CN106147262A - One turns waste into wealth Green environmental-protection building material - Google Patents
One turns waste into wealth Green environmental-protection building material Download PDFInfo
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- CN106147262A CN106147262A CN201610518074.3A CN201610518074A CN106147262A CN 106147262 A CN106147262 A CN 106147262A CN 201610518074 A CN201610518074 A CN 201610518074A CN 106147262 A CN106147262 A CN 106147262A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L97/00—Compositions of lignin-containing materials
- C08L97/02—Lignocellulosic material, e.g. wood, straw or bagasse
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/06—Biodegradable
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses one to turn waste into wealth Green environmental-protection building material, following components raw material is comprised: Plant fiber 100～150 parts according to ratio of weight and number, flour 20～30 parts, red soil 50～60 parts, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 10～12 parts, natural resin 5～15 parts, hydrogenated rosin 0.5～2.5 parts, dimethyl carbonate 0.5～3.5 parts, firming agent 3～5 parts, stabilizer 2～5 parts, dispersant 1～3 parts.The present invention turn waste into wealth Green environmental-protection building material use raw material sources extensively, be easy to get, and cost is relatively low, raw material uses degradable fiber or powder body mostly, on environment without impact, using this construction material as interior decoration, harmless, have no side effect, good product quality of the present invention, intensity are good simultaneously, low cost, easily prepares.
Description
Technical field
The present invention relates to a kind of construction material, turn waste into wealth Green environmental-protection building material particularly to one.
Background technology
Along with expanding economy, people are more and more higher to the requirement of quality of life, not only require building materials high-quality, have length
The construction material in life-span, and the feature of environmental protection of construction material is had higher requirement, the performance of building be there has also been higher wanting
Asking, along with the tail gas pollution that increases of automobile is consequently increased and the increasing of ultraviolet, pollution increases, and the environmental consciousness of people is more come
The strongest, and traditional building materials Performance comparision is single, requires weak to the feature of environmental protection of building materials.
Present a lot of construction materials in order to aspire after perfection, the purpose such as practical, light, improve joining of a lot of construction material
Side, substantial amounts of research and development or change purpose achieved by formula are equally matched to the side effect of human body or environment with it, cause
High cost, and these construction materials tend to the residue after causing use and form building waste difficult to deal with, to ring
Border brings greater impact.And, for the agricultural crop straw in rice field, discarded bagasse, wood flour etc., present processing method
It is to burn mostly, then with the ashes after burning as green manure, but this Land use systems is simpler and cruder, and, burning can increase
Toxic and harmful in air, green manure utilization rate also ratio is relatively low, therefore, needs one not only environmental protection, low cost badly but also is beneficial to construction, matter
Measure again construction material that is good and that can turn waste into wealth.
The information being disclosed in this background section is merely intended to increase the understanding of the general background to the present invention, and should not
When being considered to recognize or imply in any form this information structure prior art well known to persons skilled in the art.
Summary of the invention
It is an object of the invention to provide one to turn waste into wealth Green environmental-protection building material, thus overcome prior art medium ring
Protect the shortcoming that building material price is expensive, cost is high, construction is complicated.
For achieving the above object, the technical scheme that the present invention provides is as follows:
One turns waste into wealth Green environmental-protection building material, comprises following components raw material according to ratio of weight and number: Plant fiber
100～150 parts, flour 20～30 parts, red soil 50～60 parts, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 10～12 parts, natural resin 5～15 parts, hydrogenated rosin
0.5～2.5 part, dimethyl carbonate 0.5～3.5 parts, firming agent 3～5 parts, stabilizer 2～5 parts and dispersant 1～3 parts.
Wherein, described firming agent is for comprising following components raw material according to ratio of weight and number: Calx 20～30 parts, slag 10
～15 parts, Gypsum Fibrosum 5～10 parts, tryptophan 0.3～0.8 part and chlorogenic acid 0.1～0.35 part.
Wherein, described Plant fiber's preparation method is: taking Plant fiber, to put into cold preservation 0.5～1 in 2～4 DEG C of temperature little
Time, take out and smash and cross 100～150 mesh sieves, dry 1～2 hour, to obtain final product for 65～75 DEG C.
Wherein, described Plant fiber is bagasse, bamboo slag, straw or wood flour.
