CN106147488A - High-temperature resistant water transfer coating composition and preparation method thereof - Google Patents
High-temperature resistant water transfer coating composition and preparation method thereof Download PDFInfo
- Publication number
- CN106147488A CN106147488A CN201610607770.1A CN201610607770A CN106147488A CN 106147488 A CN106147488 A CN 106147488A CN 201610607770 A CN201610607770 A CN 201610607770A CN 106147488 A CN106147488 A CN 106147488A
- Authority
- CN
- China
- Prior art keywords
- coating composition
- temperature resistant
- water transfer
- resistant water
- transfer coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/08—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of high-temperature resistant water transfer coating composition and preparation method thereof, this coating composition includes following component: polyfunctionality resin, polyacrylate type resin, solvent, common cross-linking agent, high-temperature activation crosslinking agent.This preparation method comprises the steps: to put into polyfunctionality resin, polyacrylate type resin, common cross-linking agent and high-temperature activation crosslinking agent successively to solvent, cures after mixing；After curing terminates, adjustment solid content, to 10～50%, stirs discharging, obtains described high-temperature resistant water transfer coating composition.The present invention has following beneficial effect: the 1st, the present invention uses two-part formulations, remains to keep preferable luster effect in rear road high-temperature baking technique；2nd, film forming is preferable, the problem that can largely avoid completely shifting in transfer process；3rd, the operation of rear road is higher to concavo-convex interface tolerance；4th, operating clearance can often walk wait, and production efficiency is greatly improved.
Description
Technical field
The present invention relates to a kind of high-temperature resistant water transfer coating composition and preparation method thereof, belong to technical field of coatings.
Background technology
Water transfer is to utilize hydraulic pressure that the colour transfer paper/plastic foil with special pattern is carried out the printing side of macromolecule hydrolysis
Method.Existing water transfer printing method mainly has Double-layer water transfer and the transfer of individual layer water.Double-layer water transfer be first pattern is printed on double
In the one side in layer water-transfer printing paper face, after parching, utilize offset press last layer finishing oil, or spray one layer of paint with spray gun, pass through
24h makes it parch；First bilayer transfer paper is separated into two-layer during use, retains figuratum copy paper, then at target product
The upper nitrate paint uniformly spraying layer of transparent, then stick counter for figuratum thin paper, use cloth to wipe with flat, then apply on paper surface. at once
Water, takes thin paper off, and pattern just turns up.And the transfer of individual layer water, be first pattern to be printed on water-transfer printing paper face, wait to parch into
Row serigraphy, then last layer face oil, parch, during use cut pattern, soaked inner a few minutes, peels off paper, scrapes
Go out the water between pattern and sample.
The whole process of two tier approach is required for waiting several minutes between often walking, and needs many people to coordinate, and is both needed to manual operations, speed
Slowly；Pattern Chang Wufa completely shifts, and has parts against wear, more cannot use on the product of male and fomale(M&F).And individual layer method cannot be made
Make large scale product, be also unusable on concavo-convex obvious product.Additionally, two kinds of methods are at some special requirement high-temperature bakings
Glass, ceramic baking process in, be all difficult to keep color and luster and effect.
Content of the invention
For defect of the prior art, it is an object of the invention to provide a kind of high-temperature resistant water transfer coating composition and
Preparation method.
The present invention is achieved by the following technical solutions:
The invention provides a kind of high-temperature resistant water transfer coating composition, it includes the following component counted by weight:
Preferably, the degree of functionality of described polyfunctionality resin is not less than 2.It is unable to reach crosslinked mesh less than this scope
's.
Preferably, described polyfunctionality resin is selected from polyurethane resin, acrylic resin, epoxy resin, chlorination
At least one in acrylic resin, vinylite, vinyl chloride-vinyl acetate resin, modified cellulose resinoid.
Preferably, described common cross-linking agent selected from aromatic polyamine, multi-anhydride, in silane coupler extremely
Few one.
Preferably, described high-temperature activation crosslinking agent is selected from 2, and 5-dimethyl-2,5-double (tert-butyl peroxide) is own
One or both in alkane (double 25), Triallyl isocyanurate (TAIC).
Preferably, described solvent is selected from butanone, and ethyl acetate, n-propyl acetate, n-butyl acetate, in toluene
At least one.
