CN106147053A - A kind of efficient cable material for building and preparation method thereof - Google Patents

A kind of efficient cable material for building and preparation method thereof Download PDF

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Publication number
CN106147053A
CN106147053A CN201610530753.2A CN201610530753A CN106147053A CN 106147053 A CN106147053 A CN 106147053A CN 201610530753 A CN201610530753 A CN 201610530753A CN 106147053 A CN106147053 A CN 106147053A
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parts
stearic acid
building
cable material
rubber
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胡圣武
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Wuhu Hao Quan Construction Engineering Co Ltd
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Wuhu Hao Quan Construction Engineering Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
    • C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
    • C08L23/286—Chlorinated polyethylene
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
    • H01B3/441—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from alkenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/20—Applications use in electrical or conductive gadgets
    • C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of efficient cable material for building and preparation method thereof, including chlorinated polyethylene 30 40 parts, brucite 20 35 parts, maleic anhydride 20 35 parts, 10 15 parts of paraffin, hydrogenated nitrile-butadiene rubber 10 20 parts, compounded rubber 15 30 parts, melamine cyanurate 20 30 parts, stearic acid 12 parts, polyimide fiber 5 10 parts, Polyethylene Glycol 1 10 parts.The proportioning that the present invention uses the above-mentioned raw materials such as chlorinated polyethylene, brucite, maleic anhydride, paraffin, hydrogenated nitrile-butadiene rubber, compounded rubber, melamine cyanurate, stearic acid, polyimide fiber, modified superfine solid sulfur ash to carry out science is added in combination compatilizer, antioxidant agent, halogen-free flame retardants, plasticizer and lubricant and carries out reaction fusion, process of preparing is simple, prepared product has the most corrosion-resistant, fire protection flame retarding, insulating properties, is suitable for using at multiple fields.

Description

A kind of efficient cable material for building and preparation method thereof
Technical field
The present invention relates to composite manufacture technology field, be specifically related to a kind of efficient cable material for building and preparation thereof Method.
Background technology
Power cable is in long-term work, it is easy to accumulation heat and breaking out of fire, and fire causing death main because of Element is not the direct burning of flame, but the cigarette produced during material burning, these cigarettes not only produce substantial amounts of noxious substance, and And people can be caused to suffocate, this is only the principal element of death because of fire, and during the burning of existing most of cable material all Substantial amounts of cigarette and noxious substance can be produced, and mostly these are organic polymer, it is easy to burning, therefore encourage when fire The intensity of a fire, results in greater loss.
Electric power is the energy using electric energy as power, and the invention of electric power and application have started second time industrialization climax, from This science and technology changes the life of people.In order to ensure the Electrical Safety of people, need on the electric equipment products surface having insulating requirements Coating insulant.Insulant is used to make device at the material electrically insulated, and electric current namely can be stoped to pass through Material.Its resistivity is the highest, has good electrical insulation capability and high-temperature physical property, also has long shelf-life, moisture resistivity The feature such as good and fire-retardant.
In recent years, along with the relevant industries such as motor, electronic apparatus, automobile develop rapidly and irradiation crosslinking technological is at electricity The extensive application of line cable industry, cross-linking radiation electric wire is also in development trend faster.At present, cross-linking radiation electric wire is the most successful It is applied to motor, temperature-sensing element, high-power lamp decoration, the control of automobile low-voltage signal, all kinds of locomotive, track traffic, mineral exploration and exploitation, X The industries such as the percussion of ray high pressure and high power transmission.
Summary of the invention
For solving the problems referred to above, the invention provides a kind of efficient cable material for building and preparation method thereof.
For achieving the above object, the technical scheme that the present invention takes is:
A kind of efficient cable material for building and preparation method thereof, is prepared from including by the raw material of following weight portion: chlorination gathers Ethylene 30-40 part, brucite 20-35 part, maleic anhydride 20-35 part, paraffin 10-15 part, hydrogenated nitrile-butadiene rubber 10-20 part, multiple Close rubber 15-30 part, melamine cyanurate 20-30 part, stearic acid 1-2 part, polyimide fiber 5-10 part, Polyethylene Glycol 1-10 part, azodiisobutyronitrile 1-5 part, Stearic Acid 5-10 part, cumyl peroxide 1-10 part, carborundum 10-13 part, white carbon black 1-2 part, epoxy soybean oil 1-2 part, modified superfine solid sulfur ash 10-15 part, compatilizer 5-9 part, antioxidant agent 1-5 part, Halogen resistance Combustion agent 5-8 part, plasticizer 1-5 part and lubricant 2-6 part.
