CN106167560A - A kind of automobile oil-resistant seal ring and preparation method thereof - Google Patents

A kind of automobile oil-resistant seal ring and preparation method thereof Download PDF

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Publication number
CN106167560A
CN106167560A CN201610795087.5A CN201610795087A CN106167560A CN 106167560 A CN106167560 A CN 106167560A CN 201610795087 A CN201610795087 A CN 201610795087A CN 106167560 A CN106167560 A CN 106167560A
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CN
China
Prior art keywords
parts
seal ring
resistant seal
raw material
automobile oil
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610795087.5A
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Chinese (zh)
Inventor
孙宝林
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ANHUI MEIXIANG INDUSTRIAL Co Ltd
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ANHUI MEIXIANG INDUSTRIAL Co Ltd
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Application filed by ANHUI MEIXIANG INDUSTRIAL Co Ltd filed Critical ANHUI MEIXIANG INDUSTRIAL Co Ltd
Priority to CN201610795087.5A priority Critical patent/CN106167560A/en
Publication of CN106167560A publication Critical patent/CN106167560A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L7/00Compositions of natural rubber
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Sealing Material Composition (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to a kind of automobile oil-resistant seal ring and preparation method thereof, be made up of the raw material of following weight portion: natural rubber 70 85 parts, 35 40 parts of silicone rubber, bamboo carbon fiber 25 32 parts, zinc oxide 12 18 parts, Firebrake ZB 7 13 parts, wollastonite in powder 12 16 parts, 15 19 parts of magnesium hydroxide, white carbon black 20 27 parts, silica 18 23 parts, accelerator 5 10 parts, 36 parts of age resistor, vulcanizing agent 25 parts, paraffin oil 58 parts;The present invention, by adding bamboo carbon fiber, strengthens the adsorptivity of sealing ring, absorption abnormal flavour and harmful gas;Adding magnesium hydroxide, wollastonite in powder and Firebrake ZB is filler, improves the acid-alkali-corrosive-resisting of sealing ring, oil resistivity and wearability;The acicular texture that wollastonite in powder is special, improves the mechanical property of sealing ring, such as hot strength;Add white carbon black by with other filler synergism, further increase wearability and the intensity of sealing ring.

