CN101570104A - Easily stripped ceramic applique and processing technique thereof - Google Patents
Easily stripped ceramic applique and processing technique thereof Download PDFInfo
- Publication number
- CN101570104A CN101570104A CNA2009101073687A CN200910107368A CN101570104A CN 101570104 A CN101570104 A CN 101570104A CN A2009101073687 A CNA2009101073687 A CN A2009101073687A CN 200910107368 A CN200910107368 A CN 200910107368A CN 101570104 A CN101570104 A CN 101570104A
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- Prior art keywords
- applique
- easily stripped
- coating
- ink
- adhesive
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
- B44C1/17—Dry transfer
Landscapes
- Decoration By Transfer Pictures (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses an easily stripped ceramic applique, belonging to the technical field of silicate base material surface decaling, comprising a stripping support substrate, an applique coloring layer which is fixed at the support substrate and can be separated from the support substrate, and a transfer printing film layer; the stripping bearing substrate comprises base paper and a coating coated with silicone, fluorosilicate, polyethylene or polypropylene film, polyester or compound thereof; the transfer printing film layer comprises an ink layer and a sticky coating. The invention further discloses a processing technique of the easily stripped ceramic applique; moreover, the easily stripped ceramic applique ornament bearing base material can be stripped with ease, and paper can be reused, the technique is simple and the use is convenient.
Description
Technical field
The invention belongs to silicate base material surface applique technical field, especially design a kind of ceramic applique of easily peeling off and processing technology thereof.
Background technology
Silicate-base such as glass and pottery material products can be decorated by applique.The marble paper of this applique is made of flexible substrate and transferable shallow layer or thin layer usually.After at first the pattern decoration decorations sample of expecting being printed on the base stock of supporting, then print one deck cover layer, figure line decoration decorations sample can shift with transferable shallow layer or thin layer and be printed on pottery or glass article surface, fires then to obtain permanent adhesion figure line decoration decorations sample coating.
Realize the process of marble paper pattern bat printing to glass or ceramic comprised: at first will peel off pattern bearing bed (flexible substrate) and transferable shallow layer or thin layer, then transferable shallow layer or thin layer be placed the position of glass or ceramic expectation.
Some patents are described in detail the peelable marble paper of other type, the U.S.3 of Reed for example, 987,225 or the U.S.3 of Mackenzie, 212,913.Although described patent is described very in detail, the marble paper of this type is imprinted on the transparent plastic matrix, and its design is in order to finish the original design picture proof, is not to be used for final decoration.Reed etc. disclose the cellulose nitrate printing ink that how to use low film thickness (being generally 0.003 to 0.0005 inch) and low cohesive adhesive.Yet the hot strength of these marble papers does not still reach the hot strength of marble paper disclosed in this invention.
Keough etc. are at patent U.S.4, disclose a kind of impression label in 022,926, and it is to realize by printing radiation polymerization liquid on carrying that covers adhesive in surperficial individual areas or the supporting paper.Radiation treatment is an additional process for whole marble paper production process, is not practicality.
Shadbolt etc. are at patent U.S.Pat.No.4, and 177,309 disclose a kind of marble paper, and it comprises bearing paper, resin printing-ink and adhesive.Yet the wear resistance of this marble paper is limited and font color is single.
Traditional mode is made the method cost height of this marble paper, length consuming time.Owing on printing ink and supporting paper, ceaselessly carry out layer seal, so under the marble paper paper shearing that before final the use, must connect from behind.The demand of cutting equipment has also been caused the increase of cost, and when particularly the marble paper shape was very complicated, extra cost can be more.
Summary of the invention
The object of the present invention is to provide a kind of new easily stripped ceramic applique, solve the defective that prior art exists.
For achieving the above object, the present invention adopts following technical scheme:
A kind of easily stripped ceramic applique, comprise peelable supporting ground, be fixed in support ground and can with applique color layer and the transfer printing rete of supporting that ground separate, described transfer printing rete comprises that the form with clear gel is dissolved in the organic copolymer adhesive in the organic solvent system.
Preferred scheme is: described applique color layer comprises the multi layer colour printing ink layer, is copolymer material between the described ink lay.
More preferred scheme is: described peelable supporting ground comprises body paper and scribbles the coating of silicone, fluoro silicate, polyethylene kind or polypropylene film, polyester or its mixture; Described raw paper pulp is 60-300g/m
2, described coating is 0.3-5g/m
2
More preferred scheme is: the ink system of described ink lay comprises the adhesive of 20-50wt%, the solvent of 45-65wt%, and the plasticizer of 0-15wt%, (wt is a weight fraction to the release agent of 0.1-5wt%.
More preferred scheme is: described adhesive is the monomer homopolymers or the mixed copolymer of one or more low polar resins.
More preferred scheme is: described adhesive is (C3-C12)-alkyl acrylic methyl esters, or Isooctyl acrylate monomer, or acrylamide copolymer, or copolymer in cinnamic acrylic ester, or acrylic acid and methacryl polymer.
More preferred scheme is: described adhesive is 25-35wt%.
More preferred scheme is: described ink system also comprises the additive of 0.1-5wt%, and described additive is one or more in wetting agent, dispersant, froth breaking auxiliary agent or the rheological agent.
Another object of the present invention is to provide a kind of processing technology of new easily stripped ceramic applique, adopt following technical scheme:
A kind of processing technology of easily stripped ceramic applique comprises the steps:
1) the described coating of prefabricated last goal of the invention, ink system, and adhesive;
2) will be printed with expectation and decorate the marble paper of decorations sample and be arranged on the peelable support ground, the coating that application step 1 is prefabricated;
3) ink coating of the prefabricated ink system of application step 1 on coating;
4) the prefabricated peelable viscous coating of application step 1 on ink coating;
5) being needed on pottery, glass, porcelain class silicate substrate surface forms by a firing.
We discover, use pressure-sensitive adhesive can make the pattern transfer layer become easier from the process that marble paper is transferred on the decorated object; This new technology does not need the meltability ink lay and can at room temperature carry out.Using pressure-sensitive adhesive to carry out directly the decorative pattern transfer printing layer being transferred to better effects if on the decorated object in the process of transfer printing.
The surface of silicate products such as ceramic whiteware, pottery and glass is normally by applique and toast that above-mentioned " ceramic marble paper " decorate.After peeling off the picture bearing bed, directly be affixed on the ceramic body surface, spend in 1250 degree scopes Celsius 480 then and fire.In the sintering procedure, all organic compounds can all can decompose, only remaining inorganic color, and inorganic color can be with the continuous gathering and the base substrate fusion of heat.Fire after can will using the decal paper for ceramic ware of dextrin coating paper to be transferred to ceramic body surface applique by conventional method such as serigraphy.
Releasable paper is 60-300g/m by magma
2Body paper and 0.3-5g/m
2Coating form.Coating material can be silicone, fluoro silicate, polyethylene kind and polypropylene film or polyester (PET).Behind the layer of varnishing after the chromatography and by method hereinafter, the disengaging performance of this class paper can be not fully exerted and promote to some extent.
The front cover oil and the printing varnish system that are applicable to glass, porcelain and the ornamental decal paper of ceramic surface have been we have found that, comprise that content is the adhesive of 20%-50wt%, be dissolved in and contain the solvent system that weight proportion is 45-65wt%, the aromatic hydrocarbon of distillation range between 100 is spent to Celsius 200, the plasticizer of 0-15wt%, the special reagent that 0.1-5wt% is used to separate (weight proportion is between 0.1% to 1% usually, and following content can be mentioned).Gel can be realized (seeing embodiment 1--varnish) by dose the such rheological agent (thickener) of similar dehydrogenated castor oil derivative in prescription.
In order to improve the stripping performance of aforesaid propylene acid resin, need to add additive behind the solution bone dry to be filmed.The reagent that can select to be used to separate has microwax, siloxanes, adipic acid, certain herbaceous plants with big flowers two acid esters, aliphatic amide and glycols compound.In our embodiment, we have selected for use the compound of silicon as release agent in the front cover oil.The characteristic of front cover oil adhesive is to have HMW, but the molecular weight of varnish is lower.The polymer adhesive of printing-ink can be made up of one or more resins, and its character is that polarity is low.They should be dissolved in the above-mentioned solvent system.By weight calculating, this part content of adhesive is between 20%-50%, and is most of between 32% to 42%.
Adhesive is the homopolymers or the mixed copolymer of low polar monomer, for example (C3-C12)-alkyl acrylic methyl esters, for example 2-Ethylhexylacrylate Isooctyl acrylate monomer, Acylamid copolymers acrylamide copolymer, Styreneacrylate copolymers copolymer in cinnamic acrylic ester, acrylic acid and methacryl polymer etc.The adhesive that is applicable to front cover oil is the DEGALAN LP 62-05 that Evonik produces, and the adhesive that is applicable to varnish is the ELVACITE 4048 that Lucite produces.
In order to improve the extra fine quality of front cover oil and varnish, can add an amount of additive usually; On the whole, by weight calculating, the scope of application of these additives is 0.1 to 5%; The sum total weight ratio of these materials can not surpass 10% of front cover oil, the total constituent of varnish.The normal additive that uses is wetting agent and dispersant, for example castor oil derivative; Froth breaking auxiliary agent and flow promortor such as silicon compound; Auxiliary rheological agents such as deoxidation castor oil compound.