Further, described compounded rubber is polypropylene, polyethylene, epoxy resin, one or more mixing of polyurethane Thing.
Further, described compatilizer is that maleic anhydride is grafted ternary hydrogenated nitrile-butadiene rubber, and described age resistor is hindered phenol One in kind antioxidant, suffocated amine antioxidant, phosphite antioxidant, sulfur-bearing antioxidant, described halogen-free flame retardants is horse Come one or more in anhydride, aluminium hydroxide, Kaolin, calcium carbonate, Firebrake ZB, MCA, described plasticising Agent is paraffin dioctyl phthalate dioctyl ester, described lubricant be the one in stearic acid, zinc stearate, calcium stearate, barium stearate or Multiple.
Further, a kind of efficient cable material for building, it is prepared from including by the raw material of following weight portion: chlorination gathers Ethylene 32-38 part, brucite 22-30 part, maleic anhydride 22-30 part, paraffin 11-14 part, hydrogenated nitrile-butadiene rubber 11-18 part, multiple Close rubber 16-20 part, melamine cyanurate 24-28 part, stearic acid 1-2 part, polyimide fiber 6-9 part, Polyethylene Glycol 3-7 part, azodiisobutyronitrile 2-4 part, Stearic Acid 6-8 part, cumyl peroxide 3-8 part, carborundum 11-13 part, white carbon black 1-2 Part, epoxy soybean oil 1-2 part, modified superfine solid sulfur ash 11-14 part, compatilizer 6-8 part, antioxidant agent 2-4 part, halogen-free flame retardants 6-8 part, plasticizer 2-4 part and lubricant 3-5 part.
Further, the preparation method of a kind of efficient cable material for building, comprise the steps:
S1, weigh chlorinated polyethylene 32-38 part, maleic anhydride 22-30 part, paraffin 11-14 part, hydrogenated butyronitrile rubber according to weight portion Glue 11-18 part, compounded rubber 16-20 part, melamine cyanurate 24-28 part, stearic acid 1-2 part, polyimide fiber 6-9 Part, Polyethylene Glycol 3-7 part, azodiisobutyronitrile 2-4 part, Stearic Acid 6-8 part, cumyl peroxide 3-8 part, carborundum 11- 13 parts, white carbon black 1-2 part, epoxy soybean oil 1-2 part pour in ultrasonic dispersing machine, carry out ultrasound wave dispersion, obtain mixed solution A；
S2, enter the mixed solution A of step S1 gained adds brucite 20-35 part and modified superfine solid sulfur ash 11-14 part again Row ultrasound wave disperses, and obtains mixed solution B；
S3, will in the mixed solution B of step S2 gained add compatilizer 6-8 part, antioxidant agent 2-4 part, halogen-free flame retardants 6-8 Part, plasticizer 2-4 part and lubricant 3-5 part, react 15-25min at temperature is 60-80 DEG C；Then with 600-1000r/min Speed quickly stir 25-35min, obtain first product；
S4, the first product of step S3 gained is cooled down after, passed examination packs.
Further, in described step S1, ultrasonic frequency is 25～45KHz, rate of dispersion be 5500～ About 6000r/min, jitter time is 35～70min.
Further, in described step S2, ultrasonic frequency is 35～40KHz, rate of dispersion be 5100～ About 5600r/min, jitter time is 25～60min.
Further, a kind of efficient cable material for building, it is prepared from including by the raw material of following weight portion: chlorination gathers Ethylene 36 parts, brucite 27 parts, maleic anhydride 28 parts, 12 parts of paraffin, hydrogenated nitrile-butadiene rubber 16 parts, compounded rubber 17 parts, trimerization Cyanamide cyanurate 26 parts, stearic acid 2 parts, polyimide fiber 7 parts, Polyethylene Glycol 5 parts, azodiisobutyronitrile 3 parts, Stearic Acid 7 parts, cumyl peroxide 5 parts, carborundum 12 parts, white carbon black 1 part, epoxy soybean oil 1 part, modified superfine solid sulfur ash 13 parts, phase Hold agent 7 parts, antioxidant agent 3 parts, halogen-free flame retardants 7 parts, plasticizer 3 parts and lubricant 4 parts.