Wherein, described Enteromorpha clathrata (Roth) Grev. Emend bliding moss is that fresh lichen keeps temperature to be that 75～80 DEG C of drying obtain for 1～3 hour.
Wherein, described red soil grind into powder also crosses 180～220 mesh sieve gained.
Wherein, described stabilizer is lauryl alcohol, selenic ester polysaccharide, calcium stearate, potassium hydroxide, high glutinous carboxymethyl cellulose
One in element (HV-CMC), hydroxyethyl ether cellulose (HEC) or polyacrylamide (HPAM).
Wherein, described dispersant is polyethylene glycol 200 or PEG400.
A kind of above-mentioned Green environmental-protection building material of turning waste into wealth, its preparation method comprises following operating procedure:
(1) required each component raw material is weighed according to ratio of weight and number: Plant fiber 100～150 parts, flour 20～30
Part, red soil 50～60 parts, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 10～12 parts, natural resin 5～15 parts, hydrogenated rosin 0.5～2.5 parts, dimethyl carbonate
0.5～3.5 part, firming agent 3～5 parts, stabilizer 2～5 parts and dispersant 1～3 parts, then by flour, red soil, Enteromorpha clathrata (Roth) Grev. Emend bliding moss, steady
Determine agent, dispersant uniformly, obtain mixed powder；
(2) uniformly spray step (1) gained mixed powder after step (1) being obtained Plant fiber's tiling, obtain and slightly build
Material, compacting, uniformly send firming agent forth, to obtain final product.
Wherein, in step (2), firming agent adds water before using and makes the firming agent liquid that mass concentration is 50～68%.
Compared with prior art, there is advantages that
The present invention turn waste into wealth Green environmental-protection building material use raw material sources extensively, be easy to get, turn waste into wealth, cost is relatively
Low, raw material uses degradable fiber or powder body mostly, on environment without impact, uses this construction material as indoor dress simultaneously
Repairing, harmless, have no side effect, good product quality of the present invention, intensity are good, and low cost easily prepares.
Detailed description of the invention
It is described in detail below in conjunction with detailed description of the invention, it is to be understood that protection scope of the present invention is not by concrete
The restriction of embodiment.Natural resin in embodiment uses rosin resin.
Embodiment 1
A kind of above-mentioned Green environmental-protection building material of turning waste into wealth, its preparation method operating procedure is as follows:
(1) weigh required each component raw material according to ratio of weight and number: Plant fiber 150 parts, 30 parts of flour, pulverize
60 parts of the red soil of end excessively 220 mesh sieves, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 12 parts, rosin resin 15 parts, hydrogenated rosin 2.5 parts, dimethyl carbonate 3.5
Part, 5 parts of firming agent, stabilizer 5 parts and dispersant 3 parts, then by equal to flour, red soil, Enteromorpha clathrata (Roth) Grev. Emend bliding moss, stabilizer, dispersant
Even, obtain mixed powder；Wherein, each component raw material of firming agent: quick lime 30 parts, 15 parts of slag, 10 parts of Gypsum Fibrosum, tryptophan 0.8
Part and chlorogenic acid 0.35 part；Plant fiber's preparation method is: takes Plant fiber's bagasse and puts into cold preservation 1 hour in 2～4 DEG C of temperature,
150 mesh sieves are smashed and are crossed in taking-up, dry 1 hour, to obtain final product for 75 DEG C；Enteromorpha clathrata (Roth) Grev. Emend bliding moss is that fresh lichen keeps temperature to be that 80 DEG C of drying 1 are little
Time and obtain；Stabilizer is lauryl alcohol；Dispersant is PEG400；
(2) step (1) weighs gained firming agent add water and make the firming agent liquid that mass concentration is 50%, standby；Will
Uniformly spray step (1) gained mixed powder after the Plant fiber's tiling obtained in step (1), obtain thick construction material, with little
Type compacting of subsoil machine is compacted, and uniformly sends firming agent liquid, maintenance 28 days forth, to obtain final product.