The oil plant ratio that mill base comprises be 6-9 than 10, that is to say that the parts by weight of ceramic paint (comprising painted colorant and the suitable glassy volume that helps thereof) are 100, the printing varnish parts by weight be 60-90.
The production of film forming solution and printing varnish all is by dissolve polymer adhesive in solvent system, adds additive in the hot resin solution in solvent then.In general, this process is at high temperature carried out.Behind the cool to room temperature, just can on special paper, print front cover oil with scalping by suitable silk screen red ink paste used for seals slurry.
After new marble paper system of the present invention is decorated bearing bed and can very be stripped from easily, and paper can reuse, and technology is simple, and is easy to use.
Description of drawings
Fig. 1 is a structural representation of the present invention.
The specific embodiment
Below in conjunction with the drawings and specific embodiments the present invention is described in further details:
As shown in Figure 1, easily stripped ceramic applique of the present invention comprises peelable support ground 1, ink coating 2 and peelable viscous coating 3.
Embodiment 1 varnish (Medium)
Aromatic hydrocarbon mixed solvent (Shellsol AB
1) 56.3% (weight fraction)
Dioctyl phthalate (DOP
2) 7.3%
Elvacite?4048
3 30％
BYK?088
4 0.8％
Butyllactat
5 5.5％
Thixatrol?super
6 0.1％
1, AB type, boiling spread Celsius 186 are spent to 216 degree;
2, DOP, dioctyl phthalate;
3, ELVACITE 4048/LUCITE, fundamental component acrylic resin;
4, BYK 088, dispersant, ALTANA CHEMIE;
5, Butyllactat, solvent, boiling point 188 degree Celsius;
6, THIXATROL SUPER, thickener.
Produce as embodiment 1 and 2 kind of these material, need mix and dissolve with dissolvers and stir 30 minutes, can not cool off in this process
Embodiment 2
Method by serigraphy is printed the not ink lay of color of the same race on above-mentioned bearing paper, form the pattern decorative picture of expectation.The composition of varnish is asked for an interview embodiment 1 in the printing ink.
After decorative picture finishes printing, a little strippable front cover oil of seal on bearing bed.The printing area of front cover oil is larger than the area of carrying patterned layer.Front cover oil contains following composition:
Front cover oil (Covercoat)
Aromatic hydrocarbon mixed solvent (Shellsol A
1) 60.8%
Diisononyl phthalate (DINP
2) 4.5%
Acrylic copolymer (DEGALAN LP 62-05
3) 34.0%
BYK?088
4 0.7％
1, A type, boiling spread are taken the photograph 165 and are spent to 185 degree;
2, plasticizer;
3, Degalan LP 62-05, the EVONIK of manufacturer;
4, dispersant B YK 088, ALTANA CHEMIE.
Marble paper after the oven dry can extend 17% to 23%.
Embodiment 3 mill bases
(121235 types, FERRO), blueness contains cobalt oxide and lead borosilicate toner to ceramic pigment.With after varnish among the embodiment 1 mixes, will form mill base to it.
Pigment 75.25%;
Varnish 24.75%.
The application of embodiment 4 marble papers
After the drying, manually marble paper picture part and bearing paper are peeled off, and be immersed in the mixed solution of water and ethanol (for example 5% butanediol solution) 1 minute, be affixed on the ceramic whiteware dish then, next be that 65 squeegee ceramic blade scrapes off the watermark between decal paper and plate with Shore hardness, make it become smooth seamless.
Above content be in conjunction with concrete preferred implementation to further describing that the present invention did, can not assert that concrete enforcement of the present invention is confined to these explanations.For the general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, can also make some simple deduction or replace, all should be considered as belonging to protection scope of the present invention.
Claims (9)
1. easily stripped ceramic applique, it is characterized in that: comprise peelable supporting ground, be fixed in the applique color layer that supports ground and can separate with the support ground, with the transfer printing rete, described transfer printing rete comprises that the form with clear gel is dissolved in the organic copolymer adhesive in the organic solvent system.
2. easily stripped ceramic applique as claimed in claim 1 is characterized in that: described applique color layer comprises the multi layer colour printing ink layer, is copolymer material between the described ink lay.
3. easily stripped ceramic applique as claimed in claim 1 is characterized in that: described peelable supporting ground comprises body paper and scribbles the coating of silicone, fluoro silicate, polyethylene kind or polypropylene film, polyester or its mixture; Described raw paper pulp is 60-300g/m
2, described coating is 0.3-5g/m
2
4. as the arbitrary described easily stripped ceramic applique of claim 1-3, it is characterized in that: the ink system of described ink lay comprises the adhesive of 20-50wt%, the solvent of 45-65wt%, the plasticizer of 0-15wt%, the release agent of 0.1-5wt%.