Second aspect, present invention also offers the preparation method of a kind of high-temperature resistant water as the aforementioned transfer coating composition,
It comprises the steps:
Polyfunctionality resin, polyacrylate type resin, common cross-linking agent and high-temperature activation crosslinking agent are put into successively to
In solvent, cure after mixing；
After curing terminates, adjustment solid content, to 10～50%, stirs discharging, obtains described high-temperature resistant water transfer coating group
Compound.
Compared with prior art, the present invention has a following beneficial effect:
1st, the high-temperature resistant water transfer coating composition of the present invention, remains to keep preferable light in rear road high-temperature baking technique
Pool effect；
2nd, film forming is preferable, the problem that can largely avoid completely shifting in transfer process；
3rd, the operation of rear road is higher to concavo-convex interface tolerance；
4th, operating clearance can often walk wait, and production efficiency is greatly improved.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail.Following example will assist in the technology of this area
Personnel are further appreciated by the present invention, but do not limit the present invention in any form.It should be pointed out that, the ordinary skill to this area
For personnel, without departing from the inventive concept of the premise, some deformation can also be made and improve.These broadly fall into the present invention
Protection domain.
Embodiment 1
High-temperature resistant water transfer coating composition that the present embodiment relates to and preparation method thereof, comprises the following steps that:
First, first by whole solvents, i.e. butanone 30 kilograms, stirring in 50 kilograms of input reactors of toluene；
2nd, it is kept stirring for and by polymethyl methacrylate 10 kilograms, acrylate-epoxy resin graft copolymer 10 is public
Jin puts in reactor successively, stirs about 1 hour；
3rd, to be mixed uniformly after by pyromellitic dianhydride 2 kilograms, 2,5-dimethyl-2,5-double (tert-butyl peroxide) oneself
Alkane (double 25) 0.5kg slowly puts in reactor；
4th, after all solids dissolves and mixes, curing more than 12 hours is shut down；
5th, measure solids content, and adjust to theoretical value；
6th, slowly stir about 1 hour again, cooling, weighing and bagging.
Embodiment 2
High-temperature resistant water transfer coating composition that the present embodiment relates to and preparation method thereof, comprises the following steps that:
First, first by whole solvents, i.e. n-propyl acetate 10 kilograms, stirring in 50 kilograms of input reactors of butanone；
2nd, it is kept stirring for and by methyl methacrylate-n-BMA copolymer 15 kilograms, organosilicon epoxy
Resin 20 kilograms puts in reactor successively, stirs about 2.5 hours；
3rd, to be mixed uniformly after pyromellitic dianhydride 0.2 kilogram, Triallyl isocyanurate (TAIC) 0.1kg are delayed
In slow input reactor；
4th, after all solids dissolves and mixes, curing more than 12 hours is shut down；
5th, measure solids content, and adjust to theoretical value；
6th, slowly stir about 2.5 hours again, cooling, weighing and bagging.
Embodiment 3
High-temperature resistant water transfer coating composition that the present embodiment relates to and preparation method thereof, comprises the following steps that:
First, first by whole solvents, i.e. butanone 45 kilograms, stirring in 5 kilograms of input reactors of n-butyl acetate；
2nd, it is kept stirring for and bisphenol-A epoxy resin 20 kilograms, methyl methacrylate 10 kilograms are put into successively
In reactor, stir about 0.5 hour；
3rd, to be mixed uniformly after isobutyl group triethoxysilicane 3 kilograms, Triallyl isocyanurate (TAIC) 5kg are delayed
In slow input reactor；
4th, after all solids dissolves and mixes, curing more than 12 hours is shut down；
5th, measure solids content, and adjust to theoretical value；
6th, slowly stir about 0.5 hour again, cooling, weighing and bagging.
Comparative example 1
This comparative example comprises the following steps that:
First, first by whole solvents, i.e. butanone 35 kilograms, stirring in 25 kilograms of input reactors of n-butyl acetate；
2nd, it is kept stirring for and methyl methacrylate 20 kilograms, polystyrene 10 kilograms are put in reactor successively, stirring
Mix about 0.5 hour；
3rd, after all solids dissolves and mixes, curing more than 12 hours is shut down；
4th, measure solids content, and adjust to theoretical value；
5th, slowly stir about 0.5 hour again, cooling, weighing and bagging.