The present invention uses chlorinated polyethylene, brucite, maleic anhydride, paraffin, hydrogenated nitrile-butadiene rubber, compounded rubber, trimerization Cyanamide cyanurate, stearic acid, polyimide fiber, Polyethylene Glycol, azodiisobutyronitrile, Stearic Acid, cumyl peroxide, The above-mentioned raw materials such as carborundum, modified superfine solid sulfur ash carry out the proportioning of science and are added in combination compatilizer, antioxidant agent, halogen-free flameproof Agent, plasticizer and lubricant carry out reaction and merge, and process of preparing is simple, prepared product have the most corrosion-resistant, Fire protection flame retarding, insulating properties, be suitable for using at multiple fields.
Detailed description of the invention
In order to make objects and advantages of the present invention clearer, below in conjunction with embodiment, the present invention is carried out the most in detail Explanation.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The present invention includes being prepared from by the raw material of following weight portion: chlorinated polyethylene 30-40 part, brucite 20- 35 parts, maleic anhydride 20-35 part, paraffin 10-15 part, hydrogenated nitrile-butadiene rubber 10-20 part, compounded rubber 15-30 part, tripolycyanamide Cyanurate 20-30 part, stearic acid 1-2 part, polyimide fiber 5-10 part, Polyethylene Glycol 1-10 part, azodiisobutyronitrile 1-5 Part, Stearic Acid 5-10 part, cumyl peroxide 1-10 part, carborundum 10-13 part, white carbon black 1-2 part, epoxy soybean oil 1-2 part, Modified superfine solid sulfur ash 10-15 part, compatilizer 5-9 part, antioxidant agent 1-5 part, halogen-free flame retardants 5-8 part, plasticizer 1-5 part and Lubricant 2-6 part.
Described compounded rubber is polypropylene, polyethylene, epoxy resin, one or more mixture of polyurethane.
Described compatilizer be maleic anhydride be grafted ternary hydrogenated nitrile-butadiene rubber, described age resistor be Hinered phenols antioxidant, One in suffocated amine antioxidant, phosphite antioxidant, sulfur-bearing antioxidant, described halogen-free flame retardants is maleic anhydride, hydrogen One or more in aluminium oxide, Kaolin, calcium carbonate, Firebrake ZB, MCA, described plasticizer is paraffin two Formic acid dioctyl ester, described lubricant is one or more in stearic acid, zinc stearate, calcium stearate, barium stearate.
A kind of efficient cable material for building, is prepared from including by the raw material of following weight portion: chlorinated polyethylene 32-38 Part, brucite 22-30 part, maleic anhydride 22-30 part, paraffin 11-14 part, hydrogenated nitrile-butadiene rubber 11-18 part, compounded rubber 16- 20 parts, melamine cyanurate 24-28 part, stearic acid 1-2 part, polyimide fiber 6-9 part, Polyethylene Glycol 3-7 part, azo Bis-isobutyronitrile 2-4 part, Stearic Acid 6-8 part, cumyl peroxide 3-8 part, carborundum 11-13 part, white carbon black 1-2 part, epoxy are big Oleum Glycines 1-2 part, modified superfine solid sulfur ash 11-14 part, compatilizer 6-8 part, antioxidant agent 2-4 part, halogen-free flame retardants 6-8 part, increasing Mould agent 2-4 part and lubricant 3-5 part.
