CN106167560A - A kind of automobile oil-resistant seal ring and preparation method thereof - Google Patents
A kind of automobile oil-resistant seal ring and preparation method thereof Download PDFInfo
- Publication number
- CN106167560A CN106167560A CN201610795087.5A CN201610795087A CN106167560A CN 106167560 A CN106167560 A CN 106167560A CN 201610795087 A CN201610795087 A CN 201610795087A CN 106167560 A CN106167560 A CN 106167560A
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- parts
- seal ring
- resistant seal
- raw material
- automobile oil
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Sealing Material Composition (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a kind of automobile oil-resistant seal ring and preparation method thereof, be made up of the raw material of following weight portion: natural rubber 70 85 parts, 35 40 parts of silicone rubber, bamboo carbon fiber 25 32 parts, zinc oxide 12 18 parts, Firebrake ZB 7 13 parts, wollastonite in powder 12 16 parts, 15 19 parts of magnesium hydroxide, white carbon black 20 27 parts, silica 18 23 parts, accelerator 5 10 parts, 36 parts of age resistor, vulcanizing agent 25 parts, paraffin oil 58 parts;The present invention, by adding bamboo carbon fiber, strengthens the adsorptivity of sealing ring, absorption abnormal flavour and harmful gas;Adding magnesium hydroxide, wollastonite in powder and Firebrake ZB is filler, improves the acid-alkali-corrosive-resisting of sealing ring, oil resistivity and wearability;The acicular texture that wollastonite in powder is special, improves the mechanical property of sealing ring, such as hot strength;Add white carbon black by with other filler synergism, further increase wearability and the intensity of sealing ring.
Description
Technical field
The present invention relates to rubber composite processing technique field, be specifically related to a kind of automobile oil-resistant seal ring and system thereof
Preparation Method.
Background technology
Sealing ring is a kind of common element preventing the effects such as the leakage of gas, liquid or foreign object intrusion, seals loop material
The selection of material has significant impact to its sealing property and service life.The performance of material directly affects the usability of sealing ring
Energy.Sealing ring may apply to multiple field, such as on auto parts and components.In order to strengthen sealing, the hose end of air conditioning for automobiles
Head is often socketed with sealing ring, and owing to there being more greasy dirt inside air conditioning for automobiles, therefore sealing ring is easily corroded, meanwhile,
Gas that flexible pipe within air-conditioning often delivery temperature is higher or liquid, sealing ring after being heated readily volatilized go out abnormal flavour and harmful
Gas, these gases can lead in driver's cabin with pipeline, human body is produced bigger harm.
Summary of the invention
In order to overcome the deficiencies in the prior art, the present invention provides a kind of corrosion-resistant, high temperature resistant and oil resistant automobile to seal
Circle and preparation method thereof.
In order to realize the purpose of the present invention, adopt the following technical scheme that
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, 300 mesh standard sieves crossed by wollastonite in powder.
Further, the preparation method of a kind of automobile oil-resistant seal ring, comprise the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 95-105 DEG C, mixing 8-12min, then rise
Temperature, to 120-135 DEG C, adds remaining remaining raw material, mixing 30-50min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 220-240 DEG C,
Cure time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Beneficial effects of the present invention:
The present invention, with natural rubber, silicone rubber as rubber raw materials, by adding bamboo carbon fiber, strengthens the absorption of sealing ring
Property, absorption abnormal flavour and harmful gas;Adding magnesium hydroxide, wollastonite in powder and Firebrake ZB is filler, improves the acidproof of sealing ring
Caustic corrosion, oil resistivity and wearability;The acicular texture that wollastonite in powder is special, improves the mechanical property of sealing ring, such as stretching
Intensity;Add white carbon black by with other filler synergism, further increase wearability and the intensity of sealing ring;The present invention
Sealing ring oil resistivity and wearability strong, there is resistance to elevated temperatures, do not soften under high temperature, service life is long.
Detailed description of the invention
Elaborating embodiments of the invention below, the present embodiment is carried out under premised on technical solution of the present invention
Implement, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following enforcement
Example.