Description

A kind of automobile oil-resistant seal ring and preparation method thereof
Technical field
The present invention relates to rubber composite processing technique field, be specifically related to a kind of automobile oil-resistant seal ring and system thereof Preparation Method.
Background technology
Sealing ring is a kind of common element preventing the effects such as the leakage of gas, liquid or foreign object intrusion, seals loop material The selection of material has significant impact to its sealing property and service life.The performance of material directly affects the usability of sealing ring Energy.Sealing ring may apply to multiple field, such as on auto parts and components.In order to strengthen sealing, the hose end of air conditioning for automobiles Head is often socketed with sealing ring, and owing to there being more greasy dirt inside air conditioning for automobiles, therefore sealing ring is easily corroded, meanwhile, Gas that flexible pipe within air-conditioning often delivery temperature is higher or liquid, sealing ring after being heated readily volatilized go out abnormal flavour and harmful Gas, these gases can lead in driver's cabin with pipeline, human body is produced bigger harm.
Summary of the invention
In order to overcome the deficiencies in the prior art, the present invention provides a kind of corrosion-resistant, high temperature resistant and oil resistant automobile to seal Circle and preparation method thereof.
In order to realize the purpose of the present invention, adopt the following technical scheme that
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, it is made up of the raw material of following weight portion:
Preferably, 300 mesh standard sieves crossed by wollastonite in powder.
Further, the preparation method of a kind of automobile oil-resistant seal ring, comprise the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 95-105 DEG C, mixing 8-12min, then rise Temperature, to 120-135 DEG C, adds remaining remaining raw material, mixing 30-50min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 220-240 DEG C, Cure time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Beneficial effects of the present invention:
The present invention, with natural rubber, silicone rubber as rubber raw materials, by adding bamboo carbon fiber, strengthens the absorption of sealing ring Property, absorption abnormal flavour and harmful gas;Adding magnesium hydroxide, wollastonite in powder and Firebrake ZB is filler, improves the acidproof of sealing ring Caustic corrosion, oil resistivity and wearability;The acicular texture that wollastonite in powder is special, improves the mechanical property of sealing ring, such as stretching Intensity;Add white carbon black by with other filler synergism, further increase wearability and the intensity of sealing ring;The present invention Sealing ring oil resistivity and wearability strong, there is resistance to elevated temperatures, do not soften under high temperature, service life is long.
Detailed description of the invention
Elaborating embodiments of the invention below, the present embodiment is carried out under premised on technical solution of the present invention Implement, give detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following enforcement Example.
Embodiment 1
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 70 parts, 35 parts of silicone rubber, Bamboo carbon fiber 25 parts, zinc oxide 12 parts, Firebrake ZB 7 parts, wollastonite in powder 12 parts, 15 parts of magnesium hydroxide, white carbon black 20 parts, silicon dioxide 18 parts, accelerator 5 parts, 3 parts of age resistor, vulcanizing agent 2 parts, paraffin oil 5 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 95 DEG C, mixing 12min, then heat to 120 DEG C, add remaining remaining raw material, mixing 50min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 220 DEG C, sulfuration Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Embodiment 2
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 85 parts, 40 parts of silicone rubber, Bamboo carbon fiber 32 parts, zinc oxide 18 parts, Firebrake ZB 13 parts, wollastonite in powder 16 parts, 19 parts of magnesium hydroxide, white carbon black 27 parts, titanium dioxide Silicon 23 parts, accelerator 10 parts, 6 parts of age resistor, vulcanizing agent 5 parts, paraffin oil 8 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 105 DEG C, mixing 8min, then heat to 135 DEG C, add remaining remaining raw material, mixing 30min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 240 DEG C, sulfuration Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Embodiment 3
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 75 parts, 37 parts of silicone rubber, Bamboo carbon fiber 28 parts, zinc oxide 15 parts, Firebrake ZB 9 parts, wollastonite in powder 14 parts, 17 parts of magnesium hydroxide, white carbon black 23 parts, silicon dioxide 20 parts, accelerator 7 parts, 5 parts of age resistor, vulcanizing agent 4 parts, paraffin oil 6 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 100 DEG C, mixing 10min, then heat to 130 DEG C, add remaining remaining raw material, mixing 40min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 230 DEG C, sulfuration Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
Embodiment 4
A kind of automobile oil-resistant seal ring, is made up of the raw material of following weight portion: natural rubber 80 parts, 38 parts of silicone rubber, Bamboo carbon fiber 30 parts, zinc oxide 16 parts, Firebrake ZB 12 parts, wollastonite in powder 14 parts, 17 parts of magnesium hydroxide, white carbon black 25 parts, titanium dioxide Silicon 20 parts, accelerator 8 parts, 5 parts of age resistor, vulcanizing agent 4 parts, paraffin oil 6 parts;Wherein, 300 mesh standard sieves crossed by wollastonite in powder.
The preparation method of a kind of automobile oil-resistant seal ring, comprises the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 105 DEG C, mixing 10min, then heat to 125 DEG C, add remaining remaining raw material, mixing 45min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 235 DEG C, sulfuration Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all essences in the present invention Any amendment, equivalent and the improvement etc. made within god and principle, should be included within the scope of the present invention.

Claims (5)

1. an automobile oil-resistant seal ring, it is characterised in that be made up of the raw material of following weight portion:
A kind of automobile oil-resistant seal ring the most according to claim 1, it is characterised in that by the raw material group of following weight portion Become:
A kind of automobile oil-resistant seal ring the most according to claim 1, it is characterised in that by the raw material group of following weight portion Become:
A kind of automobile oil-resistant seal ring the most according to claim 1, it is characterised in that it is accurate that 300 targets crossed by wollastonite in powder Sieve.
5. the preparation method of an automobile oil-resistant seal ring, it is characterised in that comprise the following steps:
(1) each raw material of corresponding weight portion is weighed respectively;
(2) natural rubber and silicone rubber are joined in banbury, be heated to 95-105 DEG C, mixing 8-12min, then heat to 120-135 DEG C, add remaining remaining raw material, mixing 30-50min;
(3) glue stuff compounding prepared by step (2) is carried out mill molding by mill;
(4) being placed in the mould of vulcanizing equipment by the sizing material after step (3) molding, curing temperature is 220-240 DEG C, sulfuration Time is 5min;Then the demoulding is carried out;
(5) product after step (4) being vulcanized carries out deburring, prepares satisfactory oil-resistant seal ring.
CN201610795087.5A 2016-08-31 2016-08-31 A kind of automobile oil-resistant seal ring and preparation method thereof Pending CN106167560A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610795087.5A CN106167560A (en) 2016-08-31 2016-08-31 A kind of automobile oil-resistant seal ring and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201610795087.5A CN106167560A (en) 2016-08-31 2016-08-31 A kind of automobile oil-resistant seal ring and preparation method thereof