The preparation method of a kind of efficient cable material for building, comprises the steps:
S1, weigh chlorinated polyethylene 32-38 part, maleic anhydride 22-30 part, paraffin 11-14 part, hydrogenated butyronitrile rubber according to weight portion Glue 11-18 part, compounded rubber 16-20 part, melamine cyanurate 24-28 part, stearic acid 1-2 part, polyimide fiber 6-9 Part, Polyethylene Glycol 3-7 part, azodiisobutyronitrile 2-4 part, Stearic Acid 6-8 part, cumyl peroxide 3-8 part, carborundum 11- 13 parts, white carbon black 1-2 part, epoxy soybean oil 1-2 part pour in ultrasonic dispersing machine, carry out ultrasound wave dispersion, obtain mixed solution A；
S2, enter the mixed solution A of step S1 gained adds brucite 20-35 part and modified superfine solid sulfur ash 11-14 part again Row ultrasound wave disperses, and obtains mixed solution B；
S3, will in the mixed solution B of step S2 gained add compatilizer 6-8 part, antioxidant agent 2-4 part, halogen-free flame retardants 6-8 Part, plasticizer 2-4 part and lubricant 3-5 part, react 15-25min at temperature is 60-80 DEG C；Then with 600-1000r/min Speed quickly stir 25-35min, obtain first product；
S4, the first product of step S3 gained is cooled down after, passed examination packs.
In described step S1, ultrasonic frequency is 25～45KHz, and rate of dispersion is 5500～6000r/min left sides The right side, jitter time is 35～70min.
In described step S2, ultrasonic frequency is 35～40KHz, and rate of dispersion is 5100～5600r/min left sides The right side, jitter time is 25～60min.
Embodiment 1:
S1, weigh chlorinated polyethylene 36 parts, maleic anhydride 28 parts, 12 parts of paraffin, hydrogenated nitrile-butadiene rubber 16 parts, multiple according to weight portion Close rubber 17 parts, melamine cyanurate 26 parts, stearic acid 2 parts, polyimide fiber 7 parts, Polyethylene Glycol 5 parts, azo two Isopropyl cyanide 3 parts, Stearic Acid 7 parts, cumyl peroxide 5 parts, carborundum 12 parts, white carbon black 1 part, epoxy soybean oil 1 part are poured into super In sound wave dispersion machine, carry out ultrasound wave dispersion, obtain mixed solution A；
S2, carry out ultrasonic again by the mixed solution A of step S1 gained adds brucite 27 parts and modified superfine solid sulfur ash 13 parts Wavelength-division dissipates, and obtains mixed solution B；
S3, will in the mixed solution B of step S2 gained add compatilizer 7 parts, antioxidant agent 3 parts, halogen-free flame retardants 7 parts, plasticising Agent 3 parts and lubricant 4 parts, react 18min at temperature is 70 DEG C；Then 29min is quickly stirred with the speed of 800r/min, To first product；
S4, the first product of step S3 gained is cooled down after, passed examination packs.
In described step S1, ultrasonic frequency is 28KHz, and rate of dispersion is about 5800r/min, and jitter time is 55min。
In described step S2, ultrasonic frequency is 38KHz, and rate of dispersion is about 5400r/min, and jitter time is 45min。
Embodiment 2:
S1, weigh chlorinated polyethylene 38 parts, maleic anhydride 30 parts, 14 parts of paraffin, hydrogenated nitrile-butadiene rubber 18 parts, multiple according to weight portion Close rubber 20 parts, melamine cyanurate 28 parts, stearic acid 2 parts, polyimide fiber 9 parts, Polyethylene Glycol 7 parts, azo two Isopropyl cyanide 4 parts, Stearic Acid 8 parts, cumyl peroxide 8 parts, carborundum 13 parts, white carbon black 2 parts, epoxy soybean oil 2 parts are poured into super In sound wave dispersion machine, carry out ultrasound wave dispersion, obtain mixed solution A；
S2, carry out ultrasonic again by the mixed solution A of step S1 gained adds brucite 35 parts and modified superfine solid sulfur ash 14 parts Wavelength-division dissipates, and obtains mixed solution B；
S3, will in the mixed solution B of step S2 gained add compatilizer 8 parts, antioxidant agent 4 parts, halogen-free flame retardants 8 parts, plasticising Agent 4 parts and lubricant 5 parts, react 25min at temperature is 80 DEG C；Then 35min is quickly stirred with the speed of 1000r/min, Obtain first product；
S4, the first product of step S3 gained is cooled down after, passed examination packs.