5. easily stripped ceramic applique as claimed in claim 4 is characterized in that: described adhesive is the monomer homopolymers or the mixed copolymer of one or more low polar resins.
6. easily stripped ceramic applique as claimed in claim 5, it is characterized in that: described adhesive is (C3-C12)-alkyl acrylic methyl esters, or Isooctyl acrylate monomer, or acrylamide copolymer, or copolymer in cinnamic acrylic ester, or acrylic acid and methacryl polymer.
7. easily stripped ceramic applique as claimed in claim 6 is characterized in that: described adhesive is 25-35wt%.
8. as the arbitrary described easily stripped ceramic applique of claim 5-7, it is characterized in that: described ink system also comprises the additive of 0.1-5wt%, and described additive is one or more in wetting agent, dispersant, froth breaking auxiliary agent or the rheological agent.
9. an easily stripped ceramic applique processing technology comprises the steps:
1) prefabricated coating as claimed in claim 1, prefabricated as claim 4 or 8 described ink systems, prefabricated as the arbitrary described adhesive of claim 5-7;
2) will be printed with expectation and decorate the marble paper of decorations sample and be arranged on the peelable support ground, the coating that application step 1 is prefabricated;
3) ink coating of the prefabricated ink system of application step 1 on coating;
4) the prefabricated peelable viscous coating of application step 1 on ink coating;
5) being needed on pottery, glass, porcelain class silicate substrate surface forms by a firing.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009101073687A CN101570104A (en) | 2009-05-21 | 2009-05-21 | Easily stripped ceramic applique and processing technique thereof |
| PCT/CN2009/076134 WO2010133075A1 (en) | 2009-05-21 | 2009-12-28 | Easily stripped ceramic applique and machining technique thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009101073687A CN101570104A (en) | 2009-05-21 | 2009-05-21 | Easily stripped ceramic applique and processing technique thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101570104A true CN101570104A (en) | 2009-11-04 |
Family
ID=41229635
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2009101073687A Pending CN101570104A (en) | 2009-05-21 | 2009-05-21 | Easily stripped ceramic applique and processing technique thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN101570104A (en) |
| WO (1) | WO2010133075A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101857743A (en) * | 2010-06-04 | 2010-10-13 | 深圳市永丰源实业有限公司 | Thermosetting organic coloring printing ink and stained paper for decorating silicate and metal base materials |
| WO2010133075A1 (en) * | 2009-05-21 | 2010-11-25 | 深圳市永丰源实业有限公司 | Easily stripped ceramic applique and machining technique thereof |
| CN102971056A (en) * | 2010-03-30 | 2013-03-13 | 布里克斯蒂克斯有限责任公司 | Reusable cling decals for plastic toys, building bricks, and accessories and system for customizing |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111719334A (en) * | 2020-05-11 | 2020-09-29 | 醴陵市精陶瓷业有限公司 | Electro-optic stained paper and preparation method and application thereof |
| CN113071238B (en) * | 2021-03-29 | 2022-04-29 | 潮州市华壹陶瓷花纸有限公司 | Small membrane stained paper not prone to bursting, and preparation method and application method thereof |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH1134594A (en) * | 1997-07-18 | 1999-02-09 | Sanei Chem Kk | Thermal transfer texture printing sheet and its manufacture |
| JP2000108597A (en) * | 1998-10-08 | 2000-04-18 | Tdk Corp | Printing film for thermal transfer |
| CN1433897A (en) * | 2002-01-21 | 2003-08-06 | 林·赫王·赫珲 | Dry type transprinted ceramic adhering pattern paper |
| CN101570104A (en) * | 2009-05-21 | 2009-11-04 | 深圳市永丰源实业有限公司 | Easily stripped ceramic applique and processing technique thereof |
-
2009
- 2009-05-21 CN CNA2009101073687A patent/CN101570104A/en active Pending
- 2009-12-28 WO PCT/CN2009/076134 patent/WO2010133075A1/en active Application Filing
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010133075A1 (en) * | 2009-05-21 | 2010-11-25 | 深圳市永丰源实业有限公司 | Easily stripped ceramic applique and machining technique thereof |
| CN102971056A (en) * | 2010-03-30 | 2013-03-13 | 布里克斯蒂克斯有限责任公司 | Reusable cling decals for plastic toys, building bricks, and accessories and system for customizing |
| CN101857743A (en) * | 2010-06-04 | 2010-10-13 | 深圳市永丰源实业有限公司 | Thermosetting organic coloring printing ink and stained paper for decorating silicate and metal base materials |
| CN101857743B (en) * | 2010-06-04 | 2013-01-09 | 深圳市永丰源实业有限公司 | Thermosetting organic coloring printing ink and stained paper for decorating silicate and metal base materials |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2010133075A1 (en) | 2010-11-25 |
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Application publication date: 20091104 |