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107033402A (en) * 2017-05-10 2017-08-11 广西桂山特种橡胶制品有限公司 A kind of RUBBER O type sealing ring and preparation method thereof
CN108752678A (en) * 2018-05-29 2018-11-06 宁国中辰密封件有限公司 A kind of preparation method of high intensity caliper sealing element
CN110041574A (en) * 2019-05-05 2019-07-23 蚌埠创特新材料科技有限公司 A kind of corrosion-resistant and high-temperature resistant oil sump seal rubber material
CN110229526A (en) * 2019-06-20 2019-09-13 苏州金枪新材料股份有限公司 A kind of refractory ceramics SiClx rubber and the preparation method and application thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585484A (en) * 2011-12-30 2012-07-18 合肥市石川工程机械有限公司 Rubber material for prestressing jack sealing ring and preparation method for rubber material
CN103408879A (en) * 2013-07-01 2013-11-27 芜湖市银鸿液压件有限公司 Multi-element high polymer material composite hydraulic sealing ring and preparation method thereof
CN103408943A (en) * 2013-07-01 2013-11-27 芜湖市银鸿液压件有限公司 Silicon rubber sealing ring for hydraulic braking system of automobile, and preparation method thereof
CN103665499A (en) * 2013-11-15 2014-03-26 蚌埠赛英电子科技发展有限公司 Rubber-synthesized sealing gasket material and preparation method thereof
CN104277250A (en) * 2014-05-26 2015-01-14 安徽宁国尚鼎橡塑制品有限公司 Preparation process of rubber material for seal ring of automobile
CN105733052A (en) * 2016-04-25 2016-07-06 铜陵百锐设备配件有限公司 Rubber seal ring
CN105860527A (en) * 2016-04-13 2016-08-17 吴申龙 Wear-resistant mechanical sealing ring compound rubber material and preparation technology thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102585484A (en) * 2011-12-30 2012-07-18 合肥市石川工程机械有限公司 Rubber material for prestressing jack sealing ring and preparation method for rubber material
CN103408879A (en) * 2013-07-01 2013-11-27 芜湖市银鸿液压件有限公司 Multi-element high polymer material composite hydraulic sealing ring and preparation method thereof
CN103408943A (en) * 2013-07-01 2013-11-27 芜湖市银鸿液压件有限公司 Silicon rubber sealing ring for hydraulic braking system of automobile, and preparation method thereof
CN103665499A (en) * 2013-11-15 2014-03-26 蚌埠赛英电子科技发展有限公司 Rubber-synthesized sealing gasket material and preparation method thereof
CN104277250A (en) * 2014-05-26 2015-01-14 安徽宁国尚鼎橡塑制品有限公司 Preparation process of rubber material for seal ring of automobile
CN105860527A (en) * 2016-04-13 2016-08-17 吴申龙 Wear-resistant mechanical sealing ring compound rubber material and preparation technology thereof
CN105733052A (en) * 2016-04-25 2016-07-06 铜陵百锐设备配件有限公司 Rubber seal ring

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107033402A (en) * 2017-05-10 2017-08-11 广西桂山特种橡胶制品有限公司 A kind of RUBBER O type sealing ring and preparation method thereof
CN108752678A (en) * 2018-05-29 2018-11-06 宁国中辰密封件有限公司 A kind of preparation method of high intensity caliper sealing element
CN110041574A (en) * 2019-05-05 2019-07-23 蚌埠创特新材料科技有限公司 A kind of corrosion-resistant and high-temperature resistant oil sump seal rubber material
CN110229526A (en) * 2019-06-20 2019-09-13 苏州金枪新材料股份有限公司 A kind of refractory ceramics SiClx rubber and the preparation method and application thereof
CN110229526B (en) * 2019-06-20 2021-08-17 苏州金枪新材料股份有限公司 High-temperature-resistant ceramic silicone rubber and preparation method and application thereof

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Application publication date: 20161130