Embodiment 1
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 70 parts, 35 parts of silicone rubber,
Bamboo carbon fiber 25 parts, zinc oxide 12 parts, Firebrake ZB 7 parts, wollastonite in powder 12 parts, 15 parts of magnesium hydroxide, white carbon black 20 parts, silicon dioxide
18 parts, accelerator 5 parts, 3 parts of age resistor, vulcanizing agent 2 parts, paraffin oil 5 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 95 DEG C, mixing 12min, then heat to
120 DEG C, add remaining remaining raw material, mixing 50min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 220 DEG C, sulfuration
Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Embodiment 2
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 85 parts, 40 parts of silicone rubber,
Bamboo carbon fiber 32 parts, zinc oxide 18 parts, Firebrake ZB 13 parts, wollastonite in powder 16 parts, 19 parts of magnesium hydroxide, white carbon black 27 parts, titanium dioxide
Silicon 23 parts, accelerator 10 parts, 6 parts of age resistor, vulcanizing agent 5 parts, paraffin oil 8 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 105 DEG C, mixing 8min, then heat to
135 DEG C, add remaining remaining raw material, mixing 30min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 240 DEG C, sulfuration
Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Embodiment 3
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 75 parts, 37 parts of silicone rubber,
Bamboo carbon fiber 28 parts, zinc oxide 15 parts, Firebrake ZB 9 parts, wollastonite in powder 14 parts, 17 parts of magnesium hydroxide, white carbon black 23 parts, silicon dioxide
20 parts, accelerator 7 parts, 5 parts of age resistor, vulcanizing agent 4 parts, paraffin oil 6 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 100 DEG C, mixing 10min, then heat to
130 DEG C, add remaining remaining raw material, mixing 40min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 230 DEG C, sulfuration
Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Embodiment 4
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 80 parts, 38 parts of silicone rubber,
Bamboo carbon fiber 30 parts, zinc oxide 16 parts, Firebrake ZB 12 parts, wollastonite in powder 14 parts, 17 parts of magnesium hydroxide, white carbon black 25 parts, titanium dioxide
Silicon 20 parts, accelerator 8 parts, 5 parts of age resistor, vulcanizing agent 4 parts, paraffin oil 6 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 105 DEG C, mixing 10min, then heat to
125 DEG C, add remaining remaining raw material, mixing 45min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 235 DEG C, sulfuration
Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention
Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.
Claims (5)
1. an automobile oil-resistant seal ring, it is characterised in that be made up of the raw material of following weight portion:
A kind of automobile oil-resistant seal ring the most according to claim 1, it is characterised in that by the raw material group of following weight portion
Become:
A kind of automobile oil-resistant seal ring the most according to claim 1, it is characterised in that by the raw material group of following weight portion
Become:
A kind of automobile oil-resistant seal ring the most according to claim 1, it is characterised in that it is accurate that 300 targets crossed by wollastonite in powder
Sieve.
