CN106135238A - 一种含藻酸丙二醇酯和环氧虫啶的农药组合物 - Google Patents
一种含藻酸丙二醇酯和环氧虫啶的农药组合物 Download PDFInfo
- Publication number
- CN106135238A CN106135238A CN201610574290.XA CN201610574290A CN106135238A CN 106135238 A CN106135238 A CN 106135238A CN 201610574290 A CN201610574290 A CN 201610574290A CN 106135238 A CN106135238 A CN 106135238A
- Authority
- CN
- China
- Prior art keywords
- cycloxaprid
- propylene glycol
- glycol alginate
- composition pesticide
- pesticide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- HDSBZMRLPLPFLQ-UHFFFAOYSA-N Propylene glycol alginate Chemical compound OC1C(O)C(OC)OC(C(O)=O)C1OC1C(O)C(O)C(C)C(C(=O)OCC(C)O)O1 HDSBZMRLPLPFLQ-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 239000000770 propane-1,2-diol alginate Substances 0.000 title claims abstract description 21
- 235000010409 propane-1,2-diol alginate Nutrition 0.000 title claims abstract description 21
- NDHXMRFNYMNBKO-PWSUYJOCSA-N chembl2227757 Chemical compound [O-][N+](=O)C([C@H]1CC[C@H](O1)N1CC2)=C1N2CC1=CC=C(Cl)N=C1 NDHXMRFNYMNBKO-PWSUYJOCSA-N 0.000 title claims abstract description 20
- 239000000575 pesticide Substances 0.000 title claims abstract description 12
- 235000007164 Oryza sativa Nutrition 0.000 claims description 11
- 235000009566 rice Nutrition 0.000 claims description 11
- 238000002360 preparation method Methods 0.000 claims description 4
- 239000002552 dosage form Substances 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 230000000361 pesticidal effect Effects 0.000 claims 1
- 230000003449 preventive effect Effects 0.000 abstract description 5
- 241000488581 Panonychus citri Species 0.000 abstract 1
- 241000209094 Oryza Species 0.000 description 10
- 241000238631 Hexapoda Species 0.000 description 9
- 241001498622 Cixius wagneri Species 0.000 description 6
- 239000003814 drug Substances 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000004563 wettable powder Substances 0.000 description 4
- 239000005995 Aluminium silicate Substances 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- LCRMGUFGEDUSOG-UHFFFAOYSA-N naphthalen-1-ylsulfonyloxymethyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(OCOS(=O)(=O)C=3C4=CC=CC=C4C=CC=3)=O)=CC=CC2=C1 LCRMGUFGEDUSOG-UHFFFAOYSA-N 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 241001124076 Aphididae Species 0.000 description 2
- 241001556089 Nilaparvata lugens Species 0.000 description 2
- 241000819999 Nymphes Species 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 230000004060 metabolic process Effects 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- WCXDHFDTOYPNIE-RIYZIHGNSA-N (E)-acetamiprid Chemical compound N#C/N=C(\C)N(C)CC1=CC=C(Cl)N=C1 WCXDHFDTOYPNIE-RIYZIHGNSA-N 0.000 description 1
- NWWZPOKUUAIXIW-DHZHZOJOSA-N (E)-thiamethoxam Chemical compound [O-][N+](=O)/N=C/1N(C)COCN\1CC1=CN=C(Cl)S1 NWWZPOKUUAIXIW-DHZHZOJOSA-N 0.000 description 1