In described step S1, ultrasonic frequency is 45KHz, and rate of dispersion is about 6000r/min, and jitter time is 70min。
In described step S2, ultrasonic frequency is 40KHz, and rate of dispersion is about 5600r/min, and jitter time is 60min。
Embodiment 3:
S1, weigh chlorinated polyethylene 32 parts, maleic anhydride 22 parts, 11 parts of paraffin, hydrogenated nitrile-butadiene rubber 11 parts, multiple according to weight portion Close rubber 16 parts, melamine cyanurate 24 parts, stearic acid 1 part, polyimide fiber 6 parts, Polyethylene Glycol 3 parts, azo two Isopropyl cyanide 2 parts, Stearic Acid 6 parts, cumyl peroxide 3 parts, carborundum 11 parts, white carbon black 1 part, epoxy soybean oil 1 part are poured into super In sound wave dispersion machine, carry out ultrasound wave dispersion, obtain mixed solution A；
S2, carry out ultrasonic again by the mixed solution A of step S1 gained adds brucite 20 parts and modified superfine solid sulfur ash 11 parts Wavelength-division dissipates, and obtains mixed solution B；
S3, will in the mixed solution B of step S2 gained add compatilizer 6 parts, antioxidant agent 2 parts, halogen-free flame retardants 6 parts, plasticising Agent 2 parts and lubricant 3 parts, react 15min at temperature is 60 DEG C；Then quickly stir with the speed of 600-1000r/min 25min, obtains first product；
S4, the first product of step S3 gained is cooled down after, passed examination packs.
In described step S1, ultrasonic frequency is 25 KHz, and rate of dispersion is about 5500 r/min, and jitter time is 35min。
In described step S2, ultrasonic frequency is 35 KHz, and rate of dispersion is about 5100 r/min, and jitter time is 25min。
The present invention uses chlorinated polyethylene, brucite, maleic anhydride, paraffin, hydrogenated nitrile-butadiene rubber, compounded rubber, trimerization Cyanamide cyanurate, stearic acid, polyimide fiber, Polyethylene Glycol, azodiisobutyronitrile, Stearic Acid, cumyl peroxide, The above-mentioned raw materials such as carborundum, modified superfine solid sulfur ash carry out the proportioning of science and are added in combination compatilizer, antioxidant agent, halogen-free flameproof Agent, plasticizer and lubricant carry out reaction and merge, and process of preparing is simple, prepared product have the most corrosion-resistant, Fire protection flame retarding, insulating properties, be suitable for using at multiple fields.
The above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For Yuan, under the premise without departing from the principles of the invention, it is also possible to make some improvements and modifications, these improvements and modifications also should It is considered as protection scope of the present invention.

Claims (8)

1. an efficient cable material for building, it is characterised in that include being prepared from by the raw material of following weight portion: chlorination gathers Ethylene 30-40 part, brucite 20-35 part, maleic anhydride 20-35 part, paraffin 10-15 part, hydrogenated nitrile-butadiene rubber 10-20 part, multiple Close rubber 15-30 part, melamine cyanurate 20-30 part, stearic acid 1-2 part, polyimide fiber 5-10 part, Polyethylene Glycol 1-10 part, azodiisobutyronitrile 1-5 part, Stearic Acid 5-10 part, cumyl peroxide 1-10 part, carborundum 10-13 part, white carbon black 1-2 part, epoxy soybean oil 1-2 part, modified superfine solid sulfur ash 10-15 part, compatilizer 5-9 part, antioxidant agent 1-5 part, Halogen resistance Combustion agent 5-8 part, plasticizer 1-5 part and lubricant 2-6 part.
The efficient cable material for building of one the most according to claim 1, it is characterised in that described compounded rubber is poly-third One or more mixture in alkene, polyethylene, epoxy resin, polyurethane.
The efficient cable material for building of one the most according to claim 1, it is characterised in that described compatilizer is maleic acid Acid anhydride grafting ternary hydrogenated nitrile-butadiene rubber, described age resistor is Hinered phenols antioxidant, suffocated amine antioxidant, phosphite ester antioxygen One in agent, sulfur-bearing antioxidant, described halogen-free flame retardants be maleic anhydride, aluminium hydroxide, Kaolin, calcium carbonate, Firebrake ZB, One or more in MCA, described plasticizer is paraffin dioctyl phthalate dioctyl ester, and described lubricant is stearic One or more in acid, zinc stearate, calcium stearate, barium stearate.