5. the preparation method of an automobile oil-resistant seal ring, it is characterised in that comprise the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 95-105 DEG C, mixing 8-12min, then heat to
120-135 DEG C, add remaining remaining raw material, mixing 30-50min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 220-240 DEG C, sulfuration
Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
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CN201610795087.5A CN106167560A (en) | 2016-08-31 | 2016-08-31 | A kind of automobile oil-resistant seal ring and preparation method thereof |
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CN201610795087.5A CN106167560A (en) | 2016-08-31 | 2016-08-31 | A kind of automobile oil-resistant seal ring and preparation method thereof |
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CN201610795087.5A Pending CN106167560A (en) | 2016-08-31 | 2016-08-31 | A kind of automobile oil-resistant seal ring and preparation method thereof |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107033402A (en) * | 2017-05-10 | 2017-08-11 | 广西桂山特种橡胶制品有限公司 | A kind of RUBBER O type sealing ring and preparation method thereof |
CN108752678A (en) * | 2018-05-29 | 2018-11-06 | 宁国中辰密封件有限公司 | A kind of preparation method of high intensity caliper sealing element |
CN110041574A (en) * | 2019-05-05 | 2019-07-23 | 蚌埠创特新材料科技有限公司 | A kind of corrosion-resistant and high-temperature resistant oil sump seal rubber material |
CN110229526A (en) * | 2019-06-20 | 2019-09-13 | 苏州金枪新材料股份有限公司 | A kind of refractory ceramics SiClx rubber and the preparation method and application thereof |
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CN102585484A (en) * | 2011-12-30 | 2012-07-18 | 合肥市石川工程机械有限公司 | Rubber material for prestressing jack sealing ring and preparation method for rubber material |
CN103408879A (en) * | 2013-07-01 | 2013-11-27 | 芜湖市银鸿液压件有限公司 | Multi-element high polymer material composite hydraulic sealing ring and preparation method thereof |
CN103408943A (en) * | 2013-07-01 | 2013-11-27 | 芜湖市银鸿液压件有限公司 | Silicon rubber sealing ring for hydraulic braking system of automobile, and preparation method thereof |
CN103665499A (en) * | 2013-11-15 | 2014-03-26 | 蚌埠赛英电子科技发展有限公司 | Rubber-synthesized sealing gasket material and preparation method thereof |
CN104277250A (en) * | 2014-05-26 | 2015-01-14 | 安徽宁国尚鼎橡塑制品有限公司 | Preparation process of rubber material for seal ring of automobile |
CN105733052A (en) * | 2016-04-25 | 2016-07-06 | 铜陵百锐设备配件有限公司 | Rubber seal ring |
CN105860527A (en) * | 2016-04-13 | 2016-08-17 | 吴申龙 | Wear-resistant mechanical sealing ring compound rubber material and preparation technology thereof |
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2016
- 2016-08-31 CN CN201610795087.5A patent/CN106167560A/en active Pending
Patent Citations (7)
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CN102585484A (en) * | 2011-12-30 | 2012-07-18 | 合肥市石川工程机械有限公司 | Rubber material for prestressing jack sealing ring and preparation method for rubber material |
CN103408879A (en) * | 2013-07-01 | 2013-11-27 | 芜湖市银鸿液压件有限公司 | Multi-element high polymer material composite hydraulic sealing ring and preparation method thereof |
CN103408943A (en) * | 2013-07-01 | 2013-11-27 | 芜湖市银鸿液压件有限公司 | Silicon rubber sealing ring for hydraulic braking system of automobile, and preparation method thereof |
CN103665499A (en) * | 2013-11-15 | 2014-03-26 | 蚌埠赛英电子科技发展有限公司 | Rubber-synthesized sealing gasket material and preparation method thereof |
CN104277250A (en) * | 2014-05-26 | 2015-01-14 | 安徽宁国尚鼎橡塑制品有限公司 | Preparation process of rubber material for seal ring of automobile |
CN105860527A (en) * | 2016-04-13 | 2016-08-17 | 吴申龙 | Wear-resistant mechanical sealing ring compound rubber material and preparation technology thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107033402A (en) * | 2017-05-10 | 2017-08-11 | 广西桂山特种橡胶制品有限公司 | A kind of RUBBER O type sealing ring and preparation method thereof |
CN108752678A (en) * | 2018-05-29 | 2018-11-06 | 宁国中辰密封件有限公司 | A kind of preparation method of high intensity caliper sealing element |
CN110041574A (en) * | 2019-05-05 | 2019-07-23 | 蚌埠创特新材料科技有限公司 | A kind of corrosion-resistant and high-temperature resistant oil sump seal rubber material |
CN110229526A (en) * | 2019-06-20 | 2019-09-13 | 苏州金枪新材料股份有限公司 | A kind of refractory ceramics SiClx rubber and the preparation method and application thereof |
CN110229526B (en) * | 2019-06-20 | 2021-08-17 | 苏州金枪新材料股份有限公司 | High-temperature-resistant ceramic silicone rubber and preparation method and application thereof |
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Application publication date: 20161130 |