Embodiment 2
A kind of above-mentioned Green environmental-protection building material of turning waste into wealth, its preparation method operating procedure is as follows:
(1) weigh required each component raw material according to ratio of weight and number: Plant fiber 100 parts, 20 parts of flour, pulverize
50 parts of the red soil of end excessively 180 mesh sieves, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 10 parts, rosin resin 5 parts, hydrogenated rosin 0.5 part, dimethyl carbonate 0.5 part,
3 parts of firming agent, stabilizer 2 parts and dispersant 1 part, then by flour, red soil, Enteromorpha clathrata (Roth) Grev. Emend bliding moss, stabilizer, dispersant uniformly,
Obtain mixed powder；Wherein, each component raw material of firming agent: quick lime 20 parts, 10 parts of slag, 5 parts of Gypsum Fibrosum, tryptophan 0.3 part and
Chlorogenic acid 0.1 part；Plant fiber's preparation method is: takes Plant fiber's bamboo slag and puts into cold preservation 0.5 hour in 2 DEG C of temperature, takes out and beat
Broken and cross 100 mesh sieves, 65 DEG C dry 2 hours, to obtain final product；Enteromorpha clathrata (Roth) Grev. Emend bliding moss is that fresh lichen keeps temperature to be that 75 DEG C of drying obtain for 3 hours；
Stabilizer is high glutinous carboxymethyl cellulose (HV-CMC)；Dispersant be polyethylene glycol 200 or；
(2) step (1) weighs gained firming agent add water and make the firming agent liquid that mass concentration is 68%, standby；Will
Uniformly spray step (1) gained mixed powder after the Plant fiber's tiling obtained in step (1), obtain thick construction material, with little
Type compacting of subsoil machine is compacted, and uniformly sends firming agent liquid, maintenance 28 days forth, to obtain final product.
Embodiment 3
A kind of above-mentioned Green environmental-protection building material of turning waste into wealth, its preparation method operating procedure is as follows:
(1) weigh required each component raw material according to ratio of weight and number: Plant fiber 125 parts, 25 parts of flour, pulverize
55 parts of the red soil of end excessively 200 mesh sieves, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 11 parts, rosin resin 10 parts, hydrogenated rosin 1.5 parts, dimethyl carbonate 2.0
Part, 4 parts of firming agent, stabilizer 3.5 parts and dispersant 2 parts, then by flour, red soil, Enteromorpha clathrata (Roth) Grev. Emend bliding moss, stabilizer, dispersant
Uniformly, mixed powder is obtained；Wherein, each component raw material of firming agent: quick lime 25 parts, 12 parts of slag, 8 parts of Gypsum Fibrosum, tryptophan 0.5
Part and chlorogenic acid 2.23 parts；Plant fiber's preparation method is: takes Plant fiber's straw and puts into cold preservation 1 hour in 3 DEG C of temperature, takes out
Smash and cross 125 mesh sieves, dry 1.5 hours, to obtain final product for 70 DEG C；Enteromorpha clathrata (Roth) Grev. Emend bliding moss is that fresh lichen keeps temperature to be 78 DEG C of drying 2 hours
And obtain；Stabilizer polyacrylamide (HPAM)；Dispersant is PEG400；
(2) step (1) weighs gained firming agent add water and make the firming agent liquid that mass concentration is 59%, standby；Will
Uniformly spray step (1) gained mixed powder after the Plant fiber's tiling obtained in step (1), obtain thick construction material, with little
Type compacting of subsoil machine is compacted, and uniformly sends firming agent liquid, maintenance 28 days forth, to obtain final product.
Embodiment 4
A kind of above-mentioned Green environmental-protection building material of turning waste into wealth, its preparation method operating procedure is as follows:
(1) weigh required each component raw material according to ratio of weight and number: Plant fiber 125 parts, 25 parts of flour, pulverize
55 parts of the red soil of end excessively 200 mesh sieves, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 11 parts, rosin resin 10 parts, hydrogenated rosin 1.5 parts, dimethyl carbonate 2.0
Part, 4 parts of firming agent, stabilizer 3.5 parts and dispersant 2 parts, then by flour, red soil, Enteromorpha clathrata (Roth) Grev. Emend bliding moss, stabilizer, dispersant
Uniformly, mixed powder is obtained；Wherein, each component raw material of firming agent: quick lime 25 parts, 12 parts of slag, 8 parts of Gypsum Fibrosum, tryptophan 0.5
Part, chlorogenic acid 2.23 parts and rutin 0.5 part；Plant fiber's preparation method is: takes Plant fiber's straw and puts into cold preservation in 3 DEG C of temperature
1 hour, take out and smash and cross 125 mesh sieves, dry 1.5 hours, to obtain final product for 70 DEG C；Enteromorpha clathrata (Roth) Grev. Emend bliding moss is that fresh lichen keeps temperature to be 78 DEG C
Dry 2 hours and obtain；Stabilizer polyacrylamide (HPAM)；Dispersant is PEG400；
(2) step (1) weighs gained firming agent add water and make the firming agent liquid that mass concentration is 59%, standby；Will
Uniformly spray step (1) gained mixed powder after the Plant fiber's tiling obtained in step (1), obtain thick construction material, with little
Type compacting of subsoil machine is compacted, and uniformly sends firming agent liquid, maintenance 28 days forth, to obtain final product.