Testing the folding quality of embodiment 1～3 and the product of comparative example 1 respectively, method of testing is:
Coating composition is diluted to the solid content of 20%, after using the wet coating amount bar of 6g to be coated on a pet film,
Dry.Folding the PET film after coating, observing film-formation result, the maximum folded number of times before record fragmentation is folding number.
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | |
| Film-formation result | Can film forming | Can film forming | Can film forming | Can film forming |
| Folding number | 8 | 5 | 10 | 1 |
As shown in table 1, from test result it is evident that the folding effect of embodiment significantly improves compared with comparative example, in transfer
During can largely avoid the problem that cannot completely shift, the operation of Qie Duihou road is also obvious to concavo-convex interface tolerance
Improve.
Above the specific embodiment of the present invention is described.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformation or modification, this not shadow within the scope of the claims
Ring the flesh and blood of the present invention.
Claims (7)
1. high-temperature resistant water transfer coating composition, it is characterised in that include the following component counted by weight:
2. high-temperature resistant water transfer coating composition as claimed in claim 1, it is characterised in that the official of described polyfunctionality resin
Energy degree is not less than 2.
3. high-temperature resistant water transfer coating composition as claimed in claim 1 or 2, it is characterised in that described polyfunctionality resin
Selected from polyurethane resin, acrylic resin, epoxy resin, chlorinated polypropylene, vinylite, vinyl chloride-vinyl acetate resin, modified fibre
At least one in dimension element resinoid.
4. high-temperature resistant water transfer coating composition as claimed in claim 1, it is characterised in that described common cross-linking agent is selected from virtue
At least one in fragrant race polyamine, multi-anhydride, silane coupler.
5. high-temperature resistant water transfer coating composition as claimed in claim 1, it is characterised in that described high-temperature activation crosslinking agent selects
One or both in double (tert-butyl peroxide) hexane of 2,5-dimethyl-2,5-, Triallyl isocyanurate.
6. high-temperature resistant water transfer coating composition as claimed in claim 1, it is characterised in that described solvent is selected from butanone, vinegar
Acetoacetic ester, n-propyl acetate, n-butyl acetate, at least one in toluene.
7. a preparation method for the high-temperature resistant water transfer coating composition as described in any one in claim 1～6, it is special
Levy and be, comprise the steps:
Put into polyfunctionality resin, polyacrylate type resin, common cross-linking agent and high-temperature activation crosslinking agent to solvent successively
In, cure after mixing；
After curing terminates, adjustment solid content, to 10～50%, stirs discharging, obtains described high-temperature resistant water transfer Coating material composition
Thing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610607770.1A CN106147488B (en) | 2016-07-28 | 2016-07-28 | High-temperature resistant water transfers coating composition and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610607770.1A CN106147488B (en) | 2016-07-28 | 2016-07-28 | High-temperature resistant water transfers coating composition and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106147488A true CN106147488A (en) | 2016-11-23 |
| CN106147488B CN106147488B (en) | 2018-08-03 |
Family
ID=58060302
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610607770.1A Active CN106147488B (en) | 2016-07-28 | 2016-07-28 | High-temperature resistant water transfers coating composition and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106147488B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108219644A (en) * | 2017-12-30 | 2018-06-29 | 东莞市宏成转印材料有限公司 | A kind of photocuring stiffened water transfer printing film and preparation method thereof |
| CN109385231A (en) * | 2017-08-04 | 2019-02-26 | 禹辉（上海）新材料科技股份有限公司 | A kind of thermal transfer glue for plate glass |
| CN111591056A (en) * | 2019-09-10 | 2020-08-28 | 深圳市麦棋科技有限公司 | Transfer printing film for water transfer printing technology and preparation method and application thereof |