- MTXSIJUGVMTTMU-JTQLQIEISA-N (S)-anabasine Chemical compound N1CCCC[C@H]1C1=CC=CN=C1 MTXSIJUGVMTTMU-JTQLQIEISA-N 0.000 description 1
- 239000005875 Acetamiprid Substances 0.000 description 1
- 206010002091 Anaesthesia Diseases 0.000 description 1
- 206010003497 Asphyxia Diseases 0.000 description 1
- 241001182720 Cacopsylla pyrisuga Species 0.000 description 1
- 241001414720 Cicadellidae Species 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000738498 Epitrix pubescens Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000255967 Helicoverpa zea Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241001477931 Mythimna unipuncta Species 0.000 description 1
- 241000488583 Panonychus ulmi Species 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 241000985245 Spodoptera litura Species 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 241000018137 Trialeurodes vaporariorum Species 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 239000000783 alginic acid Substances 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 229960001126 alginic acid Drugs 0.000 description 1
- 150000004781 alginic acids Chemical class 0.000 description 1
- 229930014345 anabasine Natural products 0.000 description 1
- 230000037005 anaesthesia Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- -1 diol ester Chemical class 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000012417 linear regression Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 210000000582 semen Anatomy 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了藻酸丙二醇酯和环氧虫啶的农药组合物，其中，藻酸丙二醇酯和环氧虫啶的重量比为1:30‑30：1，本发明的组后防治柑橘红蜘蛛有优异的防效，减少了农药用药量，降低了农药在作物上残留，对作物安全，值得推广应用。
Description
技术领域
本发明属于农药制剂领域，具体涉及的是一种含藻酸丙二醇酯和环氧虫啶的农药组合物及其应用。
背景技术
藻酸丙二醇酯是一种常用的食品添加剂，对人畜和环境都无害，且其在也上可以作为一种物理作用机理的生物杀虫药物，作用方式为触杀，以其特有的粘性和物理触杀性，快速封闭和堵塞害虫用于呼吸代谢的气孔，阻断害虫的代谢和循环通道，使其窒息死亡，能够有效的防治白粉虱、红蜘蛛、梨木虱、茶小绿叶蝉、蚜虫和稻飞虱等农业上较难防治的害虫。
环氧虫啶为一种新型新烟碱类杀虫剂，由华东理工大学创制，化学名称:9-(6-氯吡啶-3-基)甲基)-4-硝基-8-氧杂-10，11-二氢咪唑并(2，3-a)双环(3，2，I)辛-3-烯，英文通用名:cycloxaprid,化学分子式C14H15C1N403。对害虫有内吸、胃毒和触杀作用，可用于防治农作物上的同翅目、鞘翅目害虫，与吡虫啉、啶虫脒、噻虫嗪等无交互抗性，对鳞翅目害虫也有效。本品使用剂量低，对环境安全，对有益生物无危害或危害极小。对小麦、棉花、水稻、果树、蔬菜等作物的蚜虫、飞虱、粉虱、跳甲、棉铃虫、小菜蛾、斜纹夜蛾、黏虫等有较高的杀虫活性。
本发明的发明人经过大量的试验，意外的发现将藻酸丙二醇酯和环氧虫啶混配后，对水稻稻飞虱具有明显的增效作用，可以降低使用成本，减少对环境的污染，同时，所述的组合物对作物安全性也较高。
发明内容
本发明的目的在于提供一种具有协同增效作用、使用成本低、防效好的含藻酸丙二醇酯的高效杀虫组合物。
为达到上述目的，本发明采用如下技术方案：一种含藻酸丙二醇酯和环氧虫啶的农药组合物，其中，藻酸丙二醇酯和环氧虫啶的重量比为1:30-30：1，优选为1:10-10:1。
进一步的，所述藻酸丙二醇酯和环氧虫啶占组合物重量比为10-70%，优选为20-50%。
进一步的，所述组合物可以辅以农药制剂加工中常规的助剂加工成为任意一种剂型，所述的剂型可以选择可湿性粉剂、水分散粒剂、水乳剂、悬浮剂、微乳剂、干悬浮剂、可分散油悬浮剂。
进一步的，所述组合物用于防治多种农业上的害虫，尤其是水稻稻飞虱。
本发明的组合物的施用频率和使用量随农作物、害虫、天气情况变化而又小量变化，可以通过使用适当的剂量达到有效防治的目的。
与现有技术相比，本发明的有益效果在于：与单剂相比，所述组合物之间具有明显的增效作用，提高了防治效果；所述的组合物活性成分具有双重作用机理，有利于延缓害虫抗药性的产生；本发明的组合物对作物安全、持效性和速效性均优良。
具体实施方式
