC floor, specifically includes following steps:
(1) each raw material of corresponding weight portion is weighed, by polyvinyl chloride resin, o-phthalic acid dibutyl ester, aluminium hydroxide, hydroxide
Magnesium, stabilizer, lubricant and epoxy soybean oil add in high speed mixer, rise high-temperature to after 220 DEG C, and rotating speed is 300r/
Min, mixing and stirring；
(2) adding filler, coloring agent and surface conditioning agent in compound prepared by step (1), regulation temperature is 90 DEG C,
Keep rotating speed constant, mix and blend 15min；
(3) closing high-speed batch mixer, the compound of cooling step (2) is to 45 DEG C；
(4) by material mill mill 25min of step (3) mix homogeneously, front roll temperature 165 DEG C, back roller 160 DEG C；
Reduce roll spacing compacting material, and during mill, play triangle bag, traction, last thin pass-out sheet；Sheet material is cut into small pieces, puts
Enter in the mould of preheating；
(5) 170 DEG C, under 6MPa pressure, use pressure forming machine tabletting, pressurize 45min, be cooled to 70 DEG C, be transferred to cold
But plate be forced into 10MPa, cold pressing 12min, cutting sample preparation and get final product.
Embodiment 5
A kind of flame-proof PVC floor, is made up of the raw material of following weight portion: polyvinyl chloride resin 100 parts, o-phthalic acid dibutyl ester
45 parts, aluminium hydroxide 50 parts, 42 parts of magnesium hydroxide, stabilizer 6 parts, filler 28 parts, lubricant 3 parts, epoxy soybean oil 5 parts,
Toner 1.2 parts, surface conditioning agent 3 parts.Wherein stabilizer is rare-earth stabilizer, and filler is the one in flyash or wollastonite,
Lubricant is stearic acid.
The preparation method on a kind of flame-proof PVC floor, specifically includes following steps:
(1) each raw material of corresponding weight portion is weighed, by polyvinyl chloride resin, o-phthalic acid dibutyl ester, aluminium hydroxide, hydroxide
Magnesium, stabilizer, lubricant and epoxy soybean oil add in high speed mixer, rise high-temperature to after 230 DEG C, and rotating speed is 280r/
Min, mixing and stirring；
(2) adding filler, coloring agent and surface conditioning agent in compound prepared by step (1), regulation temperature is 90 DEG C,
Keep rotating speed constant, mix and blend 15min；
(3) closing high-speed batch mixer, the compound of cooling step (2) is to 40 DEG C；
(4) by material mill mill 20min of step (3) mix homogeneously, front roll temperature 165 DEG C, back roller 160 DEG C；
Reduce roll spacing compacting material, and during mill, play triangle bag, traction, last thin pass-out sheet；Sheet material is cut into small pieces, puts
Enter in the mould of preheating；
(5) 170 DEG C, under 6MPa pressure, use pressure forming machine tabletting, pressurize 45min, be cooled to 70 DEG C, be transferred to cold
But plate be forced into 10MPa, cold pressing 12min, cutting sample preparation and get final product.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.
Claims (7)
1. a flame-proof PVC floor, it is characterised in that be made up of the raw material of following weight portion:
A kind of flame-proof PVC floor the most according to claim 1, it is characterised in that be made up of the raw material of following weight portion:
A kind of flame-proof PVC floor the most according to claim 1, it is characterised in that be made up of the raw material of following weight portion:
4. according to a kind of flame-proof PVC floor described in claim 1 or 2 or 3, it is characterised in that stabilizer is rare-earth stabilizer.
5. according to a kind of flame-proof PVC floor described in claim 1 or 2 or 3, it is characterised in that filler is flyash or silicon ash
One in stone.
6. according to a kind of flame-proof PVC floor described in claim 1 or 2 or 3, it is characterised in that lubricant is stearic acid.
7. the preparation method on a flame-proof PVC floor, it is characterised in that specifically include following steps:
(1) each raw material of corresponding weight portion is weighed, by polyvinyl chloride resin, o-phthalic acid dibutyl ester, aluminium hydroxide, magnesium hydroxide, steady
Determining agent, lubricant and epoxy soybean oil and add in high speed mixer, rise high-temperature to after 180-230 DEG C, rotating speed is 200-
320r/min, mixing and stirring；
(2) adding filler, coloring agent and surface conditioning agent in compound prepared by step (1), regulation temperature is 80-120 DEG C,
Keep rotating speed constant, mix and blend 10-15min；
(3) closing high-speed batch mixer, the compound of cooling step (2) is to 35-45 DEG C；
(4) by material mill mill 15-25min of step (3) mix homogeneously, front roll temperature 165 DEG C, back roller 160 DEG C；Subtract
Little roll spacing compact material, and during mill, play triangle bag, traction, last thin pass-out sheet；Sheet material is cut into small pieces, puts into
In the mould of preheating；
(5) 170 DEG C, under 6MPa pressure, use pressure forming machine tabletting, pressurize 40-50min, be cooled to 70 DEG C, be transferred to cooling
Plate is also forced into 10MPa, and cold pressing 8-15min, cuts sample preparation and get final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610681915.2A CN106167593A (en) | 2016-08-17 | 2016-08-17 | A kind of flame-proof PVC floor and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610681915.2A CN106167593A (en) | 2016-08-17 | 2016-08-17 | A kind of flame-proof PVC floor and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN106167593A true CN106167593A (en) | 2016-11-30 |
Family
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| CN201610681915.2A Pending CN106167593A (en) | 2016-08-17 | 2016-08-17 | A kind of flame-proof PVC floor and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163448A (en) * | 2017-07-12 | 2017-09-15 | 广东必图新材料科技股份有限公司 | A kind of sham wood and preparation method thereof |
| CN113248847A (en) * | 2021-06-16 | 2021-08-13 | 镇江惠泽装饰材料有限公司 | Formula and manufacturing method of high-toughness PVC (polyvinyl chloride) plate |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044804A (en) * | 2012-12-11 | 2013-04-17 | 浙江博泰塑胶有限公司 | Flame-retardant transparent floor film and production technology thereof |
| CN103923407A (en) * | 2013-08-30 | 2014-07-16 | 安徽美祥实业有限公司 | Flame retardant, low smoke, low temperature resistant and cigarette calcination resistant PVC (polyvinyl chloride) floor |
| CN104893148A (en) * | 2015-05-29 | 2015-09-09 | 桐城市诚信木塑科技材料有限公司 | Wear-resistant flame-retardant floor slab |
-
2016
- 2016-08-17 CN CN201610681915.2A patent/CN106167593A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044804A (en) * | 2012-12-11 | 2013-04-17 | 浙江博泰塑胶有限公司 | Flame-retardant transparent floor film and production technology thereof |
| CN103923407A (en) * | 2013-08-30 | 2014-07-16 | 安徽美祥实业有限公司 | Flame retardant, low smoke, low temperature resistant and cigarette calcination resistant PVC (polyvinyl chloride) floor |
| CN104893148A (en) * | 2015-05-29 | 2015-09-09 | 桐城市诚信木塑科技材料有限公司 | Wear-resistant flame-retardant floor slab |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107163448A (en) * | 2017-07-12 | 2017-09-15 | 广东必图新材料科技股份有限公司 | A kind of sham wood and preparation method thereof |
| CN113248847A (en) * | 2021-06-16 | 2021-08-13 | 镇江惠泽装饰材料有限公司 | Formula and manufacturing method of high-toughness PVC (polyvinyl chloride) plate |
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Application publication date: 20161130 |
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