Comparative example 1
Regular convention formula construction material: polyacrylonitrile carbon fiber 100 parts, 50 parts of flyash, quick lime 30 parts, wood fibre 20
Part, 20 parts of kieselguhr, magnesium oxide 10 parts, Kaolin 10 parts, Cab-O-sil 9 parts, Detitanium-ore-type titanium dioxide 5 parts, by individual component raw material
Mixing, carries out 90 DEG C of hot pressing 10～20min respectively, colds pressing 5～10min carrying out 10～15 DEG C, obtains construction material.
Test example 1 strength character is tested
1, test material and method
Use comparative example 1 gained construction material as reference examples, prepare gained with the embodiment of the present invention 3, embodiment 4
Construction material is tested jointly.
Anti-folding, comprcssive strength is tested according to GB/T 17671-1999 " strength of cement mortar detection method ".
2. test results and analysis
Table 1
| Process | 28d comprcssive strength/MPa | 28d rupture strength/MPa |
| Comparative example 1 | 42.6 | 9.7 |
| Embodiment 3 | 58.8 | 13.5 |
| Embodiment 4 | 60.0 | 14.7 |
As can be seen from the above table, embodiment 3, the gained construction material of embodiment 4, its rupture strength and comprcssive strength are the most more
Good.
Test example 2 Water Resistance Test
1. materials and methods use comparative example 1 gained construction material is as reference examples, with the embodiment of the present invention 3, reality
Execute example 4 to prepare gained construction material and jointly test.
2. construction material is immersed in tap water after 28d, wipes surface moisture, test resistance to compression, rupture strength Re, it is resistance to
Water coefficient of softing K is: K=Re/R0* 100%；
Wherein, ReIntensity index for sheet material immersion money；R0For the intensity index after sheet material immersion 28d.
3. result of the test and analysis
Table 2
| Process | Rupture strength K | Comprcssive strength K |
| Comparative example 1 | 77.9% | 66.1% |
| Embodiment 3 | 90.0% | 86.7% |
| Embodiment 4 | 93.8% | 90.9% |
As can be seen from the above table, the embodiment of the present invention 3, embodiment 4 gained construction material, the performance that it is water-fast is more preferable.By
In table 1, table 2, data understand, and embodiment 4 acquired results shows more like performance optimal, are because in embodiment 4 rutin of interpolation also
Claim rutin, there is antibiotic and sterilizing effect, but because it is contained within substantial amounts of free radical OH, in adding procedure himself structure with
And free radical can be effectively promoted the solidification of construction material, and increase its intensity, moreover it is possible to effectively strengthen its resistance to water；The present invention produces
Product construction material uses safer, environmental protection, quality good.
The aforementioned description to the specific illustrative embodiment of the present invention illustrates that and the purpose of illustration.These describe
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can much change
And change.The purpose selected exemplary embodiment and describe is to explain that the certain principles of the present invention and reality thereof should
With so that those skilled in the art be capable of and utilize the present invention various different exemplary and
Various different selections and change.The scope of the present invention is intended to be limited by claims and equivalents thereof.
Claims (10)
1. a Green environmental-protection building material of turning waste into wealth, it is characterised in that comprise following components raw material according to ratio of weight and number:
Plant fiber 100～150 parts, flour 20～30 parts, red soil 50～60 parts, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 10～12 parts, natural resin 5～15 parts,
Hydrogenated rosin 0.5～2.5 parts, dimethyl carbonate 0.5～3.5 parts, firming agent 3～5 parts, stabilizer 2～5 parts and dispersant 1～3
Part.
Green environmental-protection building material of turning waste into wealth the most according to claim 1, it is characterised in that described firming agent is for pressing
Following components raw material is comprised: Calx 20～30 parts, slag 10～15 parts, Gypsum Fibrosum 5～10 parts, tryptophan 0.3 according to ratio of weight and number
～0.8 part and chlorogenic acid 0.1～0.35 part.