为了使本发明的目的、技术方案和优点更加明确，下面结合实施例对本发明进行详细说明。
一、制剂实施例
实施例1：21%藻酸丙二醇酯·环氧虫啶可湿性粉剂（1:20）
藻酸丙二醇酯 1%
环氧虫啶 20%
亚甲基双萘磺酸钠 5%
木质素磺酸钠 4%
十二烷基硫酸钠 3%
白炭黑 5%
高岭土 余量
实施例2: 20%藻酸丙二醇酯·环氧虫啶可湿性粉剂（1:1）
藻酸丙二醇酯 10%
环氧虫啶 10%
亚甲基双萘磺酸钠 5%
木质素磺酸钠 4%
十二烷基硫酸钠 3%
白炭黑 5%
高岭土 余量
实施例3:15%藻酸丙二醇酯·环氧虫啶可湿性粉剂（3:2）
藻酸丙二醇酯 9%
环氧虫啶 6%
亚甲基双萘磺酸钠 4%
木质素磺酸钠 4%
十二烷基硫酸钠 2%
白炭黑 4%
高岭土 余量
二、室内毒力测定
为了防治农业生产上的水稻稻飞虱，发明人以藻酸丙二醇酯和环氧虫啶进行了相互复配的增效研究，试验采用稻褐飞虱为测试对象，试验方法参考《中华人民共和国农业行业标准NY/T1154.7-2006》，具体方法为：首先将藻酸丙二醇酯和环氧虫丁设置不同的浓度梯度（在预试试验的基础上，稻褐飞虱死亡率在5-90%的范围内按差级数设定）。试虫为采自田间的褐飞虱卵，温室内用水稻苗饲养3代，挑选均匀一致的3龄若虫，在直径12cm的培养皿中置放水稻幼苗，每皿接麻醉若虫30头，每处理设置4个重复，用potter 喷雾塔在50PSI压力下喷雾，每次喷一个皿，每皿喷药液3mL，待虫子苏醒后，将处理过的培养皿放入12H/12H光照培养箱内培养，72小时检查死虫数，计算死亡率。通过死亡率的机率值和系列浓度的对数值之间的线性回归分析，求出各药剂的LC50值，用孙云沛法计算混剂的共毒系数（CTC），以此来评价供试药剂对试虫的活性，试验结果见表1。
室内毒力试验结果表明，藻酸丙二醇酯在1:30-30:1的范围内，对稻飞虱的防效均表现出协同增效作用，尤其在1:10-10:1的范围内，共毒系数均大于150，协同增效作用更为突出。
三、田间药效试验
为了更好的验证本发明的组合物的实际应用效果，采用本发明的制剂实施例的制剂，做水稻稻飞虱田间药效试验，验证了本发明的药剂对稻飞虱的防治效果、有效剂量及对水稻的安全性，分别于药前、药后3天、7天各进行以此虫口数调查，采用平衡跳跃式随机取样，每小区10点、每点2丛，用盆拍法记录稻飞虱活虫数，并计算防效。试验结果见表2。
田间药效试验结果表明，藻酸丙二醇酯和环氧虫啶复配后对水稻稻飞虱具有很好的防效，明显高于单个活性成分制剂的防效，且在用药范围内，未发现药害产生，表明所述的组合物对水稻安全性也较好，值得推广应用。
Claims (4)
1.一种农药组合物，其特征在于，活性成分包含藻酸丙二醇酯和环氧虫啶。
2.根据权利要求1所述的农药组合物，其特征在于，所述组合物的重量比为1:30-30:1，优选为1:10-10:1。
3.根据权利要求1或2的农药组合物，其特征在于，所述组合物可以加工成农药制剂加工中任意一种剂型。
4.权利要求1-3中任一项权利要求所述的农药组合物用于防治水稻稻飞虱的用途。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610574290.XA CN106135238B (zh) | 2016-07-21 | 2016-07-21 | 一种含藻酸丙二醇酯和环氧虫啶的农药组合物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610574290.XA CN106135238B (zh) | 2016-07-21 | 2016-07-21 | 一种含藻酸丙二醇酯和环氧虫啶的农药组合物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN106135238A true CN106135238A (zh) | 2016-11-23 |
| CN106135238B CN106135238B (zh) | 2018-08-03 |
Family
ID=58059208
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610574290.XA Active CN106135238B (zh) | 2016-07-21 | 2016-07-21 | 一种含藻酸丙二醇酯和环氧虫啶的农药组合物 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106135238B (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113729028A (zh) * | 2021-08-19 | 2021-12-03 | 广西壮族自治区农业科学院 | 一种防治甘蔗蓟马的杀虫剂 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101926367A (zh) * | 2008-12-31 | 2010-12-29 | 浙江世佳科技有限公司 | 含藻酸丙二醇酯的杀虫组合物 |
| CN103563901A (zh) * | 2012-07-20 | 2014-02-12 | 陕西美邦农药有限公司 | 一种含藻酸丙二醇酯的高效杀虫组合物 |
| CN103563963A (zh) * | 2012-07-24 | 2014-02-12 | 陕西美邦农药有限公司 | 一种含藻酸丙二醇酯的杀虫组合物 |
-
2016
- 2016-07-21 CN CN201610574290.XA patent/CN106135238B/zh active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101926367A (zh) * | 2008-12-31 | 2010-12-29 | 浙江世佳科技有限公司 | 含藻酸丙二醇酯的杀虫组合物 |
| CN103563901A (zh) * | 2012-07-20 | 2014-02-12 | 陕西美邦农药有限公司 | 一种含藻酸丙二醇酯的高效杀虫组合物 |
| CN103563963A (zh) * | 2012-07-24 | 2014-02-12 | 陕西美邦农药有限公司 | 一种含藻酸丙二醇酯的杀虫组合物 |
Non-Patent Citations (1)
| Title |
|---|