The efficient cable material for building of one the most according to claim 1, it is characterised in that include by following weight portion Raw material is prepared from: chlorinated polyethylene 32-38 part, brucite 22-30 part, maleic anhydride 22-30 part, paraffin 11-14 part, hydrogenation Nitrile rubber 11-18 part, compounded rubber 16-20 part, melamine cyanurate 24-28 part, stearic acid 1-2 part, polyimides Fiber 6-9 part, Polyethylene Glycol 3-7 part, azodiisobutyronitrile 2-4 part, Stearic Acid 6-8 part, cumyl peroxide 3-8 part, carbon SiClx 11-13 part, white carbon black 1-2 part, epoxy soybean oil 1-2 part, modified superfine solid sulfur ash 11-14 part, compatilizer 6-8 part, antioxygen Agent agent 2-4 part, halogen-free flame retardants 6-8 part, plasticizer 2-4 part and lubricant 3-5 part.
5. according to the preparation method of a kind of efficient cable material for building described in claim 1 or 4, it is characterised in that include Following steps:
S1, weigh chlorinated polyethylene 32-38 part, maleic anhydride 22-30 part, paraffin 11-14 part, hydrogenated butyronitrile rubber according to weight portion Glue 11-18 part, compounded rubber 16-20 part, melamine cyanurate 24-28 part, stearic acid 1-2 part, polyimide fiber 6-9 Part, Polyethylene Glycol 3-7 part, azodiisobutyronitrile 2-4 part, Stearic Acid 6-8 part, cumyl peroxide 3-8 part, carborundum 11- 13 parts, white carbon black 1-2 part, epoxy soybean oil 1-2 part pour in ultrasonic dispersing machine, carry out ultrasound wave dispersion, obtain mixed solution A；
S2, enter the mixed solution A of step S1 gained adds brucite 20-35 part and modified superfine solid sulfur ash 11-14 part again Row ultrasound wave disperses, and obtains mixed solution B；
S3, will in the mixed solution B of step S2 gained add compatilizer 6-8 part, antioxidant agent 2-4 part, halogen-free flame retardants 6-8 Part, plasticizer 2-4 part and lubricant 3-5 part, react 15-25min at temperature is 60-80 DEG C；Then with 600-1000r/min Speed quickly stir 25-35min, obtain first product；
S4, the first product of step S3 gained is cooled down after, passed examination packs.
The preparation method of a kind of efficient cable material for building the most according to claim 5, it is characterised in that described step In S1, ultrasonic frequency is 25～45KHz, and rate of dispersion is 5500～about 6000r/min, jitter time be 35～ 70min。
The preparation method of a kind of efficient cable material for building the most according to claim 5, it is characterised in that described step In S2, ultrasonic frequency is 35～40KHz, and rate of dispersion is 5100～about 5600r/min, jitter time be 25～ 60min。
The efficient cable material for building of one the most according to claim 1, it is characterised in that include by following weight portion Raw material is prepared from: chlorinated polyethylene 36 parts, brucite 27 parts, maleic anhydride 28 parts, 12 parts of paraffin, hydrogenated nitrile-butadiene rubber 16 Part, compounded rubber 17 parts, melamine cyanurate 26 parts, stearic acid 2 parts, polyimide fiber 7 parts, Polyethylene Glycol 5 parts, idol Nitrogen bis-isobutyronitrile 3 parts, Stearic Acid 7 parts, cumyl peroxide 5 parts, carborundum 12 parts, white carbon black 1 part, epoxy soybean oil 1 part, change Property ultra-fine solid sulfur ash 13 parts, compatilizer 7 parts, antioxidant agent 3 parts, halogen-free flame retardants 7 parts, plasticizer 3 parts and lubricant 4 parts.
CN201610530753.2A 2016-07-07 2016-07-07 A kind of efficient cable material for building and preparation method thereof Pending CN106147053A (en)

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CN106832621A (en) * 2016-12-30 2017-06-13 安徽远征电缆科技有限公司 A kind of cable fire proofing

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CN105367858A (en) * 2015-06-09 2016-03-02 国网山东省电力公司临沂供电公司 Insulating material for transmission line

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106832621A (en) * 2016-12-30 2017-06-13 安徽远征电缆科技有限公司 A kind of cable fire proofing

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