| CN111591058A (en) * | 2019-09-10 | 2020-08-28 | 深圳市麦棋科技有限公司 | Reinforcing agent, preparation method thereof and water transfer printing method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724325A (en) * | 2009-12-14 | 2010-06-09 | 上海维凯化学品有限公司 | Radar aluminum plating transfer coating suitable for seamless molding process and preparation method thereof |
| CN102391747A (en) * | 2011-06-28 | 2012-03-28 | 北京高盟新材料股份有限公司 | Film-forming composition of seamless laser transfer coating and preparation method thereof |
-
2016
- 2016-07-28 CN CN201610607770.1A patent/CN106147488B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724325A (en) * | 2009-12-14 | 2010-06-09 | 上海维凯化学品有限公司 | Radar aluminum plating transfer coating suitable for seamless molding process and preparation method thereof |
| CN102391747A (en) * | 2011-06-28 | 2012-03-28 | 北京高盟新材料股份有限公司 | Film-forming composition of seamless laser transfer coating and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109385231A (en) * | 2017-08-04 | 2019-02-26 | 禹辉（上海）新材料科技股份有限公司 | A kind of thermal transfer glue for plate glass |
| CN108219644A (en) * | 2017-12-30 | 2018-06-29 | 东莞市宏成转印材料有限公司 | A kind of photocuring stiffened water transfer printing film and preparation method thereof |
| CN108219644B (en) * | 2017-12-30 | 2020-06-02 | 东莞市项华电子科技有限公司 | Photocuring and hardening water transfer film and preparation method thereof |
| CN111591056A (en) * | 2019-09-10 | 2020-08-28 | 深圳市麦棋科技有限公司 | Transfer printing film for water transfer printing technology and preparation method and application thereof |
| CN111591058A (en) * | 2019-09-10 | 2020-08-28 | 深圳市麦棋科技有限公司 | Reinforcing agent, preparation method thereof and water transfer printing method |
| CN111591056B (en) * | 2019-09-10 | 2021-12-31 | 深圳市麦棋科技有限公司 | Transfer printing film for water transfer printing technology and preparation method and application thereof |
| CN111591058B (en) * | 2019-09-10 | 2022-05-17 | 深圳市麦棋科技有限公司 | Reinforcing agent, preparation method thereof and water transfer printing method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106147488B (en) | 2018-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN106147488A (en) | High-temperature resistant water transfer coating composition and preparation method thereof | |
| CN108587426A (en) | A kind of anodized aluminium release printable aqueous transfer coating and preparation method thereof, application | |
| CN104073103A (en) | Thermal sublimation transferring-printing coating pulp and method for carrying out thermal sublimation transferring-printing by using same | |
| CN108059858A (en) | It is a kind of suitable for coloring coating of silver color alumite thermoprinting foil and preparation method thereof | |
| CN109722160B (en) | High-wear-resistance UV (ultraviolet) photocuring release layer applied to gold stamping material and preparation thereof | |
| CN100368625C (en) | Butyl acetate-polyvinyl alcohol copolymer emulsion color coating canvas and its producing process | |
| CN103194105A (en) | UV (Ultraviolet) gloss oil, high-gloss scrap-resisting decorative film prepared from same and preparation method of decorative film | |
| CN104497831A (en) | Crystallized coating | |
| CN106394047A (en) | Water transfer printing process | |
| CN105968942A (en) | LED-solidified water transfer printing ink and preparation method thereof | |
| CN107587358A (en) | A kind of frosted velvet breathing leather manufacture method | |
| CN106515248A (en) | Anti-scrawling heat transfer film for leathers and preparation method thereof | |
| CN105949844A (en) | High-solid low-viscosity laser alumite imaging layer coating and preparation method thereof | |
| CN105365425B (en) | Gold stamping transfer membrane process | |
| CN101570104A (en) | Easily stripped ceramic applique and processing technique thereof | |
| CN107365553A (en) | Thermal transfer PET film ultraviolet light cured varnish and preparation method thereof | |
| CN206157081U (en) | Can print from type membrane | |
| CN106046408A (en) | Printable release film and preparation method thereof | |
| CN102587157B (en) | High-emulation oil painting fabric printing process | |
| CN104723713A (en) | Simulated rubber transfer film and preparation method thereof | |
| CN106189487A (en) | A kind of water transfer inking front cover oil of LED solidification and preparation method thereof | |
| CN100368624C (en) | Art canvas with non-filler polyvinyl built coating and its production process | |
| CN206493723U (en) | A kind of pigment thermal transfer film for cloth | |
| CN105820727A (en) | Scratch-resistant PVC film and preparation method thereof | |
| CN105332318A (en) | Paste containing wax powder, manufacturing process thereof and application of paste in wallpaper |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |