CN106165692A - Compound insecticidal liquid preparation containing spiral shell worm ethyl ester - Google Patents
Compound insecticidal liquid preparation containing spiral shell worm ethyl ester Download PDFInfo
- Publication number
- CN106165692A CN106165692A CN201610584686.2A CN201610584686A CN106165692A CN 106165692 A CN106165692 A CN 106165692A CN 201610584686 A CN201610584686 A CN 201610584686A CN 106165692 A CN106165692 A CN 106165692A
- Authority
- CN
- China
- Prior art keywords
- ethyl ester
- liquid preparation
- spiral shell
- shell worm
- worm ethyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom
- A01N47/06—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having no bond to a nitrogen atom containing —O—CO—O— groups; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
Abstract
The invention discloses a kind of compound insecticidal liquid preparation containing spiral shell worm ethyl ester.This liquid preparation is made up of with green solvent effective ingredient spiral shell worm ethyl ester and chlopyrifos or Acetamiprid and surfactant, containing pesticide activity component 20%-50%, surfactant 5%-25% by percentage to the quality, surplus is patent green solvent 5 dimethylamino 2 methyl 5 oxopentanoic.Said composition is processed into cream, soluble concentrate or ultra low volume liquids by known method, and environmental safety is high, has outstanding quick-acting and lasting effect to scale insect, and prevention effect highlights, and can significantly reduce drug cost.
Description
Technical field
The present invention relates to a kind of compound insecticidal liquid preparation containing spiral shell worm ethyl ester, belong to technical field of pesticide preparations.
Background technology
Currently, along with China's economy is fast-developing with agricultural, living standards of the people significantly increase, the fruit tree of high added value
And Horticultural crops area increases substantially, pest and disease damage is caused to occur increasingly severe.Scale insect as the most important a kind of insect,
Because having valuable information for systematic on its polypide, general medicament is difficult to penetrate so that it is become a great problem of current Pest control.Along with
The disabling of methidathion, the leading pesticide control of current scale insect, based on chlopyrifos, Buprofezin etc., has produced obvious Drug resistance；
And absorption is outstanding but quick-acting is poor in Acetamiprid, market is based on complex preparation product.
Spiral shell worm ethyl ester is a kind of tetronic acid insecticides that Bayer is newly developed, has Bidirectional Conduction function, has scale insect
There is a most outstanding prevention effect, but it is easily generated Drug resistance and expensive.Therefore, by spiral shell worm ethyl ester and chlopyrifos or pyridine worm
Amidine develops into compounded pesticides becomes patent application emphasis, as patent CN102484995A (publication date on June 6th, 2012) is applied for
Spiral shell worm ethyl ester and Acetamiprid compositions, CN104255781A (publication date on January 7th, 2015) apllied spiral shell worm ethyl ester and poison
Involved spiral shell worm ethyl ester and the suspension emulsion of chlopyrifos in dead Ticks and CN102475092B (publication date on May 30th, 2012),
The above patent has all been proved spiral shell worm ethyl ester and has compounded exploitation with chlopyrifos or Acetamiprid is potentiation, answers scale insect is actual
With being worth height.In production application, spiral shell worm ethyl ester generally adds oiliness auxiliary agent when scale insect is prevented and treated, anti-to promote it
Control effect.
Owing to scale insect polypide covers coating of wax matter, contained by the liquid preparation such as cream, soluble concentrate and ultra low volume liquids
Some solvents have the effects such as molten wax, closing, for the most preferred dosage form of scale insect preventing and treating.But, along with " emulsifiable concentrates for agricultural chemicals being harmful to molten
Agent is limited the quantity " (HG/T 4576-2013) industry standard formally implemented in 1 day March in 2014 and " insecticides adjuvant limits and uses name
Singly " the issue of exposure draft, liquid preparation is faced with the problem that organic solvent limits, and with turpentine-based vegetable oil as representative
Botanical solvent there is the problem of matching degree, drug compound dissolubility former to part is too low.Therefore, develop alternative poisonous
The high-dissolvability of hazardous solvent, environmental protection, green solvent are very urgent.
Spiral shell worm ethyl ester causes spiral shell worm ethyl ester content less than 10% thus to affect because its dissolubility in ordinary organic solvents is low
Prevention effect, and organic solvent as high in the dissolubility such as dimethyl acetylamide, dimethyl sulfoxide the most banned/limit the use of, develop into liquid
The problem that body preparation is faced with solvent matching.
The present invention is contemplated to solve the exploitation compounding with chlopyrifos or Acetamiprid of current scale insect pesticide control spiral shell worm ethyl ester
The problem being difficult to present in process develop into environmental protection green liquid preparation.At present, there is not yet spiral shell worm ethyl ester and chlopyrifos or
Acetamiprid develops into the relevant report of liquid preparation.
Summary of the invention
It is an object of the invention to provide a kind of compound insecticidal liquid containing spiral shell worm ethyl ester that can be used for preventing and treating scale insect
Preparation, solves spiral shell worm ethyl ester and develops into the Solvent faced in liquid preparation, thus promote scale insect prevention effect further,
Reduce the use of poisonous and harmful solvent.
Inventor is found by a large amount of screening tests, using 5-dimethylamino-2-methyl-5 oxopentanoic as solvent
The solvent select permeability faced when spiral shell worm ethyl ester develops into liquid preparation with chlopyrifos or Acetamiprid can be solved.Relative to other
Green solvent, this solvent is high to spiral shell worm ethyl ester dissolubility, and design parameter see table 1:
Table 1 5-dimethylamino-2-methyl-5 oxopentanoic and main green solvent parameter comparison
The technical scheme is that:
A kind of compound insecticidal liquid preparation containing spiral shell worm ethyl ester, it is characterised in that contain following group by percentage to the quality
Part:
The present invention is all right:
Described chlopyrifos or Acetamiprid mass percent are 20%-30%.
Described surfactant gathers selected from fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, alkylphenol-polyethenoxy
Oxypropylene ether, aliphatic amine polyoxyethylene ether, castor oil polyoxyethylene ether, alkyl phenol formaldehyde resin polyoxyethylene ether, polyoxyethylene
One or more combination in polyoxypropylene block copolymers, alkylbenzenesulfonate and alkyl phosphate salt.
Described liquid preparation is cream, soluble concentrate or ultra low volume liquids.
Described liquid preparation is for preventing and treating the purposes of scale insect.
Compared with prior art, have the beneficial effect that produced by the present invention
1) comparing other dosage form, liquid preparation involved in the present invention is more preferable to scale insect prevention effect.
2) liquid preparation developed does not contains poisonous hazardous solvent, safety and environmental protection.
3) liquid preparation boiling point, the flash-point developed are high, have anti-drift film property and the low volatility of excellence, can significantly subtract
Few dosage, reduces cost, alleviates the impact on environment.
4) liquid preparation developed can play two-way systemic action specific to spiral shell worm ethyl ester to greatest extent, significantly carries
Rise infiltration and the absorbability of medicine, while improving drug effect, reduce cost accounting.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but the scope of protection of present invention is not limited to reality
Execute the scope of example statement.
Effective ingredient: the former medicine of spiral shell worm ethyl ester (Bayer Bitterfeld GmbH crop science company, the former medicine of chlopyrifos (Zhejiang new agrochemicals stock
Part company limited), the former medicine of Acetamiprid (Jiangsu Chang Long agrochemical company limited), 5-dimethylamino-2-methyl-5-oxopentanoic
(Solvay).
Embodiment 1:
Chlopyrifos 30%, spiral shell worm ethyl ester 15%, alkylphenol-polyethenoxy polyethenoxy ether 8%, alkylphenol-formaldehyde resin gathers
Oxygen vinyl Ether 3%, alkylbenzenesulfonate 5%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is thrown
Enter in mixing kettle, then put into solvent dissolve after, finally put into surfactant, after stirring prepare 45% chlopyrifos spiral shell worm
Ethyl ester cream.
Chlopyrifos is changed into Acetamiprid and can form new embodiment.
Embodiment 2:
Chlopyrifos 20%, spiral shell worm ethyl ester 20%, fatty alcohol-polyoxyethylene ether 7%, castor oil polyoxyethylene ether 3%, alkyl
Benzene sulfonate 4%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is put in mixing kettle, then throw
After entering solvent dissolving, finally put into surfactant, after stirring, prepare 40% chlopyrifos spiral shell worm ethyl ester cream.
Chlopyrifos is changed into Acetamiprid and can form new embodiment.
Embodiment 3:
Chlopyrifos 30%, spiral shell worm ethyl ester 10%, polyoxyethylene polyoxypropylene block copolymer 7%, alkylbenzenesulfonate
5%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is put in mixing kettle, then it is molten to put into solvent
Xie Hou, finally puts into surfactant, prepares 40% chlopyrifos spiral shell worm ethyl ester cream after stirring.
Chlopyrifos is changed into Acetamiprid and can form new embodiment.
Embodiment 4:
Chlopyrifos 20%, spiral shell worm ethyl ester 10%, polyoxyethylene polyoxypropylene block copolymer 10%, alkylphenol-formaldehyde resin
Polyoxyethylene ether 15%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is put in mixing kettle, then
After putting into solvent dissolving, finally put into surfactant, after stirring, prepare 30% chlopyrifos spiral shell worm ethyl ester soluble concentrate.