Green environmental-protection building material of turning waste into wealth the most according to claim 1, it is characterised in that described Plant fiber's system
Preparation Method is: takes Plant fiber and puts in 2～4 DEG C of temperature cold preservation 0.5～1 hour, takes out and smash and cross 100～150 mesh sieves, 65
～75 DEG C dry 1～2 hour, to obtain final product.
Green environmental-protection building material of turning waste into wealth the most according to claim 3, it is characterised in that: described Plant fiber is
Bagasse, bamboo slag, straw or wood flour.
Green environmental-protection building material of turning waste into wealth the most according to claim 1, it is characterised in that: described Enteromorpha clathrata (Roth) Grev. Emend bliding moss is new
Fresh lichen keeps temperature to be that 75～80 DEG C of drying obtain for 1～3 hour.
Green environmental-protection building material of turning waste into wealth the most according to claim 1, it is characterised in that: described red soil grinds to form
Powder also crosses 180～220 mesh sieve gained.
Green environmental-protection building material of turning waste into wealth the most according to claim 1, it is characterised in that: described stabilizer is ten
Glycol, selenic ester polysaccharide, calcium stearate, potassium hydroxide, high glutinous carboxymethyl cellulose, hydroxyethyl ether cellulose or polyacrylamide
In one.
Green environmental-protection building material of turning waste into wealth the most according to claim 1, it is characterised in that: described dispersant is poly-
Ethylene glycol 200 or PEG400.
9. the preparation method of a Green environmental-protection building material of turning waste into wealth as claimed in claim 1, it is characterised in that comprise
Following operating procedure:
(1) required each component raw material is weighed according to ratio of weight and number: Plant fiber 100～150 parts, flour 20～30 parts, red
Mud 50～60 parts, Enteromorpha clathrata (Roth) Grev. Emend bliding moss 10～12 parts, natural resin 5～15 parts, hydrogenated rosin 0.5～2.5 parts, dimethyl carbonate 0.5～
3.5 parts, firming agent 3～5 parts, stabilizer 2～5 parts and dispersant 1～3 parts, then by flour, red soil, Enteromorpha clathrata (Roth) Grev. Emend bliding moss, stabilizer,
Dispersant is uniform, obtains mixed powder；
(2) uniformly spray step (1) gained mixed powder after step (1) being obtained Plant fiber's tiling, obtain thick construction material,
Compacting, uniformly sends firming agent forth, to obtain final product.
The most according to claim 9, turn waste into wealth the preparation method of Green environmental-protection building material, it is characterised in that: step (2)
Middle firming agent adds water before using and makes the firming agent liquid that mass concentration is 50～68%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610518074.3A CN106147262A (en) | 2016-07-01 | 2016-07-01 | One turns waste into wealth Green environmental-protection building material |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610518074.3A CN106147262A (en) | 2016-07-01 | 2016-07-01 | One turns waste into wealth Green environmental-protection building material |
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| CN106147262A true CN106147262A (en) | 2016-11-23 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610518074.3A Pending CN106147262A (en) | 2016-07-01 | 2016-07-01 | One turns waste into wealth Green environmental-protection building material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751992A (en) * | 2016-12-13 | 2017-05-31 | 厦门壳氏新材料科技有限公司 | A kind of string resin pre-gelatinized composite powder, and preparation method thereof, application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1240804A (en) * | 1999-07-29 | 2000-01-12 | 马召义 | Wood-plastic material |
| CN105541254A (en) * | 2015-12-31 | 2016-05-04 | 宁波高新区围海工程技术开发有限公司 | Environment-friendly curing agent for processing high-water-content sludge |
-
2016
- 2016-07-01 CN CN201610518074.3A patent/CN106147262A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1240804A (en) * | 1999-07-29 | 2000-01-12 | 马召义 | Wood-plastic material |
| CN105541254A (en) * | 2015-12-31 | 2016-05-04 | 宁波高新区围海工程技术开发有限公司 | Environment-friendly curing agent for processing high-water-content sludge |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751992A (en) * | 2016-12-13 | 2017-05-31 | 厦门壳氏新材料科技有限公司 | A kind of string resin pre-gelatinized composite powder, and preparation method thereof, application |
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Application publication date: 20161123 |