| 刘宝生 等: "新药剂环氧虫啶对稻飞虱的杀虫活性和田间效果", 《西南农业学报》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113729028A (zh) * | 2021-08-19 | 2021-12-03 | 广西壮族自治区农业科学院 | 一种防治甘蔗蓟马的杀虫剂 |
| CN113729028B (zh) * | 2021-08-19 | 2023-03-14 | 广西壮族自治区农业科学院 | 一种防治甘蔗蓟马的杀虫剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| CN106135238B (zh) | 2018-08-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104322558A (zh) | 杀菌组合物及其应用 | |
| CN1327770C (zh) | 一种含有多抗霉素·多菌灵的杀菌组合物 | |
| CN104522054A (zh) | 一种生物源增效复配杀虫剂、制备方法及其应用 | |
| CN104824008A (zh) | 含噻螨酮和氟虫脲的农药组合物 | |
| CN105707118B (zh) | 一种含有亚胺硫磷和联苯肼酯的农药组合物 | |
| CN108812707B (zh) | 一种杀蓟马植物精油组合物、制剂及其应用 | |
| CN103636621A (zh) | 含有乙螨唑和印楝素的农药组合物 | |
| CN103858920A (zh) | 一种含有乙基多杀菌素的杀虫组合物 | |
| CN106135238B (zh) | 一种含藻酸丙二醇酯和环氧虫啶的农药组合物 | |
| CN102239891B (zh) | 一种含楝素的植物源增效复配杀虫剂及其制备方法 | |
| CN105454242B (zh) | 一种含有腈吡螨酯的农药组合物及其用途 | |
| CN101653129A (zh) | 农药组合物 | |
| CN106212494A (zh) | 一种含藻酸丙二醇酯和吡虫啉的农药组合物 | |
| CN103875700A (zh) | 一种杀虫组合物及在刺吸式口器害虫防治上的用途 | |
| CN115299446B (zh) | 一种含虫螨腈的纳米悬浮剂组合物 | |
| CN109329293A (zh) | 一种含有丁虫腈和苦参碱的杀虫杀螨组合物 | |
| CN105104402B (zh) | 杀虫杀螨组合物及其应用 | |
| CN115281199B (zh) | 一种用于防治菠菜小菜蛾的杀虫组合物 | |
| CN115281205B (zh) | 一种用于防治桃树桃小食心虫的杀虫组合物 | |
| CN109122692B (zh) | 一种具有协同增效作用的杀虫杀螨农药组合物 | |
| CN106212463A (zh) | 一种含藻酸丙二醇酯和甲氧虫酰肼的农药组合物 | |
| CN106106465A (zh) | 一种含藻酸丙二醇酯和乙螨唑的农药组合物 | |
| CN106135206B (zh) | 一种含藻酸丙二醇酯和炔螨特的农药组合物 | |
| CN101185435A (zh) | 一种含有丁醚脲有效成分的杀螨剂组合物及其应用 | |
| CN105248434A (zh) | 杀虫杀螨组合物及其应用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20180625 Address after: 312030 Lanting Pavilion Industrial Park, Keqiao District, Shaoxing, Zhejiang Applicant after: Shaoxing Keqiao Jiemeida Textile Co.,Ltd. Address before: 528000 2 Chancheng Zhi Bo Li Hai garden, Ji Hua three road, Chancheng District, Foshan, Guangdong Applicant before: Li Xiangying |
|
| TA01 | Transfer of patent application right | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191119 Address after: Room 04, shop 13C, No. 376, Zhenghe Middle Road, Chengxiang Town, Taicang City, Suzhou City, Jiangsu Province Patentee after: Taicang Shijiqiao industrial and Commercial Office Address before: 312030 Lanting Pavilion Industrial Park, Keqiao District, Shaoxing, Zhejiang Patentee before: Shaoxing Keqiao Jiemeida Textile Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240605 Address after: 226400 No. 26, Haibin 4th Road, Yangkou chemical industry park, Rudong Coastal Economic Development Zone, Nantong City, Jiangsu Province Patentee after: Nantong YABEN Chemical Co.,Ltd. Country or region after: China Address before: 215400 room 04, shop 13C, 376 Zhenghe Middle Road, Chengxiang Town, Taicang City, Suzhou City, Jiangsu Province Patentee before: Taicang Shijiqiao industrial and Commercial Office Country or region before: China |
|
| TR01 | Transfer of patent right |