Chlopyrifos is changed into Acetamiprid and can form new embodiment.
Embodiment 5:
Chlopyrifos 10%, spiral shell worm ethyl ester 20%, aliphatic amine polyoxyethylene ether 9%, alkyl phenol formaldehyde resin polyoxyethylene ether
10%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is put in mixing kettle, then it is molten to put into solvent
Xie Hou, finally puts into surfactant, synergist, prepares 30% chlopyrifos spiral shell worm ethyl ester soluble concentrate after stirring.
Chlopyrifos is changed into Acetamiprid and can form new embodiment
Embodiment 6:
Chlopyrifos 10%, spiral shell worm ethyl ester 10%, aliphatic amine polyoxyethylene ether 8%, polyoxyethylene polyoxypropylene block copolymerization
Thing 12%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is put in mixing kettle, then put into solvent
After dissolving, finally put into surfactant, after stirring, prepare 20% chlopyrifos spiral shell worm ethyl ester soluble concentrate.
Chlopyrifos is changed into Acetamiprid and can form new embodiment
Embodiment 7:
Chlopyrifos 15%, spiral shell worm ethyl ester 15%, alkyl phosphate salt 2%, polyoxyethylene polyoxypropylene block copolymer
3%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is put in mixing kettle, then it is molten to put into solvent
Xie Hou, finally puts into surfactant, prepares 30% chlopyrifos spiral shell worm ethyl ester ultra low volume liquids after stirring.
Chlopyrifos is changed into Acetamiprid and can form new embodiment.
Embodiment 8:
Chlopyrifos 30%, spiral shell worm ethyl ester 10%, castor oil polyoxyethylene ether 5%, alkyl phenol formaldehyde resin polyoxyethylene ether
4%, surplus is 5-dimethylamino-2-methyl-5-oxopentanoic.First former medicine is put in mixing kettle, then it is molten to put into solvent
Xie Hou, finally puts into surfactant, prepares 40% chlopyrifos spiral shell worm ethyl ester ultra low volume liquids after stirring.
Chlopyrifos is changed into Acetamiprid and can form new embodiment.
For further illustrating the advantage of technical solution of the present invention, present invention field control effectiveness test embodiment in detail below is entered
Row illustrates.
Spiral shell worm ethyl ester, chlopyrifos and the complex composition field control effectiveness test to honey Fructus Citri grandis scale insect
Testing and carry out in Mi You base, Pinghe County, Zhangzhou City of Fujian Province in May, 2015, experimental field on honey Fructus Citri grandis, brown circle Jie sends out
Raw heavier.Test process, using dosage and preventive effect refer to table 2, prepare related agents by experimental concentration, often process and set 4 weights
Multiple, every repeat spraying 1 strain honey Fructus Citri grandis, random district group arranges.15,30 days investigation shell borer populations before medicine, after medicine.
Table 2 spiral shell worm ethyl ester, chlopyrifos and the complex composition prevention effect to honey Fructus Citri grandis scale insect
As shown in Table 2, relative to two comparison medicaments, embodiment involved in the present invention has more preferable quick-acting and holds
Effect property, more excellent to the prevention effect of scale insect, wherein embodiment 3,8 is put up the best performance, and after medicine, preventing and treating in 15,30 days is best, reaches respectively
To 88%, more than 97%.
Claims (5)
1. the compound insecticidal liquid preparation containing spiral shell worm ethyl ester, it is characterised in that contain following group by percentage to the quality
Part:
。
Liquid preparation the most according to claim 1, it is characterised in that chlopyrifos or Acetamiprid mass percent are 20%-
30%.
Liquid preparation the most according to claim 1, it is characterised in that surfactant is selected from fatty alcohol-polyoxyethylene ether, alkane
Base phenol polyethenoxy ether, alkylphenol-polyethenoxy polyethenoxy ether, aliphatic amine polyoxyethylene ether, castor oil polyoxyethylene ether, alkane
Base fluosite polyoxyethylene ether, polyoxyethylene polyoxypropylene block copolymer, alkylbenzenesulfonate and alkyl phosphate salt
In one or more combination.
Liquid preparation the most according to claim 1, it is characterised in that liquid preparation is cream, soluble concentrate or ultra-low volume
Liquor.
5. the compound insecticidal liquid preparation containing spiral shell worm ethyl ester described in claim 1 is for preventing and treating the purposes of scale insect.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610584686.2A CN106165692A (en) | 2016-07-22 | 2016-07-22 | Compound insecticidal liquid preparation containing spiral shell worm ethyl ester |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610584686.2A CN106165692A (en) | 2016-07-22 | 2016-07-22 | Compound insecticidal liquid preparation containing spiral shell worm ethyl ester |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106165692A true CN106165692A (en) | 2016-11-30 |
Family
ID=58066291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610584686.2A Pending CN106165692A (en) | 2016-07-22 | 2016-07-22 | Compound insecticidal liquid preparation containing spiral shell worm ethyl ester |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106165692A (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101945575A (en) * | 2008-01-25 | 2011-01-12 | 罗地亚管理公司 | Use of ester amides as solvents, ester amides as such, and method for preparing ester amides |
| CN102475092A (en) * | 2010-11-29 | 2012-05-30 | 浙江新农化工股份有限公司 | Compounded insecticidal suspension emulsion with chlorpyrifos and spirotetramat and preparation method of compounded insecticidal suspension emulsion |
| CN102484995A (en) * | 2010-12-01 | 2012-06-06 | 联保作物科技有限公司 | Insecticidal composition and preparation thereof |
-
2016
- 2016-07-22 CN CN201610584686.2A patent/CN106165692A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101945575A (en) * | 2008-01-25 | 2011-01-12 | 罗地亚管理公司 | Use of ester amides as solvents, ester amides as such, and method for preparing ester amides |
| CN102475092A (en) * | 2010-11-29 | 2012-05-30 | 浙江新农化工股份有限公司 | Compounded insecticidal suspension emulsion with chlorpyrifos and spirotetramat and preparation method of compounded insecticidal suspension emulsion |
| CN102484995A (en) * | 2010-12-01 | 2012-06-06 | 联保作物科技有限公司 | Insecticidal composition and preparation thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104115845B (en) | A kind of high-efficient pesticide composition containing fluorobenzene insect amide | |
| CN104488998A (en) | Synergistic compound hicide caphidicide containing sophocarpidine and preparation method of synergistic compound hicide caphidicide | |
| CN110037014B (en) | Compound synergist containing lecithin and D-limonene and preparation method and application thereof | |
| CN104542690B (en) | A kind of gamma cyhalothrin breast granule, its preparation method and application thereof | |
| CN101843268B (en) | Botanical synergistic compound aphicide and preparation method thereof | |
| CN105707118B (en) | A kind of composition pesticide containing phosmet and Bifenazate | |
| CN106165692A (en) | Compound insecticidal liquid preparation containing spiral shell worm ethyl ester | |
| CN107926955B (en) | Mixed emulsifiable concentrate containing triclopyr ester and picloram | |
| CN104585245A (en) | Compound molluscicide | |
| CN104286010B (en) | Composition pesticide containing sulfur-phosphor and Bifenazate | |
| CN103444763A (en) | Composite pesticide containing E imidacloprid guanidine | |
| CN105230637A (en) | Herbicidal emulsifiable concentrate containing trifludimoxazin and terbuthylazine | |
| CN105475339B (en) | A kind of Synergistic insecticidal compositions and its application containing propargite and cycloprothrin | |
| CN104585179B (en) | A kind of Synergistic mite killing composition containing tebufenpyrad and spirodiclofen | |
| CN104920413B (en) | A kind of Quizalotop-ethyl, nicosulfuron and atrazine composite environment-friendly type missible oil | |
| CN107136092A (en) | A kind of herbicidal composition | |
| CN1347641A (en) | Herbicide specially for ginger and garlic field | |
| CN103651544A (en) | Acaricidal composition of profenofos and etoxazole and formula instance | |
| CN108835126A (en) | A kind of agricultural insecticidal composite and its application containing nicotine compound and mineral oil | |
| CN107232227A (en) | A kind of AVM hereinafter triazophos compound pesticide and preparation method thereof | |
| CN108013047A (en) | A kind of herbicidal composition containing caprylic acid and Quizalotop-ethyl and its application | |
| CN105557760A (en) | Synergistic insecticidal composition containing propargite and tetranactin, and application thereof | |
| CN107006471B (en) | The compound pesticide compositions and application thereof of containing chromafenozide and methoxyfenozide | |
| WO2008148178A1 (en) | Fungicide composition and process for treating agronomical cultures | |
| CN106417351A (en) | Pesticide composition containing lambda-cyfluthrin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20170922 Address after: Cangshan District of Fuzhou City, Fujian province 350000 to build a new town, Orangerie Chau Industrial Park 18-19 building warehouse garden Mountain Park B3015 zero to one Applicant after: Xinnong Dazheng Biological Engineering Co., Ltd., Fujian Address before: 518102 Xixiang Reservoir Road, Shenzhen, Guangdong, No. 113, No. Applicant before: Nuopuxin Agricultural Chemical Co., Ltd., Shenzhen |
|
| TA01 | Transfer of patent application right | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20161130 |
|
| RJ01 | Rejection of invention